Crystallography Open Database

Information card for entry 4308868

Preview

Coordinates	4308868.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C40 H54 F6 N2 O6 Os
Calculated formula	C40 H54 F6 N2 O6 Os
Title of publication	Chiral Osmium Complexes with Sterically Bulky Schiff-Base Ligands. Crystal Structures of Os(IV) Derivatives and the Reactivity and Catalytic Cyclopropanation of Alkenes with EDA
Authors of publication	Jing Zhang; Jiang-Lin Liang; Xian-Ru Sun; Hai-Bing Zhou; Nian-Yong Zhu; Zhong-Yuan Zhou; Philip Wai Hong Chan; Chi-Ming Che
Journal of publication	Inorganic Chemistry
Year of publication	2005
Journal volume	44
Pages of publication	3942 - 3954
a	12.681 ± 0.003 Å
b	14.074 ± 0.003 Å
c	14.727 ± 0.003 Å
α	67.19 ± 0.03°
β	72.51 ± 0.03°
γ	85.65 ± 0.03°
Cell volume	2308.3 ± 1.1 Å³
Cell temperature	293 ± 2 K
Ambient diffraction temperature	293 ± 2 K
Number of distinct elements	6
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.0638
Residual factor for significantly intense reflections	0.0441
Weighted residual factors for significantly intense reflections	0.111
Weighted residual factors for all reflections included in the refinement	0.1326
Goodness-of-fit parameter for all reflections included in the refinement	0.995
Diffraction radiation wavelength	0.71069 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
179126 (current)	2016-03-23	cif/4/30/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/30/88.	4308868.cif
120081	2014-07-12	Adding DOIs to range 4/30 structures.	4308868.cif
34330	2012-02-24	cif/4/ Reorganising CIF range 4 into a prefix tree.	4308868.cif
1526	2010-09-26	cif/4/ Adding new CIFs from Inorg. Chem. 2005 deposited via Web deposition site to the COD test database (and transferede to the main COD database after renaming).	4308868.cif