Crystallography Open Database

Information card for entry 4325977

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Structure parameters

Formula	C25 H28 Fe2 Mn O3 P
Calculated formula	C25 H28 Fe2 Mn O3 P
Title of publication	Heterometallic Derivatives of [Fe2Cp2(μ-PCy)(μ-CO)(CO)2]: Rational Synthesis of Polynuclear Complexes from Neutral Precursors Having Pyramidal-Phosphinidene Bridges
Authors of publication	M. Angeles Alvarez; M. Esther García; Rocío González; Alberto Ramos; Miguel A. Ruiz
Journal of publication	Inorganic Chemistry
Year of publication	2011
Journal volume	50
Pages of publication	7894 - 7906
a	14.0485 ± 0.0002 Å
b	12.405 ± 0.0002 Å
c	13.3384 ± 0.0003 Å
α	90°
β	90°
γ	90°
Cell volume	2324.5 ± 0.07 Å³
Cell temperature	120 ± 2 K
Ambient diffraction temperature	120 ± 2 K
Number of distinct elements	6
Space group number	62
Hermann-Mauguin space group symbol	P n m a
Hall space group symbol	-P 2ac 2n
Residual factor for all reflections	0.0409
Residual factor for significantly intense reflections	0.035
Weighted residual factors for significantly intense reflections	0.087
Weighted residual factors for all reflections included in the refinement	0.0939
Goodness-of-fit parameter for all reflections included in the refinement	1.054
Diffraction radiation probe	x-ray
Diffraction radiation wavelength	1.54184 Å
Diffraction radiation type	CuKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
301838 (current)	2025-08-21	Add cross-references to PubChem compounds in COD range 4/32/ Each referenced PubChem compound corresponds to the full crystal structure.	4325977.cif
179362	2016-03-23	cif/4/32/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/32/59.	4325977.cif
91935	2013-12-29	cod/ (saulius@koala.ibt.lt) Adding DOIs that could be assigned unambiguously to the rest of COD CIFs.	4325977.cif
47013	2012-03-21	../uploads/cif-deposit/cod/cif Adding structures of 4325977 via cif-deposit CGI script.	4325977.cif