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Information card for entry 4338614
Preview
| Coordinates | 4338614.cif |
|---|---|
| Original paper (by DOI) | HTML |
| External links | PubChem |
| Common name | Moris-226(Sinay) |
|---|---|
| Formula | C15 H25 F5 Li N3 Si |
| Calculated formula | C15 H25 F5 Li N3 Si |
| SMILES | [Si](N1c2c([F][Li]31[N](CC[N]3(C)C)(C)C)c(c(F)c(c2F)F)F)(C)(C)C |
| Title of publication | Synthesis of Lithium N-pentafluorophenyl,N'-trimethylsilyl 2-Pyridylamidinate and Its Cyclization to Lithium Tetrafluoro-2-(2-pyridyl)benzimidazolate via a Me3SiF Elimination. Coordination Chemistry, Reactivity, and Mechanism |
| Authors of publication | Aharonovich, Sinai; Botoshanski, Mark; Eisen, Moris S. |
| Journal of publication | Inorganic chemistry |
| Year of publication | 2009 |
| Journal volume | 48 |
| Journal issue | 12 |
| Pages of publication | 5269 - 5278 |
| a | 19.258 ± 0.004 Å |
| b | 7.277 ± 0.001 Å |
| c | 28.944 ± 0.006 Å |
| α | 90° |
| β | 100.71 ± 0.03° |
| γ | 90° |
| Cell volume | 3985.6 ± 1.4 Å3 |
| Cell temperature | 240 ± 2 K |
| Ambient diffraction temperature | 240 ± 2 K |
| Number of distinct elements | 6 |
| Space group number | 15 |
| Hermann-Mauguin space group symbol | C 1 2/c 1 |
| Hall space group symbol | -C 2yc |
| Residual factor for all reflections | 0.0791 |
| Residual factor for significantly intense reflections | 0.0592 |
| Weighted residual factors for significantly intense reflections | 0.1875 |
| Weighted residual factors for all reflections included in the refinement | 0.1956 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.12 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 301839 (current) | 2025-08-21 | Add cross-references to PubChem compounds in COD range 4/33/ Each referenced PubChem compound corresponds to the full crystal structure. |
4338614.cif |
| 209997 | 2018-08-20 | cif/4/ Updating bibliography in entries 4302324-4302326, 4338614-4338616. Marking entries 4302324-4302326 as duplicates of entries 4338614-4338616. |
4338614.cif |
| 179489 | 2016-03-23 | cif/4/33/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/33/86. |
4338614.cif |
| 114767 | 2014-05-29 | cif/ Adding structures of 4338614, 4338615, 4338616 via cif-deposit CGI script. |
4338614.cif |
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