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Information card for entry 4341760
Preview
| Coordinates | 4341760.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Common name | Gold/Palladium Carbonyl Phosphine Cluster |
|---|---|
| Formula | C102 H180 Au2 O30 P12 Pd42 |
| Calculated formula | C102 H180 Au2 O30 P12 Pd42 |
| Title of publication | Acid/Base-Controlled Au(I)/Au(0) Reductive Transformations of the Monogold [(μ14-Au)Pd22(CO)20(PEt3)8](+) Monocation into Three Different Neutral Digold Nanoclusters: Au2Pd21(CO)20(PEt3)10, Au2Pd28(CO)26(PEt3)10, and New Five-Layer Hexagonal Close-Packed (μ12-Au)2Pd42(CO)30(PEt3)12 with a Trigonal-Bipyramidal AuPd3Au Kernel. |
| Authors of publication | Mednikov, Evgueni G.; Dahl, Lawrence F. |
| Journal of publication | Inorganic chemistry |
| Year of publication | 2015 |
| Journal volume | 54 |
| Journal issue | 3 |
| Pages of publication | 1145 - 1151 |
| a | 28.2643 ± 0.001 Å |
| b | 28.2643 ± 0.001 Å |
| c | 36.1195 ± 0.0014 Å |
| α | 90° |
| β | 90° |
| γ | 120° |
| Cell volume | 24989 ± 1.6 Å3 |
| Cell temperature | 100 ± 2 K |
| Ambient diffraction temperature | 100 ± 2 K |
| Number of distinct elements | 6 |
| Space group number | 167 |
| Hermann-Mauguin space group symbol | R -3 c :H |
| Hall space group symbol | -R 3 2"c |
| Residual factor for all reflections | 0.0779 |
| Residual factor for significantly intense reflections | 0.0599 |
| Weighted residual factors for significantly intense reflections | 0.1572 |
| Weighted residual factors for all reflections included in the refinement | 0.1696 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.025 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | Yes |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 179520 (current) | 2016-03-23 | cif/4/34/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/34/17. |
4341760.cif |
| 130524 | 2015-02-04 | cif/ Updating files of 4341760 Original log message: Adding full bibliography for 4341760.cif. |
4341760.cif |
| 128205 | 2014-12-06 | cif/ Adding structures of 4341760 via cif-deposit CGI script. |
4341760.cif |
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