Crystallography Open Database

Information card for entry 4343808

Preview

Coordinates	4343808.cif

Structure parameters

Chemical name	K10 Na12 ((Co3 (Si W9 O33 (O H)) (Si W8 O29 (O H)2))2) (H2 O)49
Formula	Co6 K10 Na2 O179 Si4 W34
Calculated formula	Co6 K10 Na2 O179 Si4 W34
SMILES	O=[W]123(=O)O[W]45(O[W]678(=O)=[O][Co]9%10%11%12[O]%13%14[Si]%15%16[O]%17%18[W]%19%20%21%22=[O][Co]%23%24%13([O]=[W]%13%25(=O)(=[O]9)O[W]9%26(O[W]%27%17(O[W]%17%28%29(O[W]%30(O[W]%31(O%17)(O[W]%18(O%27)(=O)(O%21)=[O][Co]%17%18%14([O]%10[Si]%10([O]34)[O]34[W]%14%21(O[W]%27(=O)(O6)(O[W](=O)(O7)(O[W]3(O[W]4(O%14)(O2)(=[O]%17)=O)(O%21)([O]%24%18)=O)([O]%11%23)[O]8%10%27)O5)(O1)=O)[O]=%31)(=O)[O]%15%29%30)(O[W](=O)(O%28)(O9)([O]%16%13%26)O%25)(=O)=[O]%12)=O)(O%22)=O)(=O)O%20)[O]=[W]1234[O]56[W]78(=O)(O3)=[O][Co]39%10%11[O]%12%13[Co]%14%15%16%17[O]=[W]%18%20%21(O[W]%22%23(=O)([O]%24[W]%25(O[W]%26%27%28(O[W]%29(=O)(O[W]%30%31(=O)(O[W]%32(O[W]([O]%18%32[Si]%24([O]%28%29%31)[O]%11%17)(O%20)(=O)(O%23)O%26)([O]%15[Co]%13([O]=%19)([O]=[W]%11%13(O[W]%15%17(O[W]5(O1)(O[W]15%18(=O)[O]%19%20[W](=O)(=[O]3)(O7)(O5)O[W]%19(O[W](=O)(O1)(O%11)([O]%13%15[Si]6%12%20)O%17)(=[O]%16)(=O)O%18)(=O)O8)(=O)O2)(=[O]%14)=O)([O]9%30)[O]=4)(O%21)=O)O%27)(O%25)=[O]%10)=O)(O%22)(=O)=O)=O)=O)(=O)=O.[Na+].[Na+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O
Title of publication	Cobalt containing silicotungstate sandwich dimer [{Co3 (B-beta-Si W9 O33 (O H)) (B-beta-Si W8 O29 (O H)2)}2](22-)
Authors of publication	Bassil, B.S.; Kortz, U.; Keita, B.; Tigan, A.S.; Clemente-Juan, J.M.; de Oliveira, P.; Nadjo, L.
Journal of publication	Inorganic Chemistry
Year of publication	2005
Journal volume	44
Pages of publication	9360 - 9368
a	19.9466 Å
b	24.6607 Å
c	34.0978 Å
α	90°
β	102.175°
γ	90°
Cell volume	16395.4 Å³
Number of distinct elements	6
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/n 1
Hall space group symbol	-P 2yn
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
176428 (current)	2016-02-13	Replaced deprecated COD CIF data names with their more modern alternatives. The _cod_cif_authors_sg_Hall and _cod_cif_authors_sg_H-M data items were renamed to _cod_original_sg_symbol_Hall and _cod_cif_authors_sg_H-M respectively.	4343808.cif
150444	2015-07-13	cif/ Adding structures of 4343808 via cif-deposit CGI script.	4343808.cif