Crystallography Open Database

Information card for entry 4346040

Preview

Coordinates	4346040.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C30 H32 Ge N2 O11 Ru3
Calculated formula	C30 H32 Ge N2 O11 Ru3
SMILES	CC(C)(C)N1C(c2ccccc2)=[N](C(C)(C)C)[Ge]1(C(C)(C)C)[Ru]1(C#[O])(C#[O])(C#[O])[Ru](C#[O])(C#[O])(C#[O])(C#[O])[Ru]1(C#[O])(C#[O])(C#[O])C#[O]
Title of publication	Amidinatogermylene derivatives of ruthenium carbonyl: new insights into the reactivity of [Ru3(CO)12] with two-electron-donor reagents of high basicity.
Authors of publication	Álvarez-Rodríguez, Lucía; Cabeza, Javier A.; García-Álvarez, Pablo; Pérez-Carreño, Enrique; Polo, Diego
Journal of publication	Inorganic chemistry
Year of publication	2015
Journal volume	54
Journal issue	6
Pages of publication	2983 - 2994
a	17.3399 ± 0.0003 Å
b	9.1771 ± 0.0002 Å
c	22.6692 ± 0.0004 Å
α	90°
β	90°
γ	90°
Cell volume	3607.35 ± 0.12 Å³
Cell temperature	100 ± 2 K
Ambient diffraction temperature	100 ± 2 K
Number of distinct elements	6
Space group number	33
Hermann-Mauguin space group symbol	P n a 21
Hall space group symbol	P 2c -2n
Residual factor for all reflections	0.0299
Residual factor for significantly intense reflections	0.0261
Weighted residual factors for significantly intense reflections	0.0414
Weighted residual factors for all reflections included in the refinement	0.0429
Goodness-of-fit parameter for all reflections included in the refinement	1.005
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
231590 (current)	2019-11-22	cif/ Adding structures of 4346039, 4346040, 4346041, 4346042 via cif-deposit CGI script.	4346040.cif