Crystallography Open Database

Information card for entry 4346042

Preview

Coordinates	4346042.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C24 H28 Ge N2 O7 Ru2
Calculated formula	C24 H28 Ge N2 O7 Ru2
SMILES	CC(C)[N]1=C(c2ccccc2)N(C(C)C)[Ge](C(C)(C)C)([Ru]1(C#[O])(C#[O])C#[O])[Ru](C#[O])(C#[O])(C#[O])C#[O]
Title of publication	Amidinatogermylene derivatives of ruthenium carbonyl: new insights into the reactivity of [Ru3(CO)12] with two-electron-donor reagents of high basicity.
Authors of publication	Álvarez-Rodríguez, Lucía; Cabeza, Javier A.; García-Álvarez, Pablo; Pérez-Carreño, Enrique; Polo, Diego
Journal of publication	Inorganic chemistry
Year of publication	2015
Journal volume	54
Journal issue	6
Pages of publication	2983 - 2994
a	9.3494 ± 0.0001 Å
b	17.8506 ± 0.0002 Å
c	16.5316 ± 0.0002 Å
α	90°
β	90.475 ± 0.001°
γ	90°
Cell volume	2758.9 ± 0.05 Å³
Cell temperature	123 ± 2 K
Ambient diffraction temperature	123 ± 2 K
Number of distinct elements	6
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/c 1
Hall space group symbol	-P 2ybc
Residual factor for all reflections	0.0378
Residual factor for significantly intense reflections	0.0285
Weighted residual factors for significantly intense reflections	0.0671
Weighted residual factors for all reflections included in the refinement	0.0729
Goodness-of-fit parameter for all reflections included in the refinement	1.019
Diffraction radiation wavelength	1.5418 Å
Diffraction radiation type	CuKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
231590 (current)	2019-11-22	cif/ Adding structures of 4346039, 4346040, 4346041, 4346042 via cif-deposit CGI script.	4346042.cif