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Information card for entry 7001500
Preview
| Coordinates | 7001500.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C101 H118 Cl18 O12 P8 Pt2 |
|---|---|
| Calculated formula | C101 H118 Cl18 O12 P8 Pt2 |
| SMILES | [Pt]1(Cl)(Cl)[P](c2ccc(CC(P(=O)(OCC)OCC)(P(=O)(OCC)OCC)Cc3ccc(cc3)[P]([Pt](Cl)(Cl)[P](c3ccc(CC(P(=O)(OCC)OCC)(Cc4ccc(cc4)[P]1(c1ccccc1)c1ccccc1)P(=O)(OCC)OCC)cc3)(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)cc2)(c1ccccc1)c1ccccc1.C(Cl)Cl.C(Cl)Cl.C(Cl)Cl.C(Cl)Cl.C(Cl)Cl.C(Cl)Cl.C(Cl)Cl |
| Title of publication | Complexes of hydrophilic triphenylphosphines modified with gem-bis(phosphonate) moiety. An unusual simultaneous cis and trans arrangements in the Pt(ii) dinuclear complex |
| Authors of publication | Drahoš, Bohuslav; Rohlík, Zbyněk; Kotek, Jan; Císařová, Ivana; Hermann, Petr |
| Journal of publication | Dalton Transactions |
| Year of publication | 2009 |
| Journal issue | 25 |
| Pages of publication | 4942 - 4953 |
| a | 17.5897 ± 0.0002 Å |
| b | 18.3345 ± 0.0003 Å |
| c | 20.9857 ± 0.0003 Å |
| α | 84.3179 ± 0.0007° |
| β | 68.7386 ± 0.0009° |
| γ | 69.7078 ± 0.0009° |
| Cell volume | 5912.98 ± 0.15 Å3 |
| Cell temperature | 150 ± 1 K |
| Ambient diffraction temperature | 150 ± 1 K |
| Number of distinct elements | 6 |
| Space group number | 2 |
| Hermann-Mauguin space group symbol | P -1 |
| Hall space group symbol | -P 1 |
| Residual factor for all reflections | 0.0708 |
| Residual factor for significantly intense reflections | 0.0525 |
| Weighted residual factors for significantly intense reflections | 0.1362 |
| Weighted residual factors for all reflections included in the refinement | 0.1515 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.029 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 179713 (current) | 2016-03-25 | cif/7/00/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 7/00/15. |
7001500.cif |
| 120443 | 2014-07-15 | Adding 17924 DOIs guessed from source file names. | 7001500.cif |
| 35909 | 2012-02-26 | cif/7/: reorganising range 7 into a prefix-directory tree. | 7001500.cif |
| 1143 | 2010-05-03 | cif/7/ Adding CIFs from Dalton-Trans-2009/ deposition. |
7001500.cif |
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