Crystallography Open Database

Information card for entry 7009724

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Coordinates	7009724.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C43 H19 Au Cl4 Ir7 O23 P Ru3
Calculated formula	C42.45 Au Cl2.9 Ir7 O23 P Ru3
Title of publication	Synthesis and characterization of high-nuclearity iridium‒ruthenium and ‒gold mixed-metal carbonyl clusters, [Ir7Ru3(CO)23]−, [Ir7Ru3(CO)23(AuPPh3)] and [Ir6Ru3(CO)21(AuPPh3)]−, possessing tetrahedrally capped octahedral iridium cores obtained by capping reactions with [Ru3(CO)12] and [AuCl(PPh3)]
Authors of publication	Chihara, Teiji; Sato, Mayumi; Konomoto, Hiromi; Kamiguchi, Satoshi; Ogawa, Haruo; Wakatsuki, Yasuo
Journal of publication	Journal of the Chemical Society, Dalton Transactions
Year of publication	2000
Journal issue	14
Pages of publication	2295
a	17.271 ± 0.002 Å
b	17.957 ± 0.004 Å
c	21.029 ± 0.003 Å
α	90°
β	111.52 ± 0.01°
γ	90°
Cell volume	6067.2 ± 1.8 Å³
Cell temperature	294.2 K
Number of distinct elements	8
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/n 1
Hall space group symbol	-P 2yn
Residual factor for significantly intense reflections	0.0507
Weighted residual factors for all reflections included in the refinement	0.0543
Goodness-of-fit parameter for all reflections included in the refinement	1.699
Diffraction radiation wavelength	0.7107 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
176453 (current)	2016-02-16	cif/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in range 7.	7009724.cif
120443	2014-07-15	Adding 17924 DOIs guessed from source file names.	7009724.cif
35909	2012-02-26	cif/7/: reorganising range 7 into a prefix-directory tree.	7009724.cif
3896	2010-12-08	cif/7/ Adding CIFs with data from Dalton-Trans-2004-2000/.	7009724.cif