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Information card for entry 7013100
Preview
| Coordinates | 7013100.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Common name | Platinum-Thallium Carbonyl Phosphine Sandwich Cluster |
|---|---|
| Formula | C42 H90 F6 O6 P7 Pt6 Tl |
| Calculated formula | C42 H90 F6 O6 P7 Pt6 Tl |
| Title of publication | Formation of thallium(i) sandwich M3TlM3 clusters, [(μ6-Tl)M6(μ2-CO)6(PEt3)6]+ (M = Pt, Pd), with two unconnected triangular M3(μ2-CO)3(PEt3)3 units: implications of comparative analysis of isostructural 5d106s2 Tl(i)‒(M3)2 sandwiches (M = Pt, Pd) with known 5d10 Au(i)‒(Pt3)2 sandwich |
| Authors of publication | Mednikov, Evgueni G.; Dahl, Lawrence F. |
| Journal of publication | Dalton Transactions |
| Year of publication | 2003 |
| Journal issue | 15 |
| Pages of publication | 3117 - 3125 |
| a | 22.9611 ± 0.0013 Å |
| b | 24.4812 ± 0.0014 Å |
| c | 22.4513 ± 0.0013 Å |
| α | 90° |
| β | 94.795 ± 0.001° |
| γ | 90° |
| Cell volume | 12576.1 ± 1.2 Å3 |
| Cell temperature | 100 ± 2 K |
| Ambient diffraction temperature | 100 ± 2 K |
| Number of distinct elements | 7 |
| Space group number | 15 |
| Hermann-Mauguin space group symbol | C 1 2/c 1 |
| Hall space group symbol | -C 2yc |
| Residual factor for all reflections | 0.0283 |
| Residual factor for significantly intense reflections | 0.0235 |
| Weighted residual factors for significantly intense reflections | 0.0544 |
| Weighted residual factors for all reflections included in the refinement | 0.0558 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.116 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | Yes |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 179835 (current) | 2016-03-25 | cif/7/01/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 7/01/31. |
7013100.cif |
| 173443 | 2016-01-04 | cif/ (antanas@kurmis) Updating bibliographies for multiple entries. |
7013100.cif |
| 120443 | 2014-07-15 | Adding 17924 DOIs guessed from source file names. | 7013100.cif |
| 35909 | 2012-02-26 | cif/7/: reorganising range 7 into a prefix-directory tree. | 7013100.cif |
| 3896 | 2010-12-08 | cif/7/ Adding CIFs with data from Dalton-Trans-2004-2000/. |
7013100.cif |
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