Crystallography Open Database

Information card for entry 7023350

Preview

Coordinates	7023350.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C50 H70 Cl2 F12 N6 O Rh2 Sb2
Calculated formula	C50 H70 Cl2 F12 N6 O Rh2 Sb2
Title of publication	Half-sandwich rhodium and iridium complexes containing homochiral imidazolyl-imine ligands: synthesis, characterization and catalytic applications.
Authors of publication	Becerra, Alexandra; Contreras, Raúl; Carmona, Daniel; Lahoz, Fernando J.; García-Orduña, Pilar
Journal of publication	Dalton transactions (Cambridge, England : 2003)
Year of publication	2013
Journal volume	42
Journal issue	32
Pages of publication	11640 - 11651
a	8.8002 ± 0.0005 Å
b	28.1813 ± 0.0015 Å
c	12.2161 ± 0.0007 Å
α	90°
β	97.603 ± 0.001°
γ	90°
Cell volume	3003 ± 0.3 Å³
Cell temperature	100 ± 2 K
Ambient diffraction temperature	100 ± 2 K
Number of distinct elements	8
Space group number	4
Hermann-Mauguin space group symbol	P 1 21 1
Hall space group symbol	P 2yb
Residual factor for all reflections	0.0614
Residual factor for significantly intense reflections	0.048
Weighted residual factors for significantly intense reflections	0.1113
Weighted residual factors for all reflections included in the refinement	0.1179
Goodness-of-fit parameter for all reflections included in the refinement	1.03
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
179938 (current)	2016-03-25	cif/7/02/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 7/02/33.	7023350.cif
90507	2013-11-18	cif/ Adding structures of 7023350, 7023351, 7023352, 7023353, 7023354 via cif-deposit CGI script.	7023350.cif