Crystallography Open Database

Information card for entry 7025185

Preview

Coordinates	7025185.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C64 H84 Cl2 N4 O P4 Si4 Zn4
Calculated formula	C64 H84 Cl2 N4 O P4 Si4 Zn4
SMILES	C1[Zn]23[N](=P(C[Zn]45[N](=P(C[Zn]6([N](=P(C[Zn]([N](=P1(c1ccccc1)c1ccccc1)[Si](C)(C)C)([O]256)[Cl]4)(c1ccccc1)c1ccccc1)[Si](C)(C)C)[Cl]3)(c1ccccc1)c1ccccc1)[Si](C)(C)C)(c1ccccc1)c1ccccc1)[Si](C)(C)C
Title of publication	Reactivity of Zn(II), Mg(II) and Al(III) chlorides with a phosphinimine ligand: new tetrameric inverse crown ether structures.
Authors of publication	Valerio Cárdenas, Cintya; Muñoz Hernández, Miguel Angel; Grévy, Jean-Michel
Journal of publication	Dalton transactions (Cambridge, England : 2003)
Year of publication	2010
Journal volume	39
Journal issue	28
Pages of publication	6441 - 6448
a	14.8254 ± 0.0019 Å
b	14.8254 ± 0.0019 Å
c	16.278 ± 0.003 Å
α	90°
β	90°
γ	90°
Cell volume	3577.8 ± 0.9 Å³
Cell temperature	100 ± 2 K
Ambient diffraction temperature	100 ± 2 K
Number of distinct elements	8
Space group number	114
Hermann-Mauguin space group symbol	P -4 21 c
Hall space group symbol	P -4 2n
Residual factor for all reflections	0.0456
Residual factor for significantly intense reflections	0.0364
Weighted residual factors for significantly intense reflections	0.057
Weighted residual factors for all reflections included in the refinement	0.0581
Goodness-of-fit parameter for all reflections included in the refinement	0.976
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
179956 (current)	2016-03-25	cif/7/02/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 7/02/51.	7025185.cif
92873	2014-01-12	cif/ Adding structures of 7025183, 7025184, 7025185, 7025186, 7025187, 7025188 via cif-deposit CGI script.	7025185.cif