Crystallography Open Database

Information card for entry 7110219

Preview

Coordinates	7110219.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C37 H49 Ge N13
Calculated formula	C37 H49 Ge N13
SMILES	[Ge]1(=C2N(C=CN2CN2C=1N(C=C2)c1c(cccc1C(C)C)C(C)C)c1c(cccc1C(C)C)C(C)C)N=N#N.[N-]=N#N.N#CC.N#CC.N#CC
Title of publication	Synthesis and structure of the azidogermyliumylidene azide complex [L(N3)Ge:]^+^N3^-^ with covalently and ionically bonded azide ligands at germanium(II) [L = bis(N-heterocyclic carbene)]
Authors of publication	Yun Xiong; Shenglai Yao; Matthias Driess
Journal of publication	Chem.Commun.
Year of publication	2014
Journal volume	50
Pages of publication	418
a	18.2975 ± 0.0012 Å
b	15.668 ± 0.0006 Å
c	15.2402 ± 0.0011 Å
α	90°
β	114.497 ± 0.009°
γ	90°
Cell volume	3975.8 ± 0.5 Å³
Cell temperature	150 ± 2 K
Ambient diffraction temperature	150 ± 2 K
Number of distinct elements	4
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/c 1
Hall space group symbol	-P 2ybc
Residual factor for all reflections	0.052
Residual factor for significantly intense reflections	0.0371
Weighted residual factors for significantly intense reflections	0.0761
Weighted residual factors for all reflections included in the refinement	0.0816
Goodness-of-fit parameter for all reflections included in the refinement	1.012
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
180216 (current)	2016-03-26	cif/7/11/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 7/11/02.	7110219.cif
120112	2014-07-12	Adding DOIs to range 7 structures.	7110219.cif
92002	2014-01-10	cif/ Adding structures of 7110219, 7110220, 7110221 via cif-deposit CGI script.	7110219.cif