Crystallography Open Database

Information card for entry 7111584

Preview

Coordinates	7111584.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C57 H63 Eu N6
Calculated formula	C57 H63 Eu N6
SMILES	[Eu]123([N](=C(C)C=C(N1c1ccccc1C)C)c1c(cccc1)C)([N](=C(C=C(N2c1c(cccc1)C)C)C)c1c(cccc1)C)[N](=C(C)C=C(N3c1c(cccc1)C)C)c1c(cccc1)C
Title of publication	New reaction of β-diketiminatoeuropium complex: sterically induced oxidation‒coupling of β-diketiminato ligands
Authors of publication	Jiao, Rui; Shen, Xiaodong; Xue, Mingqiang; Zhang, Yong; Yao, Yingming; Shen, Qi
Journal of publication	Chemical Communications
Year of publication	2010
Journal volume	46
Journal issue	23
Pages of publication	4118 - 4120
a	19.249 ± 0.002 Å
b	12.5786 ± 0.0016 Å
c	20.355 ± 0.003 Å
α	90°
β	91.473 ± 0.005°
γ	90°
Cell volume	4926.8 ± 1.1 Å³
Cell temperature	223 ± 2 K
Ambient diffraction temperature	223 ± 2 K
Number of distinct elements	4
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/c 1
Hall space group symbol	-P 2ybc
Residual factor for all reflections	0.1729
Residual factor for significantly intense reflections	0.1098
Weighted residual factors for significantly intense reflections	0.1516
Weighted residual factors for all reflections included in the refinement	0.174
Goodness-of-fit parameter for all reflections included in the refinement	1.152
Diffraction radiation wavelength	0.71075 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
180229 (current)	2016-03-26	cif/7/11/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 7/11/15.	7111584.cif
96677	2014-01-29	cif/ Adding structures of 7111583, 7111584, 7111585 via cif-deposit CGI script.	7111584.cif