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Information card for entry 7123415
Preview
| Coordinates | 7123415.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Common name | RJW_3_184 |
|---|---|
| Chemical name | IPrNiC(SiMe3)3 |
| Formula | C37 H63 N2 Ni Si3 |
| Calculated formula | C37 H63 N2 Ni Si3 |
| Title of publication | A two-coordinate Ni(I) silyl complex: CO2 insertion and oxidatively-induced silyl migrations |
| Authors of publication | Witzke, Ryan J.; Tilley, T. Don |
| Journal of publication | Chemical Communications |
| Year of publication | 2019 |
| a | 10.9273 ± 0.0006 Å |
| b | 18.0527 ± 0.0011 Å |
| c | 20.2837 ± 0.0013 Å |
| α | 90° |
| β | 98.521 ± 0.003° |
| γ | 90° |
| Cell volume | 3957.1 ± 0.4 Å3 |
| Cell temperature | 100 ± 2 K |
| Ambient diffraction temperature | 100 ± 2 K |
| Number of distinct elements | 5 |
| Space group number | 14 |
| Hermann-Mauguin space group symbol | P 1 21/n 1 |
| Hall space group symbol | -P 2yn |
| Residual factor for all reflections | 0.0731 |
| Residual factor for significantly intense reflections | 0.0532 |
| Weighted residual factors for significantly intense reflections | 0.1264 |
| Weighted residual factors for all reflections included in the refinement | 0.1368 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.072 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 214995 (current) | 2019-05-09 | cif/ Adding structures of 7123412, 7123413, 7123414, 7123415, 7123416, 7123417 via cif-deposit CGI script. |
7123415.cif |
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Users of the data should acknowledge the original authors of the
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