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Information card for entry 7150566
Preview
| Coordinates | 7150566.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C25 H29 O2 P S Si |
|---|---|
| Calculated formula | C25 H29 O2 P S Si |
| SMILES | [Si](O[C@@]1(OCC[C@@H]1P(=S)(c1ccccc1)c1ccccc1)c1ccccc1)(C)(C)C.[Si](O[C@]1(OCC[C@H]1P(=S)(c1ccccc1)c1ccccc1)c1ccccc1)(C)(C)C |
| Title of publication | The lithiation and acyl transfer reactions of phosphine oxides, sulfides and boranes in the synthesis of cyclopropanes |
| Authors of publication | Clarke, Celia; Fox, David J.; Pedersen, Daniel Sejer; Warren, Stuart |
| Journal of publication | Organic & Biomolecular Chemistry |
| Year of publication | 2009 |
| Journal volume | 7 |
| Journal issue | 7 |
| Pages of publication | 1329 - 1336 |
| a | 32.7713 ± 0.0006 Å |
| b | 8.3741 ± 0.0002 Å |
| c | 18.3244 ± 0.0003 Å |
| α | 90° |
| β | 104.915 ± 0.001° |
| γ | 90° |
| Cell volume | 4859.34 ± 0.17 Å3 |
| Cell temperature | 180 ± 2 K |
| Ambient diffraction temperature | 180 ± 2 K |
| Number of distinct elements | 6 |
| Space group number | 15 |
| Hermann-Mauguin space group symbol | C 1 2/c 1 |
| Hall space group symbol | -C 2yc |
| Residual factor for all reflections | 0.0481 |
| Residual factor for significantly intense reflections | 0.0368 |
| Weighted residual factors for significantly intense reflections | 0.0892 |
| Weighted residual factors for all reflections included in the refinement | 0.0958 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.017 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 180291 (current) | 2016-03-26 | cif/7/15/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 7/15/05. |
7150566.cif |
| 120443 | 2014-07-15 | Adding 17924 DOIs guessed from source file names. | 7150566.cif |
| 35909 | 2012-02-26 | cif/7/: reorganising range 7 into a prefix-directory tree. | 7150566.cif |
| 1167 | 2010-05-13 | cif/ Adding data from the rest of 2009 RSC journals, Inorg-Chem-2008 and Chem-Comm-2010_18-19. |
7150566.cif |
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Users of the data should acknowledge the original authors of the
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