Crystallography Open Database

Information card for entry 7217195

Preview

Coordinates	7217195.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C25 H37 Ge N3 O6 Ru2 Si2
Calculated formula	C25 H37 Ge N3 O6 Ru2 Si2
SMILES	CC(C)(C)[N]1=C(c2ccccc2)N(CC)[Ge]2(N([Si](C)(C)C)[Si](C)(C)C)[Ru]1(C#[O])(C#[O])[Ru]2(C#[O])(C#[O])(C#[O])C#[O]
Title of publication	Steric effects in the reactions of amidinate germylenes with ruthenium carbonyl: isolation of a coordinatively unsaturated diruthenium(0) derivative
Authors of publication	Cabeza, Javier A.; Fernández-Colinas, José M.; García-Álvarez, Pablo; Polo, Diego
Journal of publication	RSC Advances
Year of publication	2014
Journal volume	4
Journal issue	59
Pages of publication	31503
a	12.0005 ± 0.0003 Å
b	17.7747 ± 0.0003 Å
c	17.9712 ± 0.0004 Å
α	112.81 ± 0.002°
β	102.108 ± 0.002°
γ	94.844 ± 0.002°
Cell volume	3396.02 ± 0.15 Å³
Cell temperature	153 ± 4 K
Ambient diffraction temperature	153 ± 4 K
Number of distinct elements	7
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.0236
Residual factor for significantly intense reflections	0.0223
Weighted residual factors for significantly intense reflections	0.0585
Weighted residual factors for all reflections included in the refinement	0.0597
Goodness-of-fit parameter for all reflections included in the refinement	1.03
Diffraction radiation wavelength	1.5418 Å
Diffraction radiation type	CuKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
180502 (current)	2016-03-26	cif/7/21/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 7/21/71.	7217195.cif
120673	2014-07-23	cif/ Adding structures of 7217195, 7217196 via cif-deposit CGI script.	7217195.cif