Crystallography Open Database
- COD Home
- Accessing COD Data
- Add Your Data
- Documentation
Information card for entry 7700094
Preview
| Coordinates | 7700094.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C12 H65.5 Cl Co2 Mo7 N12 Na O32.75 |
|---|---|
| Calculated formula | C12 H48 Cl Co2 Mo7 N12 Na O32.78 |
| Title of publication | The synthesis, structure and catalytic properties of the [Mo<sub>7</sub>O<sub>24</sub>(μ-Mo<sub>8</sub>O<sub>26</sub>)Mo<sub>7</sub>O<sub>24</sub>]<sup>16-</sup> anion formed via two intermediate heptamolybdates [Co(en)<sub>3</sub>]<sub>2</sub>[NaMo<sub>7</sub>O<sub>24</sub>]Cl·nH<sub>2</sub>O and (H<sub>3</sub>O)[Co(en)<sub>3</sub>]<sub>2</sub>[Mo<sub>7</sub>O<sub>24</sub>]Cl·9H<sub>2</sub>O. |
| Authors of publication | Damjanović, Vladimir; Pisk, Jana; Kuzman, Dino; Agustin, Dominique; Vrdoljak, Višnja; Stilinović, Vladimir; Cindrić, Marina |
| Journal of publication | Dalton transactions (Cambridge, England : 2003) |
| Year of publication | 2019 |
| Journal volume | 48 |
| Journal issue | 27 |
| Pages of publication | 9974 - 9983 |
| a | 12.3901 ± 0.0005 Å |
| b | 17.318 ± 0.0007 Å |
| c | 24.312 ± 0.002 Å |
| α | 90° |
| β | 95.74 ± 0.005° |
| γ | 90° |
| Cell volume | 5190.5 ± 0.5 Å3 |
| Cell temperature | 293 ± 2 K |
| Ambient diffraction temperature | 295 ± 2 K |
| Number of distinct elements | 8 |
| Space group number | 14 |
| Hermann-Mauguin space group symbol | P 1 21/c 1 |
| Hall space group symbol | -P 2ybc |
| Residual factor for all reflections | 0.0667 |
| Residual factor for significantly intense reflections | 0.0421 |
| Weighted residual factors for significantly intense reflections | 0.1094 |
| Weighted residual factors for all reflections included in the refinement | 0.1145 |
| Goodness-of-fit parameter for all reflections included in the refinement | 0.967 |
| Diffraction radiation wavelength | 0.7107 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | Yes |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 223871 (current) | 2019-11-07 | cif/ Updating files of 7700094, 7700095, 7700096, 7700097, 7700098, 7700099 Original log message: Adding full bibliography for 7700094--7700099.cif. |
7700094.cif |
| 215576 | 2019-05-29 | cif/ Adding structures of 7700094, 7700095, 7700096, 7700097, 7700098, 7700099 via cif-deposit CGI script. |
7700094.cif |
All data in the COD and the database itself are dedicated to the
public domain and licensed under the
CC0
License
.
Users of the data should acknowledge the original authors of the
structural data.