Crystallography Open Database

Information card for entry 7704638

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Coordinates	7704638.cif
Original paper (by DOI)	HTML

Structure parameters

Common name	Os(^Ph^ap)~2~Cl~2~ . CDCl~3~
Chemical name	Cis-bis-(2-(phenylimido)-4,6-di-tert-butylphenoxo)dichloroosmium(VI) chloroform solvate
Formula	C41 H50 Cl5 D N2 O2 Os
Calculated formula	C41 H50 Cl5 D N2 O2 Os
Title of publication	High-valent osmium iminoxolene complexes.
Authors of publication	Gianino, Jacqueline; Erickson, Alexander N.; Markovitz, Sean J.; Brown, Seth N.
Journal of publication	Dalton transactions (Cambridge, England : 2003)
Year of publication	2020
Journal volume	49
Journal issue	25
Pages of publication	8504 - 8515
a	16.8082 ± 0.0007 Å
b	40.829 ± 0.002 Å
c	12.5096 ± 0.0007 Å
α	90°
β	90°
γ	90°
Cell volume	8584.9 ± 0.7 Å³
Cell temperature	120 ± 2 K
Ambient diffraction temperature	120 ± 2 K
Number of distinct elements	7
Space group number	43
Hermann-Mauguin space group symbol	F d d 2
Hall space group symbol	F 2 -2d
Residual factor for all reflections	0.0156
Residual factor for significantly intense reflections	0.014
Weighted residual factors for significantly intense reflections	0.0322
Weighted residual factors for all reflections included in the refinement	0.0327
Goodness-of-fit parameter for all reflections included in the refinement	1.047
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
253897 (current)	2020-07-06	cif/ Updating files of 7704635, 7704636, 7704637, 7704638, 7704639, 7704640 Original log message: Adding full bibliography for 7704635--7704640.cif.	7704638.cif
252970	2020-06-06	cif/ Adding structures of 7704635, 7704636, 7704637, 7704638, 7704639, 7704640 via cif-deposit CGI script.	7704638.cif