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Information card for entry 7706850
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| Coordinates | 7706850.cif |
|---|---|
| Original paper (by DOI) | HTML |
| External links | PubChem |
| Common name | (2-bromo-3-chlorophenyl)bis(2-bromo-6-chlorophenyl)phosphane |
|---|---|
| Chemical name | (2-bromo-3-chlorophenyl)bis(2-bromo-6-chlorophenyl)phosphane |
| Formula | C18 H9 Br3 Cl3 P |
| Calculated formula | C18 H9 Br3 Cl3 P |
| Title of publication | Sterically hindered ortho-substituted phosphatriptycenes as configurationally stable P-chirogenic triarylphosphines. |
| Authors of publication | Hu, Lei; Mahaut, Damien; Tumanov, Nikolay; Wouters, Johan; Collard, Laurent; Robiette, Raphaël; Berionni, Guillaume |
| Journal of publication | Dalton transactions (Cambridge, England : 2003) |
| Year of publication | 2021 |
| Journal volume | 50 |
| Journal issue | 14 |
| Pages of publication | 4772 - 4777 |
| a | 31.4777 ± 0.0008 Å |
| b | 8.5972 ± 0.0002 Å |
| c | 14.8825 ± 0.0004 Å |
| α | 90° |
| β | 94.161 ± 0.003° |
| γ | 90° |
| Cell volume | 4016.89 ± 0.18 Å3 |
| Cell temperature | 295 ± 2 K |
| Ambient diffraction temperature | 295 ± 2 K |
| Number of distinct elements | 5 |
| Space group number | 14 |
| Hermann-Mauguin space group symbol | P 1 21/c 1 |
| Hall space group symbol | -P 2ybc |
| Residual factor for all reflections | 0.0609 |
| Residual factor for significantly intense reflections | 0.0431 |
| Weighted residual factors for significantly intense reflections | 0.0939 |
| Weighted residual factors for all reflections included in the refinement | 0.1032 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.06 |
| Diffraction radiation wavelength | 1.54184 Å |
| Diffraction radiation type | CuKα |
| Has coordinates | Yes |
| Has disorder | Yes |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 301878 (current) | 2025-08-23 | Add cross-references to PubChem compounds in COD range 7/70/ Each referenced PubChem compound corresponds to the full crystal structure. |
7706850.cif |
| 266063 | 2021-06-05 | cif/ Updating files of 7706848, 7706849, 7706850, 7706851, 7706852, 7706853, 7706854, 7706855, 7706856, 7706857, 7706858, 7706859, 7706860, 7706861 Original log message: Adding full bibliography for 7706848--7706861.cif. |
7706850.cif |
| 263055 | 2021-03-16 | cif/ Adding structures of 7706848, 7706849, 7706850, 7706851, 7706852, 7706853, 7706854, 7706855, 7706856, 7706857, 7706858, 7706859, 7706860, 7706861 via cif-deposit CGI script. |
7706850.cif |
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Users of the data should acknowledge the original authors of the
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