Crystallography Open Database

Information card for entry 7709292

Preview

Coordinates	7709292.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C64 H89 Cl3 Ga2 N4 Si
Calculated formula	C64 H89 Cl3 Ga2 N4 Si
Title of publication	Geminal C-Cl and Si-Cl bond activation of chloromethanes and chlorosilanes by gallanediyl LGa.
Authors of publication	Helling, Christoph; Ganesamoorthy, Chelladurai; Wölper, Christoph; Schulz, Stephan
Journal of publication	Dalton transactions (Cambridge, England : 2003)
Year of publication	2022
Journal volume	51
Journal issue	5
Pages of publication	2050 - 2058
a	13.931 ± 0.002 Å
b	24.762 ± 0.004 Å
c	18.434 ± 0.003 Å
α	90°
β	92.86 ± 0.007°
γ	90°
Cell volume	6351.1 ± 1.7 Å³
Cell temperature	100 ± 2 K
Ambient diffraction temperature	100 ± 2 K
Number of distinct elements	6
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/c 1
Hall space group symbol	-P 2ybc
Residual factor for all reflections	0.063
Residual factor for significantly intense reflections	0.0371
Weighted residual factors for significantly intense reflections	0.085
Weighted residual factors for all reflections included in the refinement	0.0971
Goodness-of-fit parameter for all reflections included in the refinement	1.017
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
272670 (current)	2022-02-04	cif/ Updating files of 7709288, 7709289, 7709290, 7709291, 7709292, 7709293, 7709294 Original log message: Adding full bibliography for 7709288--7709294.cif.	7709292.cif
272012	2022-01-13	cif/ Adding structures of 7709288, 7709289, 7709290, 7709291, 7709292, 7709293, 7709294 via cif-deposit CGI script.	7709292.cif