Crystallography Open Database

Information card for entry 7709319

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Coordinates	7709319.cif
Original paper (by DOI)	HTML

Structure parameters

Chemical name	tBu-POCOP-Pt-SH
Formula	C22 H40 O2 P2 Pt S
Calculated formula	C22 H40 O2 P2 Pt S
SMILES	[Pt]12([P](Oc3cccc(O[P]1(C(C)(C)C)C(C)(C)C)c23)(C(C)(C)C)C(C)(C)C)S
Title of publication	Platinum thiolate complexes supported by PBP and POCOP pincer ligands as efficient catalysts for the hydrosilylation of carbonyl compounds
Authors of publication	Xue, Man-Man; Chang, Jiarui; Zhang, Jie; Chen, Xuenian
Journal of publication	Dalton Transactions
Year of publication	2022
a	8.3204 ± 0.0003 Å
b	12.0711 ± 0.0004 Å
c	13.4168 ± 0.0004 Å
α	100.588 ± 0.003°
β	95.692 ± 0.003°
γ	104.316 ± 0.003°
Cell volume	1268.58 ± 0.08 Å³
Cell temperature	169.99 ± 0.1 K
Ambient diffraction temperature	169.99 ± 0.1 K
Number of distinct elements	6
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.0224
Residual factor for significantly intense reflections	0.0204
Weighted residual factors for significantly intense reflections	0.0484
Weighted residual factors for all reflections included in the refinement	0.0491
Goodness-of-fit parameter for all reflections included in the refinement	1.049
Diffraction radiation probe	x-ray
Diffraction radiation wavelength	1.54184 Å
Diffraction radiation type	CuKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
272117 (current)	2022-01-19	cif/ Adding structures of 7709318, 7709319, 7709320, 7709321 via cif-deposit CGI script.	7709319.cif