Crystallography Open Database

Information card for entry 7714672

Preview

Coordinates	7714672.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C59 H88 B2 Cl6 F4 P3 Rh
Calculated formula	C57 H84 B2 Cl4 F4 P3 Rh
Title of publication	Diphosphene with a phosphineborane tether and its rhodium complex.
Authors of publication	Tsurusaki, Akihiro; Takechi, Shingo; Kamikawa, Ken
Journal of publication	Dalton transactions (Cambridge, England : 2003)
Year of publication	2024
Journal volume	53
Journal issue	7
Pages of publication	2929 - 2936
a	10.4512 ± 0.0002 Å
b	13.8345 ± 0.0003 Å
c	23.1447 ± 0.0004 Å
α	97.4885 ± 0.0016°
β	96.6648 ± 0.0017°
γ	101.852 ± 0.0017°
Cell volume	3211.79 ± 0.11 Å³
Cell temperature	100.02 ± 0.1 K
Ambient diffraction temperature	100.02 ± 0.1 K
Number of distinct elements	7
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.0578
Residual factor for significantly intense reflections	0.0527
Weighted residual factors for significantly intense reflections	0.1344
Weighted residual factors for all reflections included in the refinement	0.1378
Goodness-of-fit parameter for all reflections included in the refinement	1.022
Diffraction radiation probe	x-ray
Diffraction radiation wavelength	1.54184 Å
Diffraction radiation type	CuKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
290196 (current)	2024-03-04	cif/ Updating files of 7714671, 7714672 Original log message: Adding full bibliography for 7714671--7714672.cif.	7714672.cif
288233	2023-12-12	cif/ Adding structures of 7714671, 7714672 via cif-deposit CGI script.	7714672.cif