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Information card for entry 7714822
Preview
| Coordinates | 7714822.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C89 H78 Cl2 N4 O10 P4 Ru2 |
|---|---|
| Calculated formula | C89 H78 Cl2 N4 O10 P4 Ru2 |
| SMILES | [RuH]1([P](c2ccccc2)(c2ccccc2)c2ccccc2)([P](c2ccccc2)(c2ccccc2)c2ccccc2)([N](CCC[N]2[RuH]([P](c3ccccc3)(c3ccccc3)c3ccccc3)([P](c3ccccc3)(c3ccccc3)c3ccccc3)([n]3c(C=2)cccc3)C#[O])=Cc2[n]1cccc2)C#[O].Cl(=O)(=O)(=O)[O-].Cl(=O)(=O)(=O)[O-] |
| Title of publication | Metal-ligand synergy driven functionalisation of alkylene linked bis(aldimine) on a diruthenium(II) platform. Cyclisation <i>versus</i> oxygenation. |
| Authors of publication | Biswas, Mitrali; Dey, Sanchaita; Dhara, Suman; Panda, Sanjib; Lahiri, Goutam Kumar |
| Journal of publication | Dalton transactions (Cambridge, England : 2003) |
| Year of publication | 2024 |
| Journal volume | 53 |
| Journal issue | 5 |
| Pages of publication | 2167 - 2180 |
| a | 14.3963 ± 0.0003 Å |
| b | 21.3283 ± 0.0005 Å |
| c | 27.875 ± 0.0006 Å |
| α | 90° |
| β | 91.558 ± 0.002° |
| γ | 90° |
| Cell volume | 8555.8 ± 0.3 Å3 |
| Cell temperature | 273 ± 30 K |
| Ambient diffraction temperature | 273.15 K |
| Number of distinct elements | 7 |
| Space group number | 14 |
| Hermann-Mauguin space group symbol | P 1 21/c 1 |
| Hall space group symbol | -P 2ybc |
| Residual factor for all reflections | 0.0722 |
| Residual factor for significantly intense reflections | 0.0563 |
| Weighted residual factors for significantly intense reflections | 0.1501 |
| Weighted residual factors for all reflections included in the refinement | 0.1618 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.037 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 289487 (current) | 2024-02-04 | cif/ Updating files of 7714816, 7714817, 7714818, 7714819, 7714820, 7714821, 7714822 Original log message: Adding full bibliography for 7714816--7714822.cif. |
7714822.cif |
| 288496 | 2023-12-22 | cif/ Adding structures of 7714816, 7714817, 7714818, 7714819, 7714820, 7714821, 7714822 via cif-deposit CGI script. |
7714822.cif |
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