Crystallography Open Database

Information card for entry 7716230

Preview

Coordinates	7716230.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C24 H50 Ge N2 S Si4
Calculated formula	C24 H50 Ge N2 S Si4
SMILES	[Ge]1(=S)([Si]([Si](C)(C)C)([Si](C)(C)C)[Si](C)(C)C)[N](=C(N1C(C)(C)C)c1ccccc1)C(C)(C)C
Title of publication	Activation of carbon disulfide by a hypersilyl germylene.
Authors of publication	Ajithkumar, V. S.; Khilari, Nripen; Ghanwat, Pratiksha B.; Venugopal, Geethu; Koley, Debasis; Sen, Sakya S.
Journal of publication	Dalton transactions (Cambridge, England : 2003)
Year of publication	2024
Journal volume	53
Journal issue	26
Pages of publication	10814 - 10818
a	21.115 ± 0.002 Å
b	9.603 ± 0.0011 Å
c	16.2157 ± 0.0019 Å
α	90°
β	93.596 ± 0.004°
γ	90°
Cell volume	3281.5 ± 0.6 Å³
Cell temperature	100 ± 2 K
Ambient diffraction temperature	100 ± 2 K
Number of distinct elements	6
Space group number	7
Hermann-Mauguin space group symbol	P 1 c 1
Hall space group symbol	P -2yc
Residual factor for all reflections	0.0552
Residual factor for significantly intense reflections	0.0404
Weighted residual factors for significantly intense reflections	0.0869
Weighted residual factors for all reflections included in the refinement	0.0934
Goodness-of-fit parameter for all reflections included in the refinement	1.042
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
298703 (current)	2025-04-03	cif/7: Fixing Z values and formulae	7716230.cif
293039	2024-07-05	cif/ Updating files of 7716229, 7716230 Original log message: Adding full bibliography for 7716229--7716230.cif.	7716230.cif
292145	2024-06-01	cif/ Adding structures of 7716229, 7716230 via cif-deposit CGI script.	7716230.cif