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Information card for entry 7716590
Preview
| Coordinates | 7716590.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C25 H26.5 Cl2 Co N6 O11.75 |
|---|---|
| Calculated formula | C25 H26.5 Cl2 Co N6 O11.75 |
| Title of publication | Co(III) complexes of the pentadentate NHC ligand PY4Im: carbene-induced <i>trans</i> influences and the non-disappearing <sup>13</sup>C NMR peak. |
| Authors of publication | Ismael, Fouad; Fleming, Cassandra L.; Christopher, Timothy D.; Söhnel, Tilo; Zhou, Yuchen; Krenske, Elizabeth H.; Gahan, Lawrence R.; Blackman, Allan G. |
| Journal of publication | Dalton transactions (Cambridge, England : 2003) |
| Year of publication | 2024 |
| Journal volume | 53 |
| Journal issue | 30 |
| Pages of publication | 12688 - 12697 |
| a | 9.0704 ± 0.0002 Å |
| b | 12.1819 ± 0.0003 Å |
| c | 14.3572 ± 0.0003 Å |
| α | 99.034 ± 0.002° |
| β | 105.917 ± 0.002° |
| γ | 107.125 ± 0.002° |
| Cell volume | 1408.29 ± 0.06 Å3 |
| Cell temperature | 104 ± 1 K |
| Ambient diffraction temperature | 104 ± 1 K |
| Number of distinct elements | 6 |
| Space group number | 2 |
| Hermann-Mauguin space group symbol | P -1 |
| Hall space group symbol | -P 1 |
| Residual factor for all reflections | 0.052 |
| Residual factor for significantly intense reflections | 0.0474 |
| Weighted residual factors for significantly intense reflections | 0.1247 |
| Weighted residual factors for all reflections included in the refinement | 0.1271 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.097 |
| Diffraction radiation probe | x-ray |
| Diffraction radiation wavelength | 1.54184 Å |
| Diffraction radiation type | CuKα |
| Has coordinates | Yes |
| Has disorder | Yes |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 293863 (current) | 2024-08-05 | cif/ Updating files of 7716587, 7716588, 7716589, 7716590, 7716591, 7716592, 7716593, 7716594 Original log message: Adding full bibliography for 7716587--7716594.cif. |
7716590.cif |
| 293373 | 2024-07-12 | cif/ Adding structures of 7716587, 7716588, 7716589, 7716590, 7716591, 7716592, 7716593, 7716594 via cif-deposit CGI script. |
7716590.cif |
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Users of the data should acknowledge the original authors of the
structural data.