#------------------------------------------------------------------------------
#$Date: 2021-07-16 11:45:28 +0300 (Fri, 16 Jul 2021) $
#$Revision: 267590 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/56/41/1564182.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1564182
loop_
_publ_author_name
'Zhao, Jiao-Jiao'
'Liu, Peng-Yu'
'Dong, Zhen-Peng'
'Liu, Zhi-Liang'
'Wang, Yan-Qin'
_publ_section_title
;
 Eu(III)-organic framework as a multi-responsive photoluminescence sensor
 for efficient detection of 1-naphthol, Fe3+ and MnO4− in water
;
_journal_name_full               'Inorganica Chimica Acta'
_journal_page_first              119843
_journal_paper_doi               10.1016/j.ica.2020.119843
_journal_volume                  511
_journal_year                    2020
_chemical_formula_sum            'C42 H34 Eu3 N2 O21'
_chemical_formula_weight         1358.59
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   mixed
_cell_angle_alpha                104.512(2)
_cell_angle_beta                 93.874(3)
_cell_angle_gamma                101.256(3)
_cell_formula_units_Z            2
_cell_length_a                   10.8689(18)
_cell_length_b                   12.278(2)
_cell_length_c                   16.906(3)
_cell_measurement_reflns_used    5099
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      27.56
_cell_measurement_theta_min      2.16
_cell_volume                     2125.9(6)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.941
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0222
_diffrn_reflns_av_unetI/netI     0.0491
_diffrn_reflns_Laue_measured_fraction_full 0.991
_diffrn_reflns_Laue_measured_fraction_max 0.941
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -7
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            12937
_diffrn_reflns_point_group_measured_fraction_full 0.991
_diffrn_reflns_point_group_measured_fraction_max 0.941
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.622
_diffrn_reflns_theta_min         2.303
_exptl_absorpt_coefficient_mu    4.462
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.122
_exptl_crystal_description       block
_exptl_crystal_F_000             1314
_exptl_crystal_size_max          0.240
_exptl_crystal_size_mid          0.230
_exptl_crystal_size_min          0.220
_refine_diff_density_max         2.452
_refine_diff_density_min         -1.199
_refine_diff_density_rms         0.152
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.020
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     617
_refine_ls_number_reflns         9281
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.020
_refine_ls_R_factor_all          0.0444
_refine_ls_R_factor_gt           0.0335
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0264P)²+3.2857P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0683
_refine_ls_wR_factor_ref         0.0725
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                7798
_reflns_number_total             9281
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            ICA-2020-511-119843.cif
_cod_data_source_block           1
_cod_original_cell_volume        2126.0(6)
_cod_database_code               1564182
_shelx_space_group_comment
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;
_shelx_estimated_absorpt_t_min   0.414
_shelx_estimated_absorpt_t_max   0.440
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C43 C 0.8037(9) 1.2467(7) 0.6277(5) 0.072(3) Uani 1 1 d . . . . .
H43A H 0.8219 1.3192 0.6691 0.108 Uiso 1 1 calc R U . . .
H43B H 0.7159 1.2109 0.6236 0.108 Uiso 1 1 calc R U . . .
H43C H 0.8544 1.1973 0.6424 0.108 Uiso 1 1 calc R U . . .
C1 C -0.0294(5) 0.3075(4) 0.2793(3) 0.0196(11) Uani 1 1 d . . . . .
C2 C 0.0965(5) 0.3593(4) 0.2572(3) 0.0198(11) Uani 1 1 d . . . . .
C3 C 0.1114(5) 0.4608(5) 0.2345(4) 0.0291(13) Uani 1 1 d . . . . .
H3A H 0.0443 0.4974 0.2336 0.035 Uiso 1 1 calc R U . . .
C4 C 0.2265(5) 0.5084(4) 0.2129(3) 0.0264(12) Uani 1 1 d . . . . .
H4A H 0.2347 0.5743 0.1943 0.032 Uiso 1 1 calc R U . . .
C5 C 0.3287(5) 0.4589(4) 0.2188(3) 0.0190(10) Uani 1 1 d . . . . .
C6 C 0.3145(5) 0.3578(5) 0.2429(4) 0.0346(15) Uani 1 1 d . . . . .
H6A H 0.3834 0.3243 0.2477 0.042 Uiso 1 1 calc R U . . .
C7 C 0.1984(5) 0.3070(5) 0.2597(4) 0.0340(14) Uani 1 1 d . . . . .
H7A H 0.1881 0.2369 0.2729 0.041 Uiso 1 1 calc R U . . .
C8 C 0.4544(5) 0.5173(4) 0.2015(3) 0.0209(11) Uani 1 1 d . . . . .
C9 C -0.0750(5) 0.8746(4) 0.2410(3) 0.0209(11) Uani 1 1 d . . . . .
C10 C 0.0621(5) 0.8867(4) 0.2278(3) 0.0188(10) Uani 1 1 d . . . . .
C11 C 0.1493(5) 0.9897(4) 0.2632(3) 0.0268(12) Uani 1 1 d . . . . .
H11A H 0.1232 1.0516 0.2963 0.032 Uiso 1 1 calc R U . . .
C12 C 0.2742(5) 1.0010(4) 0.2496(3) 0.0270(12) Uani 1 1 d . . . . .
H12A H 0.3311 1.0709 0.2730 0.032 Uiso 1 1 calc R U . . .
C13 C 0.3162(5) 0.9094(4) 0.2015(3) 0.0197(11) Uani 1 1 d . . . . .
C14 C 0.2288(5) 0.8065(4) 0.1646(3) 0.0274(12) Uani 1 1 d . . . . .
H14A H 0.2548 0.7448 0.1311 0.033 Uiso 1 1 calc R U . . .
C15 C 0.1038(5) 0.7964(4) 0.1779(3) 0.0254(12) Uani 1 1 d . . . . .
H15A H 0.0462 0.7275 0.1528 0.030 Uiso 1 1 calc R U . . .
C16 C 0.4539(5) 0.9192(4) 0.1902(3) 0.0189(10) Uani 1 1 d . . . . .
C17 C 0.4048(5) 0.6916(4) 0.6113(3) 0.0236(11) Uani 1 1 d . . . . .
C18 C 0.4653(5) 0.7332(4) 0.5445(3) 0.0200(11) Uani 1 1 d . . . . .
C19 C 0.4777(5) 0.6559(4) 0.4720(3) 0.0267(12) Uani 1 1 d . . . . .
H19A H 0.4518 0.5771 0.4659 0.032 Uiso 1 1 calc R U . . .
C20 C 0.5282(5) 0.6941(4) 0.4085(3) 0.0253(12) Uani 1 1 d . . . . .
H20A H 0.5346 0.6414 0.3596 0.030 Uiso 1 1 calc R U . . .
C21 C 0.5696(5) 0.8122(4) 0.4181(3) 0.0211(11) Uani 1 1 d . . . . .
C22 C 0.5634(5) 0.8890(4) 0.4924(3) 0.0244(12) Uani 1 1 d . . . . .
H22A H 0.5957 0.9674 0.5002 0.029 Uiso 1 1 calc R U . . .
C23 C 0.5097(5) 0.8508(4) 0.5554(3) 0.0223(11) Uani 1 1 d . . . . .
H23A H 0.5035 0.9033 0.6045 0.027 Uiso 1 1 calc R U . . .
C24 C 0.6201(5) 0.8562(5) 0.3483(3) 0.0222(11) Uani 1 1 d . . . . .
C25 C 0.6070(5) 0.1944(4) 0.1347(3) 0.0230(11) Uani 1 1 d . . . . .
C26 C 0.5513(6) 0.0952(5) 0.0649(3) 0.0295(13) Uani 1 1 d . . . . .
C27 C 0.4205(6) 0.0512(5) 0.0511(3) 0.0307(13) Uani 1 1 d . . . . .
H27A H 0.3682 0.0867 0.0855 0.037 Uiso 1 1 calc R U . . .
C28 C 0.3693(6) -0.0439(5) -0.0129(3) 0.0300(13) Uani 1 1 d . . . . .
H28 H 0.2826 -0.0740 -0.0217 0.036 Uiso 1 1 calc R U . . .
C29 C 0.7967(5) 0.5031(4) 0.1007(3) 0.0201(11) Uani 1 1 d . . . . .
C30 C 0.9005(5) 0.4994(4) 0.0468(3) 0.0174(10) Uani 1 1 d . . . . .
C31 C 0.9252(5) 0.5796(4) 0.0022(3) 0.0244(12) Uani 1 1 d . . . . .
H31A H 0.8746 0.6328 0.0032 0.029 Uiso 1 1 calc R U . . .
C32 C 1.0259(5) 0.5805(4) -0.0441(3) 0.0242(12) Uani 1 1 d . . . . .
H32 H 1.0437 0.6353 -0.0734 0.029 Uiso 1 1 calc R U . . .
C33 C 0.7934(5) 0.9011(4) 0.0772(3) 0.0199(11) Uani 1 1 d . . . . .
C34 C 0.9001(5) 0.9532(4) 0.0376(3) 0.0191(10) Uani 1 1 d . . . . .
C35 C 0.9218(5) 0.8949(5) -0.0395(3) 0.0294(13) Uani 1 1 d . . . . .
H35A H 0.8693 0.8240 -0.0667 0.035 Uiso 1 1 calc R U . . .
C36 C 1.0217(5) 0.9415(5) -0.0768(3) 0.0271(12) Uani 1 1 d . . . . .
H36 H 1.0359 0.9013 -0.1286 0.033 Uiso 1 1 calc R U . . .
O21 O 0.8059(4) 0.5867(3) 0.3489(3) 0.0420(11) Uani 1 1 d . . . . .
C38 C 0.8382(6) 0.6921(5) 0.3789(4) 0.0357(14) Uani 1 1 d . . . . .
H38 H 0.8546 0.7377 0.3428 0.043 Uiso 1 1 calc R U . . .
N2 N 0.8511(5) 0.7438(4) 0.4566(3) 0.0357(12) Uani 1 1 d . . . . .
C40 C 0.8220(8) 0.6822(7) 0.5187(4) 0.064(2) Uani 1 1 d . . . . .
H40A H 0.8378 0.7361 0.5722 0.095 Uiso 1 1 calc R U . . .
H40B H 0.7347 0.6427 0.5081 0.095 Uiso 1 1 calc R U . . .
H40C H 0.8744 0.6272 0.5166 0.095 Uiso 1 1 calc R U . . .
C41 C 0.8890(7) 0.8697(6) 0.4851(5) 0.066(2) Uani 1 1 d . . . . .
H41A H 0.8941 0.8938 0.5441 0.099 Uiso 1 1 calc R U . . .
H41B H 0.9702 0.8951 0.4686 0.099 Uiso 1 1 calc R U . . .
H41C H 0.8278 0.9029 0.4614 0.099 Uiso 1 1 calc R U . . .
C42 C 0.8140(6) 1.1770(6) 0.4831(4) 0.0438(16) Uani 1 1 d . . . . .
H42 H 0.7825 1.1046 0.4904 0.053 Uiso 1 1 calc R U . . .
C44 C 0.8721(8) 1.3835(6) 0.5462(5) 0.058(2) Uani 1 1 d . . . . .
H44A H 0.8795 1.4336 0.6007 0.087 Uiso 1 1 calc R U . . .
H44B H 0.9525 1.3942 0.5256 0.087 Uiso 1 1 calc R U . . .
H44C H 0.8108 1.4016 0.5108 0.087 Uiso 1 1 calc R U . . .
Eu1 Eu 0.74703(2) 1.07735(2) 0.27373(2) 0.01336(6) Uani 1 1 d . . . . .
Eu2 Eu 0.63275(2) 0.72057(2) 0.14105(2) 0.01391(6) Uani 1 1 d . . . . .
Eu3 Eu 0.70277(2) 0.40206(2) 0.26314(2) 0.01630(6) Uani 1 1 d . . . . .
N1 N 0.8326(5) 1.2661(4) 0.5483(3) 0.0394(13) Uani 1 1 d . . . . .
O1 O -0.0552(3) 0.2004(3) 0.2704(2) 0.0233(8) Uani 1 1 d . . . . .
O2 O -0.1017(3) 0.3739(3) 0.3038(2) 0.0259(8) Uani 1 1 d . . . . .
O3 O 0.4551(3) 0.5833(3) 0.1550(2) 0.0264(8) Uani 1 1 d . . . . .
O4 O 0.5543(3) 0.5020(3) 0.2359(2) 0.0261(8) Uani 1 1 d . . . . .
O5 O -0.1504(3) 0.7815(3) 0.2033(2) 0.0260(8) Uani 1 1 d . . . . .
O6 O -0.1051(3) 0.9591(3) 0.2894(2) 0.0254(8) Uani 1 1 d . . . . .
O7 O 0.5292(3) 1.0113(3) 0.2271(2) 0.0258(8) Uani 1 1 d . . . . .
O8 O 0.4841(3) 0.8328(3) 0.1450(2) 0.0271(9) Uani 1 1 d . . . . .
O9 O 0.3908(5) 0.5868(3) 0.6088(3) 0.0449(12) Uani 1 1 d . . . . .
O10 O 0.3670(4) 0.7595(3) 0.6689(2) 0.0282(9) Uani 1 1 d . . . . .
O11 O 0.6193(4) 0.7840(3) 0.2816(2) 0.0298(9) Uani 1 1 d . . . . .
O12 O 0.6585(4) 0.9636(3) 0.3615(2) 0.0290(9) Uani 1 1 d . . . . .
O13 O 0.7094(3) 0.1994(3) 0.1780(2) 0.0191(7) Uani 1 1 d . . . . .
O14 O 0.5492(4) 0.2759(3) 0.1518(3) 0.0400(11) Uani 1 1 d . . . . .
O15 O 0.8003(4) 0.4502(4) 0.1555(2) 0.0354(10) Uani 1 1 d . . . . .
O16 O 0.7129(3) 0.5565(3) 0.0894(2) 0.0236(8) Uani 1 1 d . . . . .
O17 O 0.7358(3) 0.7988(3) 0.0425(2) 0.0257(8) Uani 1 1 d . . . . .
O18 O 0.7663(3) 0.9571(3) 0.1446(2) 0.0236(8) Uani 1 1 d . . . . .
O19 O 0.8347(4) 1.1819(4) 0.4143(2) 0.0402(11) Uani 1 1 d . . . . .
O20 O 0.5068(4) 0.6364(3) 0.0036(2) 0.0333(10) Uani 1 1 d . . . . .
H20B H 0.5138 0.6849 -0.0224 0.050 Uiso 1 1 calc R U . . .
H20O H 0.443(7) 0.582(7) -0.014(5) 0.07(3) Uiso 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 C43 H43A 109.5 . .
N1 C43 H43B 109.5 . .
H43A C43 H43B 109.5 . .
N1 C43 H43C 109.5 . .
H43A C43 H43C 109.5 . .
H43B C43 H43C 109.5 . .
O2 C1 O1 124.9(5) . .
O2 C1 C2 117.7(4) . .
O1 C1 C2 117.4(4) . .
C3 C2 C7 119.2(5) . .
C3 C2 C1 119.6(5) . .
C7 C2 C1 121.2(4) . .
C2 C3 C4 120.0(5) . .
C2 C3 H3A 120.0 . .
C4 C3 H3A 120.0 . .
C5 C4 C3 120.6(5) . .
C5 C4 H4A 119.7 . .
C3 C4 H4A 119.7 . .
C4 C5 C6 119.5(5) . .
C4 C5 C8 119.3(4) . .
C6 C5 C8 121.2(5) . .
C7 C6 C5 119.9(5) . .
C7 C6 H6A 120.0 . .
C5 C6 H6A 120.0 . .
C6 C7 C2 120.7(5) . .
C6 C7 H7A 119.7 . .
C2 C7 H7A 119.7 . .
O3 C8 O4 123.1(5) . .
O3 C8 C5 117.7(5) . .
O4 C8 C5 119.2(4) . .
O3 C8 Eu2 36.1(2) . .
O4 C8 Eu2 87.7(3) . .
C5 C8 Eu2 151.5(3) . .
O5 C9 O6 125.1(5) . .
O5 C9 C10 117.7(5) . .
O6 C9 C10 117.2(4) . .
C15 C10 C11 118.3(5) . .
C15 C10 C9 120.8(4) . .
C11 C10 C9 120.9(5) . .
C12 C11 C10 120.7(5) . .
C12 C11 H11A 119.7 . .
C10 C11 H11A 119.7 . .
C11 C12 C13 120.9(5) . .
C11 C12 H12A 119.6 . .
C13 C12 H12A 119.6 . .
C12 C13 C14 118.8(5) . .
C12 C13 C16 121.1(4) . .
C14 C13 C16 120.1(5) . .
C15 C14 C13 119.9(5) . .
C15 C14 H14A 120.1 . .
C13 C14 H14A 120.1 . .
C14 C15 C10 121.5(5) . .
C14 C15 H15A 119.3 . .
C10 C15 H15A 119.3 . .
O7 C16 O8 125.0(5) . .
O7 C16 C13 117.7(4) . .
O8 C16 C13 117.2(4) . .
O9 C17 O10 120.3(5) . .
O9 C17 C18 118.6(4) . .
O10 C17 C18 121.0(4) . .
O9 C17 Eu3 57.6(3) . 2_666
O10 C17 Eu3 62.8(3) . 2_666
C18 C17 Eu3 175.9(4) . 2_666
C19 C18 C23 119.7(4) . .
C19 C18 C17 120.6(4) . .
C23 C18 C17 119.7(4) . .
C20 C19 C18 120.8(5) . .
C20 C19 H19A 119.6 . .
C18 C19 H19A 119.6 . .
C19 C20 C21 119.7(5) . .
C19 C20 H20A 120.1 . .
C21 C20 H20A 120.1 . .
C22 C21 C20 119.3(4) . .
C22 C21 C24 120.1(4) . .
C20 C21 C24 120.6(5) . .
C21 C22 C23 120.9(5) . .
C21 C22 H22A 119.5 . .
C23 C22 H22A 119.5 . .
C22 C23 C18 119.4(5) . .
C22 C23 H23A 120.3 . .
C18 C23 H23A 120.3 . .
O11 C24 O12 124.8(5) . .
O11 C24 C21 117.7(5) . .
O12 C24 C21 117.5(5) . .
O14 C25 O13 120.4(5) . .
O14 C25 C26 117.8(5) . .
O13 C25 C26 121.8(5) . .
O14 C25 Eu3 56.9(3) . .
O13 C25 Eu3 63.5(3) . .
C26 C25 Eu3 174.1(4) . .
C28 C26 C27 120.5(5) 2_655 .
C28 C26 C25 119.0(5) 2_655 .
C27 C26 C25 120.4(5) . .
C28 C27 C26 120.1(5) . .
C28 C27 H27A 119.9 . .
C26 C27 H27A 119.9 . .
C27 C28 C26 119.3(6) . 2_655
C27 C28 H28 120.3 . .
C26 C28 H28 120.3 2_655 .
O16 C29 O15 124.1(5) . .
O16 C29 C30 119.8(4) . .
O15 C29 C30 116.2(4) . .
C32 C30 C31 120.1(5) 2_765 .
C32 C30 C29 120.3(4) 2_765 .
C31 C30 C29 119.6(4) . .
C30 C31 C32 119.7(5) . .
C30 C31 H31A 120.1 . .
C32 C31 H31A 120.1 . .
C30 C32 C31 120.2(5) 2_765 .
C30 C32 H32 119.9 2_765 .
C31 C32 H32 119.9 . .
O17 C33 O18 121.8(4) . .
O17 C33 C34 117.7(4) . .
O18 C33 C34 120.4(4) . .
O17 C33 Eu2 48.0(2) . .
O18 C33 Eu2 75.8(3) . .
C34 C33 Eu2 157.4(3) . .
C36 C34 C35 119.1(4) 2_775 .
C36 C34 C33 121.2(4) 2_775 .
C35 C34 C33 119.7(5) . .
C34 C35 C36 120.4(5) . .
C34 C35 H35A 119.8 . .
C36 C35 H35A 119.8 . .
C34 C36 C35 120.4(5) 2_775 .
C34 C36 H36 119.8 2_775 .
C35 C36 H36 119.8 . .
C38 O21 Eu3 162.2(4) . .
O21 C38 N2 125.0(6) . .
O21 C38 H38 117.5 . .
N2 C38 H38 117.5 . .
C38 N2 C40 122.6(6) . .
C38 N2 C41 120.3(6) . .
C40 N2 C41 117.1(6) . .
N2 C40 H40A 109.5 . .
N2 C40 H40B 109.5 . .
H40A C40 H40B 109.5 . .
N2 C40 H40C 109.5 . .
H40A C40 H40C 109.5 . .
H40B C40 H40C 109.5 . .
N2 C41 H41A 109.5 . .
N2 C41 H41B 109.5 . .
H41A C41 H41B 109.5 . .
N2 C41 H41C 109.5 . .
H41A C41 H41C 109.5 . .
H41B C41 H41C 109.5 . .
O19 C42 N1 125.2(6) . .
O19 C42 H42 117.4 . .
N1 C42 H42 117.4 . .
N1 C44 H44A 109.5 . .
N1 C44 H44B 109.5 . .
H44A C44 H44B 109.5 . .
N1 C44 H44C 109.5 . .
H44A C44 H44C 109.5 . .
H44B C44 H44C 109.5 . .
O18 Eu1 O7 82.75(12) . .
O18 Eu1 O1 89.77(12) . 1_665
O7 Eu1 O1 149.28(13) . 1_665
O18 Eu1 O12 110.39(12) . .
O7 Eu1 O12 73.03(13) . .
O1 Eu1 O12 136.91(13) 1_665 .
O18 Eu1 O6 69.80(12) . 1_655
O7 Eu1 O6 126.22(12) . 1_655
O1 Eu1 O6 77.65(12) 1_665 1_655
O12 Eu1 O6 74.72(12) . 1_655
O18 Eu1 O19 150.38(14) . .
O7 Eu1 O19 124.70(14) . .
O1 Eu1 O19 71.79(13) 1_665 .
O12 Eu1 O19 72.76(14) . .
O6 Eu1 O19 83.44(14) 1_655 .
O18 Eu1 O13 78.01(11) . 1_565
O7 Eu1 O13 76.98(12) . 1_565
O1 Eu1 O13 72.32(11) 1_665 1_565
O12 Eu1 O13 147.28(12) . 1_565
O6 Eu1 O13 135.57(11) 1_655 1_565
O19 Eu1 O13 115.99(13) . 1_565
O18 Eu1 O10 138.00(12) . 2_676
O7 Eu1 O10 71.24(12) . 2_676
O1 Eu1 O10 96.09(12) 1_665 2_676
O12 Eu1 O10 93.18(12) . 2_676
O6 Eu1 O10 151.99(12) 1_655 2_676
O19 Eu1 O10 68.76(14) . 2_676
O13 Eu1 O10 64.58(11) 1_565 2_676
O18 Eu1 Eu3 113.17(8) . 1_565
O7 Eu1 Eu3 87.02(9) . 1_565
O1 Eu1 Eu3 68.62(9) 1_665 1_565
O12 Eu1 Eu3 128.82(9) . 1_565
O6 Eu1 Eu3 145.99(8) 1_655 1_565
O19 Eu1 Eu3 82.10(11) . 1_565
O13 Eu1 Eu3 35.56(7) 1_565 1_565
O10 Eu1 Eu3 35.70(8) 2_676 1_565
O18 Eu1 Eu2 41.60(8) . .
O7 Eu1 Eu2 64.83(9) . .
O1 Eu1 Eu2 124.90(8) 1_665 .
O12 Eu1 Eu2 69.25(9) . .
O6 Eu1 Eu2 63.95(9) 1_655 .
O19 Eu1 Eu2 134.90(10) . .
O13 Eu1 Eu2 109.11(7) 1_565 .
O10 Eu1 Eu2 135.70(9) 2_676 .
Eu3 Eu1 Eu2 141.672(11) 1_565 .
O8 Eu2 O11 77.36(14) . .
O8 Eu2 O16 154.14(13) . .
O11 Eu2 O16 120.10(13) . .
O8 Eu2 O17 92.33(13) . .
O11 Eu2 O17 135.92(12) . .
O16 Eu2 O17 86.85(12) . .
O8 Eu2 O3 81.79(13) . .
O11 Eu2 O3 79.09(13) . .
O16 Eu2 O3 83.21(12) . .
O17 Eu2 O3 142.44(13) . .
O8 Eu2 O5 127.28(12) . 1_655
O11 Eu2 O5 75.73(13) . 1_655
O16 Eu2 O5 77.74(12) . 1_655
O17 Eu2 O5 77.40(13) . 1_655
O3 Eu2 O5 134.56(12) . 1_655
O8 Eu2 O20 77.46(14) . .
O11 Eu2 O20 144.01(14) . .
O16 Eu2 O20 77.95(13) . .
O17 Eu2 O20 70.30(13) . .
O3 Eu2 O20 72.21(13) . .
O5 Eu2 O20 140.25(14) 1_655 .
O8 Eu2 O18 72.03(11) . .
O11 Eu2 O18 89.33(11) . .
O16 Eu2 O18 123.29(11) . .
O17 Eu2 O18 47.18(10) . .
O3 Eu2 O18 153.17(11) . .
O5 Eu2 O18 63.24(11) 1_655 .
O20 Eu2 O18 106.74(12) . .
O8 Eu2 C33 85.06(13) . .
O11 Eu2 C33 112.58(13) . .
O16 Eu2 C33 102.98(13) . .
O17 Eu2 C33 23.36(12) . .
O3 Eu2 C33 160.04(13) . .
O5 Eu2 C33 65.34(13) 1_655 .
O20 Eu2 C33 90.33(14) . .
O18 Eu2 C33 24.34(11) . .
O8 Eu2 C8 95.27(13) . .
O11 Eu2 C8 70.07(13) . .
O16 Eu2 C8 75.60(12) . .
O17 Eu2 C8 154.01(12) . .
O3 Eu2 C8 18.29(13) . .
O5 Eu2 C8 116.27(13) 1_655 .
O20 Eu2 C8 87.15(13) . .
O18 Eu2 C8 158.02(11) . .
C33 Eu2 C8 177.32(13) . .
O8 Eu2 Eu1 62.21(9) . .
O11 Eu2 Eu1 58.13(9) . .
O16 Eu2 Eu1 142.21(9) . .
O17 Eu2 Eu1 79.00(8) . .
O3 Eu2 Eu1 127.88(9) . .
O5 Eu2 Eu1 65.08(8) 1_655 .
O20 Eu2 Eu1 127.62(10) . .
O18 Eu2 Eu1 31.85(6) . .
C33 Eu2 Eu1 56.11(10) . .
C8 Eu2 Eu1 126.34(9) . .
O4 Eu3 O2 157.64(12) . 1_655
O4 Eu3 O15 87.34(13) . .
O2 Eu3 O15 83.78(13) 1_655 .
O4 Eu3 O21 82.00(14) . .
O2 Eu3 O21 77.30(14) 1_655 .
O15 Eu3 O21 88.52(16) . .
O4 Eu3 O14 71.99(13) . .
O2 Eu3 O14 126.64(13) 1_655 .
O15 Eu3 O14 82.22(16) . .
O21 Eu3 O14 152.69(14) . .
O4 Eu3 O9 83.30(14) . 2_666
O2 Eu3 O9 99.70(15) 1_655 2_666
O15 Eu3 O9 162.97(14) . 2_666
O21 Eu3 O9 76.14(15) . 2_666
O14 Eu3 O9 108.12(16) . 2_666
O4 Eu3 O10 117.04(13) . 2_666
O2 Eu3 O10 80.72(13) 1_655 2_666
O15 Eu3 O10 144.87(13) . 2_666
O21 Eu3 O10 118.11(14) . 2_666
O14 Eu3 O10 82.15(14) . 2_666
O9 Eu3 O10 51.84(12) 2_666 2_666
O4 Eu3 O13 124.22(12) . .
O2 Eu3 O13 74.57(12) 1_655 .
O15 Eu3 O13 81.05(13) . .
O21 Eu3 O13 150.85(13) . .
O14 Eu3 O13 52.48(12) . .
O9 Eu3 O13 115.97(12) 2_666 .
O10 Eu3 O13 64.51(11) 2_666 .
O4 Eu3 C25 97.86(14) . .
O2 Eu3 C25 100.68(14) 1_655 .
O15 Eu3 C25 79.77(15) . .
O21 Eu3 C25 168.27(15) . .
O14 Eu3 C25 26.09(14) . .
O9 Eu3 C25 115.54(15) 2_666 .
O10 Eu3 C25 72.48(13) 2_666 .
O13 Eu3 C25 26.42(12) . .
O4 Eu3 C17 100.27(14) . 2_666
O2 Eu3 C17 90.85(14) 1_655 2_666
O15 Eu3 C17 170.80(14) . 2_666
O21 Eu3 C17 97.61(15) . 2_666
O14 Eu3 C17 95.13(16) . 2_666
O9 Eu3 C17 25.76(13) 2_666 2_666
O10 Eu3 C17 26.09(12) 2_666 2_666
O13 Eu3 C17 90.33(13) . 2_666
C25 Eu3 C17 93.96(15) . 2_666
O4 Eu3 Eu1 142.81(9) . 1_545
O2 Eu3 Eu1 59.47(9) 1_655 1_545
O15 Eu3 Eu1 109.48(10) . 1_545
O21 Eu3 Eu1 129.64(11) . 1_545
O14 Eu3 Eu1 77.62(10) . 1_545
O9 Eu3 Eu1 86.33(9) 2_666 1_545
O10 Eu3 Eu1 36.14(8) 2_666 1_545
O13 Eu3 Eu1 35.04(8) . 1_545
C25 Eu3 Eu1 55.48(10) . 1_545
C17 Eu3 Eu1 61.32(10) 2_666 1_545
C42 N1 C44 124.1(6) . .
C42 N1 C43 119.0(6) . .
C44 N1 C43 116.8(6) . .
C1 O1 Eu1 129.0(3) . 1_445
C1 O2 Eu3 139.0(3) . 1_455
C8 O3 Eu2 125.6(3) . .
C8 O4 Eu3 156.9(3) . .
C9 O5 Eu2 137.4(3) . 1_455
C9 O6 Eu1 133.3(3) . 1_455
C16 O7 Eu1 138.5(3) . .
C16 O8 Eu2 141.3(3) . .
C17 O9 Eu3 96.6(3) . 2_666
C17 O10 Eu3 91.1(3) . 2_666
C17 O10 Eu1 153.2(3) . 2_676
Eu3 O10 Eu1 108.17(12) 2_666 2_676
C24 O11 Eu2 156.0(3) . .
C24 O12 Eu1 131.1(3) . .
C25 O13 Eu1 127.9(3) . 1_545
C25 O13 Eu3 90.0(3) . .
Eu1 O13 Eu3 109.40(12) 1_545 .
C25 O14 Eu3 97.0(3) . .
C29 O15 Eu3 145.2(3) . .
C29 O16 Eu2 145.3(3) . .
C33 O17 Eu2 108.6(3) . .
C33 O18 Eu1 171.4(3) . .
C33 O18 Eu2 79.9(3) . .
Eu1 O18 Eu2 106.55(11) . .
C42 O19 Eu1 137.3(4) . .
Eu2 O20 H20B 109.5 . .
Eu2 O20 H20O 132(5) . .
H20B O20 H20O 114.1 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C43 N1 1.465(9) .
C43 H43A 0.9600 .
C43 H43B 0.9600 .
C43 H43C 0.9600 .
C1 O2 1.256(6) .
C1 O1 1.258(6) .
C1 C2 1.505(6) .
C2 C3 1.377(7) .
C2 C7 1.387(7) .
C3 C4 1.386(7) .
C3 H3A 0.9300 .
C4 C5 1.376(7) .
C4 H4A 0.9300 .
C5 C6 1.385(7) .
C5 C8 1.498(6) .
C6 C7 1.376(7) .
C6 H6A 0.9300 .
C7 H7A 0.9300 .
C8 O3 1.261(6) .
C8 O4 1.266(6) .
C8 Eu2 3.269(5) .
C9 O5 1.259(6) .
C9 O6 1.263(6) .
C9 C10 1.506(7) .
C10 C15 1.389(7) .
C10 C11 1.390(7) .
C11 C12 1.378(7) .
C11 H11A 0.9300 .
C12 C13 1.388(7) .
C12 H12A 0.9300 .
C13 C14 1.394(7) .
C13 C16 1.506(7) .
C14 C15 1.378(7) .
C14 H14A 0.9300 .
C15 H15A 0.9300 .
C16 O7 1.247(6) .
C16 O8 1.256(6) .
C17 O9 1.255(6) .
C17 O10 1.262(6) .
C17 C18 1.493(7) .
C17 Eu3 2.868(5) 2_666
C18 C19 1.383(7) .
C18 C23 1.390(7) .
C19 C20 1.379(7) .
C19 H19A 0.9300 .
C20 C21 1.397(7) .
C20 H20A 0.9300 .
C21 C22 1.383(7) .
C21 C24 1.509(6) .
C22 C23 1.386(7) .
C22 H22A 0.9300 .
C23 H23A 0.9300 .
C24 O11 1.246(6) .
C24 O12 1.259(6) .
C25 O14 1.267(6) .
C25 O13 1.273(6) .
C25 C26 1.463(7) .
C25 Eu3 2.861(5) .
C26 C28 1.396(8) 2_655
C26 C27 1.400(8) .
C27 C28 1.370(7) .
C27 H27A 0.9300 .
C28 C26 1.396(8) 2_655
C28 H28 0.9300 .
C29 O16 1.252(6) .
C29 O15 1.261(6) .
C29 C30 1.497(6) .
C30 C32 1.377(7) 2_765
C30 C31 1.380(7) .
C31 C32 1.388(7) .
C31 H31A 0.9300 .
C32 C30 1.377(7) 2_765
C32 H32 0.9300 .
C33 O17 1.260(6) .
C33 O18 1.261(6) .
C33 C34 1.494(6) .
C33 Eu2 3.012(5) .
C34 C36 1.378(7) 2_775
C34 C35 1.381(7) .
C35 C36 1.391(7) .
C35 H35A 0.9300 .
C36 C34 1.378(7) 2_775
C36 H36 0.9300 .
O21 C38 1.235(7) .
O21 Eu3 2.375(4) .
C38 N2 1.292(8) .
C38 H38 0.9300 .
N2 C40 1.458(8) .
N2 C41 1.464(8) .
C40 H40A 0.9600 .
C40 H40B 0.9600 .
C40 H40C 0.9600 .
C41 H41A 0.9600 .
C41 H41B 0.9600 .
C41 H41C 0.9600 .
C42 O19 1.213(7) .
C42 N1 1.315(8) .
C42 H42 0.9300 .
C44 N1 1.432(8) .
C44 H44A 0.9600 .
C44 H44B 0.9600 .
C44 H44C 0.9600 .
Eu1 O18 2.357(3) .
Eu1 O7 2.359(3) .
Eu1 O1 2.387(3) 1_665
Eu1 O12 2.405(3) .
Eu1 O6 2.410(4) 1_655
Eu1 O19 2.428(4) .
Eu1 O13 2.528(3) 1_565
Eu1 O10 2.578(4) 2_676
Eu1 Eu3 4.1538(7) 1_565
Eu1 Eu2 4.2824(7) .
Eu2 O8 2.314(3) .
Eu2 O11 2.332(3) .
Eu2 O16 2.342(3) .
Eu2 O17 2.363(3) .
Eu2 O3 2.369(3) .
Eu2 O5 2.409(4) 1_655
Eu2 O20 2.482(4) .
Eu2 O18 2.966(3) .
Eu3 O4 2.297(4) .
Eu3 O2 2.306(4) 1_655
Eu3 O15 2.311(3) .
Eu3 O14 2.415(4) .
Eu3 O9 2.438(4) 2_666
Eu3 O10 2.551(3) 2_666
Eu3 O13 2.561(3) .
Eu3 C17 2.868(5) 2_666
Eu3 Eu1 4.1538(7) 1_545
O1 Eu1 2.387(3) 1_445
O2 Eu3 2.306(4) 1_455
O5 Eu2 2.409(4) 1_455
O6 Eu1 2.410(4) 1_455
O9 Eu3 2.438(4) 2_666
O10 Eu3 2.551(3) 2_666
O10 Eu1 2.578(4) 2_676
O13 Eu1 2.528(3) 1_545
O20 H20B 0.8200 .
O20 H20O 0.84(8) .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O20 H20B O14 0.82 2.44 3.144(6) 145.0 2_665
O20 H20B O14 0.82 2.44 3.144(6) 145.0 2_665
O20 H20B O14 0.82 2.44 3.144(6) 145.0 2_665
O20 H20B O14 0.82 2.44 3.144(6) 145.0 2_665
O20 H20O O16 0.84(8) 2.21(8) 3.033(5) 165(7) 2_665
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
O2 C1 C2 C3 -24.1(7) . . . .
O1 C1 C2 C3 154.7(5) . . . .
O2 C1 C2 C7 155.6(5) . . . .
O1 C1 C2 C7 -25.6(7) . . . .
C7 C2 C3 C4 1.2(9) . . . .
C1 C2 C3 C4 -179.1(5) . . . .
C2 C3 C4 C5 -4.0(9) . . . .
C3 C4 C5 C6 2.9(9) . . . .
C3 C4 C5 C8 -175.2(5) . . . .
C4 C5 C6 C7 0.9(9) . . . .
C8 C5 C6 C7 178.9(5) . . . .
C5 C6 C7 C2 -3.6(10) . . . .
C3 C2 C7 C6 2.5(9) . . . .
C1 C2 C7 C6 -177.2(6) . . . .
C4 C5 C8 O3 -25.2(7) . . . .
C6 C5 C8 O3 156.8(5) . . . .
C4 C5 C8 O4 152.4(5) . . . .
C6 C5 C8 O4 -25.7(8) . . . .
C4 C5 C8 Eu2 -6.0(10) . . . .
C6 C5 C8 Eu2 176.0(5) . . . .
O5 C9 C10 C15 -2.2(7) . . . .
O6 C9 C10 C15 177.8(5) . . . .
O5 C9 C10 C11 175.8(5) . . . .
O6 C9 C10 C11 -4.3(7) . . . .
C15 C10 C11 C12 -0.7(8) . . . .
C9 C10 C11 C12 -178.8(5) . . . .
C10 C11 C12 C13 -1.1(9) . . . .
C11 C12 C13 C14 2.2(8) . . . .
C11 C12 C13 C16 -176.6(5) . . . .
C12 C13 C14 C15 -1.5(8) . . . .
C16 C13 C14 C15 177.3(5) . . . .
C13 C14 C15 C10 -0.3(9) . . . .
C11 C10 C15 C14 1.4(8) . . . .
C9 C10 C15 C14 179.4(5) . . . .
C12 C13 C16 O7 1.7(7) . . . .
C14 C13 C16 O7 -177.1(5) . . . .
C12 C13 C16 O8 -179.3(5) . . . .
C14 C13 C16 O8 1.9(7) . . . .
O9 C17 C18 C19 15.5(8) . . . .
O10 C17 C18 C19 -163.8(5) . . . .
O9 C17 C18 C23 -164.4(5) . . . .
O10 C17 C18 C23 16.3(8) . . . .
C23 C18 C19 C20 -3.2(9) . . . .
C17 C18 C19 C20 176.9(5) . . . .
C18 C19 C20 C21 1.3(9) . . . .
C19 C20 C21 C22 2.3(8) . . . .
C19 C20 C21 C24 -177.5(5) . . . .
C20 C21 C22 C23 -4.0(8) . . . .
C24 C21 C22 C23 175.8(5) . . . .
C21 C22 C23 C18 2.1(8) . . . .
C19 C18 C23 C22 1.5(8) . . . .
C17 C18 C23 C22 -178.6(5) . . . .
C22 C21 C24 O11 -177.4(5) . . . .
C20 C21 C24 O11 2.4(8) . . . .
C22 C21 C24 O12 1.7(8) . . . .
C20 C21 C24 O12 -178.5(5) . . . .
O14 C25 C26 C28 140.7(6) . . . 2_655
O13 C25 C26 C28 -40.0(8) . . . 2_655
O14 C25 C26 C27 -40.3(8) . . . .
O13 C25 C26 C27 139.0(5) . . . .
C28 C26 C27 C28 1.0(9) 2_655 . . .
C25 C26 C27 C28 -178.0(5) . . . .
C26 C27 C28 C26 -1.0(9) . . . 2_655
O16 C29 C30 C32 -163.8(5) . . . 2_765
O15 C29 C30 C32 16.0(7) . . . 2_765
O16 C29 C30 C31 18.7(7) . . . .
O15 C29 C30 C31 -161.5(5) . . . .
C32 C30 C31 C32 -1.1(9) 2_765 . . .
C29 C30 C31 C32 176.4(5) . . . .
C30 C31 C32 C30 1.1(9) . . . 2_765
O17 C33 C34 C36 -171.4(5) . . . 2_775
O18 C33 C34 C36 6.0(8) . . . 2_775
Eu2 C33 C34 C36 -126.2(8) . . . 2_775
O17 C33 C34 C35 8.1(8) . . . .
O18 C33 C34 C35 -174.5(5) . . . .
Eu2 C33 C34 C35 53.3(11) . . . .
C36 C34 C35 C36 0.4(9) 2_775 . . .
C33 C34 C35 C36 -179.1(5) . . . .
C34 C35 C36 C34 -0.4(10) . . . 2_775
Eu3 O21 C38 N2 134.3(12) . . . .
O21 C38 N2 C40 -3.2(10) . . . .
O21 C38 N2 C41 -179.5(6) . . . .
O19 C42 N1 C44 4.5(11) . . . .
O19 C42 N1 C43 -179.7(7) . . . .
O2 C1 O1 Eu1 10.9(7) . . . 1_445
C2 C1 O1 Eu1 -167.8(3) . . . 1_445
O1 C1 O2 Eu3 -62.5(7) . . . 1_455
C2 C1 O2 Eu3 116.2(5) . . . 1_455
O4 C8 O3 Eu2 -12.9(7) . . . .
C5 C8 O3 Eu2 164.5(3) . . . .
O3 C8 O4 Eu3 -114.3(8) . . . .
C5 C8 O4 Eu3 68.3(10) . . . .
Eu2 C8 O4 Eu3 -121.9(8) . . . .
O6 C9 O5 Eu2 34.6(8) . . . 1_455
C10 C9 O5 Eu2 -145.5(4) . . . 1_455
O5 C9 O6 Eu1 -57.5(7) . . . 1_455
C10 C9 O6 Eu1 122.6(4) . . . 1_455
O8 C16 O7 Eu1 -21.6(8) . . . .
C13 C16 O7 Eu1 157.4(4) . . . .
O7 C16 O8 Eu2 44.8(8) . . . .
C13 C16 O8 Eu2 -134.2(4) . . . .
O10 C17 O9 Eu3 -2.6(6) . . . 2_666
C18 C17 O9 Eu3 178.1(4) . . . 2_666
O9 C17 O10 Eu3 2.4(6) . . . 2_666
C18 C17 O10 Eu3 -178.3(5) . . . 2_666
O9 C17 O10 Eu1 -134.5(6) . . . 2_676
C18 C17 O10 Eu1 44.7(11) . . . 2_676
Eu3 C17 O10 Eu1 -137.0(8) 2_666 . . 2_676
O12 C24 O11 Eu2 -13.3(13) . . . .
C21 C24 O11 Eu2 165.7(6) . . . .
O11 C24 O12 Eu1 -1.2(8) . . . .
C21 C24 O12 Eu1 179.7(3) . . . .
O14 C25 O13 Eu1 111.4(5) . . . 1_545
C26 C25 O13 Eu1 -67.9(6) . . . 1_545
Eu3 C25 O13 Eu1 114.9(3) . . . 1_545
O14 C25 O13 Eu3 -3.6(5) . . . .
C26 C25 O13 Eu3 177.2(5) . . . .
O13 C25 O14 Eu3 3.8(5) . . . .
C26 C25 O14 Eu3 -176.9(4) . . . .
O16 C29 O15 Eu3 -0.7(10) . . . .
C30 C29 O15 Eu3 179.5(4) . . . .
O15 C29 O16 Eu2 72.1(8) . . . .
C30 C29 O16 Eu2 -108.1(6) . . . .
O18 C33 O17 Eu2 -18.8(6) . . . .
C34 C33 O17 Eu2 158.5(4) . . . .
O17 C33 O18 Eu2 14.3(5) . . . .
C34 C33 O18 Eu2 -162.9(5) . . . .
N1 C42 O19 Eu1 -147.9(5) . . . .
