#------------------------------------------------------------------------------
#$Date: 2016-02-20 02:53:41 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176768 $
#$URL: svn://www.crystallography.net/cod/cif/2/10/55/2105551.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2105551
loop_
_publ_author_name
'Hammond, R. P.'
'Barbier, J.'
_publ_section_title
;
 Monoclinic and Hexagonal Nepheline Structures of (Na~3/4~/K~1/4~)AlGeO₄
;
_journal_issue                   3
_journal_name_full               'Acta Crystallographica Section B'
_journal_page_first              211
_journal_page_last               220
_journal_paper_doi               10.1107/S0108768197013177
_journal_volume                  54
_journal_year                    1998
_chemical_formula_analytical     'Al0.976 Ge1.028 K0.180 Na0.777 O4'
_chemical_formula_structural     'Al0.97 Ge1.03 K0.19 Na0.78 O4'
_chemical_formula_sum            'Al0.97 Ge1.03 K0.19 Na0.78 O4'
_chemical_formula_weight         190.31
_chemical_name_systematic
;
β-sodium potassium aluminum germanate
;
_space_group_IT_number           173
_symmetry_cell_setting           hexagonal
_symmetry_space_group_name_Hall  'P 6c'
_symmetry_space_group_name_H-M   'P 63'
_audit_creation_method           SHELXL
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                120.00
_cell_formula_units_Z            8
_cell_length_a                   10.1640(10)
_cell_length_b                   10.1640(10)
_cell_length_c                   8.540(2)
_cell_measurement_reflns_used    20
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      30
_cell_measurement_theta_min      5
_cell_volume                     764.0(2)
_computing_molecular_graphics    'SHELXTL-Plus (Sheldrick, 1991)'
_computing_structure_refinement  'SHELXL-93 (Sheldrick, 1993)'
_computing_structure_solution    'SHELXS-86 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measurement_device       'Siemens R3m/V diffractometer'
_diffrn_measurement_method       θ-2θ
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           AgK\a
_diffrn_radiation_wavelength     .56086
_diffrn_reflns_av_R_equivalents  .0853
_diffrn_reflns_av_sigmaI/netI    .1496
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       0
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            6480
_diffrn_reflns_theta_max         30.06
_diffrn_reflns_theta_min         1.83
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 100
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    4.477
_exptl_absorpt_correction_T_max  .752
_exptl_absorpt_correction_T_min  .644
_exptl_absorpt_correction_type   'empirical \y-scans'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    3.294
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       'hexagonal prism'
_exptl_crystal_F_000             715
_exptl_crystal_size_max          .14
_exptl_crystal_size_mid          .07
_exptl_crystal_size_min          .06
_refine_diff_density_max         1.010
_refine_diff_density_min         -.893
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   .00(9)
_refine_ls_extinction_coef       .0028(3)
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_all   .709
_refine_ls_goodness_of_fit_obs   .903
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_parameters     90
_refine_ls_number_reflns         3060
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      .709
_refine_ls_restrained_S_obs      .903
_refine_ls_R_factor_all          .1176
_refine_ls_R_factor_obs          .0411
_refine_ls_shift/esd_max         -.001
_refine_ls_shift/esd_mean        .000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[σ²(Fo²)+(0.0109P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         .0665
_refine_ls_wR_factor_obs         .0560
_reflns_number_observed          1380
_reflns_number_total             3060
_reflns_observed_criterion       >2sigma(I)
_cod_data_source_file            br0065.cif
_cod_data_source_block           hexagonal
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 

The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'w =
1/[\s^2^(Fo^2^)+(0.0109P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3' was
changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to 'w =
1/[\s^2^(Fo^2^)+(0.0109P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_database_code               2105551
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'-x, -y, z+1/2'
'y, -x+y, z+1/2'
'x-y, x, z+1/2'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_thermal_displace_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_type_symbol
K1 .0000 .0000 .9975(9) .0436(9) Uani d SP .72 K
Na1 .0000 .0000 .9975(9) .0436(9) Uani d SP .12 Na
Na2 .9945(3) .4380(3) .9964(4) .0300(5) Uani d . 1 Na
Al1 .3333 .6667 .1866(5) .0115(8) Uani d SP .98 Al
Ge1 .3333 .6667 .1866(5) .0115(8) Uani d SP .02 Ge
Al2 .0897(3) .3325(5) .6810(2) .0130(3) Uani d P .98 Al
Ge2 .0897(3) .3325(5) .6810(2) .0130(3) Uani d P .02 Ge
Ge3 .3333 .6667 .8000(3) .0176(3) Uani d S 1 Ge
Ge4 .08990(9) .3336(2) .30804(9) .01645(11) Uani d . 1 Ge
O1 .2664(12) .6124(13) .995(2) .027(3) Uiso d P .33 O
O2 .0158(5) .3147(6) .4953(6) .0434(13) Uani d . 1 O
O3 .1643(7) .5186(7) .7401(9) .056(3) Uani d . 1 O
O4 .1639(7) .5181(6) .2510(9) .052(3) Uani d . 1 O
O5 .2232(4) .2751(5) .3141(12) .0253(13) Uani d . 1 O
O6 .2254(6) .2762(6) .6756(7) .0239(14) Uani d . 1 O
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
O O .0056 .0036 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Na Na .0218 .0150 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Al Al .0406 .0313 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
K K .1399 .1562 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge .3016 1.1903 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
O6 K1 O6 5 6 96.6(2)
O6 K1 O6 5 4 96.6(2)
O6 K1 O6 6 4 96.6(2)
O6 K1 O5 5 4 128.9(2)
O6 K1 O5 6 4 129.41(15)
O6 K1 O5 4 4 61.77(13)
O6 K1 O5 5 5 61.77(13)
O6 K1 O5 6 5 128.9(2)
O6 K1 O5 4 5 129.41(15)
O5 K1 O5 4 5 95.4(2)
O6 K1 O5 5 6 129.41(15)
O6 K1 O5 6 6 61.77(13)
O6 K1 O5 4 6 128.9(2)
O5 K1 O5 4 6 95.4(3)
O5 K1 O5 5 6 95.4(2)
O6 K1 O2 5 5 54.60(13)
O6 K1 O2 6 5 75.15(15)
O6 K1 O2 4 5 147.7(3)
O5 K1 O2 4 5 146.1(3)
O5 K1 O2 5 5 54.31(14)
O5 K1 O2 6 5 75.16(14)
O6 K1 O2 5 6 147.7(3)
O6 K1 O2 6 6 54.60(13)
O6 K1 O2 4 6 75.15(15)
O5 K1 O2 4 6 75.16(14)
O5 K1 O2 5 6 146.1(3)
O5 K1 O2 6 6 54.31(14)
O2 K1 O2 5 6 119.996(4)
O6 K1 O2 5 4 75.15(15)
O6 K1 O2 6 4 147.7(3)
O6 K1 O2 4 4 54.60(13)
O5 K1 O2 4 4 54.31(14)
O5 K1 O2 5 4 75.16(14)
O5 K1 O2 6 4 146.1(3)
O2 K1 O2 5 4 119.996(4)
O2 K1 O2 6 4 119.996(6)
O6 K1 Al2 5 5 30.63(11)
O6 K1 Al2 6 5 72.62(13)
O6 K1 Al2 4 5 117.4(2)
O5 K1 Al2 4 5 157.60(9)
O5 K1 Al2 5 5 67.4(2)
O5 K1 Al2 6 5 100.22(12)
O2 K1 Al2 5 5 30.23(10)
O2 K1 Al2 6 5 127.1(2)
O2 K1 Al2 4 5 105.60(12)
O6 K1 Ge2 5 5 30.63(11)
O6 K1 Ge2 6 5 72.62(13)
O6 K1 Ge2 4 5 117.4(2)
O5 K1 Ge2 4 5 157.60(9)
O5 K1 Ge2 5 5 67.4(2)
O5 K1 Ge2 6 5 100.22(12)
O2 K1 Ge2 5 5 30.23(10)
O2 K1 Ge2 6 5 127.1(2)
O2 K1 Ge2 4 5 105.60(12)
Al2 K1 Ge2 5 5 .0(2)
O6 K1 Al2 5 4 72.62(13)
O6 K1 Al2 6 4 117.4(2)
O6 K1 Al2 4 4 30.63(11)
O5 K1 Al2 4 4 67.4(2)
O5 K1 Al2 5 4 100.22(11)
O5 K1 Al2 6 4 157.60(10)
O2 K1 Al2 5 4 127.1(2)
O2 K1 Al2 6 4 105.60(12)
O2 K1 Al2 4 4 30.23(10)
Al2 K1 Al2 5 4 100.56(15)
Ge2 K1 Al2 5 4 100.56(15)
O6 Na1 O6 5 6 96.6(2)
O6 Na1 O6 5 4 96.6(2)
O6 Na1 O6 6 4 96.6(2)
O6 Na1 O5 5 4 128.9(2)
O6 Na1 O5 6 4 129.41(15)
O6 Na1 O5 4 4 61.77(13)
O6 Na1 O5 5 5 61.77(13)
O6 Na1 O5 6 5 128.9(2)
O6 Na1 O5 4 5 129.41(15)
O5 Na1 O5 4 5 95.4(2)
O6 Na1 O5 5 6 129.41(15)
O6 Na1 O5 6 6 61.77(13)
O6 Na1 O5 4 6 128.9(2)
O5 Na1 O5 4 6 95.4(3)
O5 Na1 O5 5 6 95.4(2)
O6 Na1 Al2 5 5 30.63(11)
O6 Na1 Al2 6 5 72.62(13)
O6 Na1 Al2 4 5 117.4(2)
O5 Na1 Al2 4 5 157.60(9)
O5 Na1 Al2 5 5 67.4(2)
O5 Na1 Al2 6 5 100.22(12)
O6 Na1 Ge2 5 5 30.63(11)
O6 Na1 Ge2 6 5 72.62(13)
O6 Na1 Ge2 4 5 117.4(2)
O5 Na1 Ge2 4 5 157.60(9)
O5 Na1 Ge2 5 5 67.4(2)
O5 Na1 Ge2 6 5 100.22(12)
Al2 Na1 Ge2 5 5 .0(2)
O6 Na1 Al2 5 4 72.62(13)
O6 Na1 Al2 6 4 117.4(2)
O6 Na1 Al2 4 4 30.63(11)
O5 Na1 Al2 4 4 67.4(2)
O5 Na1 Al2 5 4 100.22(11)
O5 Na1 Al2 6 4 157.60(10)
Al2 Na1 Al2 5 4 100.56(15)
Ge2 Na1 Al2 5 4 100.56(15)
O6 Na1 Ge2 5 4 72.62(13)
O6 Na1 Ge2 6 4 117.4(2)
O6 Na1 Ge2 4 4 30.63(11)
O5 Na1 Ge2 4 4 67.4(2)
O5 Na1 Ge2 5 4 100.22(11)
O5 Na1 Ge2 6 4 157.60(10)
Al2 Na1 Ge2 5 4 100.56(15)
Ge2 Na1 Ge2 5 4 100.56(15)
Al2 Na1 Ge2 4 4 .0(2)
O6 Na1 Al2 5 6 117.4(2)
O6 Na1 Al2 6 6 30.63(11)
O6 Na1 Al2 4 6 72.62(13)
O5 Na1 Al2 4 6 100.22(11)
O5 Na1 Al2 5 6 157.60(10)
O5 Na1 Al2 6 6 67.4(2)
Al2 Na1 Al2 5 6 100.56(15)
Ge2 Na1 Al2 5 6 100.56(15)
Al2 Na1 Al2 4 6 100.56(15)
Ge2 Na1 Al2 4 6 100.56(15)
O6 Na1 Ge2 5 6 117.4(2)
O6 Na1 Ge2 6 6 30.63(11)
O6 Na1 Ge2 4 6 72.62(13)
O5 Na1 Ge2 4 6 100.22(11)
O5 Na1 Ge2 5 6 157.60(10)
O5 Na1 Ge2 6 6 67.4(2)
Al2 Na1 Ge2 5 6 100.56(15)
Ge2 Na1 Ge2 5 6 100.56(15)
Al2 Na1 Ge2 4 6 100.56(15)
Ge2 Na1 Ge2 4 6 100.56(15)
Al2 Na1 Ge2 6 6 .00(9)
O1 Na2 O6 1_655 6_655 106.6(4)
O1 Na2 O5 1_655 6_655 106.3(4)
O6 Na2 O5 6_655 6_655 75.9(2)
O1 Na2 O2 1_655 4_665 82.7(4)
O6 Na2 O2 6_655 4_665 140.3(2)
O5 Na2 O2 6_655 4_665 139.7(3)
O1 Na2 O4 1_655 1_656 56.6(4)
O6 Na2 O4 6_655 1_656 64.6(2)
O5 Na2 O4 6_655 1_656 125.9(2)
O2 Na2 O4 4_665 1_656 92.3(2)
O1 Na2 O3 1_655 1_655 56.0(4)
O6 Na2 O3 6_655 1_655 125.7(2)
O5 Na2 O3 6_655 1_655 64.5(2)
O2 Na2 O3 4_665 1_655 91.9(2)
O4 Na2 O3 1_656 1_655 111.2(2)
O1 Na2 O3 1_655 4_665 115.1(4)
O6 Na2 O3 6_655 4_665 79.0(2)
O5 Na2 O3 6_655 4_665 136.1(2)
O2 Na2 O3 4_665 4_665 62.6(2)
O4 Na2 O3 1_656 4_665 71.2(2)
O3 Na2 O3 1_655 4_665 154.48(11)
O1 Na2 O4 1_655 4_665 114.4(4)
O6 Na2 O4 6_655 4_665 136.2(2)
O5 Na2 O4 6_655 4_665 78.7(2)
O2 Na2 O4 4_665 4_665 62.3(2)
O4 Na2 O4 1_656 4_665 154.57(11)
O3 Na2 O4 1_655 4_665 70.8(2)
O3 Na2 O4 4_665 4_665 96.2(2)
O1 Na2 Ge4 1_655 1_656 79.8(4)
O6 Na2 Ge4 6_655 1_656 32.40(14)
O5 Na2 Ge4 6_655 1_656 100.6(2)
O2 Na2 Ge4 4_665 1_656 119.8(2)
O4 Na2 Ge4 1_656 1_656 32.30(13)
O3 Na2 Ge4 1_655 1_656 122.2(2)
O3 Na2 Ge4 4_665 1_656 74.2(2)
O4 Na2 Ge4 4_665 1_656 165.5(2)
O1 Na2 Ge2 1_655 1_655 79.4(4)
O6 Na2 Ge2 6_655 1_655 100.4(2)
O5 Na2 Ge2 6_655 1_655 32.3(2)
O2 Na2 Ge2 4_665 1_655 119.3(2)
O4 Na2 Ge2 1_656 1_655 122.3(2)
O3 Na2 Ge2 1_655 1_655 32.33(14)
O3 Na2 Ge2 4_665 1_655 165.1(2)
O4 Na2 Ge2 4_665 1_655 73.8(2)
Ge4 Na2 Ge2 1_656 1_655 113.27(8)
O1 Na2 Al2 1_655 1_655 79.4(4)
O6 Na2 Al2 6_655 1_655 100.4(2)
O5 Na2 Al2 6_655 1_655 32.3(2)
O2 Na2 Al2 4_665 1_655 119.3(2)
O4 Na2 Al2 1_656 1_655 122.3(2)
O3 Na2 Al2 1_655 1_655 32.33(14)
O3 Na2 Al2 4_665 1_655 165.1(2)
O4 Na2 Al2 4_665 1_655 73.8(2)
Ge4 Na2 Al2 1_656 1_655 113.27(8)
Ge2 Na2 Al2 1_655 1_655 .0(2)
O1 Na2 Ge2 1_655 4_665 95.2(4)
O6 Na2 Ge2 6_655 4_665 108.8(2)
O5 Na2 Ge2 6_655 4_665 155.9(2)
O2 Na2 Ge2 4_665 4_665 31.64(13)
O4 Na2 Ge2 1_656 4_665 75.2(2)
O3 Na2 Ge2 1_655 4_665 122.7(2)
O3 Na2 Ge2 4_665 4_665 31.88(13)
O4 Na2 Ge2 4_665 4_665 82.6(2)
Ge4 Na2 Ge2 1_656 4_665 93.82(11)
Ge2 Na2 Ge2 1_655 4_665 150.61(11)
Al2 Na2 Ge2 1_655 4_665 150.61(11)
O4 Al1 O4 3_565 . 110.2(3)
O4 Al1 O4 3_565 2_665 110.2(3)
O4 Al1 O4 . 2_665 110.2(3)
O4 Al1 O1 3_565 3_564 87.8(5)
O4 Al1 O1 . 3_564 119.2(5)
O4 Al1 O1 2_665 3_564 116.7(5)
O4 Al1 O1 3_565 1_554 116.7(5)
O4 Al1 O1 . 1_554 87.8(5)
O4 Al1 O1 2_665 1_554 119.2(5)
O1 Al1 O1 3_564 1_554 36.0(6)
O4 Al1 O1 3_565 2_664 119.2(5)
O4 Al1 O1 . 2_664 116.7(5)
O4 Al1 O1 2_665 2_664 87.8(5)
O1 Al1 O1 3_564 2_664 36.0(6)
O1 Al1 O1 1_554 2_664 36.0(6)
O4 Al1 Na2 3_565 3_674 48.2(3)
O4 Al1 Na2 . 3_674 135.3(2)
O4 Al1 Na2 2_665 3_674 114.1(2)
O1 Al1 Na2 3_564 3_674 41.3(4)
O1 Al1 Na2 1_554 3_674 75.8(4)
O1 Al1 Na2 2_664 3_674 71.1(5)
O4 Al1 Na2 3_565 1_454 114.1(2)
O4 Al1 Na2 . 1_454 48.2(3)
O4 Al1 Na2 2_665 1_454 135.3(2)
O1 Al1 Na2 3_564 1_454 71.1(5)
O1 Al1 Na2 1_554 1_454 41.3(4)
O1 Al1 Na2 2_664 1_454 75.8(4)
Na2 Al1 Na2 3_674 1_454 99.64(12)
O4 Al1 Na2 3_565 2_654 135.3(2)
O4 Al1 Na2 . 2_654 114.1(2)
O4 Al1 Na2 2_665 2_654 48.2(3)
O1 Al1 Na2 3_564 2_654 75.8(4)
O1 Al1 Na2 1_554 2_654 71.1(5)
O1 Al1 Na2 2_664 2_654 41.3(4)
Na2 Al1 Na2 3_674 2_654 99.64(12)
Na2 Al1 Na2 1_454 2_654 99.64(12)
O4 Ge1 O4 3_565 . 110.2(3)
O4 Ge1 O4 3_565 2_665 110.2(3)
O4 Ge1 O4 . 2_665 110.2(3)
O4 Ge1 O1 3_565 3_564 87.8(5)
O4 Ge1 O1 . 3_564 119.2(5)
O4 Ge1 O1 2_665 3_564 116.7(5)
O4 Ge1 O1 3_565 1_554 116.7(5)
O4 Ge1 O1 . 1_554 87.8(5)
O4 Ge1 O1 2_665 1_554 119.2(5)
O1 Ge1 O1 3_564 1_554 36.0(6)
O4 Ge1 O1 3_565 2_664 119.2(5)
O4 Ge1 O1 . 2_664 116.7(5)
O4 Ge1 O1 2_665 2_664 87.8(5)
O1 Ge1 O1 3_564 2_664 36.0(6)
O1 Ge1 O1 1_554 2_664 36.0(6)
O4 Ge1 Na2 3_565 3_674 48.2(3)
O4 Ge1 Na2 . 3_674 135.3(2)
O4 Ge1 Na2 2_665 3_674 114.1(2)
O1 Ge1 Na2 3_564 3_674 41.3(4)
O1 Ge1 Na2 1_554 3_674 75.8(4)
O1 Ge1 Na2 2_664 3_674 71.1(5)
O4 Ge1 Na2 3_565 1_454 114.1(2)
O4 Ge1 Na2 . 1_454 48.2(3)
O4 Ge1 Na2 2_665 1_454 135.3(2)
O1 Ge1 Na2 3_564 1_454 71.1(5)
O1 Ge1 Na2 1_554 1_454 41.3(4)
O1 Ge1 Na2 2_664 1_454 75.8(4)
Na2 Ge1 Na2 3_674 1_454 99.64(12)
O4 Ge1 Na2 3_565 2_654 135.3(2)
O4 Ge1 Na2 . 2_654 114.1(2)
O4 Ge1 Na2 2_665 2_654 48.2(3)
O1 Ge1 Na2 3_564 2_654 75.8(4)
O1 Ge1 Na2 1_554 2_654 71.1(5)
O1 Ge1 Na2 2_664 2_654 41.3(4)
Na2 Ge1 Na2 3_674 2_654 99.64(12)
Na2 Ge1 Na2 1_454 2_654 99.64(12)
O3 Al2 O2 . . 108.3(4)
O3 Al2 O5 . 6 106.3(4)
O2 Al2 O5 . 6 110.9(3)
O3 Al2 O6 . . 112.5(3)
O2 Al2 O6 . . 108.5(3)
O5 Al2 O6 6 . 110.4(3)
O3 Al2 Na2 . 1_455 55.3(3)
O2 Al2 Na2 . 1_455 128.0(2)
O5 Al2 Na2 6 1_455 51.2(3)
O6 Al2 Na2 . 1_455 123.5(2)
O3 Al2 Na2 . 4_664 59.1(3)
O2 Al2 Na2 . 4_664 51.3(2)
O5 Al2 Na2 6 4_664 110.2(2)
O6 Al2 Na2 . 4_664 139.2(2)
Na2 Al2 Na2 1_455 4_664 86.34(8)
O3 Al2 K1 . 4_554 167.1(3)
O2 Al2 K1 . 4_554 65.6(2)
O5 Al2 K1 6 4_554 86.6(3)
O6 Al2 K1 . 4_554 61.6(2)
Na2 Al2 K1 1_455 4_554 137.57(15)
Na2 Al2 K1 4_664 4_554 116.79(11)
O3 Al2 Na1 . 4_554 167.1(3)
O2 Al2 Na1 . 4_554 65.6(2)
O5 Al2 Na1 6 4_554 86.6(3)
O6 Al2 Na1 . 4_554 61.6(2)
Na2 Al2 Na1 1_455 4_554 137.57(15)
Na2 Al2 Na1 4_664 4_554 116.79(11)
K1 Al2 Na1 4_554 4_554 .0(2)
O3 Al2 Na2 . 5_564 87.7(3)
O2 Al2 Na2 . 5_564 86.4(2)
O5 Al2 Na2 6 5_564 152.0(2)
O6 Al2 Na2 . 5_564 41.8(2)
Na2 Al2 Na2 1_455 5_564 133.76(13)
Na2 Al2 Na2 4_664 5_564 97.83(13)
K1 Al2 Na2 4_554 5_564 80.73(7)
Na1 Al2 Na2 4_554 5_564 80.73(7)
O3 Ge2 O2 . . 108.3(4)
O3 Ge2 O5 . 6 106.3(4)
O2 Ge2 O5 . 6 110.9(3)
O3 Ge2 O6 . . 112.5(3)
O2 Ge2 O6 . . 108.5(3)
O5 Ge2 O6 6 . 110.4(3)
O3 Ge2 Na2 . 1_455 55.3(3)
O2 Ge2 Na2 . 1_455 128.0(2)
O5 Ge2 Na2 6 1_455 51.2(3)
O6 Ge2 Na2 . 1_455 123.5(2)
O3 Ge2 Na2 . 4_664 59.1(3)
O2 Ge2 Na2 . 4_664 51.3(2)
O5 Ge2 Na2 6 4_664 110.2(2)
O6 Ge2 Na2 . 4_664 139.2(2)
Na2 Ge2 Na2 1_455 4_664 86.34(8)
O3 Ge2 K1 . 4_554 167.1(3)
O2 Ge2 K1 . 4_554 65.6(2)
O5 Ge2 K1 6 4_554 86.6(3)
O6 Ge2 K1 . 4_554 61.6(2)
Na2 Ge2 K1 1_455 4_554 137.57(15)
Na2 Ge2 K1 4_664 4_554 116.79(11)
O3 Ge2 Na1 . 4_554 167.1(3)
O2 Ge2 Na1 . 4_554 65.6(2)
O5 Ge2 Na1 6 4_554 86.6(3)
O6 Ge2 Na1 . 4_554 61.6(2)
Na2 Ge2 Na1 1_455 4_554 137.57(15)
Na2 Ge2 Na1 4_664 4_554 116.79(11)
K1 Ge2 Na1 4_554 4_554 .0(2)
O3 Ge2 Na2 . 5_564 87.7(3)
O2 Ge2 Na2 . 5_564 86.4(2)
O5 Ge2 Na2 6 5_564 152.0(2)
O6 Ge2 Na2 . 5_564 41.8(2)
Na2 Ge2 Na2 1_455 5_564 133.76(13)
Na2 Ge2 Na2 4_664 5_564 97.83(13)
K1 Ge2 Na2 4_554 5_564 80.73(7)
Na1 Ge2 Na2 4_554 5_564 80.73(7)
O3 Ge3 O3 3_565 . 111.4(3)
O3 Ge3 O3 3_565 2_665 111.4(2)
O3 Ge3 O3 . 2_665 111.4(3)
O3 Ge3 O1 3_565 3_565 86.9(5)
O3 Ge3 O1 . 3_565 117.9(5)
O3 Ge3 O1 2_665 3_565 115.4(5)
O3 Ge3 O1 3_565 . 115.4(5)
O3 Ge3 O1 . . 86.9(5)
O3 Ge3 O1 2_665 . 117.9(5)
O1 Ge3 O1 3_565 . 35.5(6)
O3 Ge3 O1 3_565 2_665 117.9(5)
O3 Ge3 O1 . 2_665 115.4(5)
O3 Ge3 O1 2_665 2_665 86.9(5)
O1 Ge3 O1 3_565 2_665 35.5(6)
O1 Ge3 O1 . 2_665 35.5(6)
O3 Ge3 Na2 3_565 3_675 47.8(3)
O3 Ge3 Na2 . 3_675 134.8(3)
O3 Ge3 Na2 2_665 3_675 113.7(2)
O1 Ge3 Na2 3_565 3_675 40.8(4)
O1 Ge3 Na2 . 3_675 74.9(4)
O1 Ge3 Na2 2_665 3_675 70.3(5)
O3 Ge3 Na2 3_565 1_455 113.7(2)
O3 Ge3 Na2 . 1_455 47.8(3)
O3 Ge3 Na2 2_665 1_455 134.8(3)
O1 Ge3 Na2 3_565 1_455 70.3(5)
O1 Ge3 Na2 . 1_455 40.8(4)
O1 Ge3 Na2 2_665 1_455 74.9(4)
Na2 Ge3 Na2 3_675 1_455 98.65(9)
O3 Ge3 Na2 3_565 2_655 134.8(3)
O3 Ge3 Na2 . 2_655 113.7(2)
O3 Ge3 Na2 2_665 2_655 47.8(3)
O1 Ge3 Na2 3_565 2_655 74.9(4)
O1 Ge3 Na2 . 2_655 70.3(5)
O1 Ge3 Na2 2_665 2_655 40.8(4)
Na2 Ge3 Na2 3_675 2_655 98.65(9)
Na2 Ge3 Na2 1_455 2_655 98.65(9)
O4 Ge4 O6 . 6_554 106.5(3)
O4 Ge4 O5 . . 113.3(3)
O6 Ge4 O5 6_554 . 110.0(3)
O4 Ge4 O2 . . 108.3(3)
O6 Ge4 O2 6_554 . 111.0(3)
O5 Ge4 O2 . . 107.8(4)
O4 Ge4 Na2 . 1_454 55.7(3)
O6 Ge4 Na2 6_554 1_454 51.0(2)
O5 Ge4 Na2 . 1_454 124.0(4)
O2 Ge4 Na2 . 1_454 128.16(15)
O4 Ge4 Na2 . 4_664 59.2(2)
O6 Ge4 Na2 6_554 4_664 110.4(2)
O5 Ge4 Na2 . 4_664 139.2(3)
O2 Ge4 Na2 . 4_664 51.2(2)
Na2 Ge4 Na2 1_454 4_664 86.74(4)
O4 Ge4 K1 . 4_554 166.2(3)
O6 Ge4 K1 6_554 4_554 87.3(2)
O5 Ge4 K1 . 4_554 61.0(2)
O2 Ge4 K1 . 4_554 64.6(2)
Na2 Ge4 K1 1_454 4_554 138.12(10)
Na2 Ge4 K1 4_664 4_554 115.66(9)
O4 Ge4 Na1 . 4_554 166.2(3)
O6 Ge4 Na1 6_554 4_554 87.3(2)
O5 Ge4 Na1 . 4_554 61.0(2)
O2 Ge4 Na1 . 4_554 64.6(2)
Na2 Ge4 Na1 1_454 4_554 138.12(10)
Na2 Ge4 Na1 4_664 4_554 115.66(9)
K1 Ge4 Na1 4_554 4_554 .0(2)
O4 Ge4 Na2 . 5_564 87.8(2)
O6 Ge4 Na2 6_554 5_564 152.2(2)
O5 Ge4 Na2 . 5_564 42.3(3)
O2 Ge4 Na2 . 5_564 85.76(15)
Na2 Ge4 Na2 1_454 5_564 134.41(8)
Na2 Ge4 Na2 4_664 5_564 97.40(11)
K1 Ge4 Na2 4_554 5_564 80.06(6)
Na1 Ge4 Na2 4_554 5_564 80.06(6)
O1 O1 O1 3_565 2_665 60.00(2)
O1 O1 Ge1 3_565 1_556 72.0(3)
O1 O1 Ge1 2_665 1_556 72.0(3)
O1 O1 Al1 3_565 1_556 72.0(3)
O1 O1 Al1 2_665 1_556 72.0(3)
Ge1 O1 Al1 1_556 1_556 .00(11)
O1 O1 Ge3 3_565 . 72.2(3)
O1 O1 Ge3 2_665 . 72.2(3)
Ge1 O1 Ge3 1_556 . 138.5(6)
Al1 O1 Ge3 1_556 . 138.5(6)
O1 O1 Na2 3_565 1_455 139.6(17)
O1 O1 Na2 2_665 1_455 160.4(17)
Ge1 O1 Na2 1_556 1_455 110.2(7)
Al1 O1 Na2 1_556 1_455 110.2(7)
Ge3 O1 Na2 . 1_455 110.6(7)
Ge2 O2 Al2 . . .0(5)
Ge2 O2 Ge4 . . 133.8(2)
Al2 O2 Ge4 . . 133.8(2)
Ge2 O2 Na2 . 4_664 97.0(3)
Al2 O2 Na2 . 4_664 97.0(3)
Ge4 O2 Na2 . 4_664 97.0(2)
Ge2 O2 K1 . 4_554 84.2(3)
Al2 O2 K1 . 4_554 84.2(3)
Ge4 O2 K1 . 4_554 85.2(2)
Na2 O2 K1 4_664 4_554 175.4(2)
Ge3 O3 Al2 . . 138.9(4)
Ge3 O3 Ge2 . . 138.9(4)
Al2 O3 Ge2 . . .0(3)
Ge3 O3 Na2 . 1_455 103.8(4)
Al2 O3 Na2 . 1_455 92.4(3)
Ge2 O3 Na2 . 1_455 92.4(3)
Ge3 O3 Na2 . 4_664 119.4(3)
Al2 O3 Na2 . 4_664 89.0(3)
Ge2 O3 Na2 . 4_664 89.0(3)
Na2 O3 Na2 1_455 4_664 109.0(2)
Ge4 O4 Al1 . . 139.1(4)
Ge4 O4 Ge1 . . 139.1(4)
Al1 O4 Ge1 . . .0(3)
Ge4 O4 Na2 . 1_454 92.0(3)
Al1 O4 Na2 . 1_454 102.7(4)
Ge1 O4 Na2 . 1_454 102.7(4)
Ge4 O4 Na2 . 4_664 89.3(3)
Al1 O4 Na2 . 4_664 120.1(3)
Ge1 O4 Na2 . 4_664 120.1(3)
Na2 O4 Na2 1_454 4_664 109.1(2)
Ge4 O5 Ge2 . 5_554 137.1(6)
Ge4 O5 Al2 . 5_554 137.1(6)
Ge2 O5 Al2 5_554 5_554 .0(4)
Ge4 O5 Na2 . 5_564 110.2(3)
Ge2 O5 Na2 5_554 5_564 96.5(2)
Al2 O5 Na2 5_554 5_564 96.5(2)
Ge4 O5 K1 . 4_554 88.8(2)
Ge2 O5 K1 5_554 4_554 115.0(2)
Al2 O5 K1 5_554 4_554 115.0(2)
Na2 O5 K1 5_564 4_554 107.6(3)
Ge4 O5 Na1 . 4_554 88.8(2)
Ge2 O5 Na1 5_554 4_554 115.0(2)
Al2 O5 Na1 5_554 4_554 115.0(2)
Na2 O5 Na1 5_564 4_554 107.6(3)
K1 O5 Na1 4_554 4_554 .0(2)
Ge4 O6 Al2 5 . 137.2(4)
Ge4 O6 Ge2 5 . 137.2(4)
Al2 O6 Ge2 . . .0(3)
Ge4 O6 Na2 5 5_564 96.6(2)
Al2 O6 Na2 . 5_564 110.6(3)
Ge2 O6 Na2 . 5_564 110.6(3)
Ge4 O6 K1 5 4_554 114.6(2)
Al2 O6 K1 . 4_554 87.8(2)
Ge2 O6 K1 . 4_554 87.8(2)
Na2 O6 K1 5_564 4_554 108.8(2)
Ge4 O6 Na1 5 4_554 114.6(2)
Al2 O6 Na1 . 4_554 87.8(2)
Ge2 O6 Na1 . 4_554 87.8(2)
Na2 O6 Na1 5_564 4_554 108.8(2)
K1 O6 Na1 4_554 4_554 .0(2)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
K1 O6 5 3.001(7)
K1 O6 6 3.001(7)
K1 O6 4 3.001(7)
K1 O5 4 3.012(7)
K1 O5 5 3.012(7)
K1 O5 6 3.012(7)
K1 O2 5 3.122(5)
K1 O2 6 3.122(5)
K1 O2 4 3.122(5)
K1 Al2 5 3.410(5)
K1 Ge2 5 3.410(5)
K1 Al2 4 3.410(5)
Na1 O6 5 3.001(7)
Na1 O6 6 3.001(7)
Na1 O6 4 3.001(7)
Na1 O5 4 3.012(7)
Na1 O5 5 3.012(7)
Na1 O5 6 3.012(7)
Na1 Al2 5 3.410(5)
Na1 Ge2 5 3.410(5)
Na1 Al2 4 3.410(5)
Na1 Ge2 4 3.410(5)
Na1 Al2 6 3.410(5)
Na1 Ge2 6 3.410(5)
Na2 O1 1_655 2.425(11)
Na2 O6 6_655 2.496(6)
Na2 O5 6_655 2.527(8)
Na2 O2 4_665 2.567(5)
Na2 O4 1_656 2.637(9)
Na2 O3 1_655 2.650(8)
Na2 O3 4_665 2.801(8)
Na2 O4 4_665 2.811(8)
Na2 Ge4 1_656 3.190(4)
Na2 Ge2 1_655 3.222(4)
Na2 Al2 1_655 3.222(4)
Na2 Ge2 4_665 3.264(4)
Al1 O4 3_565 1.717(6)
Al1 O4 . 1.717(6)
Al1 O4 2_665 1.717(6)
Al1 O1 3_564 1.75(2)
Al1 O1 1_554 1.75(2)
Al1 O1 2_664 1.75(2)
Al1 Na2 3_674 3.449(4)
Al1 Na2 1_454 3.449(4)
Al1 Na2 2_654 3.449(4)
Ge1 O4 3_565 1.717(6)
Ge1 O4 . 1.717(6)
Ge1 O4 2_665 1.717(6)
Ge1 O1 3_564 1.75(2)
Ge1 O1 1_554 1.75(2)
Ge1 O1 2_664 1.75(2)
Ge1 Na2 3_674 3.449(4)
Ge1 Na2 1_454 3.449(4)
Ge1 Na2 2_654 3.449(4)
Al2 O3 . 1.724(7)
Al2 O2 . 1.725(5)
Al2 O5 6 1.732(8)
Al2 O6 . 1.738(5)
Al2 Na2 1_455 3.222(4)
Al2 Na2 4_664 3.264(4)
Al2 K1 4_554 3.410(5)
Al2 Na1 4_554 3.410(5)
Al2 Na2 5_564 3.507(4)
Ge2 O3 . 1.724(7)
Ge2 O2 . 1.725(5)
Ge2 O5 6 1.732(8)
Ge2 O6 . 1.738(5)
Ge2 Na2 1_455 3.222(4)
Ge2 Na2 4_664 3.264(4)
Ge2 K1 4_554 3.410(5)
Ge2 Na1 4_554 3.410(5)
Ge2 Na2 5_564 3.507(4)
Ge3 O3 3_565 1.701(6)
Ge3 O3 . 1.701(6)
Ge3 O3 2_665 1.701(6)
Ge3 O1 3_565 1.78(2)
Ge3 O1 . 1.78(2)
Ge3 O1 2_665 1.78(2)
Ge3 Na2 3_675 3.474(4)
Ge3 Na2 1_455 3.474(4)
Ge3 Na2 2_655 3.474(4)
Ge4 O4 . 1.706(6)
Ge4 O6 6_554 1.721(6)
Ge4 O5 . 1.731(4)
Ge4 O2 . 1.737(5)
Ge4 Na2 1_454 3.190(4)
Ge4 Na2 4_664 3.271(3)
Ge4 K1 4_554 3.443(4)
Ge4 Na1 4_554 3.443(4)
Ge4 Na2 5_564 3.522(3)
O1 O1 3_565 1.08(2)
O1 O1 2_665 1.08(2)
O1 Ge1 1_556 1.75(2)
O1 Al1 1_556 1.75(2)
O1 Na2 1_455 2.425(11)
O2 Na2 4_664 2.567(5)
O2 K1 4_554 3.122(5)
O3 Na2 1_455 2.650(9)
O3 Na2 4_664 2.801(8)
O4 Na2 1_454 2.637(9)
O4 Na2 4_664 2.811(8)
O5 Ge2 5_554 1.732(8)
O5 Al2 5_554 1.732(8)
O5 Na2 5_564 2.527(8)
O5 K1 4_554 3.012(7)
O5 Na1 4_554 3.012(7)
O6 Ge4 5 1.721(6)
O6 Na2 5_564 2.496(6)
O6 K1 4_554 3.001(7)
O6 Na1 4_554 3.001(7)
