#------------------------------------------------------------------------------
#$Date: 2016-02-20 05:06:23 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176774 $
#$URL: svn://www.crystallography.net/cod/cif/2/20/37/2203748.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2203748
loop_
_publ_author_name
'Khan, Muhammad S.'
'Al-Suti, Mohammed K.'
'Ahrens, Birte'
'Raithby, Paul R.'
'Teat, Simon J.'
_publ_section_title
trans-(μ-5,5'-Diethynyl-2,2'-bipyridine)bis[phenylbis(triethylphosphine)platinum(II)]
_journal_issue                   6
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m735
_journal_page_last               m737
_journal_paper_doi               10.1107/S1600536804010359
_journal_volume                  60
_journal_year                    2004
_chemical_formula_iupac          '[Pt2 (C6 H5)2 (C14 H6 N2) (C6 H15 P)4]'
_chemical_formula_moiety         'C50 H76 N2 P4 Pt2'
_chemical_formula_sum            'C50 H76 N2 P4 Pt2'
_chemical_formula_weight         1219.19
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                92.130(2)
_cell_angle_beta                 90.032(2)
_cell_angle_gamma                94.958(2)
_cell_formula_units_Z            2
_cell_length_a                   9.2651(7)
_cell_length_b                   16.6840(14)
_cell_length_c                   16.8258(14)
_cell_measurement_reflns_used    25942
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      29.3
_cell_measurement_theta_min      21.7
_cell_volume                     2589.4(4)
_computing_cell_refinement       'SAINT (Bruker, 2000)'
_computing_data_collection       'SMART (Bruker, 1998)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    'ORTEP-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'WinGX (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997)'
_diffrn_measured_fraction_theta_full 0.893
_diffrn_measured_fraction_theta_max 0.893
_diffrn_measurement_device_type  'Bruker AXS SMART 1K CCD'
_diffrn_measurement_method       'ω rotation with narrow frames'
_diffrn_radiation_monochromator  'Silicon 111'
_diffrn_radiation_source         'Daresbury SRS, Station 9.8'
_diffrn_radiation_type           synchrotron
_diffrn_radiation_wavelength     0.6941
_diffrn_reflns_av_R_equivalents  0.0237
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            25942
_diffrn_reflns_theta_full        29.31
_diffrn_reflns_theta_max         29.31
_diffrn_reflns_theta_min         1.65
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    5.554
_exptl_absorpt_correction_T_max  0.946
_exptl_absorpt_correction_T_min  0.895
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 1996)'
_exptl_crystal_colour            Yellow
_exptl_crystal_density_diffrn    1.564
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             1212
_exptl_crystal_size_max          0.02
_exptl_crystal_size_mid          0.01
_exptl_crystal_size_min          0.01
_refine_diff_density_max         1.633
_refine_diff_density_min         -1.858
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.000
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     535
_refine_ls_number_reflns         13587
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.000
_refine_ls_R_factor_all          0.0468
_refine_ls_R_factor_gt           0.0318
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[σ²(Fo²)+(0.04P)²] where P = (Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0654
_refine_ls_wR_factor_ref         0.0677
_reflns_number_gt                11103
_reflns_number_total             13587
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            dn6135.cif
_cod_data_source_block           I
_cod_database_code               2203748
_cod_database_fobs_code          2203748
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_type_symbol
Pt1 -0.056171(12) 0.219787(7) 0.268849(7) 0.02461(4) Uani d . 1 Pt
C1 0.0782(4) 0.2933(2) 0.2043(2) 0.0328(8) Uani d . 1 C
C2 0.1591(4) 0.3341(2) 0.1640(2) 0.0335(8) Uani d . 1 C
C3 0.2565(3) 0.37971(19) 0.1128(2) 0.0275(7) Uani d . 1 C
C4 0.3556(4) 0.4404(2) 0.1445(2) 0.0299(7) Uani d . 1 C
H4A 0.3561 0.4498 0.2005 0.036 Uiso calc R 1 H
C5 0.4487(3) 0.47315(18) 0.02252(19) 0.0234(6) Uani d . 1 C
N1 0.4496(3) 0.48608(17) 0.10188(17) 0.0278(6) Uani d . 1 N
C6 0.3565(3) 0.4135(2) -0.0147(2) 0.0288(7) Uani d . 1 C
H6A 0.3592 0.4049 -0.0708 0.035 Uiso calc R 1 H
C7 0.2603(4) 0.3665(2) 0.0307(2) 0.0308(7) Uani d . 1 C
H7A 0.1969 0.3252 0.0058 0.037 Uiso calc R 1 H
C8 -0.1940(3) 0.1404(2) 0.3286(2) 0.0282(7) Uani d . 1 C
C9 -0.1909(5) 0.1335(3) 0.4111(2) 0.0459(10) Uani d . 1 C
H9A -0.1245 0.1684 0.4419 0.055 Uiso calc R 1 H
C10 -0.2828(6) 0.0764(3) 0.4496(3) 0.0652(15) Uani d . 1 C
H10A -0.2781 0.0731 0.5058 0.078 Uiso calc R 1 H
C11 -0.3796(5) 0.0253(3) 0.4065(4) 0.0647(15) Uani d . 1 C
H11A -0.4417 -0.0137 0.4325 0.078 Uiso calc R 1 H
C12 -0.3856(4) 0.0311(3) 0.3263(3) 0.0539(12) Uani d . 1 C
H12A -0.4523 -0.0044 0.2962 0.065 Uiso calc R 1 H
C13 -0.2961(4) 0.0878(2) 0.2879(2) 0.0360(8) Uani d . 1 C
H13A -0.3043 0.0911 0.2319 0.043 Uiso calc R 1 H
P1 0.11175(9) 0.12746(5) 0.25446(5) 0.02818(18) Uani d . 1 P
C14 0.0654(4) 0.0264(2) 0.2895(3) 0.0411(9) Uani d . 1 C
H14A 0.0255 0.0313 0.3439 0.049 Uiso calc R 1 H
H14B -0.0123 -0.0002 0.2549 0.049 Uiso calc R 1 H
C15 0.1892(5) -0.0279(3) 0.2915(3) 0.0506(11) Uani d . 1 C
H15A 0.1496 -0.0840 0.2955 0.076 Uiso calc R 1 H
H15B 0.2515 -0.0124 0.3376 0.076 Uiso calc R 1 H
H15C 0.2462 -0.0223 0.2427 0.076 Uiso calc R 1 H
C16 0.2827(4) 0.1622(3) 0.3029(2) 0.0390(8) Uani d . 1 C
H16A 0.3552 0.1236 0.2894 0.047 Uiso calc R 1 H
H16B 0.3181 0.2149 0.2818 0.047 Uiso calc R 1 H
C17 0.2708(5) 0.1708(3) 0.3926(3) 0.0560(12) Uani d . 1 C
H17A 0.3658 0.1895 0.4152 0.084 Uiso calc R 1 H
H17B 0.2379 0.1186 0.4140 0.084 Uiso calc R 1 H
H17C 0.2010 0.2100 0.4064 0.084 Uiso calc R 1 H
C18 0.1658(4) 0.1120(2) 0.1522(2) 0.0347(8) Uani d . 1 C
H18A 0.2194 0.1619 0.1343 0.042 Uiso calc R 1 H
H18B 0.2327 0.0688 0.1494 0.042 Uiso calc R 1 H
C19 0.0395(4) 0.0892(3) 0.0957(3) 0.0486(10) Uani d . 1 C
H19A 0.0762 0.0813 0.0416 0.073 Uiso calc R 1 H
H19B -0.0258 0.1325 0.0966 0.073 Uiso calc R 1 H
H19C -0.0135 0.0393 0.1123 0.073 Uiso calc R 1 H
P2 -0.20890(9) 0.31932(5) 0.28326(5) 0.02622(17) Uani d . 1 P
C20 -0.3695(4) 0.2985(2) 0.3437(2) 0.0345(8) Uani d . 1 C
H20A -0.4257 0.2503 0.3201 0.041 Uiso calc R 1 H
H20B -0.3377 0.2847 0.3973 0.041 Uiso calc R 1 H
C21 -0.4704(5) 0.3651(3) 0.3535(3) 0.0542(12) Uani d . 1 C
H21A -0.5479 0.3488 0.3907 0.081 Uiso calc R 1 H
H21B -0.5127 0.3751 0.3018 0.081 Uiso calc R 1 H
H21C -0.4158 0.4143 0.3743 0.081 Uiso calc R 1 H
C22 -0.1162(4) 0.4095(2) 0.3288(2) 0.0369(8) Uani d . 1 C
H22A -0.0381 0.4302 0.2929 0.044 Uiso calc R 1 H
H22B -0.1856 0.4513 0.3350 0.044 Uiso calc R 1 H
C23 -0.0512(5) 0.3957(3) 0.4094(2) 0.0474(10) Uani d . 1 C
H23A 0.0012 0.4457 0.4299 0.071 Uiso calc R 1 H
H23B 0.0159 0.3536 0.4039 0.071 Uiso calc R 1 H
H23C -0.1288 0.3789 0.4463 0.071 Uiso calc R 1 H
C24 -0.2759(4) 0.3526(2) 0.1890(2) 0.0358(8) Uani d . 1 C
H24A -0.3323 0.3996 0.1994 0.043 Uiso calc R 1 H
H24B -0.1925 0.3700 0.1551 0.043 Uiso calc R 1 H
Pt2 1.032188(11) 0.724753(7) 0.232281(7) 0.02203(4) Uani d . 1 Pt
C25 -0.3718(5) 0.2862(3) 0.1442(3) 0.0526(11) Uani d . 1 C
H25A -0.4019 0.3060 0.0931 0.079 Uiso calc R 1 H
H25B -0.4578 0.2712 0.1760 0.079 Uiso calc R 1 H
H25C -0.3172 0.2391 0.1347 0.079 Uiso calc R 1 H
C26 0.8978(3) 0.7826(2) 0.1645(2) 0.0270(7) Uani d . 1 C
C27 0.8145(3) 0.8179(2) 0.1275(2) 0.0282(7) Uani d . 1 C
C28 0.7191(3) 0.8674(2) 0.0884(2) 0.0267(7) Uani d . 1 C
C29 0.6389(3) 0.8430(2) 0.0203(2) 0.0303(7) Uani d . 1 C
H29A 0.6436 0.7901 -0.0020 0.036 Uiso calc R 1 H
C30 0.5535(3) 0.8948(2) -0.0145(2) 0.0265(6) Uani d . 1 C
H30A 0.4999 0.8781 -0.0613 0.032 Uiso calc R 1 H
C31 0.5454(3) 0.97124(19) 0.01828(19) 0.0230(6) Uani d . 1 C
N2 0.6194(3) 0.99657(18) 0.08523(18) 0.0312(6) Uani d . 1 N
C32 0.7027(4) 0.9459(2) 0.1183(2) 0.0317(7) Uani d . 1 C
H32A 0.7546 0.9639 0.1653 0.038 Uiso calc R 1 H
C33 1.1639(3) 0.6651(2) 0.30475(19) 0.0295(7) Uani d . 1 C
C34 1.2448(4) 0.7037(3) 0.3676(2) 0.0368(8) Uani d . 1 C
H34A 1.2425 0.7601 0.3763 0.044 Uiso calc R 1 H
C35 1.3285(4) 0.6618(3) 0.4177(2) 0.0469(11) Uani d . 1 C
H35A 1.3819 0.6899 0.4598 0.056 Uiso calc R 1 H
C36 1.3346(4) 0.5799(3) 0.4068(3) 0.0515(12) Uani d . 1 C
H36A 1.3916 0.5515 0.4412 0.062 Uiso calc R 1 H
C37 1.2575(4) 0.5400(3) 0.3457(3) 0.0456(10) Uani d . 1 C
H37A 1.2607 0.4835 0.3378 0.055 Uiso calc R 1 H
C38 1.1744(4) 0.5820(2) 0.2952(2) 0.0353(8) Uani d . 1 C
H38A 1.1230 0.5533 0.2527 0.042 Uiso calc R 1 H
P3 1.21085(8) 0.73062(5) 0.13842(5) 0.02451(17) Uani d . 1 P
C39 1.2266(4) 0.6336(2) 0.0875(2) 0.0389(9) Uani d . 1 C
H39A 1.3060 0.6399 0.0483 0.047 Uiso calc R 1 H
H39B 1.2549 0.5953 0.1271 0.047 Uiso calc R 1 H
C40 1.0923(5) 0.5972(3) 0.0450(3) 0.0650(14) Uani d . 1 C
H40A 1.1060 0.5416 0.0277 0.098 Uiso calc R 1 H
H40B 1.0742 0.6287 -0.0014 0.098 Uiso calc R 1 H
H40C 1.0094 0.5975 0.0812 0.098 Uiso calc R 1 H
C41 1.1923(4) 0.7976(2) 0.0561(2) 0.0333(8) Uani d . 1 C
H41A 1.2740 0.7918 0.0191 0.040 Uiso calc R 1 H
H41B 1.1018 0.7796 0.0269 0.040 Uiso calc R 1 H
C42 1.1889(4) 0.8867(2) 0.0799(2) 0.0385(8) Uani d . 1 C
H42A 1.1749 0.9173 0.0323 0.058 Uiso calc R 1 H
H42B 1.2807 0.9065 0.1056 0.058 Uiso calc R 1 H
H42C 1.1089 0.8935 0.1169 0.058 Uiso calc R 1 H
C43 1.3961(3) 0.7501(2) 0.1757(2) 0.0338(8) Uani d . 1 C
H43A 1.4183 0.7042 0.2079 0.041 Uiso calc R 1 H
H43B 1.4623 0.7512 0.1295 0.041 Uiso calc R 1 H
C44 1.4305(4) 0.8267(2) 0.2254(2) 0.0396(9) Uani d . 1 C
H44A 1.5274 0.8267 0.2487 0.059 Uiso calc R 1 H
H44B 1.3588 0.8300 0.2680 0.059 Uiso calc R 1 H
H44C 1.4274 0.8733 0.1917 0.059 Uiso calc R 1 H
P4 0.84663(8) 0.71218(5) 0.32216(5) 0.02637(17) Uani d . 1 P
C45 0.8725(4) 0.6497(3) 0.4062(2) 0.0354(8) Uani d . 1 C
H45A 0.9029 0.5973 0.3859 0.042 Uiso calc R 1 H
H45B 0.9526 0.6759 0.4395 0.042 Uiso calc R 1 H
C46 0.7398(4) 0.6336(3) 0.4590(2) 0.0475(11) Uani d . 1 C
H46A 0.7637 0.5994 0.5024 0.071 Uiso calc R 1 H
H46B 0.6601 0.6063 0.4273 0.071 Uiso calc R 1 H
H46C 0.7103 0.6848 0.4812 0.071 Uiso calc R 1 H
C47 0.6787(3) 0.6703(2) 0.2762(2) 0.0333(8) Uani d . 1 C
H47A 0.5993 0.6737 0.3152 0.040 Uiso calc R 1 H
H47B 0.6568 0.7032 0.2307 0.040 Uiso calc R 1 H
C48 0.6822(5) 0.5840(3) 0.2472(3) 0.0496(10) Uani d . 1 C
H48A 0.5958 0.5679 0.2149 0.074 Uiso calc R 1 H
H48B 0.6841 0.5493 0.2929 0.074 Uiso calc R 1 H
H48C 0.7691 0.5785 0.2149 0.074 Uiso calc R 1 H
C49 0.7969(4) 0.8093(3) 0.3636(2) 0.0415(9) Uani d . 1 C
H49A 0.7735 0.8434 0.3193 0.050 Uiso calc R 1 H
H49B 0.7084 0.7999 0.3961 0.050 Uiso calc R 1 H
C50 0.9137(5) 0.8542(3) 0.4143(3) 0.0583(12) Uani d . 1 C
H50A 0.8847 0.9078 0.4293 0.087 Uiso calc R 1 H
H50B 1.0044 0.8596 0.3843 0.087 Uiso calc R 1 H
H50C 0.9280 0.8245 0.4625 0.087 Uiso calc R 1 H
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_3
_geom_angle
C1 Pt1 C8 . 176.58(14)
C1 Pt1 P2 . 89.53(9)
C8 Pt1 P2 . 92.15(9)
C1 Pt1 P1 . 86.75(9)
C8 Pt1 P1 . 91.69(9)
P2 Pt1 P1 . 175.56(3)
C2 C1 Pt1 . 177.2(3)
C1 C2 C3 . 177.1(4)
C7 C3 C4 . 116.1(3)
C7 C3 C2 . 123.4(3)
C4 C3 C2 . 120.4(3)
N1 C4 C3 . 124.8(3)
N1 C4 H4A . 117.6
C3 C4 H4A . 117.6
N1 C5 C6 . 122.0(3)
N1 C5 C5 2_665 115.9(4)
C6 C5 C5 2_665 122.1(4)
C4 N1 C5 . 117.8(3)
C7 C6 C5 . 119.3(3)
C7 C6 H6A . 120.4
C5 C6 H6A . 120.4
C6 C7 C3 . 120.0(3)
C6 C7 H7A . 120.0
C3 C7 H7A . 120.0
C13 C8 C9 . 115.6(3)
C13 C8 Pt1 . 121.0(3)
C9 C8 Pt1 . 123.4(3)
C8 C9 C10 . 121.8(4)
C8 C9 H9A . 119.1
C10 C9 H9A . 119.1
C11 C10 C9 . 120.2(5)
C11 C10 H10A . 119.9
C9 C10 H10A . 119.9
C12 C11 C10 . 119.2(4)
C12 C11 H11A . 120.4
C10 C11 H11A . 120.4
C11 C12 C13 . 120.9(4)
C11 C12 H12A . 119.6
C13 C12 H12A . 119.6
C12 C13 C8 . 122.3(4)
C12 C13 H13A . 118.9
C8 C13 H13A . 118.9
C18 P1 C16 . 102.32(17)
C18 P1 C14 . 104.65(19)
C16 P1 C14 . 105.48(19)
C18 P1 Pt1 . 112.68(12)
C16 P1 Pt1 . 111.98(13)
C14 P1 Pt1 . 118.23(12)
C15 C14 P1 . 115.9(3)
C15 C14 H14A . 108.3
P1 C14 H14A . 108.3
C15 C14 H14B . 108.3
P1 C14 H14B . 108.3
H14A C14 H14B . 107.4
C14 C15 H15A . 109.5
C14 C15 H15B . 109.5
H15A C15 H15B . 109.5
C14 C15 H15C . 109.5
H15A C15 H15C . 109.5
H15B C15 H15C . 109.5
C17 C16 P1 . 113.2(3)
C17 C16 H16A . 108.9
P1 C16 H16A . 108.9
C17 C16 H16B . 108.9
P1 C16 H16B . 108.9
H16A C16 H16B . 107.8
C16 C17 H17A . 109.5
C16 C17 H17B . 109.5
H17A C17 H17B . 109.5
C16 C17 H17C . 109.5
H17A C17 H17C . 109.5
H17B C17 H17C . 109.5
C19 C18 P1 . 113.7(3)
C19 C18 H18A . 108.8
P1 C18 H18A . 108.8
C19 C18 H18B . 108.8
P1 C18 H18B . 108.8
H18A C18 H18B . 107.7
C18 C19 H19A . 109.5
C18 C19 H19B . 109.5
H19A C19 H19B . 109.5
C18 C19 H19C . 109.5
H19A C19 H19C . 109.5
H19B C19 H19C . 109.5
C22 P2 C20 . 104.96(19)
C22 P2 C24 . 103.97(18)
C20 P2 C24 . 105.21(17)
C22 P2 Pt1 . 110.87(12)
C20 P2 Pt1 . 117.09(12)
C24 P2 Pt1 . 113.58(12)
C21 C20 P2 . 116.9(3)
C21 C20 H20A . 108.1
P2 C20 H20A . 108.1
C21 C20 H20B . 108.1
P2 C20 H20B . 108.1
H20A C20 H20B . 107.3
C20 C21 H21A . 109.5
C20 C21 H21B . 109.5
H21A C21 H21B . 109.5
C20 C21 H21C . 109.5
H21A C21 H21C . 109.5
H21B C21 H21C . 109.5
C23 C22 P2 . 113.1(3)
C23 C22 H22A . 109.0
P2 C22 H22A . 109.0
C23 C22 H22B . 109.0
P2 C22 H22B . 109.0
H22A C22 H22B . 107.8
C22 C23 H23A . 109.5
C22 C23 H23B . 109.5
H23A C23 H23B . 109.5
C22 C23 H23C . 109.5
H23A C23 H23C . 109.5
H23B C23 H23C . 109.5
C25 C24 P2 . 112.4(3)
C25 C24 H24A . 109.1
P2 C24 H24A . 109.1
C25 C24 H24B . 109.1
P2 C24 H24B . 109.1
H24A C24 H24B . 107.9
C26 Pt2 C33 . 177.92(12)
C26 Pt2 P3 . 92.89(9)
C33 Pt2 P3 . 89.19(9)
C26 Pt2 P4 . 86.63(9)
C33 Pt2 P4 . 91.28(9)
P3 Pt2 P4 . 176.53(3)
C24 C25 H25A . 109.5
C24 C25 H25B . 109.5
H25A C25 H25B . 109.5
C24 C25 H25C . 109.5
H25A C25 H25C . 109.5
H25B C25 H25C . 109.5
C27 C26 Pt2 . 176.8(3)
C26 C27 C28 . 174.1(4)
C29 C28 C32 . 115.9(3)
C29 C28 C27 . 124.0(3)
C32 C28 C27 . 120.1(3)
C30 C29 C28 . 120.3(3)
C30 C29 H29A . 119.8
C28 C29 H29A . 119.8
C29 C30 C31 . 119.9(3)
C29 C30 H30A . 120.1
C31 C30 H30A . 120.1
N2 C31 C30 . 121.5(3)
N2 C31 C31 2_675 117.4(4)
C30 C31 C31 2_675 121.2(4)
C32 N2 C31 . 118.1(3)
N2 C32 C28 . 124.3(3)
N2 C32 H32A . 117.8
C28 C32 H32A . 117.8
C34 C33 C38 . 115.6(3)
C34 C33 Pt2 . 122.9(3)
C38 C33 Pt2 . 121.6(3)
C35 C34 C33 . 122.0(4)
C35 C34 H34A . 119.0
C33 C34 H34A . 119.0
C36 C35 C34 . 120.6(4)
C36 C35 H35A . 119.7
C34 C35 H35A . 119.7
C37 C36 C35 . 119.2(3)
C37 C36 H36A . 120.4
C35 C36 H36A . 120.4
C36 C37 C38 . 120.2(4)
C36 C37 H37A . 119.9
C38 C37 H37A . 119.9
C37 C38 C33 . 122.5(4)
C37 C38 H38A . 118.8
C33 C38 H38A . 118.8
C39 P3 C43 . 99.16(17)
C39 P3 C41 . 102.75(18)
C43 P3 C41 . 106.87(17)
C39 P3 Pt2 . 112.23(13)
C43 P3 Pt2 . 116.15(12)
C41 P3 Pt2 . 117.39(12)
C40 C39 P3 . 115.7(3)
C40 C39 H39A . 108.4
P3 C39 H39A . 108.4
C40 C39 H39B . 108.4
P3 C39 H39B . 108.4
H39A C39 H39B . 107.4
C39 C40 H40A . 109.5
C39 C40 H40B . 109.5
H40A C40 H40B . 109.5
C39 C40 H40C . 109.5
H40A C40 H40C . 109.5
H40B C40 H40C . 109.5
C42 C41 P3 . 115.4(3)
C42 C41 H41A . 108.4
P3 C41 H41A . 108.4
C42 C41 H41B . 108.4
P3 C41 H41B . 108.4
H41A C41 H41B . 107.5
C41 C42 H42A . 109.5
C41 C42 H42B . 109.5
H42A C42 H42B . 109.5
C41 C42 H42C . 109.5
H42A C42 H42C . 109.5
H42B C42 H42C . 109.5
C44 C43 P3 . 116.9(2)
C44 C43 H43A . 108.1
P3 C43 H43A . 108.1
C44 C43 H43B . 108.1
P3 C43 H43B . 108.1
H43A C43 H43B . 107.3
C43 C44 H44A . 109.5
C43 C44 H44B . 109.5
H44A C44 H44B . 109.5
C43 C44 H44C . 109.5
H44A C44 H44C . 109.5
H44B C44 H44C . 109.5
C47 P4 C45 . 105.07(17)
C47 P4 C49 . 102.16(18)
C45 P4 C49 . 106.49(19)
C47 P4 Pt2 . 112.00(13)
C45 P4 Pt2 . 116.65(12)
C49 P4 Pt2 . 113.16(14)
C46 C45 P4 . 115.3(3)
C46 C45 H45A . 108.5
P4 C45 H45A . 108.5
C46 C45 H45B . 108.5
P4 C45 H45B . 108.5
H45A C45 H45B . 107.5
C45 C46 H46A . 109.5
C45 C46 H46B . 109.5
H46A C46 H46B . 109.5
C45 C46 H46C . 109.5
H46A C46 H46C . 109.5
H46B C46 H46C . 109.5
C48 C47 P4 . 113.5(2)
C48 C47 H47A . 108.9
P4 C47 H47A . 108.9
C48 C47 H47B . 108.9
P4 C47 H47B . 108.9
H47A C47 H47B . 107.7
C47 C48 H48A . 109.5
C47 C48 H48B . 109.5
H48A C48 H48B . 109.5
C47 C48 H48C . 109.5
H48A C48 H48C . 109.5
H48B C48 H48C . 109.5
C50 C49 P4 . 113.8(3)
C50 C49 H49A . 108.8
P4 C49 H49A . 108.8
C50 C49 H49B . 108.8
P4 C49 H49B . 108.8
H49A C49 H49B . 107.7
C49 C50 H50A . 109.5
C49 C50 H50B . 109.5
H50A C50 H50B . 109.5
C49 C50 H50C . 109.5
H50A C50 H50C . 109.5
H50B C50 H50C . 109.5
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
Pt1 C1 . 2.017(4)
Pt1 C8 . 2.051(3)
Pt1 P2 . 2.2794(8)
Pt1 P1 . 2.2889(8)
C1 C2 . 1.197(5)
C2 C3 . 1.438(4)
C3 C7 . 1.391(5)
C3 C4 . 1.397(5)
C4 N1 . 1.334(4)
C4 H4A . 0.9500
C5 N1 . 1.344(4)
C5 C6 . 1.386(5)
C5 C5 2_665 1.478(6)
C6 C7 . 1.385(5)
C6 H6A . 0.9500
C7 H7A . 0.9500
C8 C13 . 1.394(5)
C8 C9 . 1.397(5)
C9 C10 . 1.399(6)
C9 H9A . 0.9500
C10 C11 . 1.370(8)
C10 H10A . 0.9500
C11 C12 . 1.358(7)
C11 H11A . 0.9500
C12 C13 . 1.383(6)
C12 H12A . 0.9500
C13 H13A . 0.9500
P1 C18 . 1.808(4)
P1 C16 . 1.820(4)
P1 C14 . 1.823(4)
C14 C15 . 1.524(5)
C14 H14A . 0.9900
C14 H14B . 0.9900
C15 H15A . 0.9800
C15 H15B . 0.9800
C15 H15C . 0.9800
C16 C17 . 1.516(6)
C16 H16A . 0.9900
C16 H16B . 0.9900
C17 H17A . 0.9800
C17 H17B . 0.9800
C17 H17C . 0.9800
C18 C19 . 1.521(5)
C18 H18A . 0.9900
C18 H18B . 0.9900
C19 H19A . 0.9800
C19 H19B . 0.9800
C19 H19C . 0.9800
P2 C22 . 1.811(4)
P2 C20 . 1.818(3)
P2 C24 . 1.826(3)
C20 C21 . 1.517(5)
C20 H20A . 0.9900
C20 H20B . 0.9900
C21 H21A . 0.9800
C21 H21B . 0.9800
C21 H21C . 0.9800
C22 C23 . 1.517(5)
C22 H22A . 0.9900
C22 H22B . 0.9900
C23 H23A . 0.9800
C23 H23B . 0.9800
C23 H23C . 0.9800
C24 C25 . 1.534(6)
C24 H24A . 0.9900
C24 H24B . 0.9900
Pt2 C26 . 2.017(3)
Pt2 C33 . 2.066(3)
Pt2 P3 . 2.2869(8)
Pt2 P4 . 2.2914(9)
C25 H25A . 0.9800
C25 H25B . 0.9800
C25 H25C . 0.9800
C26 C27 . 1.199(4)
C27 C28 . 1.436(4)
C28 C29 . 1.393(5)
C28 C32 . 1.405(5)
C29 C30 . 1.368(4)
C29 H29A . 0.9500
C30 C31 . 1.380(5)
C30 H30A . 0.9500
C31 N2 . 1.354(4)
C31 C31 2_675 1.480(5)
N2 C32 . 1.330(4)
C32 H32A . 0.9500
C33 C34 . 1.400(5)
C33 C38 . 1.401(5)
C34 C35 . 1.392(5)
C34 H34A . 0.9500
C35 C36 . 1.377(7)
C35 H35A . 0.9500
C36 C37 . 1.370(6)
C36 H36A . 0.9500
C37 C38 . 1.394(5)
C37 H37A . 0.9500
C38 H38A . 0.9500
P3 C39 . 1.819(4)
P3 C43 . 1.826(3)
P3 C41 . 1.828(3)
C39 C40 . 1.505(6)
C39 H39A . 0.9900
C39 H39B . 0.9900
C40 H40A . 0.9800
C40 H40B . 0.9800
C40 H40C . 0.9800
C41 C42 . 1.528(5)
C41 H41A . 0.9900
C41 H41B . 0.9900
C42 H42A . 0.9800
C42 H42B . 0.9800
C42 H42C . 0.9800
C43 C44 . 1.511(5)
C43 H43A . 0.9900
C43 H43B . 0.9900
C44 H44A . 0.9800
C44 H44B . 0.9800
C44 H44C . 0.9800
P4 C47 . 1.811(3)
P4 C45 . 1.816(4)
P4 C49 . 1.836(4)
C45 C46 . 1.528(5)
C45 H45A . 0.9900
C45 H45B . 0.9900
C46 H46A . 0.9800
C46 H46B . 0.9800
C46 H46C . 0.9800
C47 C48 . 1.506(6)
C47 H47A . 0.9900
C47 H47B . 0.9900
C48 H48A . 0.9800
C48 H48B . 0.9800
C48 H48C . 0.9800
C49 C50 . 1.508(6)
C49 H49A . 0.9900
C49 H49B . 0.9900
C50 H50A . 0.9800
C50 H50B . 0.9800
C50 H50C . 0.9800
