#------------------------------------------------------------------------------
#$Date: 2016-02-20 05:06:23 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176774 $
#$URL: svn://www.crystallography.net/cod/cif/2/20/46/2204668.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2204668
loop_
_publ_author_name
'Therrien, Bruno'
'Süss-Fink, Georg'
_publ_section_title
;Di-μ-chloro-bis[chloro(η⁶-1,2,4-trimethylbenzene)ruthenium(II)]--dichloromethane
 (3/2)
;
_journal_issue                   12
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1766
_journal_page_last               m1768
_journal_paper_doi               10.1107/S160053680402745X
_journal_volume                  60
_journal_year                    2004
_chemical_formula_moiety         'C18 H24 Cl4 Ru2, 0.67C H2 Cl2'
_chemical_formula_sum            'C18.67 H35.33 Cl5.333 Ru2'
_chemical_formula_weight         640.93
_chemical_melting_point          '[Ru2 Cl4 (C9 H12)2], 0.67C H2 Cl2'
_chemical_name_systematic
;
Di-μ-chloro-bis[chloro(η⁶-1,2,4-
trimethylbenzene)ruthenium(II)]--dichloromethane (3/2)
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                97.105(13)
_cell_angle_beta                 90.644(13)
_cell_angle_gamma                105.358(12)
_cell_formula_units_Z            3
_cell_length_a                   9.9388(11)
_cell_length_b                   12.3703(13)
_cell_length_c                   14.4034(17)
_cell_measurement_reflns_used    7734
_cell_measurement_temperature    153(2)
_cell_measurement_theta_max      25.75
_cell_measurement_theta_min      2.05
_cell_volume                     1692.7(3)
_computing_cell_refinement       'CELL in IPDS Software'
_computing_data_collection       'EXPOSE in IPDS Software (Stoe & Cie, 2000)'
_computing_data_reduction        'INTEGRATE in IPDS Software'
_computing_molecular_graphics    'ORTEP-3 (Farrugia, 1997)'
_computing_publication_material  SHELXL97
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      153(2)
_diffrn_measured_fraction_theta_full 0.932
_diffrn_measured_fraction_theta_max 0.932
_diffrn_measurement_device_type  'Stoe IPDS'
_diffrn_measurement_method       φ
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0620
_diffrn_reflns_av_sigmaI/netI    0.0961
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            12013
_diffrn_reflns_theta_full        25.84
_diffrn_reflns_theta_max         25.84
_diffrn_reflns_theta_min         2.09
_diffrn_standards_decay_%        0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.972
_exptl_absorpt_correction_T_max  0.759
_exptl_absorpt_correction_T_min  0.463
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(Blessing, 1995)'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.886
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             948
_exptl_crystal_size_max          0.57
_exptl_crystal_size_mid          0.36
_exptl_crystal_size_min          0.14
_refine_diff_density_max         1.614
_refine_diff_density_min         -1.366
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.932
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     361
_refine_ls_number_reflns         6090
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.932
_refine_ls_R_factor_all          0.0823
_refine_ls_R_factor_gt           0.0525
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[σ²(Fo²)+(0.0745P)²] where P = (Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1276
_refine_ls_wR_factor_ref         0.1356
_reflns_number_gt                3899
_reflns_number_total             6090
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            dn6170.cif
_cod_data_source_block           I
_cod_database_code               2204668
_cod_database_fobs_code          2204668
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_type_symbol
C1 0.1255(8) 0.1103(9) 0.7401(8) 0.059(3) Uani d . 1 C
C2 0.1279(8) 0.0291(10) 0.6609(6) 0.055(3) Uani d . 1 C
C3 0.0877(7) -0.0878(10) 0.6739(7) 0.063(3) Uani d . 1 C
H3 0.0857 -0.1430 0.6235 0.076 Uiso calc R 1 H
C4 0.0507(8) -0.1201(10) 0.7639(8) 0.061(3) Uani d . 1 C
C5 0.0487(8) -0.0411(10) 0.8406(8) 0.064(3) Uani d . 1 C
H5 0.0226 -0.0632 0.8987 0.076 Uiso calc R 1 H
C6 0.0860(8) 0.0691(11) 0.8281(7) 0.063(3) Uani d . 1 C
H6 0.0863 0.1222 0.8798 0.076 Uiso calc R 1 H
C7 0.1718(10) 0.2290(11) 0.7344(10) 0.093(4) Uani d . 1 C
H7A 0.2649 0.2472 0.7124 0.139 Uiso calc R 1 H
H7B 0.1713 0.2704 0.7953 0.139 Uiso calc R 1 H
H7C 0.1104 0.2491 0.6918 0.139 Uiso calc R 1 H
C8 0.1719(10) 0.0610(11) 0.5664(7) 0.085(4) Uani d . 1 C
H8A 0.1866 -0.0035 0.5278 0.127 Uiso calc R 1 H
H8B 0.2570 0.1208 0.5735 0.127 Uiso calc R 1 H
H8C 0.1001 0.0861 0.5374 0.127 Uiso calc R 1 H
C9 0.0164(15) -0.2408(16) 0.7884(11) 0.145(7) Uani d . 1 C
H9A 0.0253 -0.2388 0.8551 0.217 Uiso calc R 1 H
H9B 0.0800 -0.2793 0.7589 0.217 Uiso calc R 1 H
H9C -0.0775 -0.2803 0.7668 0.217 Uiso calc R 1 H
C10 0.6866(8) 0.5254(9) 0.5235(9) 0.069(3) Uani d . 1 C
C11 0.6678(8) 0.4616(11) 0.4324(7) 0.055(3) Uani d . 1 C
C12 0.6388(8) 0.3460(10) 0.4191(7) 0.061(3) Uani d . 1 C
H12 0.6335 0.3088 0.3584 0.073 Uiso calc R 1 H
C13 0.6172(7) 0.2829(9) 0.4928(5) 0.049(2) Uani d . 1 C
C14 0.6326(7) 0.3426(8) 0.5866(5) 0.045(2) Uani d . 1 C
H14 0.6198 0.3010 0.6369 0.054 Uiso calc R 1 H
C15 0.6665(7) 0.4618(9) 0.6051(7) 0.053(2) Uani d . 1 C
H15 0.6758 0.4988 0.6660 0.064 Uiso calc R 1 H
C16 0.7256(10) 0.6494(12) 0.5466(10) 0.100(4) Uani d . 1 C
H16A 0.8155 0.6808 0.5229 0.150 Uiso calc R 1 H
H16B 0.7294 0.6692 0.6134 0.150 Uiso calc R 1 H
H16C 0.6573 0.6792 0.5187 0.150 Uiso calc R 1 H
C17 0.6960(11) 0.5261(12) 0.3475(8) 0.093(4) Uani d . 1 C
H17A 0.7167 0.4777 0.2953 0.140 Uiso calc R 1 H
H17B 0.7741 0.5914 0.3622 0.140 Uiso calc R 1 H
H17C 0.6150 0.5496 0.3316 0.140 Uiso calc R 1 H
C18 0.5893(9) 0.1576(9) 0.4761(6) 0.064(3) Uani d . 1 C
H18A 0.4916 0.1234 0.4820 0.096 Uiso calc R 1 H
H18B 0.6427 0.1333 0.5214 0.096 Uiso calc R 1 H
H18C 0.6155 0.1352 0.4143 0.096 Uiso calc R 1 H
C19 0.7873(7) 0.2514(7) 0.9430(5) 0.0368(19) Uani d . 1 C
C20 0.8349(7) 0.2710(7) 0.8499(5) 0.0337(18) Uani d . 1 C
C21 0.8107(6) 0.1786(7) 0.7789(5) 0.037(2) Uani d . 1 C
H21 0.8376 0.1918 0.7188 0.044 Uiso calc R 1 H
C22 0.7463(7) 0.0642(7) 0.7951(5) 0.0327(18) Uani d . 1 C
C23 0.7037(7) 0.0466(7) 0.8850(5) 0.0348(18) Uani d . 1 C
H23 0.6620 -0.0263 0.8980 0.042 Uiso calc R 1 H
C24 0.7240(7) 0.1396(7) 0.9571(5) 0.0362(18) Uani d . 1 C
H24 0.6937 0.1256 1.0164 0.043 Uiso calc R 1 H
C25 0.7993(9) 0.3469(8) 1.0198(5) 0.049(2) Uani d . 1 C
H25A 0.7515 0.3186 1.0730 0.073 Uiso calc R 1 H
H25B 0.7580 0.4019 0.9985 0.073 Uiso calc R 1 H
H25C 0.8960 0.3816 1.0373 0.073 Uiso calc R 1 H
C26 0.8995(8) 0.3874(7) 0.8277(6) 0.046(2) Uani d . 1 C
H26A 0.9055 0.3860 0.7611 0.069 Uiso calc R 1 H
H26B 0.9914 0.4152 0.8571 0.069 Uiso calc R 1 H
H26C 0.8430 0.4362 0.8506 0.069 Uiso calc R 1 H
C27 0.7201(7) -0.0280(7) 0.7158(5) 0.041(2) Uani d . 1 C
H27A 0.7975 -0.0609 0.7122 0.061 Uiso calc R 1 H
H27B 0.7095 0.0019 0.6586 0.061 Uiso calc R 1 H
H27C 0.6363 -0.0848 0.7252 0.061 Uiso calc R 1 H
C28 0.3694(10) 0.3691(9) 1.0527(7) 0.066(3) Uani d . 1 C
H28A 0.4097 0.4496 1.0704 0.079 Uiso calc R 1 H
H28B 0.4222 0.3438 1.0023 0.079 Uiso calc R 1 H
Cl1 0.36010(19) -0.14506(18) 0.79432(13) 0.0419(5) Uani d . 1 Cl
Cl2 0.39237(17) 0.10712(17) 0.91604(12) 0.0382(5) Uani d . 1 Cl
Cl3 0.46158(16) 0.09654(17) 0.70097(12) 0.0347(4) Uani d . 1 Cl
Cl4 0.54735(19) 0.34718(18) 0.83311(13) 0.0413(5) Uani d . 1 Cl
Cl5 1.01278(17) 0.5504(2) 0.60715(13) 0.0441(5) Uani d . 1 Cl
Cl6 0.92653(19) 0.2695(2) 0.55285(14) 0.0487(5) Uani d . 1 Cl
Cl7 0.3833(4) 0.2976(3) 1.1495(3) 0.1157(13) Uani d . 1 Cl
Cl8 0.1963(3) 0.3451(3) 1.0132(2) 0.0855(9) Uani d . 1 Cl
Ru1 0.25248(6) 0.00250(6) 0.77664(4) 0.0401(2) Uani d . 1 Ru
Ru2 0.61306(5) 0.17541(5) 0.84121(4) 0.02885(17) Uani d . 1 Ru
Ru3 0.81985(6) 0.41211(6) 0.51535(4) 0.0418(2) Uani d . 1 Ru
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
C2 C1 C7 . . 121.0(11) ?
C2 C1 C6 . . 117.9(10) ?
C7 C1 C6 . . 120.9(11) ?
C2 C1 Ru1 . . 71.0(5) ?
C7 C1 Ru1 . . 126.8(6) ?
C6 C1 Ru1 . . 69.2(5) ?
C1 C2 C3 . . 117.5(9) ?
C1 C2 C8 . . 123.2(10) ?
C3 C2 C8 . . 119.3(10) ?
C1 C2 Ru1 . . 70.5(5) ?
C3 C2 Ru1 . . 70.4(5) ?
C8 C2 Ru1 . . 129.5(6) ?
C4 C3 C2 . . 120.4(9) ?
C4 C3 Ru1 . . 70.6(5) ?
C2 C3 Ru1 . . 71.1(5) ?
C4 C3 H3 . . 119.8 ?
C2 C3 H3 . . 119.8 ?
Ru1 C3 H3 . . 131.3 ?
C5 C4 C3 . . 121.9(11) ?
C5 C4 C9 . . 112.6(11) ?
C3 C4 C9 . . 125.4(11) ?
C5 C4 Ru1 . . 72.9(5) ?
C3 C4 Ru1 . . 70.9(5) ?
C9 C4 Ru1 . . 127.1(8) ?
C6 C5 C4 . . 117.6(10) ?
C6 C5 Ru1 . . 69.4(5) ?
C4 C5 Ru1 . . 70.0(5) ?
C6 C5 H5 . . 121.2 ?
C4 C5 H5 . . 121.2 ?
Ru1 C5 H5 . . 132.0 ?
C5 C6 C1 . . 124.7(10) ?
C5 C6 Ru1 . . 74.3(6) ?
C1 C6 Ru1 . . 71.6(5) ?
C5 C6 H6 . . 117.7 ?
C1 C6 H6 . . 117.7 ?
Ru1 C6 H6 . . 129.1 ?
C1 C7 H7A . . 109.5 ?
C1 C7 H7B . . 109.5 ?
H7A C7 H7B . . 109.5 ?
C1 C7 H7C . . 109.5 ?
H7A C7 H7C . . 109.5 ?
H7B C7 H7C . . 109.5 ?
C2 C8 H8A . . 109.5 ?
C2 C8 H8B . . 109.5 ?
H8A C8 H8B . . 109.5 ?
C2 C8 H8C . . 109.5 ?
H8A C8 H8C . . 109.5 ?
H8B C8 H8C . . 109.5 ?
C4 C9 H9A . . 109.5 ?
C4 C9 H9B . . 109.5 ?
H9A C9 H9B . . 109.5 ?
C4 C9 H9C . . 109.5 ?
H9A C9 H9C . . 109.5 ?
H9B C9 H9C . . 109.5 ?
C11 C10 C16 . . 127.3(11) ?
C11 C10 C15 . . 117.5(9) ?
C16 C10 C15 . . 115.2(12) ?
C11 C10 Ru3 . . 71.1(5) ?
C16 C10 Ru3 . . 128.8(6) ?
C15 C10 Ru3 . . 70.3(5) ?
C12 C11 C10 . . 122.3(9) ?
C12 C11 C17 . . 119.2(10) ?
C10 C11 C17 . . 118.2(11) ?
C12 C11 Ru3 . . 71.5(5) ?
C10 C11 Ru3 . . 70.4(5) ?
C17 C11 Ru3 . . 126.8(6) ?
C11 C12 C13 . . 122.2(10) ?
C11 C12 Ru3 . . 71.7(5) ?
C13 C12 Ru3 . . 73.0(5) ?
C11 C12 H12 . . 118.9 ?
C13 C12 H12 . . 118.9 ?
Ru3 C12 H12 . . 128.8 ?
C12 C13 C14 . . 118.0(10) ?
C12 C13 C18 . . 120.8(9) ?
C14 C13 C18 . . 121.1(8) ?
C12 C13 Ru3 . . 70.2(5) ?
C14 C13 Ru3 . . 69.0(4) ?
C18 C13 Ru3 . . 128.7(6) ?
C15 C14 C13 . . 122.5(8) ?
C15 C14 Ru3 . . 71.3(4) ?
C13 C14 Ru3 . . 72.4(4) ?
C15 C14 H14 . . 118.7 ?
C13 C14 H14 . . 118.7 ?
Ru3 C14 H14 . . 130.3 ?
C14 C15 C10 . . 117.4(9) ?
C14 C15 Ru3 . . 70.6(5) ?
C10 C15 Ru3 . . 69.7(5) ?
C14 C15 H15 . . 121.3 ?
C10 C15 H15 . . 121.3 ?
Ru3 C15 H15 . . 130.8 ?
C10 C16 H16A . . 109.5 ?
C10 C16 H16B . . 109.5 ?
H16A C16 H16B . . 109.5 ?
C10 C16 H16C . . 109.5 ?
H16A C16 H16C . . 109.5 ?
H16B C16 H16C . . 109.5 ?
C11 C17 H17A . . 109.5 ?
C11 C17 H17B . . 109.5 ?
H17A C17 H17B . . 109.5 ?
C11 C17 H17C . . 109.5 ?
H17A C17 H17C . . 109.5 ?
H17B C17 H17C . . 109.5 ?
C13 C18 H18A . . 109.5 ?
C13 C18 H18B . . 109.5 ?
H18A C18 H18B . . 109.5 ?
C13 C18 H18C . . 109.5 ?
H18A C18 H18C . . 109.5 ?
H18B C18 H18C . . 109.5 ?
C24 C19 C20 . . 117.4(7) ?
C24 C19 C25 . . 121.0(7) ?
C20 C19 C25 . . 121.6(7) ?
C24 C19 Ru2 . . 69.5(4) ?
C20 C19 Ru2 . . 71.3(4) ?
C25 C19 Ru2 . . 127.8(5) ?
C21 C20 C19 . . 118.8(7) ?
C21 C20 C26 . . 120.0(7) ?
C19 C20 C26 . . 121.1(7) ?
C21 C20 Ru2 . . 69.7(4) ?
C19 C20 Ru2 . . 70.0(4) ?
C26 C20 Ru2 . . 129.0(5) ?
C20 C21 C22 . . 122.9(7) ?
C20 C21 Ru2 . . 72.8(4) ?
C22 C21 Ru2 . . 72.2(4) ?
C20 C21 H21 . . 118.6 ?
C22 C21 H21 . . 118.6 ?
Ru2 C21 H21 . . 128.9 ?
C23 C22 C21 . . 117.6(7) ?
C23 C22 C27 . . 122.8(7) ?
C21 C22 C27 . . 119.5(6) ?
C23 C22 Ru2 . . 70.6(4) ?
C21 C22 Ru2 . . 69.3(4) ?
C27 C22 Ru2 . . 128.3(5) ?
C22 C23 C24 . . 120.2(7) ?
C22 C23 Ru2 . . 72.4(4) ?
C24 C23 Ru2 . . 69.5(4) ?
C22 C23 H23 . . 119.9 ?
C24 C23 H23 . . 119.9 ?
Ru2 C23 H23 . . 130.9 ?
C19 C24 C23 . . 123.1(7) ?
C19 C24 Ru2 . . 72.7(4) ?
C23 C24 Ru2 . . 72.1(4) ?
C19 C24 H24 . . 118.5 ?
C23 C24 H24 . . 118.5 ?
Ru2 C24 H24 . . 129.4 ?
C19 C25 H25A . . 109.5 ?
C19 C25 H25B . . 109.5 ?
H25A C25 H25B . . 109.5 ?
C19 C25 H25C . . 109.5 ?
H25A C25 H25C . . 109.5 ?
H25B C25 H25C . . 109.5 ?
C20 C26 H26A . . 109.5 ?
C20 C26 H26B . . 109.5 ?
H26A C26 H26B . . 109.5 ?
C20 C26 H26C . . 109.5 ?
H26A C26 H26C . . 109.5 ?
H26B C26 H26C . . 109.5 ?
C22 C27 H27A . . 109.5 ?
C22 C27 H27B . . 109.5 ?
H27A C27 H27B . . 109.5 ?
C22 C27 H27C . . 109.5 ?
H27A C27 H27C . . 109.5 ?
H27B C27 H27C . . 109.5 ?
Cl8 C28 Cl7 . . 111.9(5) ?
Cl8 C28 H28A . . 109.2 ?
Cl7 C28 H28A . . 109.2 ?
Cl8 C28 H28B . . 109.2 ?
Cl7 C28 H28B . . 109.2 ?
H28A C28 H28B . . 107.9 ?
Ru1 Cl2 Ru2 . . 98.13(6) yes
Ru1 Cl3 Ru2 . . 98.44(6) yes
Ru3 Cl5 Ru3 2_766 . 99.36(7) yes
C6 Ru1 C4 . . 66.0(4) ?
C6 Ru1 C3 . . 80.0(4) ?
C4 Ru1 C3 . . 38.5(4) ?
C6 Ru1 C1 . . 39.2(4) ?
C4 Ru1 C1 . . 81.1(4) ?
C3 Ru1 C1 . . 68.7(4) ?
C6 Ru1 C2 . . 69.6(4) ?
C4 Ru1 C2 . . 69.8(4) ?
C3 Ru1 C2 . . 38.5(4) ?
C1 Ru1 C2 . . 38.4(4) ?
C6 Ru1 C5 . . 36.3(4) ?
C4 Ru1 C5 . . 37.1(4) ?
C3 Ru1 C5 . . 68.6(4) ?
C1 Ru1 C5 . . 69.1(4) ?
C2 Ru1 C5 . . 82.6(4) ?
C6 Ru1 Cl1 . . 141.4(3) ?
C4 Ru1 Cl1 . . 89.4(3) ?
C3 Ru1 Cl1 . . 99.4(3) ?
C1 Ru1 Cl1 . . 168.1(3) ?
C2 Ru1 Cl1 . . 131.1(3) ?
C5 Ru1 Cl1 . . 107.2(3) ?
C6 Ru1 Cl3 . . 128.8(3) ?
C4 Ru1 Cl3 . . 148.2(3) ?
C3 Ru1 Cl3 . . 111.0(3) ?
C1 Ru1 Cl3 . . 96.4(3) ?
C2 Ru1 Cl3 . . 88.5(2) ?
C5 Ru1 Cl3 . . 164.9(3) ?
Cl1 Ru1 Cl3 . . 87.82(7) yes
C6 Ru1 Cl2 . . 87.6(3) ?
C4 Ru1 Cl2 . . 130.3(3) ?
C3 Ru1 Cl2 . . 166.4(2) ?
C1 Ru1 Cl2 . . 104.8(3) ?
C2 Ru1 Cl2 . . 140.5(3) ?
C5 Ru1 Cl2 . . 98.1(3) ?
Cl1 Ru1 Cl2 . . 86.79(7) yes
Cl3 Ru1 Cl2 . . 81.11(6) yes
C24 Ru2 C21 . . 80.2(3) ?
C24 Ru2 C23 . . 38.4(3) ?
C21 Ru2 C23 . . 67.8(3) ?
C24 Ru2 C19 . . 37.8(3) ?
C21 Ru2 C19 . . 68.9(3) ?
C23 Ru2 C19 . . 69.3(3) ?
C24 Ru2 C22 . . 68.3(3) ?
C21 Ru2 C22 . . 38.5(3) ?
C23 Ru2 C22 . . 37.0(3) ?
C19 Ru2 C22 . . 82.3(3) ?
C24 Ru2 C20 . . 68.2(3) ?
C21 Ru2 C20 . . 37.5(3) ?
C23 Ru2 C20 . . 81.0(3) ?
C19 Ru2 C20 . . 38.7(3) ?
C22 Ru2 C20 . . 69.1(3) ?
C24 Ru2 Cl4 . . 125.5(2) ?
C21 Ru2 Cl4 . . 112.2(2) ?
C23 Ru2 Cl4 . . 163.7(2) ?
C19 Ru2 Cl4 . . 95.2(2) ?
C22 Ru2 Cl4 . . 149.38(19) ?
C20 Ru2 Cl4 . . 89.9(2) ?
C24 Ru2 Cl3 . . 146.1(2) ?
C21 Ru2 Cl3 . . 97.95(19) ?
C23 Ru2 Cl3 . . 109.4(2) ?
C19 Ru2 Cl3 . . 166.50(19) ?
C22 Ru2 Cl3 . . 89.15(19) ?
C20 Ru2 Cl3 . . 128.14(19) ?
Cl4 Ru2 Cl3 . . 86.82(7) yes
C24 Ru2 Cl2 . . 89.9(2) ?
C21 Ru2 Cl2 . . 160.7(2) ?
C23 Ru2 Cl2 . . 94.23(19) ?
C19 Ru2 Cl2 . . 112.40(19) ?
C22 Ru2 Cl2 . . 122.3(2) ?
C20 Ru2 Cl2 . . 150.5(2) ?
Cl4 Ru2 Cl2 . . 86.97(7) yes
Cl3 Ru2 Cl2 . . 81.01(6) yes
C14 Ru3 C10 . . 69.7(3) ?
C14 Ru3 C12 . . 67.9(3) ?
C10 Ru3 C12 . . 68.9(4) ?
C14 Ru3 C15 . . 38.1(3) ?
C10 Ru3 C15 . . 39.9(4) ?
C12 Ru3 C15 . . 82.1(4) ?
C14 Ru3 C11 . . 80.1(3) ?
C10 Ru3 C11 . . 38.5(4) ?
C12 Ru3 C11 . . 36.8(4) ?
C15 Ru3 C11 . . 69.9(3) ?
C14 Ru3 C13 . . 38.6(3) ?
C10 Ru3 C13 . . 82.1(4) ?
C12 Ru3 C13 . . 36.7(3) ?
C15 Ru3 C13 . . 69.8(3) ?
C11 Ru3 C13 . . 66.7(4) ?
C14 Ru3 Cl6 . . 92.7(3) ?
C10 Ru3 Cl6 . . 160.5(3) ?
C12 Ru3 Cl6 . . 113.1(3) ?
C15 Ru3 Cl6 . . 120.6(3) ?
C11 Ru3 Cl6 . . 149.5(3) ?
C13 Ru3 Cl6 . . 89.3(3) ?
C14 Ru3 Cl5 . 2_766 161.5(2) ?
C10 Ru3 Cl5 . 2_766 111.6(3) ?
C12 Ru3 Cl5 . 2_766 94.9(3) ?
C15 Ru3 Cl5 . 2_766 150.4(3) ?
C11 Ru3 Cl5 . 2_766 90.1(2) ?
C13 Ru3 Cl5 . 2_766 123.0(2) ?
Cl6 Ru3 Cl5 . 2_766 87.71(7) ?
C14 Ru3 Cl5 . . 117.9(2) ?
C10 Ru3 Cl5 . . 93.6(3) ?
C12 Ru3 Cl5 . . 159.2(3) ?
C15 Ru3 Cl5 . . 91.8(2) ?
C11 Ru3 Cl5 . . 122.5(3) ?
C13 Ru3 Cl5 . . 155.9(2) ?
Cl6 Ru3 Cl5 . . 87.15(7) yes
Cl5 Ru3 Cl5 2_766 . 80.64(7) yes
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
C1 C2 . 1.429(14) ?
C1 C7 . 1.431(14) ?
C1 C6 . 1.444(14) ?
C1 Ru1 . 2.167(9) ?
C2 C3 . 1.432(14) ?
C2 C8 . 1.502(13) ?
C2 Ru1 . 2.174(9) ?
C3 C4 . 1.426(14) ?
C3 Ru1 . 2.165(8) ?
C3 H3 . 0.9300 ?
C4 C5 . 1.386(14) ?
C4 C9 . 1.53(2) ?
C4 Ru1 . 2.161(8) ?
C5 C6 . 1.350(14) ?
C5 Ru1 . 2.198(8) ?
C5 H5 . 0.9300 ?
C6 Ru1 . 2.136(8) ?
C6 H6 . 0.9300 ?
C7 H7A . 0.9600 ?
C7 H7B . 0.9600 ?
C7 H7C . 0.9600 ?
C8 H8A . 0.9600 ?
C8 H8B . 0.9600 ?
C8 H8C . 0.9600 ?
C9 H9A . 0.9600 ?
C9 H9B . 0.9600 ?
C9 H9C . 0.9600 ?
C10 C11 . 1.429(15) ?
C10 C16 . 1.473(16) ?
C10 C15 . 1.480(14) ?
C10 Ru3 . 2.163(9) ?
C11 C12 . 1.371(14) ?
C11 C17 . 1.530(13) ?
C11 Ru3 . 2.173(8) ?
C12 C13 . 1.380(13) ?
C12 Ru3 . 2.171(8) ?
C12 H12 . 0.9300 ?
C13 C14 . 1.443(11) ?
C13 C18 . 1.489(14) ?
C13 Ru3 . 2.206(8) ?
C14 C15 . 1.413(12) ?
C14 Ru3 . 2.161(7) ?
C14 H14 . 0.9300 ?
C15 Ru3 . 2.171(8) ?
C15 H15 . 0.9300 ?
C16 H16A . 0.9600 ?
C16 H16B . 0.9600 ?
C16 H16C . 0.9600 ?
C17 H17A . 0.9600 ?
C17 H17B . 0.9600 ?
C17 H17C . 0.9600 ?
C18 H18A . 0.9600 ?
C18 H18B . 0.9600 ?
C18 H18C . 0.9600 ?
C19 C24 . 1.401(11) ?
C19 C20 . 1.454(10) ?
C19 C25 . 1.494(11) ?
C19 Ru2 . 2.184(7) ?
C20 C21 . 1.403(11) ?
C20 C26 . 1.489(11) ?
C20 Ru2 . 2.203(7) ?
C21 C22 . 1.440(11) ?
C21 Ru2 . 2.162(6) ?
C21 H21 . 0.9300 ?
C22 C23 . 1.391(10) ?
C22 C27 . 1.478(11) ?
C22 Ru2 . 2.201(7) ?
C23 C24 . 1.421(11) ?
C23 Ru2 . 2.178(7) ?
C23 H23 . 0.9300 ?
C24 Ru2 . 2.144(7) ?
C24 H24 . 0.9300 ?
C25 H25A . 0.9600 ?
C25 H25B . 0.9600 ?
C25 H25C . 0.9600 ?
C26 H26A . 0.9600 ?
C26 H26B . 0.9600 ?
C26 H26C . 0.9600 ?
C27 H27A . 0.9600 ?
C27 H27B . 0.9600 ?
C27 H27C . 0.9600 ?
C28 Cl8 . 1.744(10) ?
C28 Cl7 . 1.763(10) ?
C28 H28A . 0.9700 ?
C28 H28B . 0.9700 ?
Cl1 Ru1 . 2.384(2) yes
Cl2 Ru1 . 2.446(2) yes
Cl2 Ru2 . 2.4461(17) yes
Cl3 Ru1 . 2.4380(17) yes
Cl3 Ru2 . 2.4423(18) yes
Cl4 Ru2 . 2.398(2) yes
Cl5 Ru3 2_766 2.4404(18) yes
Cl5 Ru3 . 2.449(2) yes
Cl6 Ru3 . 2.396(2) yes
Ru3 Cl5 2_766 2.4404(18) ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
_geom_torsion
C7 C1 C2 C3 . . 176.3(7)
C6 C1 C2 C3 . . 1.4(10)
Ru1 C1 C2 C3 . . 54.1(6)
C7 C1 C2 C8 . . -2.9(12)
C6 C1 C2 C8 . . -177.8(7)
Ru1 C1 C2 C8 . . -125.1(8)
C7 C1 C2 Ru1 . . 122.2(8)
C6 C1 C2 Ru1 . . -52.7(6)
C1 C2 C3 C4 . . -1.7(11)
C8 C2 C3 C4 . . 177.6(7)
Ru1 C2 C3 C4 . . 52.6(7)
C1 C2 C3 Ru1 . . -54.2(6)
C8 C2 C3 Ru1 . . 125.0(7)
C2 C3 C4 C5 . . 1.6(12)
Ru1 C3 C4 C5 . . 54.4(7)
C2 C3 C4 C9 . . -175.3(9)
Ru1 C3 C4 C9 . . -122.5(10)
C2 C3 C4 Ru1 . . -52.8(7)
C3 C4 C5 C6 . . -1.3(12)
C9 C4 C5 C6 . . 176.0(9)
Ru1 C4 C5 C6 . . 52.2(7)
C3 C4 C5 Ru1 . . -53.5(7)
C9 C4 C5 Ru1 . . 123.8(9)
C4 C5 C6 C1 . . 1.1(13)
Ru1 C5 C6 C1 . . 53.6(7)
C4 C5 C6 Ru1 . . -52.5(7)
C2 C1 C6 C5 . . -1.2(12)
C7 C1 C6 C5 . . -176.1(8)
Ru1 C1 C6 C5 . . -54.8(8)
C2 C1 C6 Ru1 . . 53.6(6)
C7 C1 C6 Ru1 . . -121.3(8)
C16 C10 C11 C12 . . 176.3(8)
C15 C10 C11 C12 . . -3.1(11)
Ru3 C10 C11 C12 . . 51.5(7)
C16 C10 C11 C17 . . 2.8(12)
C15 C10 C11 C17 . . -176.6(7)
Ru3 C10 C11 C17 . . -122.1(7)
C16 C10 C11 Ru3 . . 124.8(8)
C15 C10 C11 Ru3 . . -54.6(6)
C10 C11 C12 C13 . . 4.2(12)
C17 C11 C12 C13 . . 177.6(7)
Ru3 C11 C12 C13 . . 55.1(7)
C10 C11 C12 Ru3 . . -51.0(7)
C17 C11 C12 Ru3 . . 122.5(7)
C11 C12 C13 C14 . . -3.0(11)
Ru3 C12 C13 C14 . . 51.5(6)
C11 C12 C13 C18 . . -178.5(8)
Ru3 C12 C13 C18 . . -124.0(7)
C11 C12 C13 Ru3 . . -54.5(7)
C12 C13 C14 C15 . . 1.0(11)
C18 C13 C14 C15 . . 176.6(7)
Ru3 C13 C14 C15 . . 53.1(6)
C12 C13 C14 Ru3 . . -52.1(6)
C18 C13 C14 Ru3 . . 123.4(7)
C13 C14 C15 C10 . . -0.2(10)
Ru3 C14 C15 C10 . . 53.4(6)
C13 C14 C15 Ru3 . . -53.6(6)
C11 C10 C15 C14 . . 1.1(10)
C16 C10 C15 C14 . . -178.4(7)
Ru3 C10 C15 C14 . . -53.8(6)
C11 C10 C15 Ru3 . . 55.0(6)
C16 C10 C15 Ru3 . . -124.5(7)
C24 C19 C20 C21 . . 2.3(9)
C25 C19 C20 C21 . . -175.0(7)
Ru2 C19 C20 C21 . . -51.5(6)
C24 C19 C20 C26 . . 178.1(7)
C25 C19 C20 C26 . . 0.7(10)
Ru2 C19 C20 C26 . . 124.3(7)
C24 C19 C20 Ru2 . . 53.8(6)
C25 C19 C20 Ru2 . . -123.5(7)
C19 C20 C21 C22 . . -2.9(10)
C26 C20 C21 C22 . . -178.7(6)
Ru2 C20 C21 C22 . . -54.5(6)
C19 C20 C21 Ru2 . . 51.6(6)
C26 C20 C21 Ru2 . . -124.2(6)
C20 C21 C22 C23 . . 1.6(10)
Ru2 C21 C22 C23 . . -53.2(5)
C20 C21 C22 C27 . . 177.9(6)
Ru2 C21 C22 C27 . . 123.1(6)
C20 C21 C22 Ru2 . . 54.8(6)
C21 C22 C23 C24 . . 0.2(9)
C27 C22 C23 C24 . . -176.0(6)
Ru2 C22 C23 C24 . . -52.4(6)
C21 C22 C23 Ru2 . . 52.6(5)
C27 C22 C23 Ru2 . . -123.6(6)
C20 C19 C24 C23 . . -0.6(10)
C25 C19 C24 C23 . . 176.7(7)
Ru2 C19 C24 C23 . . 54.1(6)
C20 C19 C24 Ru2 . . -54.7(5)
C25 C19 C24 Ru2 . . 122.6(7)
C22 C23 C24 C19 . . -0.6(10)
Ru2 C23 C24 C19 . . -54.3(6)
C22 C23 C24 Ru2 . . 53.7(6)
C5 C6 Ru1 C4 . . 29.6(6)
C1 C6 Ru1 C4 . . -106.1(7)
C5 C6 Ru1 C3 . . 67.3(7)
C1 C6 Ru1 C3 . . -68.5(6)
C5 C6 Ru1 C1 . . 135.7(9)
C5 C6 Ru1 C2 . . 105.8(7)
C1 C6 Ru1 C2 . . -29.9(6)
C1 C6 Ru1 C5 . . -135.7(9)
C5 C6 Ru1 Cl1 . . -25.3(9)
C1 C6 Ru1 Cl1 . . -161.0(4)
C5 C6 Ru1 Cl3 . . 176.3(5)
C1 C6 Ru1 Cl3 . . 40.6(7)
C5 C6 Ru1 Cl2 . . -107.1(6)
C1 C6 Ru1 Cl2 . . 117.2(6)
C5 C4 Ru1 C6 . . -29.0(6)
C3 C4 Ru1 C6 . . 104.8(7)
C9 C4 Ru1 C6 . . -134.8(12)
C5 C4 Ru1 C3 . . -133.8(10)
C9 C4 Ru1 C3 . . 120.4(13)
C5 C4 Ru1 C1 . . -66.9(7)
C3 C4 Ru1 C1 . . 66.9(6)
C9 C4 Ru1 C1 . . -172.7(12)
C5 C4 Ru1 C2 . . -105.0(7)
C3 C4 Ru1 C2 . . 28.8(6)
C9 C4 Ru1 C2 . . 149.2(12)
C3 C4 Ru1 C5 . . 133.8(10)
C9 C4 Ru1 C5 . . -105.8(13)
C5 C4 Ru1 Cl1 . . 120.3(6)
C3 C4 Ru1 Cl1 . . -105.9(6)
C9 C4 Ru1 Cl1 . . 14.5(11)
C5 C4 Ru1 Cl3 . . -154.7(6)
C3 C4 Ru1 Cl3 . . -21.0(10)
C9 C4 Ru1 Cl3 . . 99.4(11)
C5 C4 Ru1 Cl2 . . 35.0(8)
C3 C4 Ru1 Cl2 . . 168.8(5)
C9 C4 Ru1 Cl2 . . -70.8(12)
C4 C3 Ru1 C6 . . -63.7(6)
C2 C3 Ru1 C6 . . 69.7(6)
C2 C3 Ru1 C4 . . 133.4(8)
C4 C3 Ru1 C1 . . -102.9(7)
C2 C3 Ru1 C1 . . 30.6(5)
C4 C3 Ru1 C2 . . -133.4(8)
C4 C3 Ru1 C5 . . -27.9(6)
C2 C3 Ru1 C5 . . 105.6(6)
C4 C3 Ru1 Cl1 . . 77.1(6)
C2 C3 Ru1 Cl1 . . -149.5(5)
C4 C3 Ru1 Cl3 . . 168.3(5)
C2 C3 Ru1 Cl3 . . -58.2(5)
C4 C3 Ru1 Cl2 . . -39.2(17)
C2 C3 Ru1 Cl2 . . 94.3(14)
C2 C1 Ru1 C6 . . -131.2(8)
C7 C1 Ru1 C6 . . 113.7(13)
C2 C1 Ru1 C4 . . -68.6(6)
C7 C1 Ru1 C4 . . 176.4(12)
C6 C1 Ru1 C4 . . 62.7(6)
C2 C1 Ru1 C3 . . -30.7(5)
C7 C1 Ru1 C3 . . -145.7(12)
C6 C1 Ru1 C3 . . 100.6(7)
C7 C1 Ru1 C2 . . -115.1(13)
C6 C1 Ru1 C2 . . 131.2(8)
C2 C1 Ru1 C5 . . -105.0(6)
C7 C1 Ru1 C5 . . 139.9(12)
C6 C1 Ru1 C5 . . 26.3(6)
C2 C1 Ru1 Cl1 . . -31.0(17)
C7 C1 Ru1 Cl1 . . -146.1(10)
C6 C1 Ru1 Cl1 . . 100.2(15)
C2 C1 Ru1 Cl3 . . 79.4(5)
C7 C1 Ru1 Cl3 . . -35.6(11)
C6 C1 Ru1 Cl3 . . -149.3(6)
C2 C1 Ru1 Cl2 . . 161.9(5)
C7 C1 Ru1 Cl2 . . 46.8(11)
C6 C1 Ru1 Cl2 . . -66.9(6)
C1 C2 Ru1 C6 . . 30.5(6)
C3 C2 Ru1 C6 . . -99.8(6)
C8 C2 Ru1 C6 . . 147.9(12)
C1 C2 Ru1 C4 . . 101.5(6)
C3 C2 Ru1 C4 . . -28.8(5)
C8 C2 Ru1 C4 . . -141.1(12)
C1 C2 Ru1 C3 . . 130.3(8)
C8 C2 Ru1 C3 . . -112.3(13)
C3 C2 Ru1 C1 . . -130.3(8)
C8 C2 Ru1 C1 . . 117.4(13)
C1 C2 Ru1 C5 . . 65.5(6)
C3 C2 Ru1 C5 . . -64.8(6)
C8 C2 Ru1 C5 . . -177.1(11)
C1 C2 Ru1 Cl1 . . 171.9(4)
C3 C2 Ru1 Cl1 . . 41.7(6)
C8 C2 Ru1 Cl1 . . -70.6(11)
C1 C2 Ru1 Cl3 . . -102.3(5)
C3 C2 Ru1 Cl3 . . 127.5(5)
C8 C2 Ru1 Cl3 . . 15.2(11)
C1 C2 Ru1 Cl2 . . -28.2(7)
C3 C2 Ru1 Cl2 . . -158.4(4)
C8 C2 Ru1 Cl2 . . 89.3(11)
C4 C5 Ru1 C6 . . 131.6(10)
C6 C5 Ru1 C4 . . -131.6(10)
C6 C5 Ru1 C3 . . -102.7(7)
C4 C5 Ru1 C3 . . 28.9(7)
C6 C5 Ru1 C1 . . -28.2(6)
C4 C5 Ru1 C1 . . 103.4(7)
C6 C5 Ru1 C2 . . -65.5(7)
C4 C5 Ru1 C2 . . 66.1(7)
C6 C5 Ru1 Cl1 . . 163.8(6)
C4 C5 Ru1 Cl1 . . -64.7(7)
C6 C5 Ru1 Cl3 . . -11.1(15)
C4 C5 Ru1 Cl3 . . 120.5(11)
C6 C5 Ru1 Cl2 . . 74.6(6)
C4 C5 Ru1 Cl2 . . -153.8(6)
Ru2 Cl3 Ru1 C6 . . 88.3(3)
Ru2 Cl3 Ru1 C4 . . -163.8(6)
Ru2 Cl3 Ru1 C3 . . -177.6(3)
Ru2 Cl3 Ru1 C1 . . 112.8(3)
Ru2 Cl3 Ru1 C2 . . 150.4(3)
Ru2 Cl3 Ru1 C5 . . 96.7(11)
Ru2 Cl3 Ru1 Cl1 . . -78.38(8)
Ru2 Cl3 Ru1 Cl2 . . 8.72(7)
Ru2 Cl2 Ru1 C6 . . -138.6(3)
Ru2 Cl2 Ru1 C4 . . 166.1(4)
Ru2 Cl2 Ru1 C3 . . -162.8(14)
Ru2 Cl2 Ru1 C1 . . -103.1(3)
Ru2 Cl2 Ru1 C2 . . -85.4(4)
Ru2 Cl2 Ru1 C5 . . -173.4(3)
Ru2 Cl2 Ru1 Cl1 . . 79.59(7)
Ru2 Cl2 Ru1 Cl3 . . -8.70(7)
C19 C24 Ru2 C21 . . 68.1(5)
C23 C24 Ru2 C21 . . -66.5(4)
C19 C24 Ru2 C23 . . 134.5(6)
C23 C24 Ru2 C19 . . -134.5(6)
C19 C24 Ru2 C22 . . 106.2(5)
C23 C24 Ru2 C22 . . -28.3(4)
C19 C24 Ru2 C20 . . 31.0(4)
C23 C24 Ru2 C20 . . -103.5(5)
C19 C24 Ru2 Cl4 . . -42.3(5)
C23 C24 Ru2 Cl4 . . -176.9(3)
C19 C24 Ru2 Cl3 . . 157.8(3)
C23 C24 Ru2 Cl3 . . 23.2(6)
C19 C24 Ru2 Cl2 . . -128.6(4)
C23 C24 Ru2 Cl2 . . 96.9(4)
C20 C21 Ru2 C24 . . -66.9(5)
C22 C21 Ru2 C24 . . 67.2(4)
C20 C21 Ru2 C23 . . -104.8(5)
C22 C21 Ru2 C23 . . 29.3(4)
C20 C21 Ru2 C19 . . -29.4(4)
C22 C21 Ru2 C19 . . 104.7(5)
C20 C21 Ru2 C22 . . -134.1(6)
C22 C21 Ru2 C20 . . 134.1(6)
C20 C21 Ru2 Cl4 . . 57.6(4)
C22 C21 Ru2 Cl4 . . -168.3(3)
C20 C21 Ru2 Cl3 . . 147.4(4)
C22 C21 Ru2 Cl3 . . -78.5(4)
C20 C21 Ru2 Cl2 . . -127.1(6)
C22 C21 Ru2 Cl2 . . 7.0(8)
C22 C23 Ru2 C24 . . -133.1(6)
C22 C23 Ru2 C21 . . -30.4(4)
C24 C23 Ru2 C21 . . 102.7(5)
C22 C23 Ru2 C19 . . -105.2(5)
C24 C23 Ru2 C19 . . 27.8(4)
C24 C23 Ru2 C22 . . 133.1(6)
C22 C23 Ru2 C20 . . -67.0(4)
C24 C23 Ru2 C20 . . 66.1(4)
C22 C23 Ru2 Cl4 . . -123.9(6)
C24 C23 Ru2 Cl4 . . 9.1(9)
C22 C23 Ru2 Cl3 . . 60.4(4)
C24 C23 Ru2 Cl3 . . -166.5(4)
C22 C23 Ru2 Cl2 . . 142.4(4)
C24 C23 Ru2 Cl2 . . -84.6(4)
C20 C19 Ru2 C24 . . 130.1(7)
C25 C19 Ru2 C24 . . -113.9(8)
C24 C19 Ru2 C21 . . -101.6(5)
C20 C19 Ru2 C21 . . 28.5(5)
C25 C19 Ru2 C21 . . 144.5(8)
C24 C19 Ru2 C23 . . -28.2(4)
C20 C19 Ru2 C23 . . 101.8(5)
C25 C19 Ru2 C23 . . -142.2(7)
C24 C19 Ru2 C22 . . -64.1(5)
C20 C19 Ru2 C22 . . 65.9(5)
C25 C19 Ru2 C22 . . -178.1(7)
C24 C19 Ru2 C20 . . -130.1(7)
C25 C19 Ru2 C20 . . 116.0(9)
C24 C19 Ru2 Cl4 . . 146.6(4)
C20 C19 Ru2 Cl4 . . -83.3(4)
C25 C19 Ru2 Cl4 . . 32.6(7)
C24 C19 Ru2 Cl3 . . -115.4(9)
C20 C19 Ru2 Cl3 . . 14.7(12)
C25 C19 Ru2 Cl3 . . 130.7(8)
C24 C19 Ru2 Cl2 . . 57.7(5)
C20 C19 Ru2 Cl2 . . -172.2(4)
C25 C19 Ru2 Cl2 . . -56.2(7)
C23 C22 Ru2 C24 . . 29.2(4)
C21 C22 Ru2 C24 . . -102.0(4)
C27 C22 Ru2 C24 . . 146.2(7)
C23 C22 Ru2 C21 . . 131.2(6)
C27 C22 Ru2 C21 . . -111.9(8)
C21 C22 Ru2 C23 . . -131.2(6)
C27 C22 Ru2 C23 . . 116.9(8)
C23 C22 Ru2 C19 . . 65.6(5)
C21 C22 Ru2 C19 . . -65.6(4)
C27 C22 Ru2 C19 . . -177.5(7)
C23 C22 Ru2 C20 . . 103.3(5)
C21 C22 Ru2 C20 . . -27.9(4)
C27 C22 Ru2 C20 . . -139.8(7)
C23 C22 Ru2 Cl4 . . 152.8(4)
C21 C22 Ru2 Cl4 . . 21.6(6)
C27 C22 Ru2 Cl4 . . -90.3(7)
C23 C22 Ru2 Cl3 . . -124.9(4)
C21 C22 Ru2 Cl3 . . 103.9(4)
C27 C22 Ru2 Cl3 . . -7.9(6)
C23 C22 Ru2 Cl2 . . -46.1(5)
C21 C22 Ru2 Cl2 . . -177.3(3)
C27 C22 Ru2 Cl2 . . 70.9(7)
C21 C20 Ru2 C24 . . 102.7(5)
C19 C20 Ru2 C24 . . -30.3(5)
C26 C20 Ru2 C24 . . -144.6(8)
C19 C20 Ru2 C21 . . -133.0(7)
C26 C20 Ru2 C21 . . 112.7(8)
C21 C20 Ru2 C23 . . 65.0(5)
C19 C20 Ru2 C23 . . -68.0(5)
C26 C20 Ru2 C23 . . 177.7(7)
C21 C20 Ru2 C19 . . 133.0(7)
C26 C20 Ru2 C19 . . -114.3(9)
C21 C20 Ru2 C22 . . 28.6(4)
C19 C20 Ru2 C22 . . -104.4(5)
C26 C20 Ru2 C22 . . 141.3(7)
C21 C20 Ru2 Cl4 . . -128.6(4)
C19 C20 Ru2 Cl4 . . 98.4(4)
C26 C20 Ru2 Cl4 . . -15.9(7)
C21 C20 Ru2 Cl3 . . -42.7(5)
C19 C20 Ru2 Cl3 . . -175.7(4)
C26 C20 Ru2 Cl3 . . 70.0(8)
C21 C20 Ru2 Cl2 . . 147.7(4)
C19 C20 Ru2 Cl2 . . 14.7(7)
C26 C20 Ru2 Cl2 . . -99.6(7)
Ru1 Cl3 Ru2 C24 . . 67.6(4)
Ru1 Cl3 Ru2 C21 . . 151.8(2)
Ru1 Cl3 Ru2 C23 . . 82.6(2)
Ru1 Cl3 Ru2 C19 . . 164.8(10)
Ru1 Cl3 Ru2 C22 . . 114.2(2)
Ru1 Cl3 Ru2 C20 . . 176.5(3)
Ru1 Cl3 Ru2 Cl4 . . -96.15(7)
Ru1 Cl3 Ru2 Cl2 . . -8.72(7)
Ru1 Cl2 Ru2 C24 . . -138.5(2)
Ru1 Cl2 Ru2 C21 . . -79.7(6)
Ru1 Cl2 Ru2 C23 . . -100.3(2)
Ru1 Cl2 Ru2 C19 . . -169.7(2)
Ru1 Cl2 Ru2 C22 . . -74.5(2)
Ru1 Cl2 Ru2 C20 . . -179.6(4)
Ru1 Cl2 Ru2 Cl4 . . 95.95(8)
Ru1 Cl2 Ru2 Cl3 . . 8.69(7)
C15 C14 Ru3 C10 . . -31.3(6)
C13 C14 Ru3 C10 . . 103.3(6)
C15 C14 Ru3 C12 . . -106.1(6)
C13 C14 Ru3 C12 . . 28.6(6)
C13 C14 Ru3 C15 . . 134.6(8)
C15 C14 Ru3 C11 . . -69.8(6)
C13 C14 Ru3 C11 . . 64.8(6)
C15 C14 Ru3 C13 . . -134.6(8)
C15 C14 Ru3 Cl6 . . 140.0(5)
C13 C14 Ru3 Cl6 . . -85.4(5)
C15 C14 Ru3 Cl5 . 2_766 -129.0(7)
C13 C14 Ru3 Cl5 . 2_766 5.6(12)
C15 C14 Ru3 Cl5 . . 51.8(6)
C13 C14 Ru3 Cl5 . . -173.6(5)
C11 C10 Ru3 C14 . . -99.9(6)
C16 C10 Ru3 C14 . . 137.0(13)
C15 C10 Ru3 C14 . . 30.0(5)
C11 C10 Ru3 C12 . . -26.6(5)
C16 C10 Ru3 C12 . . -149.7(13)
C15 C10 Ru3 C12 . . 103.3(6)
C11 C10 Ru3 C15 . . -129.9(8)
C16 C10 Ru3 C15 . . 107.0(15)
C16 C10 Ru3 C11 . . -123.1(14)
C15 C10 Ru3 C11 . . 129.9(8)
C11 C10 Ru3 C13 . . -62.1(6)
C16 C10 Ru3 C13 . . 174.8(13)
C15 C10 Ru3 C13 . . 67.8(5)
C11 C10 Ru3 Cl6 . . -126.6(9)
C16 C10 Ru3 Cl6 . . 110.3(11)
C15 C10 Ru3 Cl6 . . 3.3(13)
C11 C10 Ru3 Cl5 . 2_766 60.3(6)
C16 C10 Ru3 Cl5 . 2_766 -62.8(13)
C15 C10 Ru3 Cl5 . 2_766 -169.8(5)
C11 C10 Ru3 Cl5 . . 141.7(5)
C16 C10 Ru3 Cl5 . . 18.6(12)
C15 C10 Ru3 Cl5 . . -88.4(5)
C11 C12 Ru3 C14 . . 103.5(6)
C13 C12 Ru3 C14 . . -29.9(6)
C11 C12 Ru3 C10 . . 27.7(5)
C13 C12 Ru3 C10 . . -105.7(7)
C11 C12 Ru3 C15 . . 66.8(6)
C13 C12 Ru3 C15 . . -66.6(6)
C13 C12 Ru3 C11 . . -133.4(9)
C11 C12 Ru3 C13 . . 133.4(9)
C11 C12 Ru3 Cl6 . . -173.2(5)
C13 C12 Ru3 Cl6 . . 53.4(6)
C11 C12 Ru3 Cl5 . 2_766 -83.6(5)
C13 C12 Ru3 Cl5 . 2_766 143.0(6)
C11 C12 Ru3 Cl5 . . -7.0(11)
C13 C12 Ru3 Cl5 . . -140.5(6)
C10 C15 Ru3 C14 . . -130.5(8)
C14 C15 Ru3 C10 . . 130.5(8)
C14 C15 Ru3 C12 . . 64.0(6)
C10 C15 Ru3 C12 . . -66.5(6)
C14 C15 Ru3 C11 . . 99.9(6)
C10 C15 Ru3 C11 . . -30.6(6)
C14 C15 Ru3 C13 . . 28.2(5)
C10 C15 Ru3 C13 . . -102.3(6)
C14 C15 Ru3 Cl6 . . -48.2(6)
C10 C15 Ru3 Cl6 . . -178.7(5)
C14 C15 Ru3 Cl5 . 2_766 150.0(4)
C10 C15 Ru3 Cl5 . 2_766 19.5(8)
C14 C15 Ru3 Cl5 . . -136.0(5)
C10 C15 Ru3 Cl5 . . 93.5(5)
C12 C11 Ru3 C14 . . -66.1(6)
C10 C11 Ru3 C14 . . 69.7(5)
C17 C11 Ru3 C14 . . -179.2(12)
C12 C11 Ru3 C10 . . -135.8(8)
C17 C11 Ru3 C10 . . 111.1(14)
C10 C11 Ru3 C12 . . 135.8(8)
C17 C11 Ru3 C12 . . -113.1(13)
C12 C11 Ru3 C15 . . -104.2(6)
C10 C11 Ru3 C15 . . 31.6(5)
C17 C11 Ru3 C15 . . 142.8(12)
C12 C11 Ru3 C13 . . -28.2(5)
C10 C11 Ru3 C13 . . 107.6(6)
C17 C11 Ru3 C13 . . -141.3(12)
C12 C11 Ru3 Cl6 . . 12.4(8)
C10 C11 Ru3 Cl6 . . 148.2(5)
C17 C11 Ru3 Cl6 . . -100.7(12)
C12 C11 Ru3 Cl5 . 2_766 98.1(5)
C10 C11 Ru3 Cl5 . 2_766 -126.1(5)
C17 C11 Ru3 Cl5 . 2_766 -15.0(11)
C12 C11 Ru3 Cl5 . . 177.0(5)
C10 C11 Ru3 Cl5 . . -47.1(6)
C17 C11 Ru3 Cl5 . . 64.0(12)
C12 C13 Ru3 C14 . . 132.2(9)
C18 C13 Ru3 C14 . . -113.6(10)
C12 C13 Ru3 C10 . . 65.1(7)
C14 C13 Ru3 C10 . . -67.2(6)
C18 C13 Ru3 C10 . . 179.2(8)
C14 C13 Ru3 C12 . . -132.2(9)
C18 C13 Ru3 C12 . . 114.2(10)
C12 C13 Ru3 C15 . . 104.3(7)
C14 C13 Ru3 C15 . . -27.9(5)
C18 C13 Ru3 C15 . . -141.5(8)
C12 C13 Ru3 C11 . . 28.3(6)
C14 C13 Ru3 C11 . . -104.0(6)
C18 C13 Ru3 C11 . . 142.4(8)
C12 C13 Ru3 Cl6 . . -132.4(6)
C14 C13 Ru3 Cl6 . . 95.3(5)
C18 C13 Ru3 Cl6 . . -18.3(7)
C12 C13 Ru3 Cl5 . 2_766 -45.7(7)
C14 C13 Ru3 Cl5 . 2_766 -177.9(4)
C18 C13 Ru3 Cl5 . 2_766 68.5(8)
C12 C13 Ru3 Cl5 . . 146.3(6)
C14 C13 Ru3 Cl5 . . 14.0(10)
C18 C13 Ru3 Cl5 . . -99.6(9)
Ru3 Cl5 Ru3 C14 2_766 . 179.7(3)
Ru3 Cl5 Ru3 C10 2_766 . -111.3(3)
Ru3 Cl5 Ru3 C12 2_766 . -79.1(7)
Ru3 Cl5 Ru3 C15 2_766 . -151.3(3)
Ru3 Cl5 Ru3 C11 2_766 . -84.1(3)
Ru3 Cl5 Ru3 C13 2_766 . 169.9(6)
Ru3 Cl5 Ru3 Cl6 2_766 . 88.14(8)
Ru3 Cl5 Ru3 Cl5 2_766 2_766 0.0
