#------------------------------------------------------------------------------
#$Date: 2016-02-20 22:30:07 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176789 $
#$URL: svn://www.crystallography.net/cod/cif/2/22/66/2226695.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2226695
loop_
_publ_author_name
'Sadeghi, Omid'
'Amini, Mostafa M.'
'Ng, Seik Weng'
_publ_section_title
;
 Poly[(μ₃-4-aminobenzenesulfonato-κ³N:O:O)(triphenylphosphine-κP)silver(I)]
;
_journal_coeditor_code           SU2190
_journal_issue                   7
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m855
_journal_page_last               m856
_journal_paper_doi               10.1107/S1600536810024207
_journal_volume                  66
_journal_year                    2010
_chemical_formula_iupac          '[Ag (C6 H6 N O3 S) (C18 H15 P)]'
_chemical_formula_moiety         'C24 H21 Ag N O3 P S'
_chemical_formula_sum            'C24 H21 Ag N O3 P S'
_chemical_formula_weight         542.32
_chemical_name_systematic
;
Poly[(μ₃-4-aminobenzenesulfonato-
κ³N:O:O)(triphenylphosphine-κP)silver(I)]
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 118.2290(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   28.2593(15)
_cell_length_b                   9.4085(5)
_cell_length_c                   18.5765(10)
_cell_measurement_reflns_used    8286
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      28.2
_cell_measurement_theta_min      2.4
_cell_volume                     4351.6(4)
_computing_cell_refinement       'SAINT (Bruker, 2009)'
_computing_data_collection       'APEX2 (Bruker, 2009)'
_computing_data_reduction        'SAINT (Bruker, 2009)'
_computing_molecular_graphics
'X-SEED (Barbour, 2001) and OLEX (Dolomanov et al.,  2003)'
_computing_publication_material  'publCIF (Westrip, 2010)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker SMART APEX diffractometer'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0378
_diffrn_reflns_av_sigmaI/netI    0.0329
_diffrn_reflns_limit_h_max       36
_diffrn_reflns_limit_h_min       -36
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            19921
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         1.64
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.123
_exptl_absorpt_correction_T_max  0.9460
_exptl_absorpt_correction_T_min  0.6946
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 1996)'
_exptl_crystal_colour            Colorless
_exptl_crystal_density_diffrn    1.656
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Plate
_exptl_crystal_F_000             2192
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.05
_refine_diff_density_max         0.929
_refine_diff_density_min         -0.460
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.019
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     280
_refine_ls_number_reflns         4995
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.019
_refine_ls_R_factor_all          0.0335
_refine_ls_R_factor_gt           0.0279
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0414P)²+3.5194P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0689
_refine_ls_wR_factor_ref         0.0731
_reflns_number_gt                4393
_reflns_number_total             4995
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            su2190.cif
_cod_data_source_block           I
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               2226695
_cod_database_fobs_code          2226695
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag Ag1 0.692581(6) 0.726456(18) 0.523729(10) 0.01618(6) Uani d . 1 . .
S S1 0.80640(2) 0.94131(6) 0.63130(3) 0.01479(11) Uani d . 1 . .
P P1 0.61400(2) 0.83696(6) 0.51114(3) 0.01347(12) Uani d . 1 . .
O O1 0.78580(6) 0.80116(17) 0.59157(9) 0.0175(3) Uani d . 1 . .
O O2 0.86414(6) 0.94896(18) 0.66660(10) 0.0215(3) Uani d . 1 . .
O O3 0.77760(6) 1.05818(17) 0.57660(9) 0.0199(3) Uani d . 1 . .
N N1 0.76252(7) 1.0121(2) 0.91345(11) 0.0172(4) Uani d . 1 . .
H H1A 0.7749 0.9431 0.9478 0.021 Uiso calc R 1 . .
H H1B 0.7287 1.0201 0.8978 0.021 Uiso calc R 1 . .
C C1 0.55223(9) 0.7331(2) 0.45987(14) 0.0152(4) Uani d . 1 . .
C C2 0.54236(9) 0.6587(3) 0.38905(15) 0.0241(5) Uani d . 1 . .
H H2 0.5675 0.6618 0.3687 0.029 Uiso calc R 1 . .
C C3 0.49531(10) 0.5800(3) 0.34867(16) 0.0283(6) Uani d . 1 . .
H H3 0.4881 0.5313 0.2998 0.034 Uiso calc R 1 . .
C C4 0.45886(9) 0.5712(2) 0.37823(15) 0.0236(5) Uani d . 1 . .
H H4 0.4272 0.5157 0.3504 0.028 Uiso calc R 1 . .
C C5 0.46888(9) 0.6441(2) 0.44884(15) 0.0211(5) Uani d . 1 . .
H H5 0.4440 0.6386 0.4697 0.025 Uiso calc R 1 . .
C C6 0.51523(9) 0.7254(2) 0.48923(14) 0.0171(4) Uani d . 1 . .
H H6 0.5217 0.7761 0.5373 0.021 Uiso calc R 1 . .
C C7 0.59882(8) 1.0046(2) 0.45534(12) 0.0149(4) Uani d . 1 . .
C C8 0.54666(9) 1.0490(2) 0.40320(13) 0.0189(4) Uani d . 1 . .
H H8 0.5172 0.9886 0.3932 0.023 Uiso calc R 1 . .
C C9 0.53739(10) 1.1817(3) 0.36545(15) 0.0235(5) Uani d . 1 . .
H H9 0.5017 1.2115 0.3298 0.028 Uiso calc R 1 . .
C C10 0.58010(10) 1.2702(2) 0.37993(15) 0.0228(5) Uani d . 1 . .
H H10 0.5737 1.3612 0.3548 0.027 Uiso calc R 1 . .
C C11 0.63252(10) 1.2255(2) 0.43143(14) 0.0216(5) Uani d . 1 . .
H H11 0.6619 1.2859 0.4410 0.026 Uiso calc R 1 . .
C C12 0.64191(9) 1.0932(2) 0.46869(13) 0.0186(4) Uani d . 1 . .
H H12 0.6777 1.0627 0.5033 0.022 Uiso calc R 1 . .
C C13 0.61624(8) 0.8853(2) 0.60765(12) 0.0141(4) Uani d . 1 . .
C C14 0.63746(9) 0.7881(2) 0.67208(14) 0.0184(5) Uani d . 1 . .
H H14 0.6528 0.7019 0.6663 0.022 Uiso calc R 1 . .
C C15 0.63632(9) 0.8164(3) 0.74441(14) 0.0214(5) Uani d . 1 . .
H H15 0.6501 0.7488 0.7875 0.026 Uiso calc R 1 . .
C C16 0.61496(9) 0.9438(2) 0.75397(14) 0.0197(5) Uani d . 1 . .
H H16 0.6141 0.9630 0.8036 0.024 Uiso calc R 1 . .
C C17 0.59487(8) 1.0430(2) 0.69125(13) 0.0171(4) Uani d . 1 . .
H H17 0.5807 1.1305 0.6981 0.021 Uiso calc R 1 . .
C C18 0.59550(8) 1.0140(2) 0.61829(13) 0.0157(4) Uani d . 1 . .
H H18 0.5818 1.0821 0.5754 0.019 Uiso calc R 1 . .
C C19 0.79126(8) 0.9533(2) 0.71350(12) 0.0132(4) Uani d . 1 . .
C C20 0.82240(8) 0.8805(2) 0.78608(13) 0.0154(4) Uani d . 1 . .
H H20 0.8507 0.8203 0.7906 0.019 Uiso calc R 1 . .
C C21 0.81224(8) 0.8956(2) 0.85197(13) 0.0157(4) Uani d . 1 . .
H H21 0.8335 0.8457 0.9014 0.019 Uiso calc R 1 . .
C C22 0.77081(8) 0.9840(2) 0.84538(12) 0.0144(4) Uani d . 1 . .
C C23 0.73961(8) 1.0556(2) 0.77244(13) 0.0166(4) Uani d . 1 . .
H H23 0.7112 1.1154 0.7677 0.020 Uiso calc R 1 . .
C C24 0.74968(8) 1.0406(2) 0.70679(13) 0.0157(4) Uani d . 1 . .
H H24 0.7282 1.0899 0.6572 0.019 Uiso calc R 1 . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
P1 Ag1 O1 . . 131.56(4) yes
P1 Ag1 O1 . 7_666 124.03(4) yes
P1 Ag1 N1 . 4_646 132.96(5) yes
O1 Ag1 O1 . 7_666 80.21(5) yes
O1 Ag1 N1 . 4_646 78.12(6) yes
O1 Ag1 N1 7_666 4_646 92.43(6) yes
O2 S1 O3 . . 114.68(10) ?
O2 S1 O1 . . 111.23(9) ?
O3 S1 O1 . . 111.38(9) ?
O2 S1 C19 . . 106.66(9) ?
O3 S1 C19 . . 105.65(10) ?
O1 S1 C19 . . 106.65(9) ?
C13 P1 C7 . . 103.46(10) ?
C13 P1 C1 . . 103.10(10) ?
C7 P1 C1 . . 104.85(10) ?
C13 P1 Ag1 . . 114.78(7) ?
C7 P1 Ag1 . . 113.23(7) ?
C1 P1 Ag1 . . 115.99(7) ?
S1 O1 Ag1 . . 126.03(9) ?
S1 O1 Ag1 . 7_666 108.65(8) ?
Ag1 O1 Ag1 . 7_666 99.79(5) ?
C22 N1 Ag1 . 4_656 108.76(13) ?
C22 N1 H1A . . 109.9 ?
Ag1 N1 H1A 4_656 . 109.9 ?
C22 N1 H1B . . 109.9 ?
Ag1 N1 H1B 4_656 . 109.9 ?
H1A N1 H1B . . 108.3 ?
C6 C1 C2 . . 119.4(2) ?
C6 C1 P1 . . 122.24(17) ?
C2 C1 P1 . . 118.36(18) ?
C3 C2 C1 . . 119.3(2) ?
C3 C2 H2 . . 120.4 ?
C1 C2 H2 . . 120.4 ?
C4 C3 C2 . . 121.3(2) ?
C4 C3 H3 . . 119.3 ?
C2 C3 H3 . . 119.3 ?
C3 C4 C5 . . 119.3(2) ?
C3 C4 H4 . . 120.3 ?
C5 C4 H4 . . 120.3 ?
C4 C5 C6 . . 120.1(2) ?
C4 C5 H5 . . 119.9 ?
C6 C5 H5 . . 119.9 ?
C1 C6 C5 . . 120.5(2) ?
C1 C6 H6 . . 119.7 ?
C5 C6 H6 . . 119.7 ?
C8 C7 C12 . . 119.5(2) ?
C8 C7 P1 . . 122.84(17) ?
C12 C7 P1 . . 117.63(16) ?
C7 C8 C9 . . 120.3(2) ?
C7 C8 H8 . . 119.9 ?
C9 C8 H8 . . 119.9 ?
C10 C9 C8 . . 120.1(2) ?
C10 C9 H9 . . 119.9 ?
C8 C9 H9 . . 119.9 ?
C9 C10 C11 . . 119.9(2) ?
C9 C10 H10 . . 120.1 ?
C11 C10 H10 . . 120.1 ?
C12 C11 C10 . . 120.2(2) ?
C12 C11 H11 . . 119.9 ?
C10 C11 H11 . . 119.9 ?
C11 C12 C7 . . 120.1(2) ?
C11 C12 H12 . . 120.0 ?
C7 C12 H12 . . 120.0 ?
C14 C13 C18 . . 119.0(2) ?
C14 C13 P1 . . 118.77(17) ?
C18 C13 P1 . . 122.22(16) ?
C15 C14 C13 . . 120.6(2) ?
C15 C14 H14 . . 119.7 ?
C13 C14 H14 . . 119.7 ?
C14 C15 C16 . . 120.0(2) ?
C14 C15 H15 . . 120.0 ?
C16 C15 H15 . . 120.0 ?
C17 C16 C15 . . 120.1(2) ?
C17 C16 H16 . . 119.9 ?
C15 C16 H16 . . 119.9 ?
C16 C17 C18 . . 119.9(2) ?
C16 C17 H17 . . 120.1 ?
C18 C17 H17 . . 120.1 ?
C17 C18 C13 . . 120.4(2) ?
C17 C18 H18 . . 119.8 ?
C13 C18 H18 . . 119.8 ?
C24 C19 C20 . . 119.86(19) ?
C24 C19 S1 . . 119.90(16) ?
C20 C19 S1 . . 120.19(16) ?
C19 C20 C21 . . 120.20(19) ?
C19 C20 H20 . . 119.9 ?
C21 C20 H20 . . 119.9 ?
C20 C21 C22 . . 119.88(19) ?
C20 C21 H21 . . 120.1 ?
C22 C21 H21 . . 120.1 ?
C23 C22 C21 . . 119.58(19) ?
C23 C22 N1 . . 118.87(19) ?
C21 C22 N1 . . 121.33(19) ?
C24 C23 C22 . . 120.57(19) ?
C24 C23 H23 . . 119.7 ?
C22 C23 H23 . . 119.7 ?
C23 C24 C19 . . 119.91(19) ?
C23 C24 H24 . . 120.0 ?
C19 C24 H24 . . 120.0 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Ag1 P1 . 2.3614(6) yes
Ag1 O1 . 2.4252(15) yes
Ag1 O1 7_666 2.5031(16) yes
Ag1 N1 4_646 2.3749(18) yes
S1 O2 . 1.4441(15) ?
S1 O3 . 1.4565(17) ?
S1 O1 . 1.4885(16) ?
S1 C19 . 1.774(2) ?
P1 C13 . 1.821(2) ?
P1 C7 . 1.824(2) ?
P1 C1 . 1.826(2) ?
O1 Ag1 7_666 2.5031(16) ?
N1 C22 . 1.416(3) ?
N1 Ag1 4_656 2.3749(18) ?
N1 H1A . 0.8600 ?
N1 H1B . 0.8600 ?
C1 C6 . 1.391(3) ?
C1 C2 . 1.397(3) ?
C2 C3 . 1.391(3) ?
C2 H2 . 0.9500 ?
C3 C4 . 1.380(4) ?
C3 H3 . 0.9500 ?
C4 C5 . 1.385(3) ?
C4 H4 . 0.9500 ?
C5 C6 . 1.391(3) ?
C5 H5 . 0.9500 ?
C6 H6 . 0.9500 ?
C7 C8 . 1.391(3) ?
C7 C12 . 1.398(3) ?
C8 C9 . 1.395(3) ?
C8 H8 . 0.9500 ?
C9 C10 . 1.384(4) ?
C9 H9 . 0.9500 ?
C10 C11 . 1.395(4) ?
C10 H10 . 0.9500 ?
C11 C12 . 1.388(3) ?
C11 H11 . 0.9500 ?
C12 H12 . 0.9500 ?
C13 C14 . 1.396(3) ?
C13 C18 . 1.400(3) ?
C14 C15 . 1.385(3) ?
C14 H14 . 0.9500 ?
C15 C16 . 1.391(3) ?
C15 H15 . 0.9500 ?
C16 C17 . 1.387(3) ?
C16 H16 . 0.9500 ?
C17 C18 . 1.391(3) ?
C17 H17 . 0.9500 ?
C18 H18 . 0.9500 ?
C19 C24 . 1.390(3) ?
C19 C20 . 1.393(3) ?
C20 C21 . 1.390(3) ?
C20 H20 . 0.9500 ?
C21 C22 . 1.394(3) ?
C21 H21 . 0.9500 ?
C22 C23 . 1.392(3) ?
C23 C24 . 1.384(3) ?
C23 H23 . 0.9500 ?
C24 H24 . 0.9500 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion
_geom_torsion_publ_flag
N1 Ag1 P1 C13 4_646 . . . 61.30(10) ?
O1 Ag1 P1 C13 . . . . -55.43(10) ?
O1 Ag1 P1 C13 7_666 . . . -164.36(9) ?
N1 Ag1 P1 C7 4_646 . . . 179.81(10) ?
O1 Ag1 P1 C7 . . . . 63.08(9) ?
O1 Ag1 P1 C7 7_666 . . . -45.86(9) ?
N1 Ag1 P1 C1 4_646 . . . -58.88(10) ?
O1 Ag1 P1 C1 . . . . -175.61(9) ?
O1 Ag1 P1 C1 7_666 . . . 75.45(9) ?
O2 S1 O1 Ag1 . . . . 179.26(10) ?
O3 S1 O1 Ag1 . . . . -51.46(13) ?
C19 S1 O1 Ag1 . . . . 63.33(13) ?
O2 S1 O1 Ag1 . . . 7_666 -62.88(11) ?
O3 S1 O1 Ag1 . . . 7_666 66.41(10) ?
C19 S1 O1 Ag1 . . . 7_666 -178.80(8) ?
P1 Ag1 O1 S1 . . . . -5.52(14) ?
N1 Ag1 O1 S1 4_646 . . . -143.61(12) ?
O1 Ag1 O1 S1 7_666 . . . 121.79(13) ?
P1 Ag1 O1 Ag1 . . . 7_666 -127.30(4) ?
N1 Ag1 O1 Ag1 4_646 . . 7_666 94.60(6) ?
O1 Ag1 O1 Ag1 7_666 . . 7_666 0.0 ?
C13 P1 C1 C6 . . . . 10.1(2) ?
C7 P1 C1 C6 . . . . -97.93(19) ?
Ag1 P1 C1 C6 . . . . 136.39(16) ?
C13 P1 C1 C2 . . . . -169.57(18) ?
C7 P1 C1 C2 . . . . 82.43(19) ?
Ag1 P1 C1 C2 . . . . -43.2(2) ?
C6 C1 C2 C3 . . . . 0.9(4) ?
P1 C1 C2 C3 . . . . -179.43(19) ?
C1 C2 C3 C4 . . . . -1.6(4) ?
C2 C3 C4 C5 . . . . 1.1(4) ?
C3 C4 C5 C6 . . . . 0.1(3) ?
C2 C1 C6 C5 . . . . 0.2(3) ?
P1 C1 C6 C5 . . . . -179.41(17) ?
C4 C5 C6 C1 . . . . -0.8(3) ?
C13 P1 C7 C8 . . . . -91.2(2) ?
C1 P1 C7 C8 . . . . 16.6(2) ?
Ag1 P1 C7 C8 . . . . 143.97(17) ?
C13 P1 C7 C12 . . . . 86.45(18) ?
C1 P1 C7 C12 . . . . -165.81(17) ?
Ag1 P1 C7 C12 . . . . -38.43(19) ?
C12 C7 C8 C9 . . . . -0.9(3) ?
P1 C7 C8 C9 . . . . 176.62(18) ?
C7 C8 C9 C10 . . . . -0.2(4) ?
C8 C9 C10 C11 . . . . 0.9(4) ?
C9 C10 C11 C12 . . . . -0.5(4) ?
C10 C11 C12 C7 . . . . -0.6(3) ?
C8 C7 C12 C11 . . . . 1.3(3) ?
P1 C7 C12 C11 . . . . -176.36(17) ?
C7 P1 C13 C14 . . . . -167.37(17) ?
C1 P1 C13 C14 . . . . 83.59(18) ?
Ag1 P1 C13 C14 . . . . -43.50(19) ?
C7 P1 C13 C18 . . . . 15.24(19) ?
C1 P1 C13 C18 . . . . -93.81(18) ?
Ag1 P1 C13 C18 . . . . 139.11(15) ?
C18 C13 C14 C15 . . . . 2.2(3) ?
P1 C13 C14 C15 . . . . -175.26(18) ?
C13 C14 C15 C16 . . . . -1.4(4) ?
C14 C15 C16 C17 . . . . -0.1(4) ?
C15 C16 C17 C18 . . . . 0.8(3) ?
C16 C17 C18 C13 . . . . 0.1(3) ?
C14 C13 C18 C17 . . . . -1.6(3) ?
P1 C13 C18 C17 . . . . 175.83(16) ?
O2 S1 C19 C24 . . . . 135.67(17) ?
O3 S1 C19 C24 . . . . 13.22(19) ?
O1 S1 C19 C24 . . . . -105.38(18) ?
O2 S1 C19 C20 . . . . -41.5(2) ?
O3 S1 C19 C20 . . . . -163.96(17) ?
O1 S1 C19 C20 . . . . 77.43(18) ?
C24 C19 C20 C21 . . . . -0.4(3) ?
S1 C19 C20 C21 . . . . 176.75(16) ?
C19 C20 C21 C22 . . . . -0.1(3) ?
C20 C21 C22 C23 . . . . 0.6(3) ?
C20 C21 C22 N1 . . . . -174.11(19) ?
Ag1 N1 C22 C23 4_656 . . . -80.1(2) ?
Ag1 N1 C22 C21 4_656 . . . 94.6(2) ?
C21 C22 C23 C24 . . . . -0.5(3) ?
N1 C22 C23 C24 . . . . 174.28(19) ?
C22 C23 C24 C19 . . . . 0.0(3) ?
C20 C19 C24 C23 . . . . 0.5(3) ?
S1 C19 C24 C23 . . . . -176.71(17) ?
