#------------------------------------------------------------------------------
#$Date: 2017-05-30 17:58:23 +0300 (Tue, 30 May 2017) $
#$Revision: 197043 $
#$URL: file:///home/coder/svn-repositories/cod/cif/2/23/35/2233540.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2233540
loop_
_publ_author_name
'Butcher, Ray J.'
'Chakravorty, Tapash'
'Singh, Harkesh B.'
_publ_section_title
;
 Bis{μ-2-[(dimethylamino)methyl]benzenetellurolato}bis[chloridopalladium(II)]
 dichloromethane hemisolvate
;
_journal_coeditor_code           JJ2116
_journal_issue                   2
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m141
_journal_page_last               m142
_journal_paper_doi               10.1107/S1600536812000104
_journal_volume                  68
_journal_year                    2012
_chemical_formula_iupac          '[Pd2 (C9 H12 N Te)2 Cl2], 0.5C H2 Cl2'
_chemical_formula_moiety         'C18 H24 Cl2 N2 Pd2 Te2, 0.5(C H2 Cl2)'
_chemical_formula_sum            'C18.5 H25 Cl3 N2 Pd2 Te2'
_chemical_formula_weight         849.75
_chemical_name_systematic
;
Bis{μ-2-[(dimethylamino)methyl]benzenetellurolato}bis[chloridopalladium(II)]
dichloromethane hemisolvate
;
_space_group_IT_number           18
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  'P 2 2ab'
_symmetry_space_group_name_H-M   'P 21 21 2'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   14.035(2)
_cell_length_b                   14.842(2)
_cell_length_c                   12.3188(16)
_cell_measurement_reflns_used    9437
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      26.91
_cell_measurement_theta_min      2.74
_cell_volume                     2566.1(6)
_computing_cell_refinement       'SAINT (Bruker, 2002)'
_computing_data_collection       'APEX2 (Bruker, 2005)'
_computing_data_reduction        'SAINT (Bruker, 2002)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008)'
_computing_publication_material  'SHELXTL (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.986
_diffrn_measured_fraction_theta_max 0.982
_diffrn_measurement_device_type  'Bruker APEXII CCD area-detector'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0501
_diffrn_reflns_av_sigmaI/netI    0.0325
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       11
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            36521
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         27.01
_diffrn_reflns_theta_min         3.11
_exptl_absorpt_coefficient_mu    3.950
_exptl_absorpt_correction_T_max  0.7455
_exptl_absorpt_correction_T_min  0.6147
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 1996)'
_exptl_crystal_colour            yellow-orange
_exptl_crystal_density_diffrn    2.200
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1588
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.26
_exptl_crystal_size_min          0.18
_refine_diff_density_max         2.119
_refine_diff_density_min         -0.900
_refine_ls_abs_structure_details 'Flack (1983), 2355 Friedel pairs'
_refine_ls_abs_structure_Flack   0.06(4)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.062
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     254
_refine_ls_number_reflns         5506
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.062
_refine_ls_R_factor_all          0.0426
_refine_ls_R_factor_gt           0.0392
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0501P)²+22.7234P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1005
_refine_ls_wR_factor_ref         0.1020
_reflns_number_gt                5148
_reflns_number_total             5506
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            jj2116.cif
_cod_data_source_block           I
_cod_depositor_comments
;

2017-05-25
Z value and formula fixed to values more according to usual
chemical conventions.                 miguel
;
_cod_original_formula_sum            'C37 H50 Cl6 N4 Pd4 Te4'
_cod_original_formula_weight         1699.51
_cod_original_formula_moiety         '2(C18 H24 Cl2 N2 Pd2 Te2), C H2 Cl2'
_cod_original_formula_units_Z            2
_cod_original_cell_volume        2566.0(6)
_cod_database_code               2233540
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, z'
'-x+1/2, y+1/2, -z'
'x+1/2, -y+1/2, -z'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_symmetry_multiplicity
Pd Pd1A 0.54346(4) 0.37839(4) 0.59921(5) 0.01520(13) Uani d . 1 1
Te Te1A 0.61163(3) 0.53491(4) 0.62387(4) 0.01511(12) Uani d . 1 1
Cl Cl1A 0.45795(17) 0.24470(15) 0.5665(2) 0.0284(5) Uani d . 1 1
N N1A 0.6857(5) 0.3197(5) 0.5763(6) 0.0184(15) Uani d . 1 1
C C1A 0.6689(6) 0.5129(6) 0.4639(6) 0.0177(18) Uani d . 1 1
C C2A 0.6399(6) 0.5658(6) 0.3784(7) 0.0206(17) Uani d . 1 1
H H2AA 0.5937 0.6120 0.3876 0.025 Uiso calc R 1 1
C C3A 0.6813(7) 0.5486(6) 0.2777(7) 0.025(2) Uani d . 1 1
H H3AA 0.6611 0.5822 0.2163 0.030 Uiso calc R 1 1
C C4A 0.7500(7) 0.4848(6) 0.2654(8) 0.028(2) Uani d . 1 1
H H4AA 0.7786 0.4756 0.1964 0.034 Uiso calc R 1 1
C C5A 0.7784(6) 0.4330(6) 0.3537(7) 0.0226(18) Uani d . 1 1
H H5AA 0.8267 0.3886 0.3456 0.027 Uiso calc R 1 1
C C6A 0.7354(6) 0.4470(6) 0.4537(6) 0.0169(17) Uani d . 1 1
C C7A 0.7615(6) 0.3882(7) 0.5500(7) 0.0237(19) Uani d . 1 1
H H7AA 0.8219 0.3565 0.5341 0.028 Uiso calc R 1 1
H H7AB 0.7721 0.4270 0.6142 0.028 Uiso calc R 1 1
C C8A 0.7109(7) 0.2750(7) 0.6799(8) 0.032(2) Uani d . 1 1
H H8AA 0.7769 0.2536 0.6764 0.047 Uiso calc R 1 1
H H8AB 0.6681 0.2238 0.6921 0.047 Uiso calc R 1 1
H H8AC 0.7044 0.3181 0.7397 0.047 Uiso calc R 1 1
C C9A 0.6846(7) 0.2495(7) 0.4917(8) 0.027(2) Uani d . 1 1
H H9AA 0.7483 0.2230 0.4850 0.040 Uiso calc R 1 1
H H9AB 0.6660 0.2763 0.4222 0.040 Uiso calc R 1 1
H H9AC 0.6389 0.2024 0.5116 0.040 Uiso calc R 1 1
Pd Pd1B 0.37084(4) 0.45871(4) 0.90101(5) 0.01594(14) Uani d . 1 1
Te Te1B 0.53688(4) 0.39525(3) 0.87669(4) 0.01555(12) Uani d . 1 1
Cl Cl1B 0.22964(17) 0.54079(18) 0.9375(2) 0.0370(6) Uani d . 1 1
N N1B 0.3072(5) 0.3220(5) 0.9235(6) 0.0207(15) Uani d . 1 1
C C1B 0.5141(6) 0.3441(6) 1.0358(6) 0.0175(17) Uani d . 1 1
C C2B 0.5672(6) 0.3731(6) 1.1223(7) 0.0244(19) Uani d . 1 1
H H2BA 0.6144 0.4182 1.1127 0.029 Uiso calc R 1 1
C C3B 0.5510(7) 0.3351(7) 1.2270(7) 0.026(2) Uani d . 1 1
H H3BA 0.5845 0.3568 1.2887 0.032 Uiso calc R 1 1
C C4B 0.4853(6) 0.2656(6) 1.2371(7) 0.025(2) Uani d . 1 1
H H4BA 0.4775 0.2366 1.3052 0.030 Uiso calc R 1 1
C C5B 0.4308(7) 0.2378(7) 1.1491(8) 0.030(2) Uani d . 1 1
H H5BA 0.3850 0.1913 1.1583 0.035 Uiso calc R 1 1
C C6B 0.4430(6) 0.2783(6) 1.0454(7) 0.0217(18) Uani d . 1 1
C C7B 0.3803(7) 0.2521(6) 0.9532(7) 0.025(2) Uani d . 1 1
H H7BA 0.3471 0.1954 0.9721 0.030 Uiso calc R 1 1
H H7BB 0.4206 0.2400 0.8889 0.030 Uiso calc R 1 1
C C8B 0.2650(8) 0.2964(7) 0.8194(7) 0.029(2) Uani d . 1 1
H H8BA 0.2382 0.2356 0.8250 0.043 Uiso calc R 1 1
H H8BB 0.3142 0.2975 0.7630 0.043 Uiso calc R 1 1
H H8BC 0.2143 0.3391 0.8007 0.043 Uiso calc R 1 1
C C9B 0.2331(7) 0.3257(7) 1.0054(7) 0.025(2) Uani d . 1 1
H H9BA 0.2028 0.2665 1.0119 0.038 Uiso calc R 1 1
H H9BB 0.1853 0.3705 0.9844 0.038 Uiso calc R 1 1
H H9BC 0.2612 0.3427 1.0753 0.038 Uiso calc R 1 1
Cl Cl1S -0.0241(2) 0.5950(2) 1.1834(4) 0.0643(10) Uani d . 1 1
C C1S 0.0000 0.5000 1.0976(13) 0.044(4) Uani d S 1 2
H H1SA 0.0542 0.5111 1.0521 0.052 Uiso d R 1 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Te Te -0.5308 1.6751 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
N1A Pd1A Cl1A . . 96.1(2)
N1A Pd1A Te1A . . 92.1(2)
Cl1A Pd1A Te1A . . 170.82(7)
N1A Pd1A Te1A . 2_665 173.0(2)
Cl1A Pd1A Te1A . 2_665 90.61(6)
Te1A Pd1A Te1A . 2_665 81.08(2)
N1A Pd1A Te1B . . 100.45(18)
Cl1A Pd1A Te1B . . 102.63(6)
Te1A Pd1A Te1B . . 79.84(2)
Te1A Pd1A Te1B 2_665 . 79.70(2)
C1A Te1A Pd1A . . 83.8(2)
C1A Te1A Pd1A . 2_665 106.7(2)
Pd1A Te1A Pd1A . 2_665 97.26(3)
C9A N1A C8A . . 107.2(7)
C9A N1A C7A . . 109.4(7)
C8A N1A C7A . . 108.6(7)
C9A N1A Pd1A . . 111.2(6)
C8A N1A Pd1A . . 106.5(5)
C7A N1A Pd1A . . 113.7(5)
C6A C1A C2A . . 123.0(8)
C6A C1A Te1A . . 116.8(6)
C2A C1A Te1A . . 120.2(6)
C1A C2A C3A . . 116.9(8)
C1A C2A H2AA . . 121.5
C3A C2A H2AA . . 121.5
C4A C3A C2A . . 121.5(9)
C4A C3A H3AA . . 119.2
C2A C3A H3AA . . 119.2
C3A C4A C5A . . 120.1(9)
C3A C4A H4AA . . 120.0
C5A C4A H4AA . . 120.0
C6A C5A C4A . . 119.1(8)
C6A C5A H5AA . . 120.5
C4A C5A H5AA . . 120.5
C1A C6A C5A . . 119.3(8)
C1A C6A C7A . . 120.5(7)
C5A C6A C7A . . 120.1(8)
N1A C7A C6A . . 112.7(7)
N1A C7A H7AA . . 109.0
C6A C7A H7AA . . 109.0
N1A C7A H7AB . . 109.0
C6A C7A H7AB . . 109.0
H7AA C7A H7AB . . 107.8
N1A C8A H8AA . . 109.5
N1A C8A H8AB . . 109.5
H8AA C8A H8AB . . 109.5
N1A C8A H8AC . . 109.5
H8AA C8A H8AC . . 109.5
H8AB C8A H8AC . . 109.5
N1A C9A H9AA . . 109.5
N1A C9A H9AB . . 109.5
H9AA C9A H9AB . . 109.5
N1A C9A H9AC . . 109.5
H9AA C9A H9AC . . 109.5
H9AB C9A H9AC . . 109.5
N1B Pd1B Cl1B . . 96.3(2)
N1B Pd1B Te1B . . 92.6(2)
Cl1B Pd1B Te1B . . 169.67(7)
N1B Pd1B Te1B . 2_665 172.9(2)
Cl1B Pd1B Te1B . 2_665 90.58(7)
Te1B Pd1B Te1B . 2_665 80.46(3)
N1B Pd1B Te1A . 2_665 100.24(19)
Cl1B Pd1B Te1A . 2_665 103.60(7)
Te1B Pd1B Te1A . 2_665 79.99(2)
Te1B Pd1B Te1A 2_665 2_665 79.77(2)
C1B Te1B Pd1B . . 83.4(2)
C1B Te1B Pd1B . 2_665 105.8(2)
Pd1B Te1B Pd1B . 2_665 97.92(3)
C1B Te1B Pd1A . . 153.8(2)
Pd1B Te1B Pd1A . . 99.78(2)
Pd1B Te1B Pd1A 2_665 . 99.55(2)
C9B N1B C8B . . 109.2(8)
C9B N1B C7B . . 110.3(7)
C8B N1B C7B . . 108.1(7)
C9B N1B Pd1B . . 109.8(6)
C8B N1B Pd1B . . 106.8(5)
C7B N1B Pd1B . . 112.5(6)
C2B C1B C6B . . 122.7(8)
C2B C1B Te1B . . 121.6(6)
C6B C1B Te1B . . 115.7(6)
C1B C2B C3B . . 119.5(8)
C1B C2B H2BA . . 120.2
C3B C2B H2BA . . 120.2
C4B C3B C2B . . 118.7(9)
C4B C3B H3BA . . 120.6
C2B C3B H3BA . . 120.6
C5B C4B C3B . . 121.1(8)
C5B C4B H4BA . . 119.4
C3B C4B H4BA . . 119.4
C4B C5B C6B . . 120.6(9)
C4B C5B H5BA . . 119.7
C6B C5B H5BA . . 119.7
C1B C6B C5B . . 117.2(8)
C1B C6B C7B . . 122.5(8)
C5B C6B C7B . . 120.3(8)
C6B C7B N1B . . 114.1(7)
C6B C7B H7BA . . 108.7
N1B C7B H7BA . . 108.7
C6B C7B H7BB . . 108.7
N1B C7B H7BB . . 108.7
H7BA C7B H7BB . . 107.6
N1B C8B H8BA . . 109.5
N1B C8B H8BB . . 109.5
H8BA C8B H8BB . . 109.5
N1B C8B H8BC . . 109.5
H8BA C8B H8BC . . 109.5
H8BB C8B H8BC . . 109.5
N1B C9B H9BA . . 109.5
N1B C9B H9BB . . 109.5
H9BA C9B H9BB . . 109.5
N1B C9B H9BC . . 109.5
H9BA C9B H9BC . . 109.5
H9BB C9B H9BC . . 109.5
Cl1S C1S Cl1S . 2_565 107.8(9)
Cl1S C1S H1SA . . 111.0
Cl1S C1S H1SA 2_565 . 109.2
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
Pd1A N1A . 2.196(7)
Pd1A Cl1A . 2.354(2)
Pd1A Te1A . 2.5305(8)
Pd1A Te1A 2_665 2.5467(8)
Pd1A Te1B . 3.4286(9)
Te1A C1A . 2.154(8)
Te1A Pd1A 2_665 2.5467(8)
N1A C9A . 1.474(12)
N1A C8A . 1.480(11)
N1A C7A . 1.508(12)
C1A C6A . 1.357(13)
C1A C2A . 1.375(12)
C2A C3A . 1.393(12)
C2A H2AA . 0.9500
C3A C4A . 1.360(13)
C3A H3AA . 0.9500
C4A C5A . 1.390(13)
C4A H4AA . 0.9500
C5A C6A . 1.388(11)
C5A H5AA . 0.9500
C6A C7A . 1.517(12)
C7A H7AA . 0.9900
C7A H7AB . 0.9900
C8A H8AA . 0.9800
C8A H8AB . 0.9800
C8A H8AC . 0.9800
C9A H9AA . 0.9800
C9A H9AB . 0.9800
C9A H9AC . 0.9800
Pd1B N1B . 2.235(7)
Pd1B Cl1B . 2.369(2)
Pd1B Te1B . 2.5313(8)
Pd1B Te1B 2_665 2.5427(8)
Pd1B Te1A 2_665 3.4241(9)
Te1B C1B . 2.126(8)
Te1B Pd1B 2_665 2.5427(8)
N1B C9B . 1.449(11)
N1B C8B . 1.462(11)
N1B C7B . 1.504(12)
C1B C2B . 1.370(12)
C1B C6B . 1.402(13)
C2B C3B . 1.426(11)
C2B H2BA . 0.9500
C3B C4B . 1.389(13)
C3B H3BA . 0.9500
C4B C5B . 1.389(14)
C4B H4BA . 0.9500
C5B C6B . 1.422(12)
C5B H5BA . 0.9500
C6B C7B . 1.488(13)
C7B H7BA . 0.9900
C7B H7BB . 0.9900
C8B H8BA . 0.9800
C8B H8BB . 0.9800
C8B H8BC . 0.9800
C9B H9BA . 0.9800
C9B H9BB . 0.9800
C9B H9BC . 0.9800
Cl1S C1S . 1.794(10)
C1S Cl1S 2_565 1.794(10)
C1S H1SA . 0.9600
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
C1S H1SA Cl1B . 0.96 2.87 3.827(9) 173.4
C5A H5AA Cl1A 4_556 0.95 2.91 3.778(9) 152.1
C7A H7AA Cl1A 4_556 0.99 2.73 3.681(9) 162.1
C9A H9AC Cl1A . 0.98 2.70 3.313(10) 120.9
C7B H7BA Cl1B 3_547 0.99 2.77 3.746(10) 169.2
C7B H7BB Cl1S 3_547 0.99 2.75 3.514(10) 134.8
C9B H9BB Cl1B . 0.98 2.67 3.300(11) 122.7
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
_geom_torsion
N1A Pd1A Te1A C1A . . 58.9(3)
Cl1A Pd1A Te1A C1A . . -94.4(5)
Te1A Pd1A Te1A C1A 2_665 . -119.8(2)
Te1B Pd1A Te1A C1A . . 159.2(2)
N1A Pd1A Te1A Pd1A . 2_665 164.97(18)
Cl1A Pd1A Te1A Pd1A . 2_665 11.6(4)
Te1A Pd1A Te1A Pd1A 2_665 2_665 -13.74(4)
Te1B Pd1A Te1A Pd1A . 2_665 -94.78(2)
Cl1A Pd1A N1A C9A . . 34.8(6)
Te1A Pd1A N1A C9A . . -141.0(6)
Te1A Pd1A N1A C9A 2_665 . -130.5(14)
Te1B Pd1A N1A C9A . . 138.9(6)
Cl1A Pd1A N1A C8A . . -81.7(6)
Te1A Pd1A N1A C8A . . 102.5(6)
Te1A Pd1A N1A C8A 2_665 . 113.0(15)
Te1B Pd1A N1A C8A . . 22.4(6)
Cl1A Pd1A N1A C7A . . 158.8(5)
Te1A Pd1A N1A C7A . . -17.1(5)
Te1A Pd1A N1A C7A 2_665 . -6.5(19)
Te1B Pd1A N1A C7A . . -97.1(5)
Pd1A Te1A C1A C6A . . -65.8(6)
Pd1A Te1A C1A C6A 2_665 . -161.5(6)
Pd1A Te1A C1A C2A . . 115.9(7)
Pd1A Te1A C1A C2A 2_665 . 20.1(7)
C6A C1A C2A C3A . . 0.7(13)
Te1A C1A C2A C3A . . 178.9(6)
C1A C2A C3A C4A . . -2.5(13)
C2A C3A C4A C5A . . 2.0(14)
C3A C4A C5A C6A . . 0.4(14)
C2A C1A C6A C5A . . 1.6(13)
Te1A C1A C6A C5A . . -176.7(6)
C2A C1A C6A C7A . . -177.4(8)
Te1A C1A C6A C7A . . 4.3(11)
C4A C5A C6A C1A . . -2.2(13)
C4A C5A C6A C7A . . 176.9(8)
C9A N1A C7A C6A . . 71.5(9)
C8A N1A C7A C6A . . -171.9(7)
Pd1A N1A C7A C6A . . -53.5(8)
C1A C6A C7A N1A . . 74.3(10)
C5A C6A C7A N1A . . -104.7(9)
N1B Pd1B Te1B C1B . . -60.2(3)
Cl1B Pd1B Te1B C1B . . 88.6(5)
Te1B Pd1B Te1B C1B 2_665 . 118.7(2)
Te1A Pd1B Te1B C1B 2_665 . -160.1(2)
N1B Pd1B Te1B Pd1B . 2_665 -165.28(19)
Cl1B Pd1B Te1B Pd1B . 2_665 -16.5(4)
Te1B Pd1B Te1B Pd1B 2_665 2_665 13.59(4)
Te1A Pd1B Te1B Pd1B 2_665 2_665 94.77(2)
N1B Pd1B Te1B Pd1A . . 93.54(19)
Cl1B Pd1B Te1B Pd1A . . -117.7(4)
Te1B Pd1B Te1B Pd1A 2_665 . -87.59(2)
Te1A Pd1B Te1B Pd1A 2_665 . -6.410(18)
N1A Pd1A Te1B C1B . . -83.5(5)
Cl1A Pd1A Te1B C1B . . 15.3(5)
Te1A Pd1A Te1B C1B . . -173.7(5)
Te1A Pd1A Te1B C1B 2_665 . 103.6(5)
N1A Pd1A Te1B Pd1B . . -178.4(2)
Cl1A Pd1A Te1B Pd1B . . -79.66(7)
Te1A Pd1A Te1B Pd1B . . 91.32(3)
Te1A Pd1A Te1B Pd1B 2_665 . 8.64(2)
N1A Pd1A Te1B Pd1B . 2_665 81.7(2)
Cl1A Pd1A Te1B Pd1B . 2_665 -179.49(6)
Te1A Pd1A Te1B Pd1B . 2_665 -8.52(2)
Te1A Pd1A Te1B Pd1B 2_665 2_665 -91.20(3)
Cl1B Pd1B N1B C9B . . -32.5(6)
Te1B Pd1B N1B C9B . . 142.1(6)
Te1B Pd1B N1B C9B 2_665 . 133.0(14)
Te1A Pd1B N1B C9B 2_665 . -137.6(6)
Cl1B Pd1B N1B C8B . . 85.8(6)
Te1B Pd1B N1B C8B . . -99.6(6)
Te1B Pd1B N1B C8B 2_665 . -108.7(15)
Te1A Pd1B N1B C8B 2_665 . -19.3(6)
Cl1B Pd1B N1B C7B . . -155.8(5)
Te1B Pd1B N1B C7B . . 18.8(5)
Te1B Pd1B N1B C7B 2_665 . 9.7(19)
Te1A Pd1B N1B C7B 2_665 . 99.1(5)
Pd1B Te1B C1B C2B . . -114.6(7)
Pd1B Te1B C1B C2B 2_665 . -18.2(8)
Pd1A Te1B C1B C2B . . 146.7(6)
Pd1B Te1B C1B C6B . . 66.6(6)
Pd1B Te1B C1B C6B 2_665 . 163.0(6)
Pd1A Te1B C1B C6B . . -32.2(10)
C6B C1B C2B C3B . . 0.5(14)
Te1B C1B C2B C3B . . -178.3(7)
C1B C2B C3B C4B . . 3.7(14)
C2B C3B C4B C5B . . -4.8(14)
C3B C4B C5B C6B . . 1.8(14)
C2B C1B C6B C5B . . -3.4(13)
Te1B C1B C6B C5B . . 175.4(7)
C2B C1B C6B C7B . . 175.1(8)
Te1B C1B C6B C7B . . -6.1(11)
C4B C5B C6B C1B . . 2.3(13)
C4B C5B C6B C7B . . -176.2(8)
C1B C6B C7B N1B . . -72.2(11)
C5B C6B C7B N1B . . 106.3(10)
C9B N1B C7B C6B . . -72.4(10)
C8B N1B C7B C6B . . 168.3(7)
Pd1B N1B C7B C6B . . 50.6(8)
