#------------------------------------------------------------------------------
#$Date: 2016-02-16 22:30:59 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176467 $
#$URL: svn://www.crystallography.net/cod/cif/4/00/19/4001969.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4001969
loop_
_publ_author_name
'Yao, Jinlei'
'Wang, Peng'
'Mozharivskyj, Yurij'
_publ_section_title
;
 Tuning Magnetic and Structural Transitions through Valence Electron
 Concentration in the Giant Magnetocaloric Gd5--xEuxGe4Phases
;
_journal_issue                   3
_journal_name_full               'Chemistry of Materials'
_journal_page_first              552
_journal_paper_doi               10.1021/cm203148e
_journal_volume                  24
_journal_year                    2012
_chemical_formula_sum            'Eu0.5 Gd4.5 Ge4'
_chemical_formula_weight         1073.96
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           62
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 2ac 2n'
_symmetry_space_group_name_H-M   'P n m a'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   7.5669(8)
_cell_length_b                   14.9047(15)
_cell_length_c                   7.8648(8)
_cell_measurement_reflns_used    886
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      25.73
_cell_measurement_theta_min      2.73
_cell_volume                     887.01(16)
_computing_cell_refinement       SAINT
_computing_data_collection       SMART
_computing_data_reduction        SAINT
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker SMART APEX II'
_diffrn_measurement_method       'omega scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0639
_diffrn_reflns_av_sigmaI/netI    0.0375
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -6
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       8
_diffrn_reflns_limit_l_min       -9
_diffrn_reflns_number            5894
_diffrn_reflns_theta_full        25.73
_diffrn_reflns_theta_max         25.73
_diffrn_reflns_theta_min         2.73
_exptl_absorpt_coefficient_mu    49.862
_exptl_absorpt_correction_T_max  0.3679
_exptl_absorpt_correction_T_min  0.1242
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'SADABS (Sheldrick, 2003)'
_exptl_crystal_colour            metallic
_exptl_crystal_density_diffrn    8.042
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1790
_exptl_crystal_size_max          0.158
_exptl_crystal_size_mid          0.075
_exptl_crystal_size_min          0.065
_refine_diff_density_max         1.658
_refine_diff_density_min         -1.554
_refine_diff_density_rms         0.392
_refine_ls_extinction_coef       0.00084(5)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.022
_refine_ls_matrix_type           full
_refine_ls_number_parameters     47
_refine_ls_number_reflns         886
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.022
_refine_ls_R_factor_all          0.0319
_refine_ls_R_factor_gt           0.0249
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0183P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0479
_refine_ls_wR_factor_ref         0.0503
_reflns_number_gt                763
_reflns_number_total             886
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            Gd4.5Eu0.5Ge4-100K.cif
_cod_data_source_block           pnma
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Orthorhombic' changed to
'orthorhombic' according to
/usr/data/users/saulius/automatic-downloads/retrospective/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 
;
_cod_original_sg_symbol_H-M      Pnma
_cod_original_formula_sum        'Eu0.50 Gd4.50 Ge4'
_cod_database_code               4001969
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z'
'x+1/2, -y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z'
'-x-1/2, y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Gd1 Gd 0.01890(6) 0.59590(4) 0.18125(6) 0.00612(16) Uani 0.90 1 d P
Eu1 Eu 0.01890(6) 0.59590(4) 0.18125(6) 0.00612(16) Uani 0.10 1 d P
Gd2 Gd 0.32178(6) 0.12239(4) 0.17498(6) 0.00513(15) Uani 0.90 1 d P
Eu2 Eu 0.32178(6) 0.12239(4) 0.17498(6) 0.00513(15) Uani 0.10 1 d P
Gd3 Gd 0.15208(9) 0.2500 0.51142(9) 0.00483(18) Uani 0.90 2 d SP
Eu3 Eu 0.15208(9) 0.2500 0.51142(9) 0.00483(18) Uani 0.10 2 d SP
Ge1 Ge 0.15531(14) 0.04080(8) 0.46881(13) 0.0078(3) Uani 1 1 d .
Ge2 Ge 0.02422(19) 0.2500 0.10793(19) 0.0066(3) Uani 1 2 d S
Ge3 Ge 0.27226(19) 0.2500 0.87135(19) 0.0065(4) Uani 1 2 d S
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Gd Gd -0.1653 3.9035 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Ge1 Gd1 Ge1 137.29(4) 8_665 3_556
Ge1 Gd1 Ge3 92.86(4) 8_665 2_564
Ge1 Gd1 Ge3 89.17(4) 3_556 2_564
Ge1 Gd1 Ge3 131.94(4) 8_665 5_566
Ge1 Gd1 Ge3 90.68(4) 3_556 5_566
Ge3 Gd1 Ge3 83.35(2) 2_564 5_566
Ge1 Gd1 Ge1 87.465(19) 8_665 7_565
Ge1 Gd1 Ge1 49.94(4) 3_556 7_565
Ge3 Gd1 Ge1 88.13(3) 2_564 7_565
Ge3 Gd1 Ge1 139.89(4) 5_566 7_565
Ge1 Gd1 Ge2 83.65(3) 8_665 5_565
Ge1 Gd1 Ge2 138.72(4) 3_556 5_565
Ge3 Gd1 Ge2 82.40(3) 2_564 5_565
Ge3 Gd1 Ge2 48.31(4) 5_566 5_565
Ge1 Gd1 Ge2 166.65(4) 7_565 5_565
Ge1 Gd1 Eu3 145.58(3) 8_665 5_566
Ge1 Gd1 Eu3 55.07(2) 3_556 5_566
Ge3 Gd1 Eu3 52.78(3) 2_564 5_566
Ge3 Gd1 Eu3 51.63(3) 5_566 5_566
Ge1 Gd1 Eu3 92.74(3) 7_565 5_566
Ge2 Gd1 Eu3 89.01(3) 5_565 5_566
Ge1 Gd1 Gd3 145.58(3) 8_665 5_566
Ge1 Gd1 Gd3 55.07(2) 3_556 5_566
Ge3 Gd1 Gd3 52.78(3) 2_564 5_566
Ge3 Gd1 Gd3 51.63(3) 5_566 5_566
Ge1 Gd1 Gd3 92.74(3) 7_565 5_566
Ge2 Gd1 Gd3 89.01(3) 5_565 5_566
Eu3 Gd1 Gd3 0.00(2) 5_566 5_566
Ge1 Gd1 Eu3 54.80(3) 8_665 2_564
Ge1 Gd1 Eu3 140.23(3) 3_556 2_564
Ge3 Gd1 Eu3 51.23(3) 2_564 2_564
Ge3 Gd1 Eu3 88.32(3) 5_566 2_564
Ge1 Gd1 Eu3 116.00(3) 7_565 2_564
Ge2 Gd1 Eu3 50.65(3) 5_565 2_564
Eu3 Gd1 Eu3 95.172(18) 5_566 2_564
Gd3 Gd1 Eu3 95.172(18) 5_566 2_564
Ge1 Gd1 Gd3 54.80(3) 8_665 2_564
Ge1 Gd1 Gd3 140.23(3) 3_556 2_564
Ge3 Gd1 Gd3 51.23(3) 2_564 2_564
Ge3 Gd1 Gd3 88.32(3) 5_566 2_564
Ge1 Gd1 Gd3 116.00(3) 7_565 2_564
Ge2 Gd1 Gd3 50.65(3) 5_565 2_564
Eu3 Gd1 Gd3 95.172(18) 5_566 2_564
Gd3 Gd1 Gd3 95.172(18) 5_566 2_564
Eu3 Gd1 Gd3 0.00(2) 2_564 2_564
Ge1 Gd1 Gd2 104.46(3) 8_665 4_455
Ge1 Gd1 Gd2 49.20(2) 3_556 4_455
Ge3 Gd1 Gd2 133.27(3) 2_564 4_455
Ge3 Gd1 Gd2 112.73(3) 5_566 4_455
Ge1 Gd1 Gd2 50.67(2) 7_565 4_455
Ge2 Gd1 Gd2 141.61(3) 5_565 4_455
Eu3 Gd1 Gd2 102.083(17) 5_566 4_455
Gd3 Gd1 Gd2 102.083(17) 5_566 4_455
Eu3 Gd1 Gd2 158.279(18) 2_564 4_455
Gd3 Gd1 Gd2 158.279(18) 2_564 4_455
Ge1 Gd1 Eu2 104.46(3) 8_665 4_455
Ge1 Gd1 Eu2 49.20(2) 3_556 4_455
Ge3 Gd1 Eu2 133.27(3) 2_564 4_455
Ge3 Gd1 Eu2 112.73(3) 5_566 4_455
Ge1 Gd1 Eu2 50.67(2) 7_565 4_455
Ge2 Gd1 Eu2 141.61(3) 5_565 4_455
Eu3 Gd1 Eu2 102.083(17) 5_566 4_455
Gd3 Gd1 Eu2 102.083(17) 5_566 4_455
Eu3 Gd1 Eu2 158.279(18) 2_564 4_455
Gd3 Gd1 Eu2 158.279(18) 2_564 4_455
Gd2 Gd1 Eu2 0.000(19) 4_455 4_455
Ge1 Gd2 Ge1 96.82(2) . 2_554
Ge1 Gd2 Ge2 91.97(4) . 6_656
Ge1 Gd2 Ge2 144.79(4) 2_554 6_656
Ge1 Gd2 Ge2 94.59(4) . .
Ge1 Gd2 Ge2 118.34(4) 2_554 .
Ge2 Gd2 Ge2 94.70(3) 6_656 .
Ge1 Gd2 Ge1 119.51(4) . 6_656
Ge1 Gd2 Ge1 53.77(4) 2_554 6_656
Ge2 Gd2 Ge1 92.41(4) 6_656 6_656
Ge2 Gd2 Ge1 144.88(4) . 6_656
Ge1 Gd2 Ge3 145.61(4) . 1_554
Ge1 Gd2 Ge3 95.22(3) 2_554 1_554
Ge2 Gd2 Ge3 96.47(3) 6_656 1_554
Ge2 Gd2 Ge3 51.60(4) . 1_554
Ge1 Gd2 Ge3 93.44(4) 6_656 1_554
Ge1 Gd2 Eu3 151.71(3) . 6_656
Ge1 Gd2 Eu3 100.31(3) 2_554 6_656
Ge2 Gd2 Eu3 61.40(3) 6_656 6_656
Ge2 Gd2 Eu3 96.84(3) . 6_656
Ge1 Gd2 Eu3 57.33(3) 6_656 6_656
Ge3 Gd2 Eu3 54.56(3) 1_554 6_656
Ge1 Gd2 Gd3 151.71(3) . 6_656
Ge1 Gd2 Gd3 100.31(3) 2_554 6_656
Ge2 Gd2 Gd3 61.40(3) 6_656 6_656
Ge2 Gd2 Gd3 96.84(3) . 6_656
Ge1 Gd2 Gd3 57.33(3) 6_656 6_656
Ge3 Gd2 Gd3 54.56(3) 1_554 6_656
Eu3 Gd2 Gd3 0.00(2) 6_656 6_656
Ge1 Gd2 Gd3 57.75(3) . .
Ge1 Gd2 Gd3 153.01(3) 2_554 .
Ge2 Gd2 Gd3 53.77(3) 6_656 .
Ge2 Gd2 Gd3 60.82(3) . .
Ge1 Gd2 Gd3 143.86(3) 6_656 .
Ge3 Gd2 Gd3 101.89(3) 1_554 .
Eu3 Gd2 Gd3 106.612(19) 6_656 .
Gd3 Gd2 Gd3 106.612(19) 6_656 .
Ge1 Gd2 Eu1 64.47(3) . 4
Ge1 Gd2 Eu1 54.78(3) 2_554 4
Ge2 Gd2 Eu1 100.16(2) 6_656 4
Ge2 Gd2 Eu1 154.49(3) . 4
Ge1 Gd2 Eu1 55.38(2) 6_656 4
Ge3 Gd2 Eu1 144.91(3) 1_554 4
Eu3 Gd2 Eu1 108.453(18) 6_656 4
Gd3 Gd2 Eu1 108.453(18) 6_656 4
Gd3 Gd2 Eu1 112.881(18) . 4
Ge1 Gd2 Gd1 64.47(3) . 4
Ge1 Gd2 Gd1 54.78(3) 2_554 4
Ge2 Gd2 Gd1 100.16(2) 6_656 4
Ge2 Gd2 Gd1 154.49(3) . 4
Ge1 Gd2 Gd1 55.38(2) 6_656 4
Ge3 Gd2 Gd1 144.91(3) 1_554 4
Eu3 Gd2 Gd1 108.453(18) 6_656 4
Gd3 Gd2 Gd1 108.453(18) 6_656 4
Gd3 Gd2 Gd1 112.881(18) . 4
Eu1 Gd2 Gd1 0.00(2) 4 4
Ge2 Gd3 Ge3 90.63(4) 6_656 .
Ge2 Gd3 Ge3 179.35(5) 6_656 6_557
Ge3 Gd3 Ge3 90.02(3) . 6_557
Ge2 Gd3 Ge1 87.64(2) 6_656 7_565
Ge3 Gd3 Ge1 95.70(2) . 7_565
Ge3 Gd3 Ge1 92.30(2) 6_557 7_565
Ge2 Gd3 Ge1 87.64(2) 6_656 .
Ge3 Gd3 Ge1 95.70(2) . .
Ge3 Gd3 Ge1 92.30(2) 6_557 .
Ge1 Gd3 Ge1 167.70(5) 7_565 .
Ge2 Gd3 Ge2 88.52(3) 6_656 .
Ge3 Gd3 Ge2 179.15(5) . .
Ge3 Gd3 Ge2 90.83(4) 6_557 .
Ge1 Gd3 Ge2 84.26(2) 7_565 .
Ge1 Gd3 Ge2 84.26(2) . .
Ge2 Gd3 Eu2 123.39(3) 6_656 4_455
Ge3 Gd3 Eu2 128.55(3) . 4_455
Ge3 Gd3 Eu2 56.12(3) 6_557 4_455
Ge1 Gd3 Eu2 54.18(2) 7_565 4_455
Ge1 Gd3 Eu2 120.40(3) . 4_455
Ge2 Gd3 Eu2 52.06(2) . 4_455
Ge2 Gd3 Gd2 123.39(3) 6_656 4_455
Ge3 Gd3 Gd2 128.55(3) . 4_455
Ge3 Gd3 Gd2 56.12(3) 6_557 4_455
Ge1 Gd3 Gd2 54.18(2) 7_565 4_455
Ge1 Gd3 Gd2 120.40(3) . 4_455
Ge2 Gd3 Gd2 52.06(2) . 4_455
Eu2 Gd3 Gd2 0.000(11) 4_455 4_455
Ge2 Gd3 Eu2 123.39(3) 6_656 6_556
Ge3 Gd3 Eu2 128.55(3) . 6_556
Ge3 Gd3 Eu2 56.12(3) 6_557 6_556
Ge1 Gd3 Eu2 120.40(3) 7_565 6_556
Ge1 Gd3 Eu2 54.18(2) . 6_556
Ge2 Gd3 Eu2 52.06(2) . 6_556
Eu2 Gd3 Eu2 66.57(2) 4_455 6_556
Gd2 Gd3 Eu2 66.57(2) 4_455 6_556
Ge2 Gd3 Gd2 123.39(3) 6_656 6_556
Ge3 Gd3 Gd2 128.55(3) . 6_556
Ge3 Gd3 Gd2 56.12(3) 6_557 6_556
Ge1 Gd3 Gd2 120.40(3) 7_565 6_556
Ge1 Gd3 Gd2 54.18(2) . 6_556
Ge2 Gd3 Gd2 52.06(2) . 6_556
Eu2 Gd3 Gd2 66.57(2) 4_455 6_556
Gd2 Gd3 Gd2 66.57(2) 4_455 6_556
Eu2 Gd3 Gd2 0.000(18) 6_556 6_556
Ge2 Gd3 Gd2 54.08(3) 6_656 .
Ge3 Gd3 Gd2 127.38(3) . .
Ge3 Gd3 Gd2 125.44(3) 6_557 .
Ge1 Gd3 Gd2 117.15(3) 7_565 .
Ge1 Gd3 Gd2 51.43(2) . .
Ge2 Gd3 Gd2 52.00(2) . .
Eu2 Gd3 Gd2 104.05(2) 4_455 .
Gd2 Gd3 Gd2 104.05(2) 4_455 .
Eu2 Gd3 Gd2 69.318(14) 6_556 .
Gd2 Gd3 Gd2 69.318(14) 6_556 .
Ge1 Ge1 Gd2 135.58(6) 5_556 .
Ge1 Ge1 Eu2 64.88(4) 5_556 2
Gd2 Ge1 Eu2 139.82(4) . 2
Ge1 Ge1 Gd2 64.88(4) 5_556 2
Gd2 Ge1 Gd2 139.82(4) . 2
Eu2 Ge1 Gd2 0.00(2) 2 2
Ge1 Ge1 Eu2 61.35(4) 5_556 6_556
Gd2 Ge1 Eu2 84.02(3) . 6_556
Eu2 Ge1 Eu2 126.23(4) 2 6_556
Gd2 Ge1 Eu2 126.23(4) 2 6_556
Ge1 Ge1 Gd2 61.35(4) 5_556 6_556
Gd2 Ge1 Gd2 84.02(3) . 6_556
Eu2 Ge1 Gd2 126.23(4) 2 6_556
Gd2 Ge1 Gd2 126.23(4) 2 6_556
Eu2 Ge1 Gd2 0.00(2) 6_556 6_556
Ge1 Ge1 Gd1 135.92(6) 5_556 8_656
Gd2 Ge1 Gd1 88.45(3) . 8_656
Eu2 Ge1 Gd1 82.76(3) 2 8_656
Gd2 Ge1 Gd1 82.76(3) 2 8_656
Eu2 Ge1 Gd1 139.65(4) 6_556 8_656
Gd2 Ge1 Gd1 139.65(4) 6_556 8_656
Ge1 Ge1 Eu1 135.92(6) 5_556 8_656
Gd2 Ge1 Eu1 88.45(3) . 8_656
Eu2 Ge1 Eu1 82.76(3) 2 8_656
Gd2 Ge1 Eu1 82.76(3) 2 8_656
Eu2 Ge1 Eu1 139.65(4) 6_556 8_656
Gd2 Ge1 Eu1 139.65(4) 6_556 8_656
Gd1 Ge1 Eu1 0.00(2) 8_656 8_656
Ge1 Ge1 Gd3 115.02(6) 5_556 .
Gd2 Ge1 Gd3 70.83(3) . .
Eu2 Ge1 Gd3 140.09(4) 2 .
Gd2 Ge1 Gd3 140.09(4) 2 .
Eu2 Ge1 Gd3 68.49(3) 6_556 .
Gd2 Ge1 Gd3 68.49(3) 6_556 .
Gd1 Ge1 Gd3 71.59(3) 8_656 .
Eu1 Ge1 Gd3 71.59(3) 8_656 .
Ge1 Ge1 Eu1 66.07(4) 5_556 3_546
Gd2 Ge1 Eu1 140.03(4) . 3_546
Eu2 Ge1 Eu1 76.01(3) 2 3_546
Gd2 Ge1 Eu1 76.01(3) 2 3_546
Eu2 Ge1 Eu1 82.70(3) 6_556 3_546
Gd2 Ge1 Eu1 82.70(3) 6_556 3_546
Gd1 Ge1 Eu1 78.04(3) 8_656 3_546
Eu1 Ge1 Eu1 78.04(3) 8_656 3_546
Gd3 Ge1 Eu1 69.23(3) . 3_546
Ge3 Ge2 Eu3 116.81(6) 1_554 6_556
Ge3 Ge2 Gd3 116.81(6) 1_554 6_556
Eu3 Ge2 Gd3 0.00(3) 6_556 6_556
Ge3 Ge2 Eu2 140.22(2) 1_554 4_455
Eu3 Ge2 Eu2 72.15(3) 6_556 4_455
Gd3 Ge2 Eu2 72.15(3) 6_556 4_455
Ge3 Ge2 Gd2 140.22(2) 1_554 4_455
Eu3 Ge2 Gd2 72.15(3) 6_556 4_455
Gd3 Ge2 Gd2 72.15(3) 6_556 4_455
Eu2 Ge2 Gd2 0.00(2) 4_455 4_455
Ge3 Ge2 Eu2 140.21(2) 1_554 6_556
Eu3 Ge2 Eu2 72.15(3) 6_556 6_556
Gd3 Ge2 Eu2 72.15(3) 6_556 6_556
Eu2 Ge2 Eu2 79.33(4) 4_455 6_556
Gd2 Ge2 Eu2 79.33(4) 4_455 6_556
Ge3 Ge2 Gd2 140.21(2) 1_554 6_556
Eu3 Ge2 Gd2 72.15(3) 6_556 6_556
Gd3 Ge2 Gd2 72.15(3) 6_556 6_556
Eu2 Ge2 Gd2 79.33(4) 4_455 6_556
Gd2 Ge2 Gd2 79.33(4) 4_455 6_556
Eu2 Ge2 Gd2 0.00(3) 6_556 6_556
Ge3 Ge2 Gd2 65.79(4) 1_554 .
Eu3 Ge2 Gd2 140.27(2) 6_556 .
Gd3 Ge2 Gd2 140.27(2) 6_556 .
Eu2 Ge2 Gd2 133.72(5) 4_455 .
Gd2 Ge2 Gd2 133.72(5) 4_455 .
Eu2 Ge2 Gd2 83.12(2) 6_556 .
Gd2 Ge2 Gd2 83.12(2) 6_556 .
Ge3 Ge2 Eu2 65.79(4) 1_554 7_565
Eu3 Ge2 Eu2 140.27(2) 6_556 7_565
Gd3 Ge2 Eu2 140.27(2) 6_556 7_565
Eu2 Ge2 Eu2 83.12(2) 4_455 7_565
Gd2 Ge2 Eu2 83.12(2) 4_455 7_565
Eu2 Ge2 Eu2 133.72(5) 6_556 7_565
Gd2 Ge2 Eu2 133.72(5) 6_556 7_565
Gd2 Ge2 Eu2 78.87(4) . 7_565
Ge3 Ge2 Gd2 65.79(4) 1_554 7_565
Eu3 Ge2 Gd2 140.27(2) 6_556 7_565
Gd3 Ge2 Gd2 140.27(2) 6_556 7_565
Eu2 Ge2 Gd2 83.12(2) 4_455 7_565
Gd2 Ge2 Gd2 83.12(2) 4_455 7_565
Eu2 Ge2 Gd2 133.72(5) 6_556 7_565
Gd2 Ge2 Gd2 133.72(5) 6_556 7_565
Gd2 Ge2 Gd2 78.87(4) . 7_565
Eu2 Ge2 Gd2 0.00(3) 7_565 7_565
Ge3 Ge2 Eu1 65.07(4) 1_554 5_565
Eu3 Ge2 Eu1 71.54(3) 6_556 5_565
Gd3 Ge2 Eu1 71.54(3) 6_556 5_565
Eu2 Ge2 Eu1 84.16(2) 4_455 5_565
Gd2 Ge2 Eu1 84.16(2) 4_455 5_565
Eu2 Ge2 Eu1 143.20(5) 6_556 5_565
Gd2 Ge2 Eu1 143.20(5) 6_556 5_565
Gd2 Ge2 Eu1 130.38(5) . 5_565
Eu2 Ge2 Eu1 75.51(2) 7_565 5_565
Gd2 Ge2 Eu1 75.51(2) 7_565 5_565
Ge2 Ge3 Gd3 116.94(6) 1_556 .
Ge2 Ge3 Eu3 117.46(6) 1_556 6_657
Gd3 Ge3 Eu3 125.60(5) . 6_657
Ge2 Ge3 Gd3 117.46(6) 1_556 6_657
Gd3 Ge3 Gd3 125.60(5) . 6_657
Eu3 Ge3 Gd3 0.0 6_657 6_657
Ge2 Ge3 Eu2 62.61(4) 1_556 7_566
Gd3 Ge3 Eu2 140.94(2) . 7_566
Eu3 Ge3 Eu2 69.32(3) 6_657 7_566
Gd3 Ge3 Eu2 69.32(3) 6_657 7_566
Ge2 Ge3 Gd2 62.61(4) 1_556 7_566
Gd3 Ge3 Gd2 140.94(2) . 7_566
Eu3 Ge3 Gd2 69.32(3) 6_657 7_566
Gd3 Ge3 Gd2 69.32(3) 6_657 7_566
Eu2 Ge3 Gd2 0.000(18) 7_566 7_566
Ge2 Ge3 Eu2 62.61(4) 1_556 1_556
Gd3 Ge3 Eu2 140.93(2) . 1_556
Eu3 Ge3 Eu2 69.32(3) 6_657 1_556
Gd3 Ge3 Eu2 69.32(3) 6_657 1_556
Eu2 Ge3 Eu2 76.40(4) 7_566 1_556
Gd2 Ge3 Eu2 76.40(4) 7_566 1_556
Ge2 Ge3 Gd2 62.61(4) 1_556 1_556
Gd3 Ge3 Gd2 140.93(2) . 1_556
Eu3 Ge3 Gd2 69.32(3) 6_657 1_556
Gd3 Ge3 Gd2 69.32(3) 6_657 1_556
Eu2 Ge3 Gd2 76.40(4) 7_566 1_556
Gd2 Ge3 Gd2 76.40(4) 7_566 1_556
Eu2 Ge3 Gd2 0.00(3) 1_556 1_556
Ge2 Ge3 Gd1 133.43(2) 1_556 2_565
Gd3 Ge3 Gd1 72.71(3) . 2_565
Eu3 Ge3 Gd1 70.65(3) 6_657 2_565
Gd3 Ge3 Gd1 70.65(3) 6_657 2_565
Eu2 Ge3 Gd1 81.78(2) 7_566 2_565
Gd2 Ge3 Gd1 81.78(2) 7_566 2_565
Eu2 Ge3 Gd1 139.03(5) 1_556 2_565
Gd2 Ge3 Gd1 139.03(5) 1_556 2_565
Ge2 Ge3 Eu1 133.43(2) 1_556 2_565
Gd3 Ge3 Eu1 72.71(3) . 2_565
Eu3 Ge3 Eu1 70.65(3) 6_657 2_565
Gd3 Ge3 Eu1 70.65(3) 6_657 2_565
Eu2 Ge3 Eu1 81.78(2) 7_566 2_565
Gd2 Ge3 Eu1 81.78(2) 7_566 2_565
Eu2 Ge3 Eu1 139.03(5) 1_556 2_565
Gd2 Ge3 Eu1 139.03(5) 1_556 2_565
Gd1 Ge3 Eu1 0.00(3) 2_565 2_565
Ge2 Ge3 Eu1 133.43(2) 1_556 8_656
Gd3 Ge3 Eu1 72.71(3) . 8_656
Eu3 Ge3 Eu1 70.65(3) 6_657 8_656
Gd3 Ge3 Eu1 70.65(3) 6_657 8_656
Eu2 Ge3 Eu1 139.03(5) 7_566 8_656
Gd2 Ge3 Eu1 139.03(5) 7_566 8_656
Eu2 Ge3 Eu1 81.78(2) 1_556 8_656
Gd2 Ge3 Eu1 81.78(2) 1_556 8_656
Gd1 Ge3 Eu1 93.11(4) 2_565 8_656
Eu1 Ge3 Eu1 93.11(4) 2_565 8_656
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Gd1 Ge1 3.0893(12) 8_665
Gd1 Ge1 3.1601(12) 3_556
Gd1 Ge3 3.1636(12) 2_564
Gd1 Ge3 3.2094(12) 5_566
Gd1 Ge1 3.2143(12) 7_565
Gd1 Ge2 3.2488(12) 5_565
Gd1 Eu3 3.5765(8) 5_566
Gd1 Gd3 3.5765(8) 5_566
Gd1 Eu3 3.6412(8) 2_564
Gd1 Gd3 3.6412(8) 2_564
Gd1 Gd2 3.7534(8) 4_455
Gd1 Eu2 3.7534(8) 4_455
Gd2 Ge1 2.8993(12) .
Gd2 Ge1 2.9283(13) 2_554
Gd2 Ge2 2.9798(13) 6_656
Gd2 Ge2 2.9943(13) .
Gd2 Ge1 3.0211(12) 6_656
Gd2 Ge3 3.0758(13) 1_554
Gd2 Eu3 3.4661(8) 6_656
Gd2 Gd3 3.4661(8) 6_656
Gd2 Gd3 3.5026(8) .
Gd2 Eu1 3.7534(8) 4
Gd2 Gd1 3.7534(8) 4
Gd3 Ge2 2.9683(16) 6_656
Gd3 Ge3 2.9732(17) .
Gd3 Ge3 3.0183(16) 6_557
Gd3 Ge1 3.1361(12) 7_565
Gd3 Ge1 3.1361(12) .
Gd3 Ge2 3.3176(17) .
Gd3 Eu2 3.4661(8) 4_455
Gd3 Gd2 3.4661(8) 4_455
Gd3 Eu2 3.4661(8) 6_556
Gd3 Gd2 3.4661(8) 6_556
Ge1 Ge1 2.692(2) 5_556
Ge1 Eu2 2.9283(13) 2
Ge1 Gd2 2.9283(13) 2
Ge1 Eu2 3.0211(12) 6_556
Ge1 Gd2 3.0211(12) 6_556
Ge1 Gd1 3.0892(12) 8_656
Ge1 Eu1 3.0892(12) 8_656
Ge1 Eu1 3.1601(12) 3_546
Ge2 Ge3 2.643(2) 1_554
Ge2 Eu3 2.9682(16) 6_556
Ge2 Gd3 2.9682(16) 6_556
Ge2 Eu2 2.9798(13) 4_455
Ge2 Gd2 2.9798(13) 4_455
Ge2 Eu2 2.9798(13) 6_556
Ge2 Gd2 2.9798(13) 6_556
Ge2 Eu2 2.9943(13) 7_565
Ge2 Gd2 2.9943(13) 7_565
Ge2 Eu1 3.2489(12) 5_565
Ge3 Ge2 2.643(2) 1_556
Ge3 Eu3 3.0184(16) 6_657
Ge3 Gd3 3.0184(16) 6_657
Ge3 Eu2 3.0759(13) 7_566
Ge3 Gd2 3.0759(13) 7_566
Ge3 Eu2 3.0759(13) 1_556
Ge3 Gd2 3.0759(13) 1_556
Ge3 Gd1 3.1636(12) 2_565
Ge3 Eu1 3.1636(12) 2_565
Ge3 Eu1 3.1636(12) 8_656
