#------------------------------------------------------------------------------
#$Date: 2016-03-21 03:39:43 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178436 $
#$URL: svn://www.crystallography.net/cod/cif/4/02/57/4025741.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4025741
loop_
_publ_author_name
'Daniel J. Kerr'
'Jonathan M. White'
'Bernard L. Flynn'
_publ_section_title
;
 A Reductive-Coupling plus Nazarov Cyclization Sequence in the Asymmetric
 Synthesis of Five-Membered Carbocycles
;
_journal_name_full               'Journal of Organic Chemistry'
_journal_page_first              7073
_journal_page_last               7084
_journal_paper_doi               10.1021/jo100736p
_journal_volume                  75
_journal_year                    2010
_chemical_formula_sum            'C24 H21 N O5'
_chemical_formula_weight         403.42
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           4
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'P 2yb'
_symmetry_space_group_name_H-M   'P 1 21 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 114.551(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   9.483(2)
_cell_length_b                   22.611(5)
_cell_length_c                   10.386(2)
_cell_measurement_reflns_used    5974
_cell_measurement_temperature    130(2)
_cell_measurement_theta_max      26.13
_cell_measurement_theta_min      2.34
_cell_volume                     2025.6(7)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      130(2)
_diffrn_measured_fraction_theta_full 0.982
_diffrn_measured_fraction_theta_max 0.982
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0249
_diffrn_reflns_av_sigmaI/netI    0.0434
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       28
_diffrn_reflns_limit_k_min       -29
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            16944
_diffrn_reflns_theta_full        27.55
_diffrn_reflns_theta_max         27.55
_diffrn_reflns_theta_min         1.80
_exptl_absorpt_coefficient_mu    0.093
_exptl_absorpt_correction_T_max  1.00
_exptl_absorpt_correction_T_min  0.866
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.323
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             848
_exptl_crystal_size_max          0.45
_exptl_crystal_size_mid          0.40
_exptl_crystal_size_min          0.35
_refine_diff_density_max         0.388
_refine_diff_density_min         -0.240
_refine_diff_density_rms         0.049
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   -0.6(8)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.237
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     551
_refine_ls_number_reflns         8789
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.237
_refine_ls_R_factor_all          0.0571
_refine_ls_R_factor_gt           0.0515
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0615P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1247
_refine_ls_wR_factor_ref         0.1281
_reflns_number_gt                7915
_reflns_number_total             8789
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            jo100736p_si_002.cif
_cod_data_source_block           jmwbf3
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to the built-in table from CIF Core dictionary named
'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'Multi-scan'
changed to 'multi-scan' according to the built-in table from CIF Core
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1646 2011-03-28 12:23:43Z adriana 
;
_cod_original_cell_volume        2025.5(8)
_cod_original_sg_symbol_H-M      'P 1 21 1 '
_cod_database_code               4025741
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.1169(3) 0.91484(11) 0.2828(3) 0.0355(6) Uani 1 1 d . . .
C2 C 0.0682(3) 0.99801(12) 0.1458(3) 0.0425(6) Uani 1 1 d . . .
H2A H -0.0438 1.0023 0.0845 0.051 Uiso 1 1 calc R . .
H2B H 0.1278 1.0210 0.1041 0.051 Uiso 1 1 calc R . .
C3 C 0.1052(3) 1.01898(10) 0.2968(2) 0.0316(5) Uani 1 1 d . . .
H3 H 0.0218 1.0458 0.2976 0.038 Uiso 1 1 calc R . .
C4 C 0.2610(3) 1.04856(10) 0.3656(2) 0.0290(5) Uani 1 1 d . . .
C5 C 0.3975(3) 1.01677(11) 0.4104(3) 0.0352(5) Uani 1 1 d . . .
H5 H 0.3945 0.9748 0.4053 0.042 Uiso 1 1 calc R . .
C6 C 0.5395(3) 1.04605(12) 0.4631(3) 0.0373(6) Uani 1 1 d . . .
H6 H 0.6329 1.0239 0.4936 0.045 Uiso 1 1 calc R . .
C7 C 0.5455(3) 1.10685(13) 0.4714(3) 0.0401(6) Uani 1 1 d . . .
H7 H 0.6426 1.1267 0.5065 0.048 Uiso 1 1 calc R . .
C8 C 0.4092(3) 1.13866(11) 0.4280(3) 0.0390(6) Uani 1 1 d . . .
H8 H 0.4128 1.1806 0.4342 0.047 Uiso 1 1 calc R . .
C9 C 0.2670(3) 1.10993(11) 0.3756(3) 0.0337(5) Uani 1 1 d . . .
H9 H 0.1738 1.1322 0.3466 0.040 Uiso 1 1 calc R . .
C10 C 0.0768(3) 0.96010(10) 0.4863(2) 0.0277(5) Uani 1 1 d . . .
C11 C 0.0860(3) 0.90121(9) 0.5575(2) 0.0262(5) Uani 1 1 d . . .
H11 H 0.0594 0.8691 0.4849 0.031 Uiso 1 1 calc R . .
C12 C 0.2530(3) 0.89176(9) 0.6693(2) 0.0280(5) Uani 1 1 d . . .
C13 C 0.2371(3) 0.86573(10) 0.7919(2) 0.0289(5) Uani 1 1 d . . .
C14 C 0.0910(3) 0.86673(10) 0.7774(2) 0.0289(5) Uani 1 1 d . . .
C15 C -0.0179(3) 0.89468(10) 0.6398(2) 0.0276(5) Uani 1 1 d . . .
H15 H -0.0469 0.9350 0.6601 0.033 Uiso 1 1 calc R . .
C16 C 0.0441(3) 0.84210(13) 0.8865(3) 0.0400(6) Uani 1 1 d . . .
H16A H -0.0462 0.8155 0.8414 0.048 Uiso 1 1 calc R . .
H16B H 0.0140 0.8746 0.9338 0.048 Uiso 1 1 calc R . .
C17 C 0.1805(4) 0.80763(14) 0.9955(3) 0.0481(7) Uani 1 1 d . . .
H17A H 0.1646 0.8026 1.0832 0.058 Uiso 1 1 calc R . .
H17B H 0.1853 0.7678 0.9578 0.058 Uiso 1 1 calc R . .
C18 C 0.3308(3) 0.83953(14) 1.0292(3) 0.0455(7) Uani 1 1 d . . .
H18A H 0.3262 0.8791 1.0679 0.055 Uiso 1 1 calc R . .
H18B H 0.4165 0.8173 1.1025 0.055 Uiso 1 1 calc R . .
C19 C -0.1647(3) 0.85923(10) 0.5626(2) 0.0262(5) Uani 1 1 d . . .
C20 C -0.3053(3) 0.88083(11) 0.5528(3) 0.0331(5) Uani 1 1 d . . .
H20 H -0.3091 0.9177 0.5952 0.040 Uiso 1 1 calc R . .
C21 C -0.4410(3) 0.84897(12) 0.4814(3) 0.0393(6) Uani 1 1 d . . .
H21 H -0.5372 0.8642 0.4747 0.047 Uiso 1 1 calc R . .
C22 C -0.4364(3) 0.79534(12) 0.4203(3) 0.0370(6) Uani 1 1 d . . .
H22 H -0.5295 0.7740 0.3697 0.044 Uiso 1 1 calc R . .
C23 C -0.2970(3) 0.77277(12) 0.4328(3) 0.0363(6) Uani 1 1 d . . .
H23 H -0.2932 0.7353 0.3929 0.044 Uiso 1 1 calc R . .
C24 C -0.1616(3) 0.80463(11) 0.5035(3) 0.0324(5) Uani 1 1 d . . .
H24 H -0.0655 0.7888 0.5115 0.039 Uiso 1 1 calc R . .
O1 O 0.1345(2) 0.86339(7) 0.31168(19) 0.0455(5) Uani 1 1 d . . .
O2 O 0.1136(2) 0.93653(8) 0.16127(18) 0.0455(5) Uani 1 1 d . . .
O3 O 0.0562(2) 1.00576(7) 0.53606(19) 0.0357(4) Uani 1 1 d . . .
O4 O 0.36927(19) 0.90420(7) 0.65582(18) 0.0339(4) Uani 1 1 d . . .
O5 O 0.3622(2) 0.84602(8) 0.90470(18) 0.0365(4) Uani 1 1 d . . .
N1 N 0.1005(2) 0.96180(8) 0.3629(2) 0.0295(4) Uani 1 1 d . . .
C1' C 0.4522(3) 0.62660(11) 0.1884(3) 0.0356(6) Uani 1 1 d . . .
C2' C 0.5938(3) 0.54077(12) 0.2403(3) 0.0398(6) Uani 1 1 d . . .
H2C H 0.6463 0.5336 0.3436 0.048 Uiso 1 1 calc R . .
H2D H 0.6488 0.5184 0.1931 0.048 Uiso 1 1 calc R . .
C3' C 0.4254(3) 0.52248(11) 0.1832(2) 0.0332(5) Uani 1 1 d . . .
H3 H 0.4081 0.4950 0.2508 0.040 Uiso 1 1 calc R . .
C4' C 0.3657(3) 0.49502(13) 0.0367(3) 0.0433(7) Uani 1 1 d . . .
C5' C 0.3425(4) 0.5309(2) -0.0822(3) 0.0667(10) Uani 1 1 d . . .
H5' H 0.3569 0.5725 -0.0718 0.080 Uiso 1 1 calc R . .
C6' C 0.2987(5) 0.5048(3) -0.2126(4) 0.0945(18) Uani 1 1 d . . .
H6' H 0.2796 0.5285 -0.2937 0.113 Uiso 1 1 calc R . .
C7' C 0.2827(5) 0.4446(3) -0.2253(5) 0.119(3) Uani 1 1 d . . .
H7' H 0.2565 0.4267 -0.3151 0.143 Uiso 1 1 calc R . .
C8' C 0.3034(5) 0.4101(2) -0.1129(5) 0.114(2) Uani 1 1 d . . .
H8' H 0.2897 0.3685 -0.1240 0.136 Uiso 1 1 calc R . .
C9' C 0.3449(4) 0.43591(16) 0.0195(4) 0.0757(12) Uani 1 1 d . . .
H9' H 0.3587 0.4117 0.0987 0.091 Uiso 1 1 calc R . .
C10' C 0.2040(3) 0.58277(10) 0.1765(2) 0.0276(5) Uani 1 1 d . . .
C11' C 0.1295(3) 0.64312(10) 0.1545(2) 0.0257(5) Uani 1 1 d . . .
H11' H 0.2132 0.6732 0.1984 0.031 Uiso 1 1 calc R . .
C12' C 0.0446(3) 0.65697(11) -0.0051(2) 0.0313(5) Uani 1 1 d . . .
C13' C -0.0901(3) 0.69188(10) -0.0181(2) 0.0298(5) Uani 1 1 d . . .
C14' C -0.1120(3) 0.69122(10) 0.1015(2) 0.0291(5) Uani 1 1 d . A .
C15' C 0.0065(3) 0.65247(10) 0.2141(2) 0.0271(5) Uani 1 1 d . . .
H15' H -0.0427 0.6135 0.2156 0.033 Uiso 1 1 calc R . .
C16' C -0.2432(3) 0.72239(15) 0.1137(3) 0.0488(7) Uani 1 1 d . . .
C17' C -0.3737(5) 0.7272(2) -0.0373(5) 0.0413(15) Uani 0.583(8) 1 d P A 1
H17C H -0.4209 0.6878 -0.0692 0.050 Uiso 0.583(8) 1 calc PR A 1
H17D H -0.4555 0.7542 -0.0369 0.050 Uiso 0.583(8) 1 calc PR A 1
C17A C -0.2914(8) 0.7738(3) -0.0181(7) 0.044(2) Uani 0.417(8) 1 d P A 2
H17E H -0.3891 0.7936 -0.0296 0.053 Uiso 0.417(8) 1 calc PR A 2
H17F H -0.2091 0.8042 0.0088 0.053 Uiso 0.417(8) 1 calc PR A 2
C18' C -0.3090(4) 0.75003(16) -0.1376(3) 0.0584(9) Uani 1 1 d . . .
C19' C 0.0741(2) 0.67786(10) 0.3629(2) 0.0241(4) Uani 1 1 d . . .
C20' C 0.0556(3) 0.64829(10) 0.4718(2) 0.0298(5) Uani 1 1 d . . .
H20' H -0.0069 0.6137 0.4516 0.036 Uiso 1 1 calc R . .
C21' C 0.1277(3) 0.66869(11) 0.6103(3) 0.0350(6) Uani 1 1 d . . .
H21' H 0.1135 0.6482 0.6839 0.042 Uiso 1 1 calc R . .
C22' C 0.2199(3) 0.71861(11) 0.6412(2) 0.0320(5) Uani 1 1 d . . .
H22' H 0.2713 0.7320 0.7362 0.038 Uiso 1 1 calc R . .
C23' C 0.2368(3) 0.74900(10) 0.5331(2) 0.0298(5) Uani 1 1 d . . .
H23' H 0.2997 0.7835 0.5537 0.036 Uiso 1 1 calc R . .
C24' C 0.1624(3) 0.72933(9) 0.3948(2) 0.0267(5) Uani 1 1 d . . .
H24' H 0.1718 0.7513 0.3208 0.032 Uiso 1 1 calc R . .
O1' O 0.4270(2) 0.67845(9) 0.1769(2) 0.0468(5) Uani 1 1 d . . .
O2' O 0.5909(2) 0.60351(9) 0.2093(2) 0.0449(5) Uani 1 1 d . . .
O3' O 0.1391(2) 0.53772(7) 0.18284(18) 0.0349(4) Uani 1 1 d . . .
O4' O 0.0845(2) 0.64121(9) -0.09531(17) 0.0434(5) Uani 1 1 d . . .
O5' O -0.1789(2) 0.71818(8) -0.14242(18) 0.0395(4) Uani 1 1 d . A .
N1' N 0.3527(2) 0.58000(9) 0.18105(19) 0.0288(4) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 C1 O2 122.5(2) . . ?
O1 C1 N1 128.9(2) . . ?
O2 C1 N1 108.5(2) . . ?
O2 C2 C3 104.62(19) . . ?
N1 C3 C4 112.52(19) . . ?
N1 C3 C2 99.62(19) . . ?
C4 C3 C2 112.7(2) . . ?
C5 C4 C9 119.4(2) . . ?
C5 C4 C3 121.8(2) . . ?
C9 C4 C3 118.7(2) . . ?
C4 C5 C6 120.2(2) . . ?
C7 C6 C5 120.5(3) . . ?
C8 C7 C6 119.4(3) . . ?
C7 C8 C9 120.6(2) . . ?
C8 C9 C4 119.9(2) . . ?
O3 C10 N1 119.2(2) . . ?
O3 C10 C11 122.2(2) . . ?
N1 C10 C11 118.53(19) . . ?
C10 C11 C12 108.93(18) . . ?
C10 C11 C15 115.60(18) . . ?
C12 C11 C15 105.02(18) . . ?
O4 C12 C13 128.8(2) . . ?
O4 C12 C11 125.8(2) . . ?
C13 C12 C11 105.4(2) . . ?
C14 C13 O5 127.1(2) . . ?
C14 C13 C12 111.9(2) . . ?
O5 C13 C12 121.0(2) . . ?
C13 C14 C16 122.3(2) . . ?
C13 C14 C15 112.6(2) . . ?
C16 C14 C15 125.1(2) . . ?
C14 C15 C19 113.32(19) . . ?
C14 C15 C11 102.68(18) . . ?
C19 C15 C11 114.30(18) . . ?
C14 C16 C17 109.0(2) . . ?
C18 C17 C16 110.8(2) . . ?
O5 C18 C17 111.6(2) . . ?
C20 C19 C24 118.7(2) . . ?
C20 C19 C15 119.8(2) . . ?
C24 C19 C15 121.5(2) . . ?
C19 C20 C21 120.4(2) . . ?
C22 C21 C20 120.2(2) . . ?
C23 C22 C21 119.8(2) . . ?
C22 C23 C24 120.0(2) . . ?
C23 C24 C19 120.8(2) . . ?
C1 O2 C2 110.2(2) . . ?
C13 O5 C18 112.0(2) . . ?
C10 N1 C1 128.94(19) . . ?
C10 N1 C3 120.10(19) . . ?
C1 N1 C3 110.92(19) . . ?
O1' C1' O2' 122.6(2) . . ?
O1' C1' N1' 129.4(2) . . ?
O2' C1' N1' 108.0(2) . . ?
O2' C2' C3' 105.1(2) . . ?
N1' C3' C4' 111.7(2) . . ?
N1' C3' C2' 100.1(2) . . ?
C4' C3' C2' 113.5(2) . . ?
C9' C4' C5' 119.3(3) . . ?
C9' C4' C3' 120.7(3) . . ?
C5' C4' C3' 119.8(3) . . ?
C6' C5' C4' 119.2(4) . . ?
C5' C6' C7' 119.8(5) . . ?
C8' C7' C6' 121.3(4) . . ?
C7' C8' C9' 119.6(5) . . ?
C4' C9' C8' 120.7(4) . . ?
O3' C10' N1' 119.5(2) . . ?
O3' C10' C11' 123.6(2) . . ?
N1' C10' C11' 116.72(19) . . ?
C10' C11' C12' 110.36(17) . . ?
C10' C11' C15' 116.55(18) . . ?
C12' C11' C15' 104.99(18) . . ?
O4' C12' C13' 129.5(2) . . ?
O4' C12' C11' 125.8(2) . . ?
C13' C12' C11' 104.78(18) . . ?
C14' C13' O5' 127.9(2) . . ?
C14' C13' C12' 112.0(2) . . ?
O5' C13' C12' 120.1(2) . . ?
C13' C14' C16' 122.2(2) . . ?
C13' C14' C15' 111.7(2) . . ?
C16' C14' C15' 126.0(2) . . ?
C19' C15' C14' 115.50(18) . . ?
C19' C15' C11' 112.91(18) . . ?
C14' C15' C11' 102.13(17) . . ?
C14' C16' C17' 107.0(3) . . ?
C14' C16' C17A 102.1(3) . . ?
C17' C16' C17A 45.9(3) . . ?
C18' C17' C16' 110.0(3) . . ?
C18' C17A C16' 111.8(5) . . ?
C17A C18' O5' 117.8(4) . . ?
C17A C18' C17' 53.6(4) . . ?
O5' C18' C17' 116.9(3) . . ?
C20' C19' C24' 118.5(2) . . ?
C20' C19' C15' 120.3(2) . . ?
C24' C19' C15' 121.14(19) . . ?
C21' C20' C19' 120.7(2) . . ?
C22' C21' C20' 120.2(2) . . ?
C21' C22' C23' 119.6(2) . . ?
C22' C23' C24' 120.1(2) . . ?
C23' C24' C19' 120.9(2) . . ?
C1' O2' C2' 110.0(2) . . ?
C13' O5' C18' 112.8(2) . . ?
C10' N1' C1' 128.3(2) . . ?
C10' N1' C3' 120.2(2) . . ?
C1' N1' C3' 111.47(19) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 O1 1.196(3) . ?
C1 O2 1.342(3) . ?
C1 N1 1.397(3) . ?
C2 O2 1.444(3) . ?
C2 C3 1.533(4) . ?
C3 N1 1.473(3) . ?
C3 C4 1.504(3) . ?
C4 C5 1.381(4) . ?
C4 C9 1.391(3) . ?
C5 C6 1.392(4) . ?
C6 C7 1.377(4) . ?
C7 C8 1.381(4) . ?
C8 C9 1.388(4) . ?
C10 O3 1.206(3) . ?
C10 N1 1.391(3) . ?
C10 C11 1.508(3) . ?
C11 C12 1.541(3) . ?
C11 C15 1.557(3) . ?
C12 O4 1.201(3) . ?
C12 C13 1.466(3) . ?
C13 C14 1.330(3) . ?
C13 O5 1.351(3) . ?
C14 C16 1.487(3) . ?
C14 C15 1.510(3) . ?
C15 C19 1.515(3) . ?
C16 C17 1.531(4) . ?
C17 C18 1.503(4) . ?
C18 O5 1.449(3) . ?
C19 C20 1.383(3) . ?
C19 C24 1.385(3) . ?
C20 C21 1.390(4) . ?
C21 C22 1.377(4) . ?
C22 C23 1.372(4) . ?
C23 C24 1.387(3) . ?
C1' O1' 1.192(3) . ?
C1' O2' 1.346(3) . ?
C1' N1' 1.395(3) . ?
C2' O2' 1.453(3) . ?
C2' C3' 1.512(4) . ?
C3' N1' 1.468(3) . ?
C3' C4' 1.518(3) . ?
C4' C9' 1.352(5) . ?
C4' C5' 1.416(5) . ?
C5' C6' 1.374(5) . ?
C6' C7' 1.372(8) . ?
C7' C8' 1.348(8) . ?
C8' C9' 1.391(5) . ?
C10' O3' 1.206(3) . ?
C10' N1' 1.392(3) . ?
C10' C11' 1.510(3) . ?
C11' C12' 1.544(3) . ?
C11' C15' 1.546(3) . ?
C12' O4' 1.201(3) . ?
C12' C13' 1.459(3) . ?
C13' C14' 1.342(3) . ?
C13' O5' 1.351(3) . ?
C14' C16' 1.481(4) . ?
C14' C15' 1.519(3) . ?
C15' C19' 1.518(3) . ?
C16' C17' 1.546(5) . ?
C16' C17A 1.707(7) . ?
C17' C18' 1.503(6) . ?
C17A C18' 1.298(7) . ?
C18' O5' 1.447(4) . ?
C19' C20' 1.386(3) . ?
C19' C24' 1.391(3) . ?
C20' C21' 1.390(3) . ?
C21' C22' 1.381(4) . ?
C22' C23' 1.382(3) . ?
C23' C24' 1.384(3) . ?
