#------------------------------------------------------------------------------
#$Date: 2019-10-02 17:38:14 +0300 (Wed, 02 Oct 2019) $
#$Revision: 219038 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/06/07/4060767.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4060767
loop_
_publ_author_name
'Meijer, Michel D.'
'Kleij, Arjan W.'
'Williams, B. Scott'
'Ellis, Dianne'
'Lutz, Martin'
'Spek, Anthony L.'
'van Klink, Gerard P. M.'
'van Koten, Gerard'
_publ_section_title
;
 Construction of Supported Organometallics Using Cycloplatinated
 Arylamine Ligands
;
_journal_coden_ASTM              ORGND7
_journal_issue                   2
_journal_name_full               Organometallics
_journal_page_first              264
_journal_page_last               271
_journal_paper_doi               10.1021/om010500g
_journal_volume                  21
_journal_year                    2002
_chemical_formula_moiety         'C60 H60 I2 N2 O4 P2 Pt2'
_chemical_formula_sum            'C60 H60 I2 N2 O4 P2 Pt2'
_chemical_formula_weight         1579.02
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     heavy
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 116.5565(7)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   30.3152(5)
_cell_length_b                   11.1579(2)
_cell_length_c                   18.7133(3)
_cell_measurement_temperature    150(2)
_cell_volume                     5662.01(17)
_computing_cell_refinement       'DENZO 1.11.0'
_computing_data_collection       'Nonius COLLECT'
_computing_data_reduction        'DENZO 1.11.0'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'DIRDIF-97 (Beurskens et al., 1997)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Nonius KappaCCD'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'rotating anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0704
_diffrn_reflns_av_sigmaI/netI    0.0408
_diffrn_reflns_limit_h_max       38
_diffrn_reflns_limit_h_min       -39
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            42384
_diffrn_reflns_theta_full        27.46
_diffrn_reflns_theta_max         27.46
_diffrn_reflns_theta_min         1.50
_exptl_absorpt_coefficient_mu    6.130
_exptl_absorpt_correction_T_max  0.85
_exptl_absorpt_correction_T_min  0.59
_exptl_absorpt_correction_type   analytical
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.852
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             3032
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.06
_exptl_crystal_size_min          0.03
_refine_diff_density_max         1.470
_refine_diff_density_min         -0.830
_refine_diff_density_rms         0.123
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.025
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     359
_refine_ls_number_reflns         6461
_refine_ls_number_restraints     3
_refine_ls_restrained_S_all      1.042
_refine_ls_R_factor_all          0.0374
_refine_ls_R_factor_gt           0.0269
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0139P)²+21.3085P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0524
_refine_ls_wR_factor_ref         0.0554
_reflns_number_gt                5535
_reflns_number_total             6461
_reflns_threshold_expression     I>2σ(I)
_cod_depositor_comments
;
The following automatic conversions were performed:

'_refine_ls_hydrogen_treatment' value 'constrained' was replaced with
the value 'constr' as specified in the replacement file
'src/cod-tools/trunk/data/replacement-values/replacement_values.lst'.

Automatic conversion script
Id: cif_fix_values 5376 2017-05-30 11:51:03Z andrius 

 Updated bibliographic information.

 Antanas Vaitkus,
 2019-10-02
;
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               4060767
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Pt1 Pt 0.622139(5) 0.627103(13) 0.523844(8) 0.01824(5) Uani 1 1 d .
I1 I 0.698183(9) 0.76735(2) 0.617512(16) 0.02945(7) Uani 1 1 d .
P1 P 0.67164(3) 0.48977(9) 0.51038(6) 0.0202(2) Uani 1 1 d .
N1 N 0.57011(11) 0.7501(3) 0.53530(18) 0.0221(7) Uani 1 1 d .
O1 O 0.53471(18) 0.2816(5) 0.2663(3) 0.0218(11) Uani 0.50 1 d P
O2 O 0.5016(3) 0.1628(7) 0.3256(6) 0.085(3) Uani 0.50 1 d P
O3 O 0.5309(3) -0.0131(7) 0.1892(4) 0.063(2) Uani 0.50 1 d P
O4 O 0.5501(3) -0.1036(5) 0.3065(4) 0.0515(18) Uani 0.50 1 d PD
C1 C 0.55871(13) 0.5540(3) 0.4408(2) 0.0201(8) Uani 1 1 d .
C2 C 0.51578(13) 0.6037(3) 0.4390(2) 0.0199(8) Uani 1 1 d .
C3 C 0.46918(14) 0.5767(4) 0.3785(2) 0.0255(9) Uani 1 1 d .
H3 H 0.4408 0.6126 0.3787 0.031 Uiso 1 1 calc R
C4 C 0.46387(13) 0.4980(4) 0.3182(2) 0.0254(9) Uani 1 1 d .
H4 H 0.4321 0.4806 0.2765 0.030 Uiso 1 1 calc R
C5 C 0.50553(14) 0.4445(3) 0.3193(2) 0.0220(8) Uani 1 1 d .
C6 C 0.55197(13) 0.4717(3) 0.3800(2) 0.0209(8) Uani 1 1 d .
H6 H 0.5800 0.4334 0.3803 0.025 Uiso 1 1 calc R
C7 C 0.52260(14) 0.6848(4) 0.5071(2) 0.0262(9) Uani 1 1 d .
H7A H 0.4951 0.7429 0.4894 0.031 Uiso 1 1 calc R
H7B H 0.5224 0.6368 0.5514 0.031 Uiso 1 1 calc R
C8 C 0.56355(16) 0.8529(4) 0.4819(3) 0.0319(10) Uani 1 1 d .
H8A H 0.5515 0.8243 0.4268 0.048 Uiso 1 1 calc R
H8B H 0.5952 0.8938 0.4983 0.048 Uiso 1 1 calc R
H8C H 0.5396 0.9088 0.4851 0.048 Uiso 1 1 calc R
C9 C 0.58295(15) 0.7949(4) 0.6170(2) 0.0308(10) Uani 1 1 d .
H9A H 0.5555 0.8424 0.6160 0.046 Uiso 1 1 calc R
H9B H 0.6126 0.8449 0.6355 0.046 Uiso 1 1 calc R
H9C H 0.5892 0.7267 0.6533 0.046 Uiso 1 1 calc R
C10 C 0.5000 0.3658(5) 0.2500 0.0280(13) Uani 1 2 d S
H10 H 0.4680 0.3222 0.2325 0.034 Uiso 0.50 1 calc PR
C11 C 0.5324(4) 0.1824(8) 0.3049(6) 0.042(2) Uani 0.50 1 d P
C12 C 0.5720(4) 0.0948(8) 0.3147(6) 0.044(2) Uani 0.50 1 d P
H12A H 0.5895 0.0683 0.3710 0.053 Uiso 0.50 1 calc PR
H12B H 0.5962 0.1326 0.2997 0.053 Uiso 0.50 1 calc PR
C13 C 0.5476(4) -0.0133(9) 0.2601(6) 0.045(2) Uani 0.50 1 d P
C141 C 0.5381(3) -0.1978(8) 0.2564(6) 0.041(2) Uiso 0.50 1 d PD
H14A H 0.5590 -0.2683 0.2822 0.050 Uiso 0.50 1 calc PR
H14B H 0.5408 -0.1779 0.2070 0.050 Uiso 0.50 1 calc PR
C142 C 0.5179(2) -0.2205(7) 0.2614(5) 0.033(2) Uiso 0.50 1 d P
H14C H 0.5379 -0.1504 0.2886 0.050 Uiso 0.50 1 calc PR
H14D H 0.5197 -0.2335 0.2109 0.050 Uiso 0.50 1 calc PR
H14E H 0.5306 -0.2913 0.2955 0.050 Uiso 0.50 1 calc PR
C15 C 0.73789(14) 0.5061(4) 0.5752(2) 0.0257(9) Uani 1 1 d .
C16 C 0.75638(15) 0.4693(4) 0.6543(2) 0.0358(10) Uani 1 1 d .
H16 H 0.7352 0.4324 0.6728 0.043 Uiso 1 1 calc R
C17 C 0.80551(19) 0.4865(6) 0.7057(3) 0.0628(16) Uani 1 1 d .
H17 H 0.8180 0.4616 0.7598 0.075 Uiso 1 1 calc R
C18 C 0.8364(2) 0.5390(7) 0.6796(4) 0.085(2) Uani 1 1 d .
H18 H 0.8701 0.5508 0.7156 0.102 Uiso 1 1 calc R
C19 C 0.81869(17) 0.5745(5) 0.6017(3) 0.0571(15) Uani 1 1 d .
H19 H 0.8403 0.6102 0.5836 0.069 Uiso 1 1 calc R
C20 C 0.76948(14) 0.5588(4) 0.5491(3) 0.0318(10) Uani 1 1 d .
H20 H 0.7573 0.5841 0.4952 0.038 Uiso 1 1 calc R
C21 C 0.66158(13) 0.3379(3) 0.5352(2) 0.0230(8) Uani 1 1 d .
C22 C 0.69671(15) 0.2480(4) 0.5489(3) 0.0329(10) Uani 1 1 d .
H22 H 0.7252 0.2656 0.5420 0.039 Uiso 1 1 calc R
C23 C 0.69077(17) 0.1346(4) 0.5723(3) 0.0390(11) Uani 1 1 d .
H23 H 0.7145 0.0742 0.5800 0.047 Uiso 1 1 calc R
C24 C 0.64988(17) 0.1090(4) 0.5847(3) 0.0403(11) Uani 1 1 d .
H24 H 0.6458 0.0312 0.6015 0.048 Uiso 1 1 calc R
C25 C 0.61543(16) 0.1963(4) 0.5726(3) 0.0403(11) Uani 1 1 d .
H25 H 0.5876 0.1788 0.5815 0.048 Uiso 1 1 calc R
C26 C 0.62074(14) 0.3098(4) 0.5474(3) 0.0294(9) Uani 1 1 d .
H26 H 0.5963 0.3689 0.5384 0.035 Uiso 1 1 calc R
C27 C 0.66888(13) 0.4849(4) 0.4103(2) 0.0252(9) Uani 1 1 d .
C28 C 0.67263(14) 0.3785(4) 0.3743(2) 0.0321(10) Uani 1 1 d .
H28 H 0.6744 0.3038 0.3997 0.038 Uiso 1 1 calc R
C29 C 0.67377(15) 0.3825(5) 0.3008(3) 0.0429(13) Uani 1 1 d .
H29 H 0.6766 0.3104 0.2762 0.051 Uiso 1 1 calc R
C30 C 0.67077(16) 0.4910(6) 0.2637(3) 0.0459(14) Uani 1 1 d .
H30 H 0.6716 0.4932 0.2136 0.055 Uiso 1 1 calc R
C31 C 0.66656(17) 0.5957(5) 0.2984(3) 0.0460(13) Uani 1 1 d .
H31 H 0.6645 0.6701 0.2723 0.055 Uiso 1 1 calc R
C32 C 0.66530(15) 0.5932(4) 0.3721(2) 0.0336(10) Uani 1 1 d .
H32 H 0.6620 0.6657 0.3959 0.040 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
I I -0.4742 1.8119 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 Pt1 N1 81.27(13) . .
C1 Pt1 P1 95.29(11) . .
N1 Pt1 P1 175.79(9) . .
C1 Pt1 I1 167.90(11) . .
N1 Pt1 I1 90.96(8) . .
P1 Pt1 I1 92.83(3) . .
C21 P1 C15 100.53(18) . .
C21 P1 C27 107.23(18) . .
C15 P1 C27 102.41(17) . .
C21 P1 Pt1 114.35(12) . .
C15 P1 Pt1 116.68(13) . .
C27 P1 Pt1 114.07(13) . .
C8 N1 C7 109.0(3) . .
C8 N1 C9 109.3(3) . .
C7 N1 C9 107.3(3) . .
C8 N1 Pt1 108.0(2) . .
C7 N1 Pt1 106.6(2) . .
C9 N1 Pt1 116.5(2) . .
C11 O1 C10 118.4(6) . .
C13 O4 C141 102.8(8) . .
C2 C1 C6 116.3(3) . .
C2 C1 Pt1 114.3(3) . .
C6 C1 Pt1 129.0(3) . .
C3 C2 C1 121.8(3) . .
C3 C2 C7 121.7(3) . .
C1 C2 C7 116.4(3) . .
C4 C3 C2 120.5(3) . .
C4 C3 H3 119.8 . .
C2 C3 H3 119.8 . .
C3 C4 C5 119.2(3) . .
C3 C4 H4 120.4 . .
C5 C4 H4 120.4 . .
C4 C5 C6 120.0(3) . .
C4 C5 C10 119.1(3) . .
C6 C5 C10 120.7(3) . .
C5 C6 C1 122.1(3) . .
C5 C6 H6 118.9 . .
C1 C6 H6 118.9 . .
N1 C7 C2 110.0(3) . .
N1 C7 H7A 109.7 . .
C2 C7 H7A 109.7 . .
N1 C7 H7B 109.7 . .
C2 C7 H7B 109.7 . .
H7A C7 H7B 108.2 . .
N1 C8 H8A 109.5 . .
N1 C8 H8B 109.5 . .
H8A C8 H8B 109.5 . .
N1 C8 H8C 109.5 . .
H8A C8 H8C 109.5 . .
H8B C8 H8C 109.5 . .
N1 C9 H9A 109.5 . .
N1 C9 H9B 109.5 . .
H9A C9 H9B 109.5 . .
N1 C9 H9C 109.5 . .
H9A C9 H9C 109.5 . .
H9B C9 H9C 109.5 . .
O1 C10 C5 116.0(3) . .
O1 C10 C5 112.1(2) . 2_655
C5 C10 C5 108.9(4) . 2_655
O1 C10 H10 106.4 . .
C5 C10 H10 106.4 . .
C5 C10 H10 106.4 2_655 .
O2 C11 O1 124.7(8) . .
O2 C11 C12 123.3(9) . .
O1 C11 C12 111.9(8) . .
C11 C12 C13 108.0(8) . .
C11 C12 H12A 110.1 . .
C13 C12 H12A 110.1 . .
C11 C12 H12B 110.1 . .
C13 C12 H12B 110.1 . .
H12A C12 H12B 108.4 . .
O3 C13 O4 127.6(11) . .
O3 C13 C12 125.3(9) . .
O4 C13 C12 107.1(8) . .
O4 C141 C142 101.6(6) . 2_655
O4 C141 H14A 111.4 . .
C142 C141 H14A 111.4 2_655 .
O4 C141 H14B 111.4 . .
C142 C141 H14B 111.4 2_655 .
H14A C141 H14B 109.3 . .
C141 C142 H14C 109.5 2_655 .
C141 C142 H14D 109.5 2_655 .
H14C C142 H14D 109.5 . .
C141 C142 H14E 109.5 2_655 .
H14C C142 H14E 109.5 . .
H14D C142 H14E 109.5 . .
C20 C15 C16 119.2(4) . .
C20 C15 P1 122.3(3) . .
C16 C15 P1 118.5(3) . .
C17 C16 C15 119.9(4) . .
C17 C16 H16 120.1 . .
C15 C16 H16 120.1 . .
C18 C17 C16 120.6(5) . .
C18 C17 H17 119.7 . .
C16 C17 H17 119.7 . .
C17 C18 C19 120.0(5) . .
C17 C18 H18 120.0 . .
C19 C18 H18 120.0 . .
C18 C19 C20 120.3(5) . .
C18 C19 H19 119.8 . .
C20 C19 H19 119.8 . .
C19 C20 C15 119.9(4) . .
C19 C20 H20 120.0 . .
C15 C20 H20 120.0 . .
C26 C21 C22 117.8(4) . .
C26 C21 P1 121.0(3) . .
C22 C21 P1 121.0(3) . .
C23 C22 C21 121.4(4) . .
C23 C22 H22 119.3 . .
C21 C22 H22 119.3 . .
C22 C23 C24 119.7(4) . .
C22 C23 H23 120.2 . .
C24 C23 H23 120.2 . .
C25 C24 C23 119.8(4) . .
C25 C24 H24 120.1 . .
C23 C24 H24 120.1 . .
C24 C25 C26 120.7(4) . .
C24 C25 H25 119.7 . .
C26 C25 H25 119.7 . .
C25 C26 C21 120.6(4) . .
C25 C26 H26 119.7 . .
C21 C26 H26 119.7 . .
C32 C27 C28 119.8(4) . .
C32 C27 P1 117.3(3) . .
C28 C27 P1 122.8(3) . .
C29 C28 C27 119.6(4) . .
C29 C28 H28 120.2 . .
C27 C28 H28 120.2 . .
C30 C29 C28 120.1(4) . .
C30 C29 H29 120.0 . .
C28 C29 H29 120.0 . .
C31 C30 C29 120.6(4) . .
C31 C30 H30 119.7 . .
C29 C30 H30 119.7 . .
C30 C31 C32 120.0(5) . .
C30 C31 H31 120.0 . .
C32 C31 H31 120.0 . .
C27 C32 C31 119.9(4) . .
C27 C32 H32 120.1 . .
C31 C32 H32 120.1 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt1 C1 2.027(4) .
Pt1 N1 2.172(3) .
Pt1 P1 2.2364(10) .
Pt1 I1 2.6874(3) .
P1 C21 1.818(4) .
P1 C15 1.833(4) .
P1 C27 1.837(4) .
N1 C8 1.475(5) .
N1 C7 1.485(5) .
N1 C9 1.485(5) .
O1 C11 1.341(10) .
O1 C10 1.340(6) .
O2 C11 1.181(11) .
O3 C13 1.190(11) .
O4 C13 1.311(11) .
O4 C141 1.346(8) .
C1 C2 1.401(5) .
C1 C6 1.404(5) .
C2 C3 1.392(5) .
C2 C7 1.499(5) .
C3 C4 1.381(5) .
C3 H3 0.9500 .
C4 C5 1.389(5) .
C4 H4 0.9500 .
C5 C6 1.391(5) .
C5 C10 1.512(5) .
C6 H6 0.9500 .
C7 H7A 0.9900 .
C7 H7B 0.9900 .
C8 H8A 0.9800 .
C8 H8B 0.9800 .
C8 H8C 0.9800 .
C9 H9A 0.9800 .
C9 H9B 0.9800 .
C9 H9C 0.9800 .
C10 C5 1.512(5) 2_655
C10 H10 1.0000 .
C11 C12 1.495(12) .
C12 C13 1.539(14) .
C12 H12A 0.9900 .
C12 H12B 0.9900 .
C141 C142 1.598(8) 2_655
C141 H14A 0.9900 .
C141 H14B 0.9900 .
C142 C141 1.598(8) 2_655
C142 H14C 0.9800 .
C142 H14D 0.9800 .
C142 H14E 0.9800 .
C15 C20 1.386(5) .
C15 C16 1.388(5) .
C16 C17 1.378(6) .
C16 H16 0.9500 .
C17 C18 1.366(7) .
C17 H17 0.9500 .
C18 C19 1.368(7) .
C18 H18 0.9500 .
C19 C20 1.382(6) .
C19 H19 0.9500 .
C20 H20 0.9500 .
C21 C26 1.392(5) .
C21 C22 1.401(5) .
C22 C23 1.377(6) .
C22 H22 0.9500 .
C23 C24 1.389(6) .
C23 H23 0.9500 .
C24 C25 1.371(6) .
C24 H24 0.9500 .
C25 C26 1.385(6) .
C25 H25 0.9500 .
C26 H26 0.9500 .
C27 C32 1.384(6) .
C27 C28 1.395(6) .
C28 C29 1.391(6) .
C28 H28 0.9500 .
C29 C30 1.379(7) .
C29 H29 0.9500 .
C30 C31 1.370(7) .
C30 H30 0.9500 .
C31 C32 1.397(6) .
C31 H31 0.9500 .
C32 H32 0.9500 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_4
C1 Pt1 P1 C21 -61.90(17) .
I1 Pt1 P1 C21 127.09(14) .
C1 Pt1 P1 C15 -178.76(17) .
I1 Pt1 P1 C15 10.23(15) .
C1 Pt1 P1 C27 62.04(17) .
I1 Pt1 P1 C27 -108.98(14) .
C1 Pt1 N1 C8 -92.8(3) .
I1 Pt1 N1 C8 77.9(2) .
C1 Pt1 N1 C7 24.2(2) .
I1 Pt1 N1 C7 -165.1(2) .
C1 Pt1 N1 C9 143.9(3) .
I1 Pt1 N1 C9 -45.4(3) .
N1 Pt1 C1 C2 -7.7(3) .
P1 Pt1 C1 C2 169.9(3) .
I1 Pt1 C1 C2 -58.2(6) .
N1 Pt1 C1 C6 164.3(4) .
P1 Pt1 C1 C6 -18.1(3) .
I1 Pt1 C1 C6 113.8(5) .
C6 C1 C2 C3 -2.5(5) .
Pt1 C1 C2 C3 170.6(3) .
C6 C1 C2 C7 175.7(3) .
Pt1 C1 C2 C7 -11.2(4) .
C1 C2 C3 C4 0.7(6) .
C7 C2 C3 C4 -177.4(4) .
C2 C3 C4 C5 1.0(6) .
C3 C4 C5 C6 -0.8(6) .
C3 C4 C5 C10 -175.4(4) .
C4 C5 C6 C1 -1.0(6) .
C10 C5 C6 C1 173.5(4) .
C2 C1 C6 C5 2.6(5) .
Pt1 C1 C6 C5 -169.2(3) .
C8 N1 C7 C2 80.7(4) .
C9 N1 C7 C2 -161.1(3) .
Pt1 N1 C7 C2 -35.6(4) .
C3 C2 C7 N1 -149.2(4) .
C1 C2 C7 N1 32.6(5) .
C11 O1 C10 C5 77.0(7) .
C11 O1 C10 C5 -157.0(6) 2_655
C4 C5 C10 O1 -154.3(4) .
C6 C5 C10 O1 31.1(6) .
C4 C5 C10 C5 78.1(3) 2_655
C6 C5 C10 C5 -96.5(4) 2_655
C10 O1 C11 O2 0.5(15) .
C10 O1 C11 C12 177.0(6) .
O2 C11 C12 C13 66.8(14) .
O1 C11 C12 C13 -109.8(9) .
C141 O4 C13 O3 11.0(13) .
C141 O4 C13 C12 -167.3(7) .
C11 C12 C13 O3 72.4(12) .
C11 C12 C13 O4 -109.2(9) .
C13 O4 C141 C142 -101.9(8) 2_655
C21 P1 C15 C20 137.1(4) .
C27 P1 C15 C20 26.7(4) .
Pt1 P1 C15 C20 -98.7(3) .
C21 P1 C15 C16 -46.0(4) .
C27 P1 C15 C16 -156.5(3) .
Pt1 P1 C15 C16 78.2(4) .
C20 C15 C16 C17 0.6(7) .
P1 C15 C16 C17 -176.4(4) .
C15 C16 C17 C18 -0.3(9) .
C16 C17 C18 C19 -0.3(11) .
C17 C18 C19 C20 0.7(11) .
C18 C19 C20 C15 -0.4(9) .
C16 C15 C20 C19 -0.2(7) .
P1 C15 C20 C19 176.7(4) .
C15 P1 C21 C26 136.5(3) .
C27 P1 C21 C26 -116.9(3) .
Pt1 P1 C21 C26 10.6(4) .
C15 P1 C21 C22 -38.2(4) .
C27 P1 C21 C22 68.4(4) .
Pt1 P1 C21 C22 -164.1(3) .
C26 C21 C22 C23 1.3(6) .
P1 C21 C22 C23 176.1(3) .
C21 C22 C23 C24 -1.7(7) .
C22 C23 C24 C25 0.8(7) .
C23 C24 C25 C26 0.6(7) .
C24 C25 C26 C21 -1.0(7) .
C22 C21 C26 C25 0.1(6) .
P1 C21 C26 C25 -174.7(3) .
C21 P1 C27 C32 166.9(3) .
C15 P1 C27 C32 -87.8(3) .
Pt1 P1 C27 C32 39.2(3) .
C21 P1 C27 C28 -16.3(4) .
C15 P1 C27 C28 89.1(3) .
Pt1 P1 C27 C28 -143.9(3) .
C32 C27 C28 C29 1.3(6) .
P1 C27 C28 C29 -175.4(3) .
C27 C28 C29 C30 -0.6(6) .
C28 C29 C30 C31 -0.1(7) .
C29 C30 C31 C32 0.0(7) .
C28 C27 C32 C31 -1.4(6) .
P1 C27 C32 C31 175.5(3) .
C30 C31 C32 C27 0.7(7) .
