#------------------------------------------------------------------------------
#$Date: 2016-02-16 22:30:59 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176467 $
#$URL: svn://www.crystallography.net/cod/cif/4/06/34/4063445.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4063445
loop_
_publ_author_name
'Gaillard, Sylvain'
'Slawin, Alexandra M. Z.'
'Bonura, Allen T.'
'Stevens, Edwin D.'
'Nolan, Steven P.'
_publ_section_title
;
 Synthetic and Structural Studies of [AuCl3(NHC)] Complexes
;
_journal_issue                   2
_journal_name_full               Organometallics
_journal_page_first              394
_journal_paper_doi               10.1021/om900814e
_journal_volume                  29
_journal_year                    2010
_chemical_formula_sum            'C15.5 H25 Au Cl4 N2'
_chemical_formula_weight         578.14
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 108.4170(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   15.1152(8)
_cell_length_b                   17.8557(10)
_cell_length_c                   15.9701(8)
_cell_measurement_reflns_used    15354
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      28.37
_cell_measurement_theta_min      2.24
_cell_volume                     4089.5(4)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      120(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0422
_diffrn_reflns_av_sigmaI/netI    0.0204
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            63893
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.76
_exptl_absorpt_coefficient_mu    7.716
_exptl_absorpt_correction_T_max  0.1483
_exptl_absorpt_correction_T_min  0.0904
_exptl_absorpt_correction_type   empirical
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.878
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       cube
_exptl_crystal_F_000             2232
_exptl_crystal_size_max          0.60
_exptl_crystal_size_mid          0.45
_exptl_crystal_size_min          0.40
_refine_diff_density_max         3.738
_refine_diff_density_min         -4.094
_refine_diff_density_rms         0.393
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.282
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     406
_refine_ls_number_reflns         7183
_refine_ls_number_restraints     349
_refine_ls_restrained_S_all      1.253
_refine_ls_R_factor_all          0.0755
_refine_ls_R_factor_gt           0.0737
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0000P)²+460.9103P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2110
_refine_ls_wR_factor_ref         0.2114
_reflns_number_gt                6922
_reflns_number_total             7183
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om900814e_si_002.cif
_cod_data_source_block           AuCl3(ICy)
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to the built-in table from CIF Core dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1673 2011-04-08 12:14:43Z adriana 
;
_cod_original_cell_volume        4089.4(4)
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_original_formula_sum        'C15.50 H25 Au Cl4 N2'
_cod_database_code               4063445
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.02999(5) 0.62554(4) 0.77975(5) 0.01142(19) Uani 1 1 d U . .
Cl1 Cl 0.1226(3) 0.7281(2) 0.7788(4) 0.0220(10) Uani 1 1 d U . .
C1 C -0.1293(13) 0.5951(10) 0.8822(12) 0.015(3) Uani 1 1 d U . .
H1 H -0.1104 0.6427 0.8595 0.019 Uiso 1 1 calc R . .
N1 N -0.1110(11) 0.5327(8) 0.8282(10) 0.014(2) Uani 1 1 d U . .
C2 C -0.2352(14) 0.5999(11) 0.8677(14) 0.021(3) Uani 1 1 d U . .
H2A H -0.2690 0.6100 0.8047 0.025 Uiso 1 1 calc R . .
H2B H -0.2578 0.5517 0.8840 0.025 Uiso 1 1 calc R . .
Cl2 Cl 0.1449(3) 0.5699(3) 0.8908(3) 0.0222(10) Uani 1 1 d U . .
N2 N -0.0480(10) 0.4691(8) 0.7460(10) 0.012(2) Uani 1 1 d U . .
Cl3 Cl -0.0900(4) 0.6762(3) 0.6700(4) 0.0331(13) Uani 1 1 d U . .
C3 C -0.2532(14) 0.6627(12) 0.9247(14) 0.023(3) Uani 1 1 d U . .
H3A H -0.3203 0.6631 0.9194 0.028 Uiso 1 1 calc R . .
H3B H -0.2384 0.7113 0.9023 0.028 Uiso 1 1 calc R . .
C4 C -0.1952(14) 0.6547(12) 1.0229(14) 0.023(3) Uani 1 1 d U . .
H4A H -0.2075 0.6981 1.0562 0.028 Uiso 1 1 calc R . .
H4B H -0.2146 0.6088 1.0472 0.028 Uiso 1 1 calc R . .
C5 C -0.0914(14) 0.6506(11) 1.0351(13) 0.020(3) Uani 1 1 d U . .
H5A H -0.0565 0.6408 1.0979 0.024 Uiso 1 1 calc R . .
H5B H -0.0699 0.6991 1.0185 0.024 Uiso 1 1 calc R . .
C6 C -0.0719(13) 0.5879(10) 0.9775(12) 0.016(3) Uani 1 1 d U . .
H6A H -0.0050 0.5888 0.9824 0.019 Uiso 1 1 calc R . .
H6B H -0.0853 0.5390 1.0001 0.019 Uiso 1 1 calc R . .
C7 C -0.0512(12) 0.5383(10) 0.7807(12) 0.012(2) Uani 1 1 d U . .
C8 C -0.1432(13) 0.4615(10) 0.8231(13) 0.015(3) Uani 1 1 d U . .
H8 H -0.1854 0.4434 0.8517 0.017 Uiso 1 1 calc R . .
C9 C -0.1077(12) 0.4213(10) 0.7727(12) 0.014(3) Uani 1 1 d U . .
H9 H -0.1199 0.3700 0.7575 0.017 Uiso 1 1 calc R . .
C10 C 0.0074(13) 0.4475(11) 0.6884(13) 0.017(3) Uani 1 1 d U . .
H10 H 0.0408 0.4932 0.6782 0.021 Uiso 1 1 calc R . .
C11 C -0.0563(14) 0.4208(12) 0.5990(13) 0.023(3) Uani 1 1 d U . .
H11A H -0.0994 0.4615 0.5696 0.027 Uiso 1 1 calc R . .
H11B H -0.0940 0.3777 0.6072 0.027 Uiso 1 1 calc R . .
C12 C 0.0033(15) 0.3975(12) 0.5418(14) 0.024(3) Uani 1 1 d U . .
H12A H -0.0378 0.3770 0.4853 0.028 Uiso 1 1 calc R . .
H12B H 0.0350 0.4423 0.5283 0.028 Uiso 1 1 calc R . .
C13 C 0.0752(15) 0.3399(12) 0.5859(14) 0.026(4) Uani 1 1 d U . .
H13A H 0.0434 0.2932 0.5936 0.032 Uiso 1 1 calc R . .
H13B H 0.1135 0.3286 0.5474 0.032 Uiso 1 1 calc R . .
C14 C 0.1359(15) 0.3651(13) 0.6717(15) 0.029(4) Uani 1 1 d U . .
H14A H 0.1740 0.4077 0.6630 0.034 Uiso 1 1 calc R . .
H14B H 0.1789 0.3240 0.6999 0.034 Uiso 1 1 calc R . .
C15 C 0.0805(14) 0.3900(12) 0.7347(14) 0.023(3) Uani 1 1 d U . .
H15A H 0.0499 0.3460 0.7514 0.028 Uiso 1 1 calc R . .
H15B H 0.1239 0.4119 0.7893 0.028 Uiso 1 1 calc R . .
Cl21 Cl 0.5687(4) 0.3987(3) 0.8689(4) 0.0339(13) Uani 1 1 d U . .
Au21 Au 0.52995(5) 0.32690(4) 0.74109(5) 0.0153(2) Uani 1 1 d U . .
C21 C 0.4087(12) 0.3650(9) 0.5211(11) 0.010(3) Uani 1 1 d U . .
H21 H 0.4393 0.4023 0.5680 0.012 Uiso 1 1 calc R . .
N21 N 0.4546(11) 0.2875(9) 0.5512(10) 0.017(3) Uani 1 1 d U . .
Cl22 Cl 0.6624(4) 0.3609(3) 0.7131(4) 0.0348(13) Uani 1 1 d U . .
N22 N 0.5257(11) 0.1932(9) 0.6282(11) 0.017(3) Uani 1 1 d U . .
C22 C 0.4301(15) 0.3874(12) 0.4378(14) 0.023(3) Uani 1 1 d U . .
H22A H 0.4041 0.3501 0.3904 0.028 Uiso 1 1 calc R . .
H22B H 0.4983 0.3906 0.4493 0.028 Uiso 1 1 calc R . .
Cl23 Cl 0.3929(3) 0.2876(3) 0.7588(3) 0.0272(11) Uani 1 1 d U . .
C23 C 0.3839(15) 0.4652(12) 0.4104(16) 0.029(4) Uani 1 1 d U . .
H23A H 0.4150 0.5027 0.4558 0.035 Uiso 1 1 calc R . .
H23B H 0.3925 0.4808 0.3539 0.035 Uiso 1 1 calc R . .
C24 C 0.2801(15) 0.4634(12) 0.3996(14) 0.026(4) Uani 1 1 d U . .
H24A H 0.2530 0.5138 0.3833 0.032 Uiso 1 1 calc R . .
H24B H 0.2480 0.4282 0.3518 0.032 Uiso 1 1 calc R . .
C25 C 0.2660(14) 0.4387(11) 0.4853(13) 0.021(3) Uani 1 1 d U . .
H25A H 0.1984 0.4361 0.4775 0.025 Uiso 1 1 calc R . .
H25B H 0.2943 0.4760 0.5320 0.025 Uiso 1 1 calc R . .
C26 C 0.3105(13) 0.3617(10) 0.5140(12) 0.014(3) Uani 1 1 d U . .
H26A H 0.3038 0.3477 0.5717 0.016 Uiso 1 1 calc R . .
H26B H 0.2787 0.3233 0.4702 0.016 Uiso 1 1 calc R . .
C27 C 0.5015(12) 0.2659(10) 0.6319(12) 0.013(2) Uani 1 1 d U . .
C28 C 0.4492(14) 0.2286(11) 0.4915(13) 0.018(3) Uani 1 1 d U . .
H28 H 0.4206 0.2295 0.4293 0.022 Uiso 1 1 calc R . .
C29 C 0.4929(15) 0.1710(11) 0.5411(13) 0.023(3) Uani 1 1 d U . .
H29 H 0.5002 0.1225 0.5197 0.028 Uiso 1 1 calc R . .
C30 C 0.5761(12) 0.1470(10) 0.7030(13) 0.017(3) Uani 1 1 d U . .
H30 H 0.5972 0.1798 0.7564 0.020 Uiso 1 1 calc R . .
C31 C 0.6631(13) 0.1134(12) 0.6870(15) 0.024(3) Uani 1 1 d U . .
H31A H 0.7052 0.1544 0.6817 0.029 Uiso 1 1 calc R . .
H31B H 0.6441 0.0851 0.6308 0.029 Uiso 1 1 calc R . .
C32 C 0.7158(15) 0.0606(12) 0.7632(15) 0.026(4) Uani 1 1 d U . .
H32A H 0.7692 0.0372 0.7498 0.031 Uiso 1 1 calc R . .
H32B H 0.7404 0.0896 0.8186 0.031 Uiso 1 1 calc R . .
C33 C 0.6495(14) 0.0005(11) 0.7743(14) 0.022(3) Uani 1 1 d U . .
H33A H 0.6827 -0.0329 0.8237 0.027 Uiso 1 1 calc R . .
H33B H 0.6282 -0.0301 0.7199 0.027 Uiso 1 1 calc R . .
C34 C 0.5646(14) 0.0351(12) 0.7929(14) 0.023(3) Uani 1 1 d U . .
H34A H 0.5223 -0.0054 0.7992 0.028 Uiso 1 1 calc R . .
H34B H 0.5856 0.0631 0.8493 0.028 Uiso 1 1 calc R . .
C35 C 0.5124(13) 0.0872(11) 0.7198(13) 0.017(3) Uani 1 1 d U . .
H35A H 0.4610 0.1114 0.7358 0.021 Uiso 1 1 calc R . .
H35B H 0.4846 0.0579 0.6651 0.021 Uiso 1 1 calc R . .
Cl41 Cl 0.8281(8) 0.2386(6) 0.4276(8) 0.090(3) Uani 1 1 d U . .
C41 C 0.7505(18) 0.2323(15) 0.4874(19) 0.043(5) Uani 1 1 d U . .
H41A H 0.7855 0.2237 0.5504 0.052 Uiso 1 1 calc R . .
H41B H 0.7084 0.1891 0.4660 0.052 Uiso 1 1 calc R . .
Cl42 Cl 0.6840(8) 0.3147(6) 0.4767(9) 0.101(4) Uani 1 1 d U . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C7 Au1 Cl3 88.5(5) . . ?
C7 Au1 Cl2 88.5(5) . . ?
Cl3 Au1 Cl2 176.87(18) . . ?
C7 Au1 Cl1 179.1(5) . . ?
Cl3 Au1 Cl1 91.01(18) . . ?
Cl2 Au1 Cl1 92.07(17) . . ?
N1 C1 C6 111.7(15) . . ?
N1 C1 C2 109.1(15) . . ?
C6 C1 C2 113.3(16) . . ?
C7 N1 C8 109.1(15) . . ?
C7 N1 C1 123.2(15) . . ?
C8 N1 C1 127.5(16) . . ?
C3 C2 C1 108.9(16) . . ?
C7 N2 C9 108.6(15) . . ?
C7 N2 C10 126.2(15) . . ?
C9 N2 C10 125.2(15) . . ?
C2 C3 C4 112.8(17) . . ?
C5 C4 C3 111.6(17) . . ?
C4 C5 C6 110.1(16) . . ?
C1 C6 C5 112.8(15) . . ?
N1 C7 N2 106.1(15) . . ?
N1 C7 Au1 125.9(13) . . ?
N2 C7 Au1 127.3(13) . . ?
C9 C8 N1 109.9(16) . . ?
C8 C9 N2 106.3(16) . . ?
N2 C10 C15 110.0(16) . . ?
N2 C10 C11 110.5(15) . . ?
C15 C10 C11 113.0(17) . . ?
C10 C11 C12 109.2(17) . . ?
C13 C12 C11 112.5(18) . . ?
C14 C13 C12 112.1(18) . . ?
C13 C14 C15 112.8(18) . . ?
C10 C15 C14 109.5(17) . . ?
C27 Au21 Cl22 86.2(5) . . ?
C27 Au21 Cl23 89.2(5) . . ?
Cl22 Au21 Cl23 175.4(2) . . ?
C27 Au21 Cl21 178.0(5) . . ?
Cl22 Au21 Cl21 91.9(2) . . ?
Cl23 Au21 Cl21 92.7(2) . . ?
C26 C21 C22 116.0(15) . . ?
C26 C21 N21 109.4(14) . . ?
C22 C21 N21 107.8(14) . . ?
C27 N21 C28 110.0(16) . . ?
C27 N21 C21 127.8(15) . . ?
C28 N21 C21 122.2(15) . . ?
C27 N22 C29 107.7(16) . . ?
C27 N22 C30 125.9(16) . . ?
C29 N22 C30 126.4(16) . . ?
C21 C22 C23 106.2(17) . . ?
C24 C23 C22 111.6(18) . . ?
C25 C24 C23 109.8(17) . . ?
C24 C25 C26 110.9(16) . . ?
C21 C26 C25 109.0(15) . . ?
N21 C27 N22 107.9(16) . . ?
N21 C27 Au21 126.8(14) . . ?
N22 C27 Au21 125.3(13) . . ?
C29 C28 N21 105.2(17) . . ?
C28 C29 N22 109.1(18) . . ?
N22 C30 C35 110.4(15) . . ?
N22 C30 C31 109.8(16) . . ?
C35 C30 C31 112.2(16) . . ?
C30 C31 C32 111.2(17) . . ?
C33 C32 C31 109.1(17) . . ?
C32 C33 C34 111.3(17) . . ?
C35 C34 C33 111.3(17) . . ?
C34 C35 C30 111.4(16) . . ?
Cl41 C41 Cl42 110.9(16) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 C7 1.986(18) . ?
Au1 Cl3 2.274(5) . ?
Au1 Cl2 2.281(5) . ?
Au1 Cl1 2.307(5) . ?
C1 N1 1.49(2) . ?
C1 C6 1.50(3) . ?
C1 C2 1.55(3) . ?
N1 C7 1.35(2) . ?
N1 C8 1.35(2) . ?
C2 C3 1.52(3) . ?
N2 C7 1.36(2) . ?
N2 C9 1.40(2) . ?
N2 C10 1.48(2) . ?
C3 C4 1.54(3) . ?
C4 C5 1.52(3) . ?
C5 C6 1.54(3) . ?
C8 C9 1.31(3) . ?
C10 C15 1.52(3) . ?
C10 C11 1.52(3) . ?
C11 C12 1.53(3) . ?
C12 C13 1.50(3) . ?
C13 C14 1.46(3) . ?
C14 C15 1.56(3) . ?
Cl21 Au21 2.323(5) . ?
Au21 C27 1.984(18) . ?
Au21 Cl22 2.267(6) . ?
Au21 Cl23 2.288(5) . ?
C21 C26 1.45(2) . ?
C21 C22 1.52(2) . ?
C21 N21 1.55(2) . ?
N21 C27 1.32(2) . ?
N21 C28 1.40(2) . ?
N22 C27 1.35(2) . ?
N22 C29 1.38(3) . ?
N22 C30 1.45(2) . ?
C22 C23 1.56(3) . ?
C23 C24 1.52(3) . ?
C24 C25 1.52(3) . ?
C25 C26 1.54(2) . ?
C28 C29 1.34(3) . ?
C30 C35 1.52(3) . ?
C30 C31 1.54(3) . ?
C31 C32 1.55(3) . ?
C32 C33 1.52(3) . ?
C33 C34 1.54(3) . ?
C34 C35 1.51(3) . ?
Cl41 C41 1.74(3) . ?
C41 Cl42 1.76(3) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C6 C1 N1 C7 -97(2) . . . . ?
C2 C1 N1 C7 136.6(18) . . . . ?
C6 C1 N1 C8 77(2) . . . . ?
C2 C1 N1 C8 -49(2) . . . . ?
N1 C1 C2 C3 178.7(16) . . . . ?
C6 C1 C2 C3 54(2) . . . . ?
C1 C2 C3 C4 -54(2) . . . . ?
C2 C3 C4 C5 56(2) . . . . ?
C3 C4 C5 C6 -54(2) . . . . ?
N1 C1 C6 C5 -178.5(15) . . . . ?
C2 C1 C6 C5 -55(2) . . . . ?
C4 C5 C6 C1 54(2) . . . . ?
C8 N1 C7 N2 0(2) . . . . ?
C1 N1 C7 N2 175.7(16) . . . . ?
C8 N1 C7 Au1 -170.5(13) . . . . ?
C1 N1 C7 Au1 5(3) . . . . ?
C9 N2 C7 N1 0(2) . . . . ?
C10 N2 C7 N1 179.5(16) . . . . ?
C9 N2 C7 Au1 171.1(13) . . . . ?
C10 N2 C7 Au1 -10(3) . . . . ?
Cl3 Au1 C7 N1 -87.6(16) . . . . ?
Cl2 Au1 C7 N1 91.9(16) . . . . ?
Cl1 Au1 C7 N1 -36(39) . . . . ?
Cl3 Au1 C7 N2 103.5(16) . . . . ?
Cl2 Au1 C7 N2 -77.0(16) . . . . ?
Cl1 Au1 C7 N2 155(36) . . . . ?
C7 N1 C8 C9 -1(2) . . . . ?
C1 N1 C8 C9 -176.2(17) . . . . ?
N1 C8 C9 N2 1(2) . . . . ?
C7 N2 C9 C8 -1(2) . . . . ?
C10 N2 C9 C8 179.9(17) . . . . ?
C7 N2 C10 C15 116(2) . . . . ?
C9 N2 C10 C15 -66(2) . . . . ?
C7 N2 C10 C11 -119(2) . . . . ?
C9 N2 C10 C11 60(2) . . . . ?
N2 C10 C11 C12 -178.9(16) . . . . ?
C15 C10 C11 C12 -55(2) . . . . ?
C10 C11 C12 C13 55(2) . . . . ?
C11 C12 C13 C14 -56(3) . . . . ?
C12 C13 C14 C15 55(3) . . . . ?
N2 C10 C15 C14 177.6(16) . . . . ?
C11 C10 C15 C14 54(2) . . . . ?
C13 C14 C15 C10 -53(3) . . . . ?
C26 C21 N21 C27 -96(2) . . . . ?
C22 C21 N21 C27 136.8(19) . . . . ?
C26 C21 N21 C28 83(2) . . . . ?
C22 C21 N21 C28 -44(2) . . . . ?
C26 C21 C22 C23 57(2) . . . . ?
N21 C21 C22 C23 -179.6(16) . . . . ?
C21 C22 C23 C24 -55(2) . . . . ?
C22 C23 C24 C25 58(3) . . . . ?
C23 C24 C25 C26 -57(2) . . . . ?
C22 C21 C26 C25 -58(2) . . . . ?
N21 C21 C26 C25 179.4(14) . . . . ?
C24 C25 C26 C21 56(2) . . . . ?
C28 N21 C27 N22 -1(2) . . . . ?
C21 N21 C27 N22 177.6(16) . . . . ?
C28 N21 C27 Au21 179.9(13) . . . . ?
C21 N21 C27 Au21 -1(3) . . . . ?
C29 N22 C27 N21 1(2) . . . . ?
C30 N22 C27 N21 -178.3(16) . . . . ?
C29 N22 C27 Au21 179.6(14) . . . . ?
C30 N22 C27 Au21 0(3) . . . . ?
Cl22 Au21 C27 N21 -90.3(16) . . . . ?
Cl23 Au21 C27 N21 89.3(16) . . . . ?
Cl21 Au21 C27 N21 -107(15) . . . . ?
Cl22 Au21 C27 N22 91.3(16) . . . . ?
Cl23 Au21 C27 N22 -89.1(16) . . . . ?
Cl21 Au21 C27 N22 75(15) . . . . ?
C27 N21 C28 C29 1(2) . . . . ?
C21 N21 C28 C29 -177.7(16) . . . . ?
N21 C28 C29 N22 -1(2) . . . . ?
C27 N22 C29 C28 0(2) . . . . ?
C30 N22 C29 C28 179.2(18) . . . . ?
C27 N22 C30 C35 111(2) . . . . ?
C29 N22 C30 C35 -68(2) . . . . ?
C27 N22 C30 C31 -125(2) . . . . ?
C29 N22 C30 C31 56(2) . . . . ?
N22 C30 C31 C32 -177.1(17) . . . . ?
C35 C30 C31 C32 -54(2) . . . . ?
C30 C31 C32 C33 56(2) . . . . ?
C31 C32 C33 C34 -58(2) . . . . ?
C32 C33 C34 C35 58(2) . . . . ?
C33 C34 C35 C30 -55(2) . . . . ?
N22 C30 C35 C34 176.0(16) . . . . ?
C31 C30 C35 C34 53(2) . . . . ?
