#------------------------------------------------------------------------------
#$Date: 2016-03-21 06:50:10 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178536 $
#$URL: svn://www.crystallography.net/cod/cif/4/06/42/4064289.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4064289
loop_
_publ_author_name
'Chakraborty, Tapash'
'Sharma, Sagar'
'Singh, Harkesh B.'
'Butcher, Ray J.'
_publ_section_title
;
 Reactions of Di-o-tolyl Telluride and Selenide with Palladium Acetate:
 Isolation of a Novel Palladium Complex of a Tellurenic Acid Anhydride and
 Related Trinuclear and Tetranuclear Palladium Complexes
;
_journal_issue                   9
_journal_name_full               Organometallics
_journal_page_first              2525
_journal_paper_doi               10.1021/om2000184
_journal_volume                  30
_journal_year                    2011
_chemical_formula_moiety         'C36 H40 O8 Pd4 Se4'
_chemical_formula_sum            'C36 H40 O8 Pd4 Se4'
_chemical_formula_weight         1342.12
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 104.214(7)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   18.1021(12)
_cell_length_b                   13.1486(9)
_cell_length_c                   18.6113(12)
_cell_measurement_reflns_used    3933
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      77.2694
_cell_measurement_theta_min      4.5402
_cell_volume                     4294.2(5)
_computing_cell_refinement
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.52 (release 06-11-2009 CrysAlis171 .NET)
(compiled Nov  6 2009,16:24:50)
;
_computing_data_collection
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.52 (release 06-11-2009 CrysAlis171 .NET)
(compiled Nov  6 2009,16:24:50)
;
_computing_data_reduction
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.52 (release 06-11-2009 CrysAlis171 .NET)
(compiled Nov  6 2009,16:24:50)
;
_computing_molecular_graphics    'Shelxtl (Bruker, 1998)'
_computing_publication_material  Shelxtl
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 10.5081
_diffrn_measured_fraction_theta_full 0.978
_diffrn_measured_fraction_theta_max 0.957
_diffrn_measurement_device_type  'Xcalibur, Ruby, Gemini'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_reflns_av_R_equivalents  0.0999
_diffrn_reflns_av_sigmaI/netI    0.0842
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            8812
_diffrn_reflns_theta_full        67.50
_diffrn_reflns_theta_max         77.55
_diffrn_reflns_theta_min         4.54
_exptl_absorpt_coefficient_mu    17.558
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.06088
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.52 (release 06-11-2009 CrysAlis171 .NET)
(compiled Nov  6 2009,16:24:50)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            red-brown
_exptl_crystal_density_diffrn    2.076
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       'irregular needle'
_exptl_crystal_F_000             2560
_exptl_crystal_size_max          0.41
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.17
_refine_diff_density_max         2.313
_refine_diff_density_min         -1.205
_refine_diff_density_rms         0.315
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.356
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     226
_refine_ls_number_reflns         4370
_refine_ls_number_restraints     15
_refine_ls_restrained_S_all      1.354
_refine_ls_R_factor_all          0.1281
_refine_ls_R_factor_gt           0.0975
_refine_ls_shift/su_max          0.023
_refine_ls_shift/su_mean         0.002
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1113P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2267
_refine_ls_wR_factor_ref         0.2501
_reflns_number_gt                2925
_reflns_number_total             4370
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om2000184_si_002.cif
_cod_data_source_block           6
_cod_database_code               4064289
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pd1 Pd 0.82729(5) 0.34684(7) 0.44779(5) 0.0618(2) Uani 1 1 d . A .
Pd2 Pd 0.86213(5) 0.21450(8) 0.57594(5) 0.0655(2) Uani 1 1 d . . .
Se1 Se 0.73541(7) 0.25046(10) 0.36150(7) 0.0607(3) Uani 1 1 d . . .
Se2 Se 0.71699(8) 0.42612(10) 0.47138(7) 0.0688(3) Uani 1 1 d . . .
O11 O 0.9168(5) 0.2656(10) 0.4236(5) 0.087(3) Uani 1 1 d . . .
O12 O 0.9456(6) 0.1679(11) 0.5227(7) 0.107(4) Uani 1 1 d . . .
O21 O 0.9033(7) 0.4406(9) 0.5203(6) 0.093(3) Uani 1 1 d . . .
O22 O 0.9260(7) 0.3404(10) 0.6211(6) 0.107(4) Uani 1 1 d . . .
C11 C 0.9559(7) 0.2016(13) 0.4625(9) 0.080(4) Uani 1 1 d . A .
C12 C 1.0212(8) 0.1524(16) 0.4366(9) 0.101(6) Uani 1 1 d . . .
H12A H 1.0420 0.2006 0.4081 0.151 Uiso 1 1 calc R A .
H12B H 1.0025 0.0942 0.4064 0.151 Uiso 1 1 calc R . .
H12C H 1.0602 0.1314 0.4789 0.151 Uiso 1 1 calc R . .
C21 C 0.9363(9) 0.4186(13) 0.5872(8) 0.084(4) Uani 1 1 d . A .
C22 C 0.9892(16) 0.5012(19) 0.6285(14) 0.164(11) Uani 1 1 d . . .
H22A H 1.0267 0.4711 0.6684 0.246 Uiso 1 1 calc R A .
H22B H 0.9600 0.5502 0.6481 0.246 Uiso 1 1 calc R . .
H22C H 1.0142 0.5343 0.5950 0.246 Uiso 1 1 calc R . .
C1A C 0.6869(5) 0.5300(6) 0.3958(4) 0.079(4) Uani 1 1 d G A .
C2A C 0.6253(5) 0.5141(7) 0.3355(5) 0.084(4) Uani 1 1 d G . .
H2AA H 0.5981 0.4535 0.3314 0.101 Uiso 1 1 calc R A .
C3A C 0.6043(6) 0.5887(10) 0.2815(5) 0.109(6) Uani 1 1 d G A .
H3AA H 0.5631 0.5781 0.2411 0.131 Uiso 1 1 calc R . .
C4A C 0.6450(9) 0.6793(9) 0.2877(7) 0.157(10) Uani 1 1 d G . .
H4AA H 0.6310 0.7292 0.2515 0.188 Uiso 1 1 calc R A .
C5A C 0.7066(9) 0.6952(7) 0.3479(8) 0.125(7) Uani 1 1 d G A .
H5AA H 0.7339 0.7558 0.3521 0.150 Uiso 1 1 calc R . .
C6A C 0.7276(6) 0.6206(7) 0.4020(6) 0.102(5) Uani 1 1 d G . .
C7A C 0.7995(13) 0.6392(14) 0.4598(15) 0.129(9) Uani 1 1 d . A .
H7AA H 0.8200 0.7042 0.4514 0.194 Uiso 1 1 calc R . .
H7AB H 0.8358 0.5869 0.4572 0.194 Uiso 1 1 calc R . .
H7AC H 0.7890 0.6384 0.5079 0.194 Uiso 1 1 calc R . .
C1BA C 0.7139(9) 0.3387(11) 0.2773(7) 0.055(3) Uani 0.526(12) 1 d PGD A 1
C2BA C 0.7674(8) 0.4115(13) 0.2703(8) 0.064(4) Uani 0.526(12) 1 d PGD A 1
H2BA H 0.8119 0.4191 0.3075 0.077 Uiso 0.526(12) 1 calc PR A 1
C3BA C 0.7543(11) 0.4731(14) 0.2077(9) 0.086(6) Uani 0.526(12) 1 d PGD A 1
H3BA H 0.7901 0.5218 0.2031 0.103 Uiso 0.526(12) 1 calc PR A 1
C4BA C 0.6878(12) 0.4617(14) 0.1521(8) 0.094(8) Uani 0.526(12) 1 d PGD A 1
H4BA H 0.6790 0.5029 0.1102 0.113 Uiso 0.526(12) 1 calc PR A 1
C5BA C 0.6343(9) 0.3889(15) 0.1590(8) 0.089(7) Uani 0.526(12) 1 d PGD A 1
H5BA H 0.5898 0.3813 0.1218 0.107 Uiso 0.526(12) 1 calc PR A 1
C6BA C 0.6474(9) 0.3273(13) 0.2216(8) 0.080(6) Uani 0.526(12) 1 d PGD A 1
C7BA C 0.5911(14) 0.245(2) 0.2228(16) 0.095(7) Uani 0.526(12) 1 d PD A 1
H7BA H 0.5459 0.2559 0.1840 0.142 Uiso 0.526(12) 1 calc PR A 1
H7BB H 0.5782 0.2445 0.2699 0.142 Uiso 0.526(12) 1 calc PR A 1
H7BC H 0.6129 0.1801 0.2153 0.142 Uiso 0.526(12) 1 calc PR A 1
C1BB C 0.6979(10) 0.3264(14) 0.2695(7) 0.055(3) Uani 0.474(12) 1 d PGD A 2
C2BB C 0.6276(10) 0.2939(15) 0.2271(9) 0.064(4) Uani 0.474(12) 1 d PGD A 2
H2BB H 0.6013 0.2427 0.2447 0.077 Uiso 0.474(12) 1 calc PR A 2
C3BB C 0.5967(10) 0.3378(18) 0.1584(9) 0.086(6) Uani 0.474(12) 1 d PGD A 2
H3BB H 0.5497 0.3160 0.1300 0.103 Uiso 0.474(12) 1 calc PR A 2
C4BB C 0.6361(13) 0.4143(17) 0.1320(8) 0.094(8) Uani 0.474(12) 1 d PGD A 2
H4BB H 0.6155 0.4436 0.0860 0.113 Uiso 0.474(12) 1 calc PR A 2
C5BB C 0.7064(13) 0.4468(16) 0.1744(10) 0.089(7) Uani 0.474(12) 1 d PGD A 2
H5BB H 0.7328 0.4979 0.1567 0.107 Uiso 0.474(12) 1 calc PR A 2
C6BB C 0.7373(10) 0.4029(16) 0.2431(9) 0.080(6) Uani 0.474(12) 1 d PGD A 2
C7BB C 0.8143(15) 0.442(3) 0.2817(17) 0.095(7) Uani 0.474(12) 1 d PD A 2
H7BD H 0.8296 0.4938 0.2518 0.142 Uiso 0.474(12) 1 calc PR A 2
H7BE H 0.8505 0.3874 0.2894 0.142 Uiso 0.474(12) 1 calc PR A 2
H7BF H 0.8123 0.4707 0.3287 0.142 Uiso 0.474(12) 1 calc PR A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd 0.1215 3.9337 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Se Se -0.7943 1.1372 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O21 Pd1 O11 91.1(5) . .
O21 Pd1 Se1 175.8(3) . .
O11 Pd1 Se1 91.9(3) . .
O21 Pd1 Se2 94.1(4) . .
O11 Pd1 Se2 174.5(3) . .
Se1 Pd1 Se2 83.04(5) . .
O21 Pd1 Pd2 81.2(3) . .
O11 Pd1 Pd2 81.2(3) . .
Se1 Pd1 Pd2 102.19(5) . .
Se2 Pd1 Pd2 97.69(5) . .
O22 Pd2 O12 91.8(6) . .
O22 Pd2 Se2 176.2(4) . 7_656
O12 Pd2 Se2 92.1(4) . 7_656
O22 Pd2 Se1 93.1(4) . 7_656
O12 Pd2 Se1 174.1(4) . 7_656
Se2 Pd2 Se1 83.11(5) 7_656 7_656
O22 Pd2 Pd1 80.9(3) . .
O12 Pd2 Pd1 79.8(3) . .
Se2 Pd2 Pd1 99.97(5) 7_656 .
Se1 Pd2 Pd1 104.38(5) 7_656 .
C1BA Se1 C1BB 9.8(8) . .
C1BA Se1 Pd1 101.5(5) . .
C1BB Se1 Pd1 110.8(5) . .
C1BA Se1 Pd2 104.9(5) . 7_656
C1BB Se1 Pd2 100.9(6) . 7_656
Pd1 Se1 Pd2 92.66(5) . 7_656
C1A Se2 Pd2 104.1(3) . 7_656
C1A Se2 Pd1 105.8(3) . .
Pd2 Se2 Pd1 92.72(6) 7_656 .
C11 O11 Pd1 126.6(9) . .
C11 O12 Pd2 126.9(10) . .
C21 O21 Pd1 125.1(10) . .
C21 O22 Pd2 126.3(10) . .
O11 C11 O12 125.4(13) . .
O11 C11 C12 119.2(14) . .
O12 C11 C12 115.3(14) . .
C11 C12 H12A 109.5 . .
C11 C12 H12B 109.5 . .
H12A C12 H12B 109.5 . .
C11 C12 H12C 109.5 . .
H12A C12 H12C 109.5 . .
H12B C12 H12C 109.5 . .
O22 C21 O21 126.2(14) . .
O22 C21 C22 119.1(15) . .
O21 C21 C22 114.6(15) . .
C21 C22 H22A 109.5 . .
C21 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
C21 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
C2A C1A C6A 120.0 . .
C2A C1A Se2 120.4(5) . .
C6A C1A Se2 119.6(5) . .
C1A C2A C3A 120.0 . .
C1A C2A H2AA 120.0 . .
C3A C2A H2AA 120.0 . .
C4A C3A C2A 120.0 . .
C4A C3A H3AA 120.0 . .
C2A C3A H3AA 120.0 . .
C3A C4A C5A 120.0 . .
C3A C4A H4AA 120.0 . .
C5A C4A H4AA 120.0 . .
C4A C5A C6A 120.0 . .
C4A C5A H5AA 120.0 . .
C6A C5A H5AA 120.0 . .
C5A C6A C1A 120.0 . .
C5A C6A C7A 116.2(10) . .
C1A C6A C7A 123.5(10) . .
C6A C7A H7AA 109.5 . .
C6A C7A H7AB 109.5 . .
H7AA C7A H7AB 109.5 . .
C6A C7A H7AC 109.5 . .
H7AA C7A H7AC 109.5 . .
H7AB C7A H7AC 109.5 . .
C2BA C1BA C6BA 120.0 . .
C2BA C1BA Se1 119.2(8) . .
C6BA C1BA Se1 120.7(8) . .
C3BA C2BA C1BA 120.0 . .
C3BA C2BA H2BA 120.0 . .
C1BA C2BA H2BA 120.0 . .
C2BA C3BA C4BA 120.0 . .
C2BA C3BA H3BA 120.0 . .
C4BA C3BA H3BA 120.0 . .
C5BA C4BA C3BA 120.0 . .
C5BA C4BA H4BA 120.0 . .
C3BA C4BA H4BA 120.0 . .
C4BA C5BA C6BA 120.0 . .
C4BA C5BA H5BA 120.0 . .
C6BA C5BA H5BA 120.0 . .
C5BA C6BA C1BA 120.0 . .
C5BA C6BA C7BA 117.4(12) . .
C1BA C6BA C7BA 122.4(12) . .
C2BB C1BB C6BB 120.0 . .
C2BB C1BB Se1 114.4(9) . .
C6BB C1BB Se1 125.5(9) . .
C3BB C2BB C1BB 120.0 . .
C3BB C2BB H2BB 120.0 . .
C1BB C2BB H2BB 120.0 . .
C2BB C3BB C4BB 120.0 . .
C2BB C3BB H3BB 120.0 . .
C4BB C3BB H3BB 120.0 . .
C5BB C4BB C3BB 120.0 . .
C5BB C4BB H4BB 120.0 . .
C3BB C4BB H4BB 120.0 . .
C4BB C5BB C6BB 120.0 . .
C4BB C5BB H5BB 120.0 . .
C6BB C5BB H5BB 120.0 . .
C5BB C6BB C1BB 120.0 . .
C5BB C6BB C7BB 114.5(15) . .
C1BB C6BB C7BB 125.4(15) . .
C6BB C7BB H7BD 109.5 . .
C6BB C7BB H7BE 109.5 . .
H7BD C7BB H7BE 109.5 . .
C6BB C7BB H7BF 109.5 . .
H7BD C7BB H7BF 109.5 . .
H7BE C7BB H7BF 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pd1 O21 2.079(11) .
Pd1 O11 2.080(10) .
Pd1 Se1 2.3748(16) .
Pd1 Se2 2.3868(17) .
Pd1 Pd2 2.8939(12) .
Pd2 O22 2.075(11) .
Pd2 O12 2.092(11) .
Pd2 Se2 2.3720(17) 7_656
Pd2 Se1 2.3864(15) 7_656
Se1 C1BA 1.912(11) .
Se1 C1BB 1.954(12) .
Se1 Pd2 2.3864(15) 7_656
Se2 C1A 1.941(7) .
Se2 Pd2 2.3719(17) 7_656
O11 C11 1.218(18) .
O12 C11 1.26(2) .
O21 C21 1.275(17) .
O22 C21 1.245(18) .
C11 C12 1.526(18) .
C12 H12A 0.9600 .
C12 H12B 0.9600 .
C12 H12C 0.9600 .
C21 C22 1.52(2) .
C22 H22A 0.9600 .
C22 H22B 0.9600 .
C22 H22C 0.9600 .
C1A C2A 1.3900 .
C1A C6A 1.3900 .
C2A C3A 1.3900 .
C2A H2AA 0.9300 .
C3A C4A 1.3900 .
C3A H3AA 0.9300 .
C4A C5A 1.3900 .
C4A H4AA 0.9300 .
C5A C6A 1.3900 .
C5A H5AA 0.9300 .
C6A C7A 1.49(2) .
C7A H7AA 0.9600 .
C7A H7AB 0.9600 .
C7A H7AC 0.9600 .
C1BA C2BA 1.3900 .
C1BA C6BA 1.3900 .
C2BA C3BA 1.3900 .
C2BA H2BA 0.9300 .
C3BA C4BA 1.3900 .
C3BA H3BA 0.9300 .
C4BA C5BA 1.3900 .
C4BA H4BA 0.9300 .
C5BA C6BA 1.3900 .
C5BA H5BA 0.9300 .
C6BA C7BA 1.50(2) .
C7BA H7BA 0.9600 .
C7BA H7BB 0.9600 .
C7BA H7BC 0.9600 .
C1BB C2BB 1.3900 .
C1BB C6BB 1.3900 .
C2BB C3BB 1.3900 .
C2BB H2BB 0.9300 .
C3BB C4BB 1.3900 .
C3BB H3BB 0.9300 .
C4BB C5BB 1.3900 .
C4BB H4BB 0.9300 .
C5BB C6BB 1.3900 .
C5BB H5BB 0.9300 .
C6BB C7BB 1.49(2) .
C7BB H7BD 0.9600 .
C7BB H7BE 0.9600 .
C7BB H7BF 0.9600 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O21 Pd1 Pd2 O22 2.6(6) . .
O11 Pd1 Pd2 O22 95.1(5) . .
Se1 Pd1 Pd2 O22 -174.9(4) . .
Se2 Pd1 Pd2 O22 -90.4(4) . .
O21 Pd1 Pd2 O12 -90.8(6) . .
O11 Pd1 Pd2 O12 1.6(5) . .
Se1 Pd1 Pd2 O12 91.7(4) . .
Se2 Pd1 Pd2 O12 176.2(4) . .
O21 Pd1 Pd2 Se2 178.9(4) . 7_656
O11 Pd1 Pd2 Se2 -88.7(3) . 7_656
Se1 Pd1 Pd2 Se2 1.36(6) . 7_656
Se2 Pd1 Pd2 Se2 85.86(6) . 7_656
O21 Pd1 Pd2 Se1 93.5(4) . 7_656
O11 Pd1 Pd2 Se1 -174.0(3) . 7_656
Se1 Pd1 Pd2 Se1 -84.01(6) . 7_656
Se2 Pd1 Pd2 Se1 0.48(6) . 7_656
O21 Pd1 Se1 C1BA 37(5) . .
O11 Pd1 Se1 C1BA -98.2(6) . .
Se2 Pd1 Se1 C1BA 84.0(5) . .
Pd2 Pd1 Se1 C1BA -179.5(5) . .
O21 Pd1 Se1 C1BB 34(5) . .
O11 Pd1 Se1 C1BB -101.2(7) . .
Se2 Pd1 Se1 C1BB 81.0(6) . .
Pd2 Pd1 Se1 C1BB 177.4(6) . .
O21 Pd1 Se1 Pd2 -69(5) . 7_656
O11 Pd1 Se1 Pd2 156.0(3) . 7_656
Se2 Pd1 Se1 Pd2 -21.74(5) . 7_656
Pd2 Pd1 Se1 Pd2 74.67(5) . 7_656
O21 Pd1 Se2 C1A 93.4(4) . .
O11 Pd1 Se2 C1A -107(3) . .
Se1 Pd1 Se2 C1A -83.6(3) . .
Pd2 Pd1 Se2 C1A 175.0(3) . .
O21 Pd1 Se2 Pd2 -161.2(3) . 7_656
O11 Pd1 Se2 Pd2 -2(3) . 7_656
Se1 Pd1 Se2 Pd2 21.88(5) . 7_656
Pd2 Pd1 Se2 Pd2 -79.55(5) . 7_656
O21 Pd1 O11 C11 76.8(14) . .
Se1 Pd1 O11 C11 -106.1(13) . .
Se2 Pd1 O11 C11 -83(3) . .
Pd2 Pd1 O11 C11 -4.1(13) . .
O22 Pd2 O12 C11 -80.7(15) . .
Se2 Pd2 O12 C11 99.4(15) 7_656 .
Se1 Pd2 O12 C11 134(3) 7_656 .
Pd1 Pd2 O12 C11 -0.3(15) . .
O11 Pd1 O21 C21 -81.7(15) . .
Se1 Pd1 O21 C21 143(4) . .
Se2 Pd1 O21 C21 96.4(14) . .
Pd2 Pd1 O21 C21 -0.8(14) . .
O12 Pd2 O22 C21 73.2(16) . .
Se2 Pd2 O22 C21 -109(5) 7_656 .
Se1 Pd2 O22 C21 -110.2(16) 7_656 .
Pd1 Pd2 O22 C21 -6.1(15) . .
Pd1 O11 C11 O12 5(3) . .
Pd1 O11 C11 C12 -177.8(11) . .
Pd2 O12 C11 O11 -3(3) . .
Pd2 O12 C11 C12 -179.6(12) . .
Pd2 O22 C21 O21 8(3) . .
Pd2 O22 C21 C22 -176.2(17) . .
Pd1 O21 C21 O22 -4(3) . .
Pd1 O21 C21 C22 -179.7(16) . .
Pd2 Se2 C1A C2A 6.3(6) 7_656 .
Pd1 Se2 C1A C2A 103.3(5) . .
Pd2 Se2 C1A C6A -173.5(5) 7_656 .
Pd1 Se2 C1A C6A -76.5(5) . .
C6A C1A C2A C3A 0.0 . .
Se2 C1A C2A C3A -179.8(7) . .
C1A C2A C3A C4A 0.0 . .
C2A C3A C4A C5A 0.0 . .
C3A C4A C5A C6A 0.0 . .
C4A C5A C6A C1A 0.0 . .
C4A C5A C6A C7A 173.2(15) . .
C2A C1A C6A C5A 0.0 . .
Se2 C1A C6A C5A 179.8(7) . .
C2A C1A C6A C7A -172.7(16) . .
Se2 C1A C6A C7A 7.1(16) . .
C1BB Se1 C1BA C2BA -174(6) . .
Pd1 Se1 C1BA C2BA 22.6(10) . .
Pd2 Se1 C1BA C2BA 118.5(9) 7_656 .
C1BB Se1 C1BA C6BA 3(5) . .
Pd1 Se1 C1BA C6BA -160.5(8) . .
Pd2 Se1 C1BA C6BA -64.6(9) 7_656 .
C6BA C1BA C2BA C3BA 0.0 . .
Se1 C1BA C2BA C3BA 177.0(11) . .
C1BA C2BA C3BA C4BA 0.0 . .
C2BA C3BA C4BA C5BA 0.0 . .
C3BA C4BA C5BA C6BA 0.0 . .
C4BA C5BA C6BA C1BA 0.0 . .
C4BA C5BA C6BA C7BA -175(2) . .
C2BA C1BA C6BA C5BA 0.0 . .
Se1 C1BA C6BA C5BA -176.9(12) . .
C2BA C1BA C6BA C7BA 175(2) . .
Se1 C1BA C6BA C7BA -2(2) . .
C1BA Se1 C1BB C2BB -176(6) . .
Pd1 Se1 C1BB C2BB -158.7(9) . .
Pd2 Se1 C1BB C2BB -61.6(10) 7_656 .
C1BA Se1 C1BB C6BB 7(5) . .
Pd1 Se1 C1BB C6BB 25.2(13) . .
Pd2 Se1 C1BB C6BB 122.4(11) 7_656 .
C6BB C1BB C2BB C3BB 0.0 . .
Se1 C1BB C2BB C3BB -176.3(13) . .
C1BB C2BB C3BB C4BB 0.0 . .
C2BB C3BB C4BB C5BB 0.0 . .
C3BB C4BB C5BB C6BB 0.0 . .
C4BB C5BB C6BB C1BB 0.0 . .
C4BB C5BB C6BB C7BB 178(3) . .
C2BB C1BB C6BB C5BB 0.0 . .
Se1 C1BB C6BB C5BB 175.9(14) . .
C2BB C1BB C6BB C7BB -178(3) . .
Se1 C1BB C6BB C7BB -2(3) . .
