#------------------------------------------------------------------------------
#$Date: 2016-02-16 22:30:59 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176467 $
#$URL: svn://www.crystallography.net/cod/cif/4/06/45/4064518.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4064518
loop_
_publ_author_name
'Tanabe, Makoto'
'Jiang, Jian'
'Yamazawa, Hideto'
'Osakada, Kohtaro'
'Ohmura, Toshimichi'
'Suginome, Michinori'
_publ_section_title
;
 Dinuclear Palladium and Platinum Complexes with Bridging Silylene
 Ligands. Preparation Using (Aminosilyl)boronic Ester as the Ligand
 Precursor and Their Reactions with Alkynes
;
_journal_issue                   15
_journal_name_full               Organometallics
_journal_page_first              3981
_journal_paper_doi               10.1021/om200156g
_journal_volume                  30
_journal_year                    2011
_chemical_formula_moiety         'C42.50 H50 P2 Pt Si2'
_chemical_formula_sum            'C42.5 H50 P2 Pt Si2'
_chemical_formula_weight         874.07
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90.0000
_cell_angle_beta                 108.257(3)
_cell_angle_gamma                90.0000
_cell_formula_units_Z            4
_cell_length_a                   12.678(3)
_cell_length_b                   18.481(4)
_cell_length_c                   18.113(4)
_cell_measurement_reflns_used    12447
_cell_measurement_temperature    113
_cell_measurement_theta_max      27.48
_cell_measurement_theta_min      3.22
_cell_volume                     4030.3(16)
_computing_cell_refinement       CrystalClear
_computing_data_collection       'CrystalClear (Rigaku/MSC Inc., 2006)'
_computing_data_reduction        CrystalClear
_computing_molecular_graphics    'CrystalStructure 4.0'
_computing_publication_material  'CrystalStructure 4.0 (Rigaku, 2010)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SIR2002 (Burla, et al., 2003)'
_diffrn_ambient_temperature      113
_diffrn_detector_area_resol_mean 7.314
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Rigaku Saturn70'
_diffrn_measurement_method       ω
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.0539
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            32417
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    3.634
_exptl_absorpt_correction_T_max  0.403
_exptl_absorpt_correction_T_min  0.322
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'REQAB (Rigaku, 1998)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.440
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1764.00
_exptl_crystal_size_max          0.300
_exptl_crystal_size_mid          0.300
_exptl_crystal_size_min          0.250
_refine_diff_density_max         2.290
_refine_diff_density_min         -1.080
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.994
_refine_ls_hydrogen_treatment    constr
_refine_ls_number_parameters     442
_refine_ls_number_reflns         9213
_refine_ls_number_restraints     6
_refine_ls_R_factor_all          0.0371
_refine_ls_R_factor_gt           0.0299
_refine_ls_shift/su_max          0.002
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[σ²(Fo²)+(0.0291P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0669
_refine_ls_wR_factor_ref         0.0700
_reflns_number_gt                7504
_reflns_number_total             9213
_reflns_threshold_expression     F²>2.0σ(F²)
_cod_data_source_file            om200156g_si_001.cif
_cod_data_source_block           complex3
_cod_original_cell_volume        4030.3(15)
_cod_original_formula_sum        'C42.50 H50 P2 Pt Si2'
_cod_database_code               4064518
loop_
_symmetry_equiv_pos_site_id
_symmetry_equiv_pos_as_xyz
1 +X,+Y,+Z
2 -X,1/2+Y,1/2-Z
3 -X,-Y,-Z
4 +X,1/2-Y,1/2+Z
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Pt1 Pt 0.670983(9) 0.255860(6) 0.272306(6) 0.01470(4) Uani 1.0 4 d .
P1 P 0.56463(7) 0.16143(4) 0.19961(5) 0.01876(18) Uani 1.0 4 d .
P2 P 0.80904(7) 0.25238(4) 0.21068(5) 0.01845(18) Uani 1.0 4 d .
Si1 Si 0.75980(7) 0.35228(4) 0.35474(5) 0.01528(18) Uani 1.0 4 d .
Si2 Si 0.53803(7) 0.27734(5) 0.33612(5) 0.01762(18) Uani 1.0 4 d .
C1 C 0.6831(3) 0.38072(15) 0.42511(17) 0.0156(7) Uani 1.0 4 d .
C2 C 0.5828(3) 0.35025(16) 0.41115(18) 0.0190(7) Uani 1.0 4 d .
C3 C 0.7228(3) 0.43561(16) 0.48715(17) 0.0164(7) Uani 1.0 4 d .
C4 C 0.6543(3) 0.49335(15) 0.49285(18) 0.0173(7) Uani 1.0 4 d .
C5 C 0.6871(3) 0.54251(16) 0.55412(19) 0.0215(7) Uani 1.0 4 d .
C6 C 0.7892(3) 0.53621(16) 0.61098(18) 0.0198(7) Uani 1.0 4 d .
C7 C 0.8590(3) 0.48028(16) 0.60484(18) 0.0202(7) Uani 1.0 4 d .
C8 C 0.8274(3) 0.43063(16) 0.54402(17) 0.0183(7) Uani 1.0 4 d .
C9 C 0.8223(3) 0.58870(18) 0.6780(2) 0.0301(9) Uani 1.0 4 d .
C10 C 0.9051(3) 0.32245(16) 0.41451(17) 0.0174(7) Uani 1.0 4 d .
C11 C 0.9213(4) 0.25034(16) 0.4351(3) 0.0306(9) Uani 1.0 4 d .
C12 C 1.0243(4) 0.2229(2) 0.4767(3) 0.0440(11) Uani 1.0 4 d .
C13 C 1.1164(3) 0.26841(19) 0.4992(2) 0.0340(9) Uani 1.0 4 d .
C14 C 1.1026(3) 0.34046(19) 0.4821(2) 0.0300(9) Uani 1.0 4 d .
C15 C 0.9982(3) 0.36701(18) 0.4393(2) 0.0257(8) Uani 1.0 4 d .
C16 C 0.7673(3) 0.44124(16) 0.30277(18) 0.0175(7) Uani 1.0 4 d .
C17 C 0.8225(3) 0.50279(15) 0.34209(19) 0.0194(7) Uani 1.0 4 d .
C18 C 0.8273(3) 0.56664(17) 0.3026(2) 0.0264(8) Uani 1.0 4 d .
C19 C 0.7761(3) 0.57122(18) 0.2232(2) 0.0269(8) Uani 1.0 4 d .
C20 C 0.7168(3) 0.51270(18) 0.1840(2) 0.0284(8) Uani 1.0 4 d .
C21 C 0.7129(3) 0.44887(17) 0.22356(18) 0.0218(7) Uani 1.0 4 d .
C22 C 0.5067(3) 0.20188(17) 0.39757(18) 0.0233(8) Uani 1.0 4 d .
C23 C 0.4135(4) 0.20339(19) 0.4245(2) 0.0323(9) Uani 1.0 4 d .
C24 C 0.4018(4) 0.1530(2) 0.4784(3) 0.0431(12) Uani 1.0 4 d .
C25 C 0.4820(4) 0.1007(2) 0.5076(2) 0.0448(12) Uani 1.0 4 d .
C26 C 0.5735(4) 0.0981(2) 0.4820(2) 0.0407(10) Uani 1.0 4 d .
C27 C 0.5846(4) 0.14833(18) 0.4276(2) 0.0311(9) Uani 1.0 4 d .
C28 C 0.4060(3) 0.31179(17) 0.26251(18) 0.0199(7) Uani 1.0 4 d .
C29 C 0.3035(3) 0.27544(19) 0.2363(2) 0.0250(8) Uani 1.0 4 d .
C30 C 0.2144(3) 0.3040(2) 0.1780(2) 0.0313(9) Uani 1.0 4 d .
C31 C 0.2243(3) 0.3697(2) 0.1441(2) 0.0346(9) Uani 1.0 4 d .
C32 C 0.3245(4) 0.40706(19) 0.1694(2) 0.0306(9) Uani 1.0 4 d .
C33 C 0.4126(3) 0.37822(18) 0.22743(18) 0.0245(8) Uani 1.0 4 d .
C34 C 0.6363(3) 0.08619(16) 0.1716(2) 0.0256(8) Uani 1.0 4 d .
C35 C 0.4691(3) 0.10920(18) 0.2360(2) 0.0285(9) Uani 1.0 4 d .
C36 C 0.4722(3) 0.19455(19) 0.10798(18) 0.0300(9) Uani 1.0 4 d .
C37 C 0.9024(3) 0.17510(18) 0.2382(2) 0.0291(8) Uani 1.0 4 d .
C38 C 0.9115(3) 0.32427(18) 0.2244(2) 0.0305(9) Uani 1.0 4 d .
C39 C 0.7591(3) 0.24878(16) 0.1049(2) 0.0267(8) Uani 1.0 4 d .
C40 C 0.0078(9) 0.4938(5) -0.0370(5) 0.060(4) Uani 0.5000 4 d .
C41 C 0.0085(7) 0.4825(3) -0.1145(4) 0.089(3) Uani 1.0 4 d .
C42 C 0.0926(8) 0.5224(5) -0.0604(5) 0.076(4) Uani 0.5000 4 d .
C43 C 0.0893(6) 0.5327(3) 0.0166(4) 0.085(3) Uani 1.0 4 d .
C44 C 0.0948(9) 0.5463(5) 0.0966(5) 0.055(3) Uani 0.5000 4 d .
H1 H 0.5348 0.3656 0.4392 0.0229 Uiso 1.0 4 calc R
H2 H 0.5841 0.4991 0.4542 0.0208 Uiso 1.0 4 calc R
H3 H 0.6387 0.5809 0.5569 0.0258 Uiso 1.0 4 calc R
H4 H 0.9299 0.4758 0.6430 0.0242 Uiso 1.0 4 calc R
H5 H 0.8771 0.3931 0.5410 0.0220 Uiso 1.0 4 calc R
H6 H 0.7692 0.5857 0.7072 0.0361 Uiso 1.0 4 calc R
H7 H 0.8225 0.6380 0.6580 0.0361 Uiso 1.0 4 calc R
H8 H 0.8968 0.5766 0.7123 0.0361 Uiso 1.0 4 calc R
H9 H 0.8594 0.2185 0.4202 0.0367 Uiso 1.0 4 calc R
H10 H 1.0322 0.1730 0.4898 0.0528 Uiso 1.0 4 calc R
H11 H 1.1879 0.2496 0.5261 0.0407 Uiso 1.0 4 calc R
H12 H 1.1641 0.3725 0.4993 0.0360 Uiso 1.0 4 calc R
H13 H 0.9904 0.4170 0.4268 0.0308 Uiso 1.0 4 calc R
H14 H 0.8572 0.5007 0.3967 0.0233 Uiso 1.0 4 calc R
H15 H 0.8660 0.6073 0.3302 0.0317 Uiso 1.0 4 calc R
H16 H 0.7816 0.6142 0.1959 0.0322 Uiso 1.0 4 calc R
H17 H 0.6786 0.5161 0.1298 0.0341 Uiso 1.0 4 calc R
H18 H 0.6717 0.4091 0.1956 0.0261 Uiso 1.0 4 calc R
H19 H 0.3581 0.2394 0.4056 0.0387 Uiso 1.0 4 calc R
H20 H 0.3381 0.1546 0.4953 0.0517 Uiso 1.0 4 calc R
H21 H 0.4741 0.0669 0.5449 0.0538 Uiso 1.0 4 calc R
H22 H 0.6288 0.0622 0.5015 0.0488 Uiso 1.0 4 calc R
H23 H 0.6481 0.1457 0.4104 0.0374 Uiso 1.0 4 calc R
H24 H 0.2952 0.2303 0.2589 0.0299 Uiso 1.0 4 calc R
H25 H 0.1460 0.2784 0.1612 0.0376 Uiso 1.0 4 calc R
H26 H 0.1633 0.3891 0.1040 0.0416 Uiso 1.0 4 calc R
H27 H 0.3322 0.4523 0.1467 0.0367 Uiso 1.0 4 calc R
H28 H 0.4803 0.4045 0.2442 0.0294 Uiso 1.0 4 calc R
H29 H 0.6805 0.0603 0.2182 0.0307 Uiso 1.0 4 calc R
H30 H 0.6853 0.1046 0.1434 0.0307 Uiso 1.0 4 calc R
H31 H 0.5816 0.0531 0.1379 0.0307 Uiso 1.0 4 calc R
H32 H 0.4142 0.1418 0.2462 0.0342 Uiso 1.0 4 calc R
H33 H 0.5107 0.0846 0.2842 0.0342 Uiso 1.0 4 calc R
H34 H 0.4309 0.0732 0.1971 0.0342 Uiso 1.0 4 calc R
H35 H 0.4209 0.1559 0.0821 0.0360 Uiso 1.0 4 calc R
H36 H 0.5159 0.2098 0.0746 0.0360 Uiso 1.0 4 calc R
H37 H 0.4297 0.2358 0.1176 0.0360 Uiso 1.0 4 calc R
H38 H 0.9403 0.1762 0.2943 0.0349 Uiso 1.0 4 calc R
H39 H 0.9575 0.1773 0.2105 0.0349 Uiso 1.0 4 calc R
H40 H 0.8595 0.1302 0.2245 0.0349 Uiso 1.0 4 calc R
H41 H 0.9679 0.3101 0.2005 0.0366 Uiso 1.0 4 calc R
H42 H 0.9471 0.3326 0.2801 0.0366 Uiso 1.0 4 calc R
H43 H 0.8748 0.3688 0.1999 0.0366 Uiso 1.0 4 calc R
H44 H 0.7203 0.2029 0.0881 0.0320 Uiso 1.0 4 calc R
H45 H 0.8223 0.2524 0.0848 0.0320 Uiso 1.0 4 calc R
H46 H 0.7080 0.2891 0.0849 0.0320 Uiso 1.0 4 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
H H 0.0000 0.0000
;
International Tables for Crystallography
(1992, Vol. C, Table 6.1.1.4)
;
P P 0.1023 0.0942
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
Pt Pt -1.7033 8.3905
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
Si Si 0.0817 0.0704
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_publ_flag
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
P1 Pt1 P2 95.49(4) yes . .
P1 Pt1 Si1 172.09(4) yes . .
P1 Pt1 Si2 91.55(4) yes . .
P2 Pt1 Si1 92.42(4) yes . .
P2 Pt1 Si2 171.75(3) yes . .
Si1 Pt1 Si2 80.56(4) yes . .
Pt1 P1 C34 118.49(11) yes . .
Pt1 P1 C35 121.42(12) yes . .
Pt1 P1 C36 110.89(12) yes . .
C34 P1 C35 98.19(17) yes . .
C34 P1 C36 103.82(17) yes . .
C35 P1 C36 101.36(16) yes . .
Pt1 P2 C37 114.06(14) yes . .
Pt1 P2 C38 121.39(14) yes . .
Pt1 P2 C39 115.79(14) yes . .
C37 P2 C38 99.21(16) yes . .
C37 P2 C39 103.94(16) yes . .
C38 P2 C39 99.67(17) yes . .
Pt1 Si1 C1 112.82(10) yes . .
Pt1 Si1 C10 108.95(10) yes . .
Pt1 Si1 C16 115.05(10) yes . .
C1 Si1 C10 107.80(14) yes . .
C1 Si1 C16 101.94(15) yes . .
C10 Si1 C16 109.93(14) yes . .
Pt1 Si2 C2 112.12(12) yes . .
Pt1 Si2 C22 118.41(12) yes . .
Pt1 Si2 C28 108.76(13) yes . .
C2 Si2 C22 100.04(15) yes . .
C2 Si2 C28 105.63(14) yes . .
C22 Si2 C28 110.98(16) yes . .
Si1 C1 C2 114.3(3) yes . .
Si1 C1 C3 125.0(3) yes . .
C2 C1 C3 120.5(4) yes . .
Si2 C2 C1 119.6(3) yes . .
C1 C3 C4 120.5(3) yes . .
C1 C3 C8 122.0(3) yes . .
C4 C3 C8 117.5(3) yes . .
C3 C4 C5 121.2(3) yes . .
C4 C5 C6 120.9(3) yes . .
C5 C6 C7 118.3(3) yes . .
C5 C6 C9 120.3(3) yes . .
C7 C6 C9 121.4(3) yes . .
C6 C7 C8 121.5(3) yes . .
C3 C8 C7 120.6(3) yes . .
Si1 C10 C11 117.9(3) yes . .
Si1 C10 C15 125.7(3) yes . .
C11 C10 C15 116.3(3) yes . .
C10 C11 C12 122.4(4) yes . .
C11 C12 C13 120.0(4) yes . .
C12 C13 C14 119.1(4) yes . .
C13 C14 C15 120.0(4) yes . .
C10 C15 C14 122.1(3) yes . .
Si1 C16 C17 122.7(3) yes . .
Si1 C16 C21 120.7(3) yes . .
C17 C16 C21 116.6(3) yes . .
C16 C17 C18 121.4(3) yes . .
C17 C18 C19 120.3(3) yes . .
C18 C19 C20 119.4(4) yes . .
C19 C20 C21 120.1(3) yes . .
C16 C21 C20 122.2(3) yes . .
Si2 C22 C23 122.6(3) yes . .
Si2 C22 C27 120.0(3) yes . .
C23 C22 C27 116.7(4) yes . .
C22 C23 C24 121.0(4) yes . .
C23 C24 C25 120.6(5) yes . .
C24 C25 C26 119.4(4) yes . .
C25 C26 C27 119.8(4) yes . .
C22 C27 C26 122.4(4) yes . .
Si2 C28 C29 126.6(3) yes . .
Si2 C28 C33 116.7(3) yes . .
C29 C28 C33 116.5(3) yes . .
C28 C29 C30 121.4(4) yes . .
C29 C30 C31 120.4(4) yes . .
C30 C31 C32 119.4(3) yes . .
C31 C32 C33 119.8(4) yes . .
C28 C33 C32 122.5(4) yes . .
C40 C40 C41 172.7(9) yes 3_565 .
C40 C40 C42 125.2(8) yes 3_565 .
C40 C40 C43 63.3(6) yes 3_565 .
C40 C40 C43 56.5(6) yes 3_565 3_565
C40 C40 C44 112.6(9) yes 3_565 3_565
C41 C40 C42 60.4(7) yes . .
C41 C40 C43 122.6(9) yes . .
C41 C40 C43 117.5(7) yes . 3_565
C41 C40 C44 61.2(6) yes . 3_565
C42 C40 C43 62.1(7) yes . .
C42 C40 C43 175.2(8) yes . 3_565
C42 C40 C44 121.4(8) yes . 3_565
C43 C40 C43 119.7(8) yes . 3_565
C43 C40 C44 174.4(10) yes . 3_565
C43 C40 C44 56.3(6) yes 3_565 3_565
C40 C41 C42 58.3(6) yes . .
C40 C41 C44 64.8(6) yes . 3_565
C42 C41 C44 122.9(7) yes . 3_565
C40 C42 C41 61.3(6) yes . .
C40 C42 C43 58.9(6) yes . .
C41 C42 C43 120.2(9) yes . .
C40 C43 C40 60.3(6) yes . 3_565
C40 C43 C42 58.9(6) yes . .
C40 C43 C44 125.9(8) yes . .
C40 C43 C42 119.0(6) yes 3_565 .
C40 C43 C44 65.8(6) yes 3_565 .
C42 C43 C44 175.2(8) yes . .
C40 C44 C41 54.0(6) yes 3_565 3_565
C40 C44 C43 57.9(6) yes 3_565 .
C41 C44 C43 111.8(7) yes 3_565 .
Si2 C2 H1 120.215 no . .
C1 C2 H1 120.201 no . .
C3 C4 H2 119.385 no . .
C5 C4 H2 119.381 no . .
C4 C5 H3 119.532 no . .
C6 C5 H3 119.526 no . .
C6 C7 H4 119.273 no . .
C8 C7 H4 119.263 no . .
C3 C8 H5 119.726 no . .
C7 C8 H5 119.722 no . .
C6 C9 H6 109.477 no . .
C6 C9 H7 109.469 no . .
C6 C9 H8 109.463 no . .
H6 C9 H7 109.476 no . .
H6 C9 H8 109.471 no . .
H7 C9 H8 109.472 no . .
C10 C11 H9 118.800 no . .
C12 C11 H9 118.806 no . .
C11 C12 H10 120.005 no . .
C13 C12 H10 120.005 no . .
C12 C13 H11 120.440 no . .
C14 C13 H11 120.423 no . .
C13 C14 H12 120.015 no . .
C15 C14 H12 120.011 no . .
C10 C15 H13 118.954 no . .
C14 C15 H13 118.952 no . .
C16 C17 H14 119.321 no . .
C18 C17 H14 119.327 no . .
C17 C18 H15 119.841 no . .
C19 C18 H15 119.826 no . .
C18 C19 H16 120.334 no . .
C20 C19 H16 120.315 no . .
C19 C20 H17 119.962 no . .
C21 C20 H17 119.965 no . .
C16 C21 H18 118.903 no . .
C20 C21 H18 118.930 no . .
C22 C23 H19 119.521 no . .
C24 C23 H19 119.516 no . .
C23 C24 H20 119.692 no . .
C25 C24 H20 119.700 no . .
C24 C25 H21 120.277 no . .
C26 C25 H21 120.279 no . .
C25 C26 H22 120.072 no . .
C27 C26 H22 120.090 no . .
C22 C27 H23 118.795 no . .
C26 C27 H23 118.787 no . .
C28 C29 H24 119.283 no . .
C30 C29 H24 119.284 no . .
C29 C30 H25 119.804 no . .
C31 C30 H25 119.797 no . .
C30 C31 H26 120.317 no . .
C32 C31 H26 120.315 no . .
C31 C32 H27 120.098 no . .
C33 C32 H27 120.102 no . .
C28 C33 H28 118.759 no . .
C32 C33 H28 118.773 no . .
P1 C34 H29 109.464 no . .
P1 C34 H30 109.466 no . .
P1 C34 H31 109.474 no . .
H29 C34 H30 109.474 no . .
H29 C34 H31 109.475 no . .
H30 C34 H31 109.474 no . .
P1 C35 H32 109.470 no . .
P1 C35 H33 109.473 no . .
P1 C35 H34 109.468 no . .
H32 C35 H33 109.467 no . .
H32 C35 H34 109.469 no . .
H33 C35 H34 109.480 no . .
P1 C36 H35 109.466 no . .
P1 C36 H36 109.472 no . .
P1 C36 H37 109.471 no . .
H35 C36 H36 109.471 no . .
H35 C36 H37 109.474 no . .
H36 C36 H37 109.473 no . .
P2 C37 H38 109.472 no . .
P2 C37 H39 109.477 no . .
P2 C37 H40 109.469 no . .
H38 C37 H39 109.477 no . .
H38 C37 H40 109.469 no . .
H39 C37 H40 109.463 no . .
P2 C38 H41 109.470 no . .
P2 C38 H42 109.467 no . .
P2 C38 H43 109.473 no . .
H41 C38 H42 109.465 no . .
H41 C38 H43 109.477 no . .
H42 C38 H43 109.476 no . .
P2 C39 H44 109.475 no . .
P2 C39 H45 109.466 no . .
P2 C39 H46 109.469 no . .
H44 C39 H45 109.473 no . .
H44 C39 H46 109.472 no . .
H45 C39 H46 109.472 no . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_publ_flag
_geom_bond_site_symmetry_2
Pt1 P1 2.3420(8) yes .
Pt1 P2 2.3533(11) yes .
Pt1 Si1 2.3705(9) yes .
Pt1 Si2 2.3571(11) yes .
P1 C34 1.818(4) yes .
P1 C35 1.826(4) yes .
P1 C36 1.812(3) yes .
P2 C37 1.822(4) yes .
P2 C38 1.820(4) yes .
P2 C39 1.821(4) yes .
Si1 C1 1.903(4) yes .
Si1 C10 1.903(3) yes .
Si1 C16 1.912(4) yes .
Si2 C2 1.871(4) yes .
Si2 C22 1.902(4) yes .
Si2 C28 1.894(3) yes .
C1 C2 1.340(5) yes .
C1 C3 1.480(4) yes .
C3 C4 1.400(5) yes .
C3 C8 1.404(4) yes .
C4 C5 1.393(5) yes .
C5 C6 1.384(4) yes .
C6 C7 1.387(5) yes .
C6 C9 1.507(5) yes .
C7 C8 1.393(5) yes .
C10 C11 1.382(5) yes .
C10 C15 1.393(5) yes .
C11 C12 1.383(6) yes .
C12 C13 1.392(6) yes .
C13 C14 1.366(5) yes .
C14 C15 1.397(5) yes .
C16 C17 1.407(4) yes .
C16 C21 1.391(5) yes .
C17 C18 1.391(5) yes .
C18 C19 1.383(5) yes .
C19 C20 1.380(5) yes .
C20 C21 1.390(5) yes .
C22 C23 1.413(6) yes .
C22 C27 1.383(5) yes .
C23 C24 1.389(6) yes .
C24 C25 1.382(6) yes .
C25 C26 1.378(8) yes .
C26 C27 1.393(6) yes .
C28 C29 1.406(5) yes .
C28 C33 1.397(5) yes .
C29 C30 1.387(5) yes .
C30 C31 1.383(6) yes .
C31 C32 1.391(6) yes .
C32 C33 1.379(5) yes .
C40 C40 1.435(13) yes 3_565
C40 C41 1.421(11) yes .
C40 C42 1.378(15) yes .
C40 C43 1.378(10) yes .
C40 C43 1.476(13) yes 3_565
C40 C44 1.590(12) yes 3_565
C41 C42 1.409(10) yes .
C41 C44 1.539(15) yes 3_565
C42 C43 1.422(12) yes .
C43 C44 1.451(12) yes .
C2 H1 0.950 no .
C4 H2 0.950 no .
C5 H3 0.950 no .
C7 H4 0.950 no .
C8 H5 0.950 no .
C9 H6 0.980 no .
C9 H7 0.980 no .
C9 H8 0.980 no .
C11 H9 0.950 no .
C12 H10 0.950 no .
C13 H11 0.950 no .
C14 H12 0.950 no .
C15 H13 0.950 no .
C17 H14 0.950 no .
C18 H15 0.950 no .
C19 H16 0.950 no .
C20 H17 0.950 no .
C21 H18 0.950 no .
C23 H19 0.950 no .
C24 H20 0.950 no .
C25 H21 0.950 no .
C26 H22 0.950 no .
C27 H23 0.950 no .
C29 H24 0.950 no .
C30 H25 0.950 no .
C31 H26 0.950 no .
C32 H27 0.950 no .
C33 H28 0.950 no .
C34 H29 0.980 no .
C34 H30 0.980 no .
C34 H31 0.980 no .
C35 H32 0.980 no .
C35 H33 0.980 no .
C35 H34 0.980 no .
C36 H35 0.980 no .
C36 H36 0.980 no .
C36 H37 0.980 no .
C37 H38 0.980 no .
C37 H39 0.980 no .
C37 H40 0.980 no .
C38 H41 0.980 no .
C38 H42 0.980 no .
C38 H43 0.980 no .
C39 H44 0.980 no .
C39 H45 0.980 no .
C39 H46 0.980 no .
