#------------------------------------------------------------------------------
#$Date: 2016-03-21 06:56:37 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178541 $
#$URL: svn://www.crystallography.net/cod/cif/4/06/47/4064798.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4064798
loop_
_publ_author_name
'Li, Baolin'
'Matsuo, Tsukasa'
'Fukunaga, Takeo'
'Hashizume, Daisuke'
'Fueno, Hiroyuki'
'Tanaka, Kazuyoshi'
'Tamao, Kohei'
_publ_section_title
;
 Neutral and Cationic Gold(I) Complexes with π-Conjugated Phosphasilene
 Ligands
;
_journal_issue                   13
_journal_name_full               Organometallics
_journal_page_first              3453
_journal_paper_doi               10.1021/om2003442
_journal_volume                  30
_journal_year                    2011
_chemical_formula_moiety         'C118 H184 Au2 Cl2 P2 Si2, 2(C H2 Cl2)'
_chemical_formula_sum            'C120 H188 Au2 Cl6 P2 Si2'
_chemical_formula_weight         2355.46
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90
_cell_angle_beta                 92.044(2)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   13.3517(14)
_cell_length_b                   25.810(3)
_cell_length_c                   16.9047(17)
_cell_measurement_reflns_used    16860
_cell_measurement_temperature    100
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.0
_cell_volume                     5821.8(11)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalClear
_computing_molecular_graphics    'ORTEP-3 for Windows'
_computing_publication_material  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    SIR92
_diffrn_ambient_temperature      100
_diffrn_detector_area_resol_mean 29.26
_diffrn_measured_fraction_theta_full 0.980
_diffrn_measured_fraction_theta_max 0.980
_diffrn_measurement_device_type  'Rigaku Saturn'
_diffrn_measurement_method       ω-scan
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus rotating anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0318
_diffrn_reflns_av_sigmaI/netI    0.0327
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       33
_diffrn_reflns_limit_k_min       -33
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            47158
_diffrn_reflns_theta_full        27.51
_diffrn_reflns_theta_max         27.51
_diffrn_reflns_theta_min         3.01
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    2.748
_exptl_absorpt_correction_T_max  0.7706
_exptl_absorpt_correction_T_min  0.6833
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Jacobson, R. (1998) Private communication'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.344
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2452
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.10
_refine_diff_density_max         2.160
_refine_diff_density_min         -0.879
_refine_diff_density_rms         0.095
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.087
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     641
_refine_ls_number_reflns         13120
_refine_ls_number_restraints     4
_refine_ls_restrained_S_all      1.088
_refine_ls_R_factor_all          0.0378
_refine_ls_R_factor_gt           0.0323
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0200P)²+10.2732P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0652
_refine_ls_wR_factor_ref         0.0682
_reflns_number_gt                11737
_reflns_number_total             13120
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            om2003442_si_002.cif
_cod_data_source_block           5a
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               4064798
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.148159(8) 0.157412(4) 0.203073(6) 0.01748(3) Uani 1 1 d . . .
Cl1 Cl 0.20805(6) 0.18873(3) 0.08744(4) 0.03091(17) Uani 1 1 d . . .
P1 P 0.08255(5) 0.12711(3) 0.31328(4) 0.01506(13) Uani 1 1 d . . .
Si1 Si 0.09818(5) 0.04916(3) 0.34322(4) 0.01404(14) Uani 1 1 d . . .
C1 C 0.17230(19) 0.00102(10) 0.28646(15) 0.0145(5) Uani 1 1 d . . .
C2 C 0.2732(2) -0.01123(10) 0.30970(15) 0.0171(5) Uani 1 1 d . . .
C3 C 0.3458(2) 0.01859(11) 0.36493(16) 0.0190(6) Uani 1 1 d . . .
C4 C 0.4461(2) -0.01213(11) 0.35976(17) 0.0212(6) Uani 1 1 d . . .
H4A H 0.4971 0.0097 0.3347 0.025 Uiso 1 1 calc R . .
H4B H 0.4716 -0.0215 0.4136 0.025 Uiso 1 1 calc R . .
C5 C 0.4272(2) -0.06207(11) 0.30983(17) 0.0214(6) Uani 1 1 d . . .
C6 C 0.3219(2) -0.05310(11) 0.27540(16) 0.0193(6) Uani 1 1 d . . .
C7 C 0.2762(2) -0.08117(11) 0.21415(16) 0.0218(6) Uani 1 1 d . . .
H7 H 0.3098 -0.1097 0.1915 0.026 Uiso 1 1 calc R . .
C8 C 0.1805(2) -0.06714(10) 0.18619(15) 0.0182(6) Uani 1 1 d . . .
C9 C 0.1255(2) -0.08957(11) 0.11403(16) 0.0201(6) Uani 1 1 d . . .
C10 C 0.0195(2) -0.06539(11) 0.11958(16) 0.0204(6) Uani 1 1 d . . .
H10A H -0.0001 -0.0485 0.0688 0.024 Uiso 1 1 calc R . .
H10B H -0.0300 -0.0929 0.1300 0.024 Uiso 1 1 calc R . .
C11 C 0.0204(2) -0.02487(10) 0.18747(16) 0.0170(5) Uani 1 1 d . . .
C12 C 0.12735(19) -0.02841(10) 0.22361(15) 0.0150(5) Uani 1 1 d . . .
C13 C 0.3126(2) 0.02383(12) 0.45077(17) 0.0249(6) Uani 1 1 d . . .
H13A H 0.3610 0.0468 0.4793 0.030 Uiso 1 1 calc R . .
H13B H 0.2469 0.0416 0.4496 0.030 Uiso 1 1 calc R . .
C14 C 0.3031(2) -0.02558(13) 0.49905(18) 0.0297(7) Uani 1 1 d . . .
H14A H 0.3698 -0.0404 0.5098 0.045 Uiso 1 1 calc R . .
H14B H 0.2615 -0.0506 0.4692 0.045 Uiso 1 1 calc R . .
H14C H 0.2719 -0.0176 0.5492 0.045 Uiso 1 1 calc R . .
C15 C 0.3603(2) 0.07434(12) 0.3334(2) 0.0312(7) Uani 1 1 d . . .
H15A H 0.2988 0.0943 0.3433 0.037 Uiso 1 1 calc R . .
H15B H 0.4158 0.0906 0.3648 0.037 Uiso 1 1 calc R . .
C16 C 0.3829(3) 0.07970(14) 0.2462(2) 0.0429(9) Uani 1 1 d . . .
H16A H 0.4467 0.0626 0.2360 0.064 Uiso 1 1 calc R . .
H16B H 0.3874 0.1165 0.2325 0.064 Uiso 1 1 calc R . .
H16C H 0.3291 0.0634 0.2140 0.064 Uiso 1 1 calc R . .
C17 C 0.4313(2) -0.11026(11) 0.36475(17) 0.0229(6) Uani 1 1 d . . .
H17A H 0.4977 -0.1109 0.3927 0.027 Uiso 1 1 calc R . .
H17B H 0.3804 -0.1057 0.4054 0.027 Uiso 1 1 calc R . .
C18 C 0.4142(3) -0.16260(12) 0.3258(2) 0.0361(8) Uani 1 1 d . . .
H18A H 0.3464 -0.1640 0.3019 0.054 Uiso 1 1 calc R . .
H18B H 0.4221 -0.1900 0.3657 0.054 Uiso 1 1 calc R . .
H18C H 0.4632 -0.1677 0.2847 0.054 Uiso 1 1 calc R . .
C19 C 0.5031(2) -0.06678(13) 0.24306(18) 0.0292(7) Uani 1 1 d . . .
H19A H 0.4821 -0.0956 0.2077 0.035 Uiso 1 1 calc R . .
H19B H 0.5009 -0.0345 0.2113 0.035 Uiso 1 1 calc R . .
C20 C 0.6112(2) -0.07623(15) 0.2726(2) 0.0361(8) Uani 1 1 d . . .
H20A H 0.6292 -0.0511 0.3142 0.054 Uiso 1 1 calc R . .
H20B H 0.6563 -0.0722 0.2285 0.054 Uiso 1 1 calc R . .
H20C H 0.6173 -0.1114 0.2940 0.054 Uiso 1 1 calc R . .
C21 C 0.1202(2) -0.14911(11) 0.11692(18) 0.0259(7) Uani 1 1 d . . .
H21A H 0.1892 -0.1630 0.1210 0.031 Uiso 1 1 calc R . .
H21B H 0.0857 -0.1595 0.1653 0.031 Uiso 1 1 calc R . .
C22 C 0.0656(3) -0.17367(12) 0.0450(2) 0.0321(7) Uani 1 1 d . . .
H22A H -0.0008 -0.1579 0.0375 0.048 Uiso 1 1 calc R . .
H22B H 0.0583 -0.2110 0.0538 0.048 Uiso 1 1 calc R . .
H22C H 0.1044 -0.1678 -0.0023 0.048 Uiso 1 1 calc R . .
C23 C 0.1745(2) -0.07081(12) 0.03750(17) 0.0243(6) Uani 1 1 d . . .
H23A H 0.1293 -0.0803 -0.0079 0.029 Uiso 1 1 calc R . .
H23B H 0.1778 -0.0325 0.0393 0.029 Uiso 1 1 calc R . .
C24 C 0.2784(3) -0.09087(14) 0.02073(19) 0.0344(8) Uani 1 1 d . . .
H24A H 0.3258 -0.0795 0.0628 0.052 Uiso 1 1 calc R . .
H24B H 0.2993 -0.0773 -0.0302 0.052 Uiso 1 1 calc R . .
H24C H 0.2772 -0.1288 0.0188 0.052 Uiso 1 1 calc R . .
C25 C -0.0580(2) -0.03855(11) 0.24884(16) 0.0203(6) Uani 1 1 d . . .
H25A H -0.0526 -0.0128 0.2922 0.024 Uiso 1 1 calc R . .
H25B H -0.1254 -0.0348 0.2232 0.024 Uiso 1 1 calc R . .
C26 C -0.0505(2) -0.09268(11) 0.28548(18) 0.0267(7) Uani 1 1 d . . .
H26A H -0.0686 -0.1187 0.2452 0.040 Uiso 1 1 calc R . .
H26B H -0.0965 -0.0952 0.3292 0.040 Uiso 1 1 calc R . .
H26C H 0.0183 -0.0988 0.3055 0.040 Uiso 1 1 calc R . .
C27 C -0.0060(2) 0.02928(10) 0.15427(16) 0.0196(6) Uani 1 1 d . . .
H27A H -0.0723 0.0272 0.1263 0.024 Uiso 1 1 calc R . .
H27B H -0.0126 0.0534 0.1994 0.024 Uiso 1 1 calc R . .
C28 C 0.0684(2) 0.05238(11) 0.09792(17) 0.0237(6) Uani 1 1 d . . .
H28A H 0.1346 0.0545 0.1246 0.036 Uiso 1 1 calc R . .
H28B H 0.0462 0.0872 0.0820 0.036 Uiso 1 1 calc R . .
H28C H 0.0721 0.0303 0.0509 0.036 Uiso 1 1 calc R . .
C29 C 0.00206(19) 0.16776(10) 0.37416(15) 0.0141(5) Uani 1 1 d . . .
C30 C 0.04473(19) 0.19664(10) 0.43825(15) 0.0140(5) Uani 1 1 d . . .
C31 C 0.15554(19) 0.20309(10) 0.46564(15) 0.0154(5) Uani 1 1 d . . .
C32 C 0.1504(2) 0.24862(10) 0.52599(16) 0.0185(6) Uani 1 1 d . . .
H32A H 0.1956 0.2416 0.5724 0.022 Uiso 1 1 calc R . .
H32B H 0.1722 0.2812 0.5010 0.022 Uiso 1 1 calc R . .
C33 C 0.0412(2) 0.25414(10) 0.55260(15) 0.0169(5) Uani 1 1 d . . .
C34 C -0.01595(19) 0.22681(10) 0.48531(15) 0.0149(5) Uani 1 1 d . . .
C35 C -0.1182(2) 0.23111(10) 0.46875(15) 0.0165(5) Uani 1 1 d . . .
H35 H -0.1594 0.2510 0.5019 0.020 Uiso 1 1 calc R . .
C36 C -0.15891(19) 0.20585(10) 0.40295(16) 0.0158(5) Uani 1 1 d . . .
C37 C -0.26868(19) 0.20820(10) 0.37716(16) 0.0178(5) Uani 1 1 d . . .
C38 C -0.2678(2) 0.18214(11) 0.29493(16) 0.0188(6) Uani 1 1 d . . .
H38A H -0.2731 0.2088 0.2529 0.023 Uiso 1 1 calc R . .
H38B H -0.3258 0.1584 0.2883 0.023 Uiso 1 1 calc R . .
C39 C -0.16837(19) 0.15125(10) 0.28791(15) 0.0159(5) Uani 1 1 d . . .
C40 C -0.10157(19) 0.17419(10) 0.35530(15) 0.0148(5) Uani 1 1 d . . .
C41 C 0.1945(2) 0.15322(10) 0.50683(17) 0.0196(6) Uani 1 1 d . . .
H41A H 0.1510 0.1454 0.5516 0.023 Uiso 1 1 calc R . .
H41B H 0.1877 0.1242 0.4688 0.023 Uiso 1 1 calc R . .
C42 C 0.3030(2) 0.15538(13) 0.5382(2) 0.0321(7) Uani 1 1 d . . .
H42A H 0.3207 0.1224 0.5639 0.048 Uiso 1 1 calc R . .
H42B H 0.3107 0.1836 0.5766 0.048 Uiso 1 1 calc R . .
H42C H 0.3473 0.1614 0.4941 0.048 Uiso 1 1 calc R . .
C43 C 0.2243(2) 0.21864(11) 0.39770(17) 0.0211(6) Uani 1 1 d . . .
H43A H 0.2876 0.2327 0.4211 0.025 Uiso 1 1 calc R . .
H43B H 0.2411 0.1871 0.3677 0.025 Uiso 1 1 calc R . .
C44 C 0.1795(2) 0.25845(12) 0.34005(18) 0.0276(7) Uani 1 1 d . . .
H44A H 0.1194 0.2440 0.3134 0.041 Uiso 1 1 calc R . .
H44B H 0.2287 0.2672 0.3006 0.041 Uiso 1 1 calc R . .
H44C H 0.1614 0.2898 0.3691 0.041 Uiso 1 1 calc R . .
C45 C 0.0284(2) 0.22603(11) 0.63236(16) 0.0229(6) Uani 1 1 d . . .
H45A H 0.0487 0.1894 0.6259 0.028 Uiso 1 1 calc R . .
H45B H 0.0753 0.2418 0.6721 0.028 Uiso 1 1 calc R . .
C46 C -0.0760(3) 0.22688(14) 0.66519(19) 0.0343(8) Uani 1 1 d . . .
H46A H -0.0976 0.2629 0.6718 0.051 Uiso 1 1 calc R . .
H46B H -0.0750 0.2092 0.7165 0.051 Uiso 1 1 calc R . .
H46C H -0.1228 0.2091 0.6284 0.051 Uiso 1 1 calc R . .
C47 C 0.0098(2) 0.31148(10) 0.55726(16) 0.0181(6) Uani 1 1 d . . .
H47A H 0.0214 0.3281 0.5056 0.022(8) Uiso 1 1 calc R . .
H47B H -0.0630 0.3131 0.5663 0.016(7) Uiso 1 1 calc R . .
C48 C 0.0654(2) 0.34233(11) 0.62224(18) 0.0243(6) Uani 1 1 d . . .
H48A H 0.0454 0.3299 0.6742 0.037 Uiso 1 1 calc R . .
H48B H 0.0485 0.3791 0.6167 0.037 Uiso 1 1 calc R . .
H48C H 0.1378 0.3377 0.6175 0.037 Uiso 1 1 calc R . .
C49 C -0.3283(2) 0.17686(12) 0.43762(18) 0.0238(6) Uani 1 1 d . . .
H49A H -0.2995 0.1416 0.4415 0.029 Uiso 1 1 calc R . .
H49B H -0.3190 0.1934 0.4902 0.029 Uiso 1 1 calc R . .
C50 C -0.4407(2) 0.17213(15) 0.4184(2) 0.0421(9) Uani 1 1 d . . .
H50A H -0.4512 0.1556 0.3666 0.063 Uiso 1 1 calc R . .
H50B H -0.4711 0.2067 0.4172 0.063 Uiso 1 1 calc R . .
H50C H -0.4719 0.1511 0.4590 0.063 Uiso 1 1 calc R . .
C51 C -0.3096(2) 0.26434(11) 0.37294(18) 0.0258(7) Uani 1 1 d . . .
H51A H -0.3780 0.2634 0.3485 0.031 Uiso 1 1 calc R . .
H51B H -0.3152 0.2774 0.4276 0.031 Uiso 1 1 calc R . .
C52 C -0.2475(3) 0.30276(12) 0.3270(2) 0.0345(8) Uani 1 1 d . . .
H52A H -0.1784 0.3027 0.3485 0.052 Uiso 1 1 calc R . .
H52B H -0.2760 0.3375 0.3319 0.052 Uiso 1 1 calc R . .
H52C H -0.2481 0.2927 0.2711 0.052 Uiso 1 1 calc R . .
C53 C -0.1865(2) 0.09301(10) 0.30504(17) 0.0187(6) Uani 1 1 d . . .
H53A H -0.1210 0.0750 0.3060 0.022 Uiso 1 1 calc R . .
H53B H -0.2136 0.0899 0.3586 0.022 Uiso 1 1 calc R . .
C54 C -0.2578(2) 0.06450(12) 0.2464(2) 0.0277(7) Uani 1 1 d . . .
H54A H -0.2651 0.0284 0.2632 0.042 Uiso 1 1 calc R . .
H54B H -0.2303 0.0655 0.1934 0.042 Uiso 1 1 calc R . .
H54C H -0.3235 0.0815 0.2451 0.042 Uiso 1 1 calc R . .
C55 C -0.1273(2) 0.15832(11) 0.20441(16) 0.0188(6) Uani 1 1 d . . .
H55A H -0.0704 0.1342 0.1985 0.023 Uiso 1 1 calc R . .
H55B H -0.1803 0.1483 0.1649 0.023 Uiso 1 1 calc R . .
C56 C -0.0920(2) 0.21337(11) 0.18544(17) 0.0238(6) Uani 1 1 d . . .
H56A H -0.1493 0.2371 0.1858 0.036 Uiso 1 1 calc R . .
H56B H -0.0630 0.2138 0.1330 0.036 Uiso 1 1 calc R . .
H56C H -0.0414 0.2244 0.2254 0.036 Uiso 1 1 calc R . .
C57 C 0.04129(19) 0.02252(10) 0.43279(15) 0.0162(5) Uani 1 1 d . . .
C58 C 0.05357(19) -0.03052(10) 0.44913(15) 0.0164(5) Uani 1 1 d . . .
H58 H 0.0900 -0.0515 0.4141 0.020 Uiso 1 1 calc R . .
C59 C 0.0132(2) -0.05266(10) 0.51568(16) 0.0171(5) Uani 1 1 d . . .
H59 H 0.0229 -0.0885 0.5261 0.021 Uiso 1 1 calc R . .
Cl2 Cl 0.24259(9) 0.05458(5) -0.07539(7) 0.0662(3) Uani 1 1 d D . .
Cl3A Cl 0.43656(16) 0.05020(10) 0.00108(18) 0.1037(9) Uani 0.669(3) 1 d PD A 1
C60A C 0.3260(3) 0.0846(2) -0.0116(3) 0.0830(18) Uani 0.669(3) 1 d PD A 1
H60A H 0.2951 0.0888 0.0404 0.100 Uiso 0.669(3) 1 calc PR A 1
H60B H 0.3410 0.1195 -0.0321 0.100 Uiso 0.669(3) 1 calc PR A 1
Cl3B Cl 0.3827(3) 0.04419(19) 0.0550(3) 0.1037(9) Uani 0.331(3) 1 d PD A 2
C60B C 0.3260(3) 0.0846(2) -0.0116(3) 0.0830(18) Uani 0.331(3) 1 d PD A 2
H60C H 0.3780 0.1017 -0.0427 0.100 Uiso 0.331(3) 1 calc PR A 2
H60D H 0.2903 0.1119 0.0174 0.100 Uiso 0.331(3) 1 calc PR A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
P1 Au1 Cl1 177.32(3) . .
C29 P1 Si1 118.01(9) . .
C29 P1 Au1 121.44(8) . .
Si1 P1 Au1 120.20(4) . .
C57 Si1 C1 114.35(12) . .
C57 Si1 P1 121.14(9) . .
C1 Si1 P1 124.47(9) . .
C12 C1 C2 117.2(2) . .
C12 C1 Si1 121.36(19) . .
C2 C1 Si1 121.14(19) . .
C6 C2 C1 120.4(2) . .
C6 C2 C3 110.4(2) . .
C1 C2 C3 129.0(2) . .
C2 C3 C13 115.0(2) . .
C2 C3 C15 110.0(2) . .
C13 C3 C15 106.7(2) . .
C2 C3 C4 103.7(2) . .
C13 C3 C4 111.9(2) . .
C15 C3 C4 109.5(2) . .
C5 C4 C3 109.1(2) . .
C5 C4 H4A 109.9 . .
C3 C4 H4A 109.9 . .
C5 C4 H4B 109.9 . .
C3 C4 H4B 109.9 . .
H4A C4 H4B 108.3 . .
C6 C5 C19 110.7(2) . .
C6 C5 C17 111.3(2) . .
C19 C5 C17 111.3(2) . .
C6 C5 C4 102.2(2) . .
C19 C5 C4 111.3(2) . .
C17 C5 C4 109.7(2) . .
C7 C6 C2 121.0(3) . .
C7 C6 C5 125.6(2) . .
C2 C6 C5 113.3(2) . .
C6 C7 C8 119.4(3) . .
C6 C7 H7 120.3 . .
C8 C7 H7 120.3 . .
C12 C8 C7 120.6(2) . .
C12 C8 C9 113.5(2) . .
C7 C8 C9 125.8(2) . .
C8 C9 C21 112.2(2) . .
C8 C9 C23 110.2(2) . .
C21 C9 C23 111.1(2) . .
C8 C9 C10 102.4(2) . .
C21 C9 C10 110.9(2) . .
C23 C9 C10 109.8(2) . .
C11 C10 C9 109.4(2) . .
C11 C10 H10A 109.8 . .
C9 C10 H10A 109.8 . .
C11 C10 H10B 109.8 . .
C9 C10 H10B 109.8 . .
H10A C10 H10B 108.2 . .
C12 C11 C25 111.3(2) . .
C12 C11 C27 113.3(2) . .
C25 C11 C27 107.5(2) . .
C12 C11 C10 103.7(2) . .
C25 C11 C10 110.9(2) . .
C27 C11 C10 110.2(2) . .
C8 C12 C1 121.0(2) . .
C8 C12 C11 110.1(2) . .
C1 C12 C11 128.9(2) . .
C14 C13 C3 117.7(2) . .
C14 C13 H13A 107.9 . .
C3 C13 H13A 107.9 . .
C14 C13 H13B 107.9 . .
C3 C13 H13B 107.9 . .
H13A C13 H13B 107.2 . .
C13 C14 H14A 109.5 . .
C13 C14 H14B 109.5 . .
H14A C14 H14B 109.5 . .
C13 C14 H14C 109.5 . .
H14A C14 H14C 109.5 . .
H14B C14 H14C 109.5 . .
C16 C15 C3 116.7(3) . .
C16 C15 H15A 108.1 . .
C3 C15 H15A 108.1 . .
C16 C15 H15B 108.1 . .
C3 C15 H15B 108.1 . .
H15A C15 H15B 107.3 . .
C15 C16 H16A 109.5 . .
C15 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
C15 C16 H16C 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
C18 C17 C5 116.9(2) . .
C18 C17 H17A 108.1 . .
C5 C17 H17A 108.1 . .
C18 C17 H17B 108.1 . .
C5 C17 H17B 108.1 . .
H17A C17 H17B 107.3 . .
C17 C18 H18A 109.5 . .
C17 C18 H18B 109.5 . .
H18A C18 H18B 109.5 . .
C17 C18 H18C 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
C20 C19 C5 114.1(3) . .
C20 C19 H19A 108.7 . .
C5 C19 H19A 108.7 . .
C20 C19 H19B 108.7 . .
C5 C19 H19B 108.7 . .
H19A C19 H19B 107.6 . .
C19 C20 H20A 109.5 . .
C19 C20 H20B 109.5 . .
H20A C20 H20B 109.5 . .
C19 C20 H20C 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
C22 C21 C9 114.1(2) . .
C22 C21 H21A 108.7 . .
C9 C21 H21A 108.7 . .
C22 C21 H21B 108.7 . .
C9 C21 H21B 108.7 . .
H21A C21 H21B 107.6 . .
C21 C22 H22A 109.5 . .
C21 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
C21 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
C24 C23 C9 117.8(3) . .
C24 C23 H23A 107.9 . .
C9 C23 H23A 107.9 . .
C24 C23 H23B 107.9 . .
C9 C23 H23B 107.9 . .
H23A C23 H23B 107.2 . .
C23 C24 H24A 109.5 . .
C23 C24 H24B 109.5 . .
H24A C24 H24B 109.5 . .
C23 C24 H24C 109.5 . .
H24A C24 H24C 109.5 . .
H24B C24 H24C 109.5 . .
C26 C25 C11 116.5(2) . .
C26 C25 H25A 108.2 . .
C11 C25 H25A 108.2 . .
C26 C25 H25B 108.2 . .
C11 C25 H25B 108.2 . .
H25A C25 H25B 107.3 . .
C25 C26 H26A 109.5 . .
C25 C26 H26B 109.5 . .
H26A C26 H26B 109.5 . .
C25 C26 H26C 109.5 . .
H26A C26 H26C 109.5 . .
H26B C26 H26C 109.5 . .
C28 C27 C11 115.9(2) . .
C28 C27 H27A 108.3 . .
C11 C27 H27A 108.3 . .
C28 C27 H27B 108.3 . .
C11 C27 H27B 108.3 . .
H27A C27 H27B 107.4 . .
C27 C28 H28A 109.5 . .
C27 C28 H28B 109.5 . .
H28A C28 H28B 109.5 . .
C27 C28 H28C 109.5 . .
H28A C28 H28C 109.5 . .
H28B C28 H28C 109.5 . .
C30 C29 C40 118.2(2) . .
C30 C29 P1 119.99(19) . .
C40 C29 P1 121.66(19) . .
C34 C30 C29 120.3(2) . .
C34 C30 C31 109.8(2) . .
C29 C30 C31 129.8(2) . .
C30 C31 C41 110.4(2) . .
C30 C31 C43 113.1(2) . .
C41 C31 C43 110.6(2) . .
C30 C31 C32 102.3(2) . .
C41 C31 C32 110.8(2) . .
C43 C31 C32 109.3(2) . .
C33 C32 C31 108.9(2) . .
C33 C32 H32A 109.9 . .
C31 C32 H32A 109.9 . .
C33 C32 H32B 109.9 . .
C31 C32 H32B 109.9 . .
H32A C32 H32B 108.3 . .
C34 C33 C47 110.7(2) . .
C34 C33 C45 111.5(2) . .
C47 C33 C45 111.5(2) . .
C34 C33 C32 101.1(2) . .
C47 C33 C32 111.4(2) . .
C45 C33 C32 110.2(2) . .
C35 C34 C30 121.1(2) . .
C35 C34 C33 125.3(2) . .
C30 C34 C33 113.5(2) . .
C36 C35 C34 118.7(2) . .
C36 C35 H35 120.7 . .
C34 C35 H35 120.7 . .
C35 C36 C40 122.1(2) . .
C35 C36 C37 124.1(2) . .
C40 C36 C37 113.7(2) . .
C36 C37 C38 101.7(2) . .
C36 C37 C49 107.7(2) . .
C38 C37 C49 112.8(2) . .
C36 C37 C51 112.7(2) . .
C38 C37 C51 112.3(2) . .
C49 C37 C51 109.3(2) . .
C37 C38 C39 109.0(2) . .
C37 C38 H38A 109.9 . .
C39 C38 H38A 109.9 . .
C37 C38 H38B 109.9 . .
C39 C38 H38B 109.9 . .
H38A C38 H38B 108.3 . .
C40 C39 C55 114.6(2) . .
C40 C39 C53 108.9(2) . .
C55 C39 C53 110.4(2) . .
C40 C39 C38 102.7(2) . .
C55 C39 C38 109.9(2) . .
C53 C39 C38 110.0(2) . .
C36 C40 C29 119.3(2) . .
C36 C40 C39 109.7(2) . .
C29 C40 C39 131.0(2) . .
C42 C41 C31 115.2(2) . .
C42 C41 H41A 108.5 . .
C31 C41 H41A 108.5 . .
C42 C41 H41B 108.5 . .
C31 C41 H41B 108.5 . .
H41A C41 H41B 107.5 . .
C41 C42 H42A 109.5 . .
C41 C42 H42B 109.5 . .
H42A C42 H42B 109.5 . .
C41 C42 H42C 109.5 . .
H42A C42 H42C 109.5 . .
H42B C42 H42C 109.5 . .
C44 C43 C31 114.8(2) . .
C44 C43 H43A 108.6 . .
C31 C43 H43A 108.6 . .
C44 C43 H43B 108.6 . .
C31 C43 H43B 108.6 . .
H43A C43 H43B 107.5 . .
C43 C44 H44A 109.5 . .
C43 C44 H44B 109.5 . .
H44A C44 H44B 109.5 . .
C43 C44 H44C 109.5 . .
H44A C44 H44C 109.5 . .
H44B C44 H44C 109.5 . .
C46 C45 C33 116.3(2) . .
C46 C45 H45A 108.2 . .
C33 C45 H45A 108.2 . .
C46 C45 H45B 108.2 . .
C33 C45 H45B 108.2 . .
H45A C45 H45B 107.4 . .
C45 C46 H46A 109.5 . .
C45 C46 H46B 109.5 . .
H46A C46 H46B 109.5 . .
C45 C46 H46C 109.5 . .
H46A C46 H46C 109.5 . .
H46B C46 H46C 109.5 . .
C48 C47 C33 114.3(2) . .
C48 C47 H47A 108.7 . .
C33 C47 H47A 108.7 . .
C48 C47 H47B 108.7 . .
C33 C47 H47B 108.7 . .
H47A C47 H47B 107.6 . .
C47 C48 H48A 109.5 . .
C47 C48 H48B 109.5 . .
H48A C48 H48B 109.5 . .
C47 C48 H48C 109.5 . .
H48A C48 H48C 109.5 . .
H48B C48 H48C 109.5 . .
C50 C49 C37 115.2(3) . .
C50 C49 H49A 108.5 . .
C37 C49 H49A 108.5 . .
C50 C49 H49B 108.5 . .
C37 C49 H49B 108.5 . .
H49A C49 H49B 107.5 . .
C49 C50 H50A 109.5 . .
C49 C50 H50B 109.5 . .
H50A C50 H50B 109.5 . .
C49 C50 H50C 109.5 . .
H50A C50 H50C 109.5 . .
H50B C50 H50C 109.5 . .
C52 C51 C37 115.8(2) . .
C52 C51 H51A 108.3 . .
C37 C51 H51A 108.3 . .
C52 C51 H51B 108.3 . .
C37 C51 H51B 108.3 . .
H51A C51 H51B 107.4 . .
C51 C52 H52A 109.5 . .
C51 C52 H52B 109.5 . .
H52A C52 H52B 109.5 . .
C51 C52 H52C 109.5 . .
H52A C52 H52C 109.5 . .
H52B C52 H52C 109.5 . .
C54 C53 C39 116.1(2) . .
C54 C53 H53A 108.3 . .
C39 C53 H53A 108.3 . .
C54 C53 H53B 108.3 . .
C39 C53 H53B 108.3 . .
H53A C53 H53B 107.4 . .
C53 C54 H54A 109.5 . .
C53 C54 H54B 109.5 . .
H54A C54 H54B 109.5 . .
C53 C54 H54C 109.5 . .
H54A C54 H54C 109.5 . .
H54B C54 H54C 109.5 . .
C56 C55 C39 115.0(2) . .
C56 C55 H55A 108.5 . .
C39 C55 H55A 108.5 . .
C56 C55 H55B 108.5 . .
C39 C55 H55B 108.5 . .
H55A C55 H55B 107.5 . .
C55 C56 H56A 109.5 . .
C55 C56 H56B 109.5 . .
H56A C56 H56B 109.5 . .
C55 C56 H56C 109.5 . .
H56A C56 H56C 109.5 . .
H56B C56 H56C 109.5 . .
C59 C57 C58 118.8(2) 3_556 .
C59 C57 Si1 122.9(2) 3_556 .
C58 C57 Si1 118.3(2) . .
C59 C58 C57 121.0(2) . .
C59 C58 H58 119.5 . .
C57 C58 H58 119.5 . .
C58 C59 C57 120.2(2) . 3_556
C58 C59 H59 119.9 . .
C57 C59 H59 119.9 3_556 .
Cl2 C60A Cl3A 112.4(3) . .
Cl2 C60A H60A 109.1 . .
Cl3A C60A H60A 109.1 . .
Cl2 C60A H60B 109.1 . .
Cl3A C60A H60B 109.1 . .
H60A C60A H60B 107.9 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Au1 P1 2.2286(7) .
Au1 Cl1 2.2860(7) .
P1 C29 1.842(3) .
P1 Si1 2.0832(10) .
Si1 C57 1.850(3) .
Si1 C1 1.874(3) .
C1 C12 1.421(4) .
C1 C2 1.426(4) .
C2 C6 1.398(4) .
C2 C3 1.529(4) .
C3 C13 1.538(4) .
C3 C15 1.549(4) .
C3 C4 1.562(4) .
C4 C5 1.556(4) .
C4 H4A 0.9900 .
C4 H4B 0.9900 .
C5 C6 1.520(4) .
C5 C19 1.549(4) .
C5 C17 1.552(4) .
C6 C7 1.387(4) .
C7 C8 1.394(4) .
C7 H7 0.9500 .
C8 C12 1.391(4) .
C8 C9 1.516(4) .
C9 C21 1.539(4) .
C9 C23 1.548(4) .
C9 C10 1.552(4) .
C10 C11 1.552(4) .
C10 H10A 0.9900 .
C10 H10B 0.9900 .
C11 C12 1.536(4) .
C11 C25 1.540(4) .
C11 C27 1.542(4) .
C13 C14 1.522(4) .
C13 H13A 0.9900 .
C13 H13B 0.9900 .
C14 H14A 0.9800 .
C14 H14B 0.9800 .
C14 H14C 0.9800 .
C15 C16 1.521(5) .
C15 H15A 0.9900 .
C15 H15B 0.9900 .
C16 H16A 0.9800 .
C16 H16B 0.9800 .
C16 H16C 0.9800 .
C17 C18 1.516(4) .
C17 H17A 0.9900 .
C17 H17B 0.9900 .
C18 H18A 0.9800 .
C18 H18B 0.9800 .
C18 H18C 0.9800 .
C19 C20 1.529(4) .
C19 H19A 0.9900 .
C19 H19B 0.9900 .
C20 H20A 0.9800 .
C20 H20B 0.9800 .
C20 H20C 0.9800 .
C21 C22 1.532(4) .
C21 H21A 0.9900 .
C21 H21B 0.9900 .
C22 H22A 0.9800 .
C22 H22B 0.9800 .
C22 H22C 0.9800 .
C23 C24 1.517(4) .
C23 H23A 0.9900 .
C23 H23B 0.9900 .
C24 H24A 0.9800 .
C24 H24B 0.9800 .
C24 H24C 0.9800 .
C25 C26 1.530(4) .
C25 H25A 0.9900 .
C25 H25B 0.9900 .
C26 H26A 0.9800 .
C26 H26B 0.9800 .
C26 H26C 0.9800 .
C27 C28 1.522(4) .
C27 H27A 0.9900 .
C27 H27B 0.9900 .
C28 H28A 0.9800 .
C28 H28B 0.9800 .
C28 H28C 0.9800 .
C29 C30 1.418(4) .
C29 C40 1.419(3) .
C30 C34 1.393(4) .
C30 C31 1.543(3) .
C31 C41 1.545(4) .
C31 C43 1.548(4) .
C31 C32 1.559(4) .
C32 C33 1.547(4) .
C32 H32A 0.9900 .
C32 H32B 0.9900 .
C33 C34 1.521(3) .
C33 C47 1.541(4) .
C33 C45 1.546(4) .
C34 C35 1.388(4) .
C35 C36 1.384(4) .
C35 H35 0.9500 .
C36 C40 1.395(4) .
C36 C37 1.515(4) .
C37 C38 1.545(4) .
C37 C49 1.546(4) .
C37 C51 1.549(4) .
C38 C39 1.557(4) .
C38 H38A 0.9900 .
C38 H38B 0.9900 .
C39 C40 1.540(3) .
C39 C55 1.543(4) .
C39 C53 1.551(4) .
C41 C42 1.526(4) .
C41 H41A 0.9900 .
C41 H41B 0.9900 .
C42 H42A 0.9800 .
C42 H42B 0.9800 .
C42 H42C 0.9800 .
C43 C44 1.524(4) .
C43 H43A 0.9900 .
C43 H43B 0.9900 .
C44 H44A 0.9800 .
C44 H44B 0.9800 .
C44 H44C 0.9800 .
C45 C46 1.519(4) .
C45 H45A 0.9900 .
C45 H45B 0.9900 .
C46 H46A 0.9800 .
C46 H46B 0.9800 .
C46 H46C 0.9800 .
C47 C48 1.527(4) .
C47 H47A 0.9900 .
C47 H47B 0.9900 .
C48 H48A 0.9800 .
C48 H48B 0.9800 .
C48 H48C 0.9800 .
C49 C50 1.529(4) .
C49 H49A 0.9900 .
C49 H49B 0.9900 .
C50 H50A 0.9800 .
C50 H50B 0.9800 .
C50 H50C 0.9800 .
C51 C52 1.523(5) .
C51 H51A 0.9900 .
C51 H51B 0.9900 .
C52 H52A 0.9800 .
C52 H52B 0.9800 .
C52 H52C 0.9800 .
C53 C54 1.538(4) .
C53 H53A 0.9900 .
C53 H53B 0.9900 .
C54 H54A 0.9800 .
C54 H54B 0.9800 .
C54 H54C 0.9800 .
C55 C56 1.534(4) .
C55 H55A 0.9900 .
C55 H55B 0.9900 .
C56 H56A 0.9800 .
C56 H56B 0.9800 .
C56 H56C 0.9800 .
C57 C59 1.393(4) 3_556
C57 C58 1.405(4) .
C58 C59 1.388(4) .
C58 H58 0.9500 .
C59 C57 1.393(4) 3_556
C59 H59 0.9500 .
Cl2 C60A 1.707(5) .
Cl3A C60A 1.729(4) .
C60A H60A 0.9900 .
C60A H60B 0.9900 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C29 P1 Si1 C57 -4.75(14) . .
Au1 P1 Si1 C57 -178.17(10) . .
C29 P1 Si1 C1 177.45(13) . .
Au1 P1 Si1 C1 4.03(12) . .
C57 Si1 C1 C12 91.7(2) . .
P1 Si1 C1 C12 -90.3(2) . .
C57 Si1 C1 C2 -81.9(2) . .
P1 Si1 C1 C2 96.0(2) . .
C12 C1 C2 C6 -4.7(4) . .
Si1 C1 C2 C6 169.3(2) . .
C12 C1 C2 C3 169.2(3) . .
Si1 C1 C2 C3 -16.9(4) . .
C6 C2 C3 C13 -123.3(3) . .
C1 C2 C3 C13 62.4(4) . .
C6 C2 C3 C15 116.3(3) . .
C1 C2 C3 C15 -58.0(4) . .
C6 C2 C3 C4 -0.7(3) . .
C1 C2 C3 C4 -175.0(3) . .
C2 C3 C4 C5 -6.3(3) . .
C13 C3 C4 C5 118.3(3) . .
C15 C3 C4 C5 -123.6(3) . .
C3 C4 C5 C6 10.2(3) . .
C3 C4 C5 C19 128.4(2) . .
C3 C4 C5 C17 -108.0(3) . .
C1 C2 C6 C7 4.9(4) . .
C3 C2 C6 C7 -170.1(3) . .
C1 C2 C6 C5 -177.3(2) . .
C3 C2 C6 C5 7.8(3) . .
C19 C5 C6 C7 48.0(4) . .
C17 C5 C6 C7 -76.4(4) . .
C4 C5 C6 C7 166.6(3) . .
C19 C5 C6 C2 -129.7(3) . .
C17 C5 C6 C2 105.9(3) . .
C4 C5 C6 C2 -11.2(3) . .
C2 C6 C7 C8 0.4(4) . .
C5 C6 C7 C8 -177.2(3) . .
C6 C7 C8 C12 -5.7(4) . .
C6 C7 C8 C9 172.4(3) . .
C12 C8 C9 C21 -128.4(3) . .
C7 C8 C9 C21 53.3(4) . .
C12 C8 C9 C23 107.2(3) . .
C7 C8 C9 C23 -71.0(3) . .
C12 C8 C9 C10 -9.5(3) . .
C7 C8 C9 C10 172.2(3) . .
C8 C9 C10 C11 7.1(3) . .
C21 C9 C10 C11 127.0(2) . .
C23 C9 C10 C11 -109.9(3) . .
C9 C10 C11 C12 -2.9(3) . .
C9 C10 C11 C25 -122.4(2) . .
C9 C10 C11 C27 118.6(2) . .
C7 C8 C12 C1 5.8(4) . .
C9 C8 C12 C1 -172.6(2) . .
C7 C8 C12 C11 -173.5(2) . .
C9 C8 C12 C11 8.2(3) . .
C2 C1 C12 C8 -0.6(4) . .
Si1 C1 C12 C8 -174.5(2) . .
C2 C1 C12 C11 178.5(2) . .
Si1 C1 C12 C11 4.6(4) . .
C25 C11 C12 C8 116.2(3) . .
C27 C11 C12 C8 -122.5(3) . .
C10 C11 C12 C8 -3.0(3) . .
C25 C11 C12 C1 -63.0(3) . .
C27 C11 C12 C1 58.3(4) . .
C10 C11 C12 C1 177.8(3) . .
C2 C3 C13 C14 63.8(3) . .
C15 C3 C13 C14 -173.9(2) . .
C4 C3 C13 C14 -54.2(3) . .
C2 C3 C15 C16 -48.5(3) . .
C13 C3 C15 C16 -173.8(3) . .
C4 C3 C15 C16 64.8(3) . .
C6 C5 C17 C18 67.5(3) . .
C19 C5 C17 C18 -56.5(4) . .
C4 C5 C17 C18 179.9(3) . .
C6 C5 C19 C20 -179.6(3) . .
C17 C5 C19 C20 -55.3(4) . .
C4 C5 C19 C20 67.5(3) . .
C8 C9 C21 C22 -179.7(3) . .
C23 C9 C21 C22 -55.8(3) . .
C10 C9 C21 C22 66.5(3) . .
C8 C9 C23 C24 68.8(3) . .
C21 C9 C23 C24 -56.2(3) . .
C10 C9 C23 C24 -179.2(3) . .
C12 C11 C25 C26 -59.5(3) . .
C27 C11 C25 C26 175.9(2) . .
C10 C11 C25 C26 55.3(3) . .
C12 C11 C27 C28 51.1(3) . .
C25 C11 C27 C28 174.4(2) . .
C10 C11 C27 C28 -64.6(3) . .
Si1 P1 C29 C30 94.0(2) . .
Au1 P1 C29 C30 -92.7(2) . .
Si1 P1 C29 C40 -90.7(2) . .
Au1 P1 C29 C40 82.6(2) . .
C40 C29 C30 C34 5.6(4) . .
P1 C29 C30 C34 -178.97(19) . .
C40 C29 C30 C31 -171.4(2) . .
P1 C29 C30 C31 4.1(4) . .
C34 C30 C31 C41 108.7(2) . .
C29 C30 C31 C41 -74.0(3) . .
C34 C30 C31 C43 -126.7(2) . .
C29 C30 C31 C43 50.5(4) . .
C34 C30 C31 C32 -9.3(3) . .
C29 C30 C31 C32 168.0(3) . .
C30 C31 C32 C33 18.9(3) . .
C41 C31 C32 C33 -98.9(3) . .
C43 C31 C32 C33 139.0(2) . .
C31 C32 C33 C34 -20.7(3) . .
C31 C32 C33 C47 -138.3(2) . .
C31 C32 C33 C45 97.4(3) . .
C29 C30 C34 C35 -2.8(4) . .
C31 C30 C34 C35 174.7(2) . .
C29 C30 C34 C33 178.5(2) . .
C31 C30 C34 C33 -3.9(3) . .
C47 C33 C34 C35 -45.2(3) . .
C45 C33 C34 C35 79.6(3) . .
C32 C33 C34 C35 -163.3(3) . .
C47 C33 C34 C30 133.4(2) . .
C45 C33 C34 C30 -101.8(3) . .
C32 C33 C34 C30 15.3(3) . .
C30 C34 C35 C36 -1.7(4) . .
C33 C34 C35 C36 176.8(2) . .
C34 C35 C36 C40 3.3(4) . .
C34 C35 C36 C37 -178.7(2) . .
C35 C36 C37 C38 170.3(3) . .
C40 C36 C37 C38 -11.5(3) . .
C35 C36 C37 C49 -70.9(3) . .
C40 C36 C37 C49 107.3(3) . .
C35 C36 C37 C51 49.8(4) . .
C40 C36 C37 C51 -132.0(3) . .
C36 C37 C38 C39 17.4(3) . .
C49 C37 C38 C39 -97.7(3) . .
C51 C37 C38 C39 138.2(2) . .
C37 C38 C39 C40 -17.0(3) . .
C37 C38 C39 C55 -139.4(2) . .
C37 C38 C39 C53 98.8(2) . .
C35 C36 C40 C29 -0.5(4) . .
C37 C36 C40 C29 -178.6(2) . .
C35 C36 C40 C39 179.3(2) . .
C37 C36 C40 C39 1.1(3) . .
C30 C29 C40 C36 -4.0(4) . .
P1 C29 C40 C36 -179.34(19) . .
C30 C29 C40 C39 176.4(2) . .
P1 C29 C40 C39 1.0(4) . .
C55 C39 C40 C36 129.0(2) . .
C53 C39 C40 C36 -106.8(2) . .
C38 C39 C40 C36 9.8(3) . .
C55 C39 C40 C29 -51.3(4) . .
C53 C39 C40 C29 72.8(3) . .
C38 C39 C40 C29 -170.5(3) . .
C30 C31 C41 C42 -178.7(2) . .
C43 C31 C41 C42 55.3(3) . .
C32 C31 C41 C42 -66.1(3) . .
C30 C31 C43 C44 40.6(3) . .
C41 C31 C43 C44 165.0(2) . .
C32 C31 C43 C44 -72.7(3) . .
C34 C33 C45 C46 -67.0(3) . .
C47 C33 C45 C46 57.3(3) . .
C32 C33 C45 C46 -178.5(2) . .
C34 C33 C47 C48 -178.7(2) . .
C45 C33 C47 C48 56.6(3) . .
C32 C33 C47 C48 -67.0(3) . .
C36 C37 C49 C50 -176.5(3) . .
C38 C37 C49 C50 -65.0(3) . .
C51 C37 C49 C50 60.7(3) . .
C36 C37 C51 C52 50.0(3) . .
C38 C37 C51 C52 -64.3(3) . .
C49 C37 C51 C52 169.8(2) . .
C40 C39 C53 C54 176.1(2) . .
C55 C39 C53 C54 -57.3(3) . .
C38 C39 C53 C54 64.2(3) . .
C40 C39 C55 C56 -48.0(3) . .
C53 C39 C55 C56 -171.5(2) . .
C38 C39 C55 C56 67.0(3) . .
C1 Si1 C57 C59 177.5(2) . 3_556
P1 Si1 C57 C59 -0.5(3) . 3_556
C1 Si1 C57 C58 -2.8(2) . .
P1 Si1 C57 C58 179.24(17) . .
C59 C57 C58 C59 -0.7(4) 3_556 .
Si1 C57 C58 C59 179.6(2) . .
C57 C58 C59 C57 0.7(4) . 3_556
