#------------------------------------------------------------------------------
#$Date: 2016-03-21 07:01:35 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178545 $
#$URL: svn://www.crystallography.net/cod/cif/4/06/52/4065205.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4065205
loop_
_publ_author_name
'Ou, Ya-Ping'
'Jiang, Chuanyin'
'Wu, Di'
'Xia, Jianlong'
'Yin, Jun'
'Jin, Shan'
'Yu, Guang-Ao'
'Liu, Sheng Hua'
_publ_section_title
;
 Synthesis, Characterization, and Properties of Anthracene-Bridged
 Bimetallic Ruthenium Vinyl Complexes
 [RuCl(CO)(PMe3)3]2(μ-CH═CH-anthracene-CH═CH)
;
_journal_issue                   21
_journal_name_full               Organometallics
_journal_page_first              5763
_journal_paper_doi               10.1021/om200622q
_journal_volume                  30
_journal_year                    2011
_chemical_formula_sum            'C21 H35 Cl7 O P3 Ru'
_chemical_formula_weight         745.62
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 97.221(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   10.3117(19)
_cell_length_b                   12.025(2)
_cell_length_c                   27.538(5)
_cell_measurement_reflns_used    2715
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      20.78
_cell_measurement_theta_min      2.21
_cell_volume                     3387.6(10)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0671
_diffrn_reflns_av_sigmaI/netI    0.0680
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            19848
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         1.85
_exptl_absorpt_coefficient_mu    1.170
_exptl_absorpt_correction_T_max  0.8919
_exptl_absorpt_correction_T_min  0.8348
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.462
_exptl_crystal_density_meas      0
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1508
_exptl_crystal_size_max          0.16
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.10
_refine_diff_density_max         0.871
_refine_diff_density_min         -1.154
_refine_diff_density_rms         0.113
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.182
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     307
_refine_ls_number_reflns         5969
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.182
_refine_ls_R_factor_all          0.1098
_refine_ls_R_factor_gt           0.0873
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0703P)²+9.0836P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1818
_refine_ls_wR_factor_ref         0.1917
_reflns_number_gt                4746
_reflns_number_total             5969
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om200622q_si_002.cif
_cod_data_source_block           t
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_cell_volume        3387.5(11)
_cod_original_sg_symbol_H-M      P2(1)/n
_cod_database_code               4065205
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.3568(11) 0.0577(8) 0.7634(5) 0.091(4) Uani 1 1 d .
H1A H 0.3992 0.0167 0.7908 0.136 Uiso 1 1 calc R
H1B H 0.4066 0.0511 0.7364 0.136 Uiso 1 1 calc R
H1C H 0.2706 0.0283 0.7542 0.136 Uiso 1 1 calc R
C2 C 0.3053(17) 0.2690(11) 0.7206(5) 0.135(6) Uani 1 1 d .
H2A H 0.3782 0.2633 0.7023 0.202 Uiso 1 1 calc R
H2B H 0.2860 0.3460 0.7255 0.202 Uiso 1 1 calc R
H2C H 0.2305 0.2335 0.7029 0.202 Uiso 1 1 calc R
C3 C 0.1891(10) 0.2033(13) 0.8038(5) 0.131(6) Uani 1 1 d .
H3A H 0.1202 0.1885 0.7778 0.197 Uiso 1 1 calc R
H3B H 0.1759 0.2752 0.8175 0.197 Uiso 1 1 calc R
H3C H 0.1887 0.1475 0.8287 0.197 Uiso 1 1 calc R
C4 C 0.8337(10) 0.2870(11) 0.7877(5) 0.103(4) Uani 1 1 d .
H4A H 0.8636 0.3121 0.8202 0.155 Uiso 1 1 calc R
H4B H 0.8138 0.3501 0.7667 0.155 Uiso 1 1 calc R
H4C H 0.9008 0.2434 0.7756 0.155 Uiso 1 1 calc R
C5 C 0.7583(14) 0.0698(10) 0.8074(5) 0.117(5) Uani 1 1 d .
H5A H 0.6930 0.0127 0.8022 0.175 Uiso 1 1 calc R
H5B H 0.7917 0.0729 0.8415 0.175 Uiso 1 1 calc R
H5C H 0.8283 0.0535 0.7886 0.175 Uiso 1 1 calc R
C6 C 0.6481(13) 0.1851(13) 0.7219(4) 0.117(5) Uani 1 1 d .
H6A H 0.7164 0.1433 0.7097 0.175 Uiso 1 1 calc R
H6B H 0.6412 0.2570 0.7066 0.175 Uiso 1 1 calc R
H6C H 0.5667 0.1462 0.7147 0.175 Uiso 1 1 calc R
C7 C 0.8100(10) 0.2582(10) 0.9188(5) 0.097(4) Uani 1 1 d .
H7A H 0.8619 0.2933 0.9459 0.146 Uiso 1 1 calc R
H7B H 0.8616 0.2484 0.8924 0.146 Uiso 1 1 calc R
H7C H 0.7806 0.1870 0.9288 0.146 Uiso 1 1 calc R
C8 C 0.7387(14) 0.4826(10) 0.8879(5) 0.115(5) Uani 1 1 d .
H8A H 0.6698 0.5358 0.8800 0.172 Uiso 1 1 calc R
H8B H 0.7903 0.4778 0.8613 0.172 Uiso 1 1 calc R
H8C H 0.7930 0.5058 0.9170 0.172 Uiso 1 1 calc R
C9 C 0.6011(12) 0.3639(12) 0.9555(4) 0.108(5) Uani 1 1 d .
H9A H 0.5626 0.2953 0.9643 0.162 Uiso 1 1 calc R
H9B H 0.5356 0.4210 0.9519 0.162 Uiso 1 1 calc R
H9C H 0.6698 0.3847 0.9807 0.162 Uiso 1 1 calc R
C10 C 0.5208(8) 0.4087(8) 0.7978(3) 0.055(2) Uani 1 1 d .
C11 C 0.3783(7) 0.3442(6) 0.8719(3) 0.0386(17) Uani 1 1 d .
H11 H 0.3447 0.2933 0.8924 0.046 Uiso 1 1 calc R
C12 C 0.3275(8) 0.4445(7) 0.8732(3) 0.047(2) Uani 1 1 d .
H12 H 0.3552 0.4970 0.8519 0.057 Uiso 1 1 calc R
C13 C 0.2297(8) 0.4826(7) 0.9054(3) 0.0448(19) Uani 1 1 d .
C14 C 0.1850(7) 0.4173(6) 0.9405(3) 0.0420(18) Uani 1 1 d .
H14 H 0.2163 0.3450 0.9448 0.050 Uiso 1 1 calc R
C15 C 0.0917(7) 0.4566(6) 0.9707(3) 0.0328(16) Uani 1 1 d .
C16 C 0.0441(7) 0.5694(6) 0.9644(3) 0.0359(17) Uani 1 1 d .
C17 C 0.0940(8) 0.6360(7) 0.9281(3) 0.054(2) Uani 1 1 d .
H17 H 0.0654 0.7090 0.9233 0.065 Uiso 1 1 calc R
C18 C 0.1823(9) 0.5941(7) 0.9008(3) 0.059(2) Uani 1 1 d .
H18 H 0.2138 0.6402 0.8778 0.071 Uiso 1 1 calc R
C19 C -0.0475(7) 0.6070(6) 0.9935(3) 0.0415(18) Uani 1 1 d .
H19 H -0.0803 0.6787 0.9885 0.050 Uiso 1 1 calc R
C20 C 0.6170(13) 0.8294(11) 0.9028(5) 0.107(4) Uani 1 1 d .
H20 H 0.5841 0.9048 0.9071 0.128 Uiso 1 1 calc R
C21 C 0.2366(16) 0.0106(11) 0.9358(6) 0.126(6) Uani 1 1 d .
H21 H 0.3050 0.0593 0.9260 0.151 Uiso 1 1 calc R
Cl1 Cl 0.5109(2) 0.10734(19) 0.88237(9) 0.0630(6) Uani 1 1 d .
Cl2 Cl 0.5419(5) 0.7766(4) 0.84806(19) 0.1579(18) Uani 1 1 d .
Cl3 Cl 0.7823(4) 0.8360(4) 0.90133(16) 0.1443(16) Uani 1 1 d .
Cl4 Cl 0.5855(6) 0.7489(5) 0.9521(2) 0.187(2) Uani 1 1 d .
Cl5 Cl 0.1968(10) -0.0800(5) 0.8902(3) 0.292(5) Uani 1 1 d .
Cl6 Cl 0.2998(9) -0.0557(6) 0.9881(3) 0.277(4) Uani 1 1 d .
Cl7 Cl 0.1102(6) 0.0925(5) 0.9468(3) 0.199(3) Uani 1 1 d .
O1 O 0.5197(7) 0.4865(6) 0.7769(3) 0.077(2) Uani 1 1 d .
P1 P 0.3455(2) 0.2011(2) 0.77981(9) 0.0609(7) Uani 1 1 d .
P2 P 0.6865(3) 0.2020(2) 0.78847(10) 0.0642(7) Uani 1 1 d .
P3 P 0.6678(2) 0.3461(2) 0.89815(9) 0.0584(6) Uani 1 1 d .
Ru1 Ru 0.51998(5) 0.27810(5) 0.83240(2) 0.0331(2) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
P1 C1 H1A 109.5 .
P1 C1 H1B 109.5 .
H1A C1 H1B 109.5 .
P1 C1 H1C 109.5 .
H1A C1 H1C 109.5 .
H1B C1 H1C 109.5 .
P1 C2 H2A 109.5 .
P1 C2 H2B 109.5 .
H2A C2 H2B 109.5 .
P1 C2 H2C 109.5 .
H2A C2 H2C 109.5 .
H2B C2 H2C 109.5 .
P1 C3 H3A 109.5 .
P1 C3 H3B 109.5 .
H3A C3 H3B 109.5 .
P1 C3 H3C 109.5 .
H3A C3 H3C 109.5 .
H3B C3 H3C 109.5 .
P2 C4 H4A 109.5 .
P2 C4 H4B 109.5 .
H4A C4 H4B 109.5 .
P2 C4 H4C 109.5 .
H4A C4 H4C 109.5 .
H4B C4 H4C 109.5 .
P2 C5 H5A 109.5 .
P2 C5 H5B 109.5 .
H5A C5 H5B 109.5 .
P2 C5 H5C 109.5 .
H5A C5 H5C 109.5 .
H5B C5 H5C 109.5 .
P2 C6 H6A 109.5 .
P2 C6 H6B 109.5 .
H6A C6 H6B 109.5 .
P2 C6 H6C 109.5 .
H6A C6 H6C 109.5 .
H6B C6 H6C 109.5 .
P3 C7 H7A 109.5 .
P3 C7 H7B 109.5 .
H7A C7 H7B 109.5 .
P3 C7 H7C 109.5 .
H7A C7 H7C 109.5 .
H7B C7 H7C 109.5 .
P3 C8 H8A 109.5 .
P3 C8 H8B 109.5 .
H8A C8 H8B 109.5 .
P3 C8 H8C 109.5 .
H8A C8 H8C 109.5 .
H8B C8 H8C 109.5 .
P3 C9 H9A 109.5 .
P3 C9 H9B 109.5 .
H9A C9 H9B 109.5 .
P3 C9 H9C 109.5 .
H9A C9 H9C 109.5 .
H9B C9 H9C 109.5 .
O1 C10 Ru1 179.1(9) .
C12 C11 Ru1 132.1(6) .
C12 C11 H11 114.0 .
Ru1 C11 H11 114.0 .
C11 C12 C13 126.6(7) .
C11 C12 H12 116.7 .
C13 C12 H12 116.7 .
C14 C13 C18 117.3(7) .
C14 C13 C12 123.7(7) .
C18 C13 C12 119.0(7) .
C13 C14 C15 122.2(7) .
C13 C14 H14 118.9 .
C15 C14 H14 118.9 .
C19 C15 C14 122.9(7) 3_567
C19 C15 C16 118.2(6) 3_567
C14 C15 C16 118.8(6) .
C19 C16 C17 123.5(7) .
C19 C16 C15 118.7(7) .
C17 C16 C15 117.8(6) .
C18 C17 C16 120.5(7) .
C18 C17 H17 119.7 .
C16 C17 H17 119.7 .
C17 C18 C13 123.3(8) .
C17 C18 H18 118.3 .
C13 C18 H18 118.3 .
C15 C19 C16 123.0(7) 3_567
C15 C19 H19 118.5 3_567
C16 C19 H19 118.5 .
Cl3 C20 Cl2 109.5(7) .
Cl3 C20 Cl4 109.3(7) .
Cl2 C20 Cl4 111.7(9) .
Cl3 C20 H20 108.7 .
Cl2 C20 H20 108.7 .
Cl4 C20 H20 108.7 .
Cl5 C21 Cl7 113.1(11) .
Cl5 C21 Cl6 111.1(8) .
Cl7 C21 Cl6 110.1(9) .
Cl5 C21 H21 107.4 .
Cl7 C21 H21 107.4 .
Cl6 C21 H21 107.4 .
C1 P1 C3 101.2(6) .
C1 P1 C2 102.7(6) .
C3 P1 C2 101.9(8) .
C1 P1 Ru1 117.7(4) .
C3 P1 Ru1 114.5(4) .
C2 P1 Ru1 116.4(5) .
C5 P2 C4 100.7(6) .
C5 P2 C6 102.7(6) .
C4 P2 C6 97.2(6) .
C5 P2 Ru1 118.9(4) .
C4 P2 Ru1 116.1(4) .
C6 P2 Ru1 117.8(4) .
C9 P3 C8 103.4(7) .
C9 P3 C7 100.0(6) .
C8 P3 C7 104.2(6) .
C9 P3 Ru1 115.4(4) .
C8 P3 Ru1 115.0(4) .
C7 P3 Ru1 116.8(4) .
C10 Ru1 C11 89.7(3) .
C10 Ru1 P1 94.0(3) .
C11 Ru1 P1 86.5(2) .
C10 Ru1 P3 93.3(3) .
C11 Ru1 P3 84.0(2) .
P1 Ru1 P3 167.99(10) .
C10 Ru1 P2 90.8(3) .
C11 Ru1 P2 178.8(2) .
P1 Ru1 P2 94.59(10) .
P3 Ru1 P2 94.84(10) .
C10 Ru1 Cl1 176.7(3) .
C11 Ru1 Cl1 87.1(2) .
P1 Ru1 Cl1 86.36(9) .
P3 Ru1 Cl1 85.82(9) .
P2 Ru1 Cl1 92.49(9) .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 P1 1.790(10) .
C1 H1A 0.9600 .
C1 H1B 0.9600 .
C1 H1C 0.9600 .
C2 P1 1.824(13) .
C2 H2A 0.9600 .
C2 H2B 0.9600 .
C2 H2C 0.9600 .
C3 P1 1.818(12) .
C3 H3A 0.9600 .
C3 H3B 0.9600 .
C3 H3C 0.9600 .
C4 P2 1.832(11) .
C4 H4A 0.9600 .
C4 H4B 0.9600 .
C4 H4C 0.9600 .
C5 P2 1.803(11) .
C5 H5A 0.9600 .
C5 H5B 0.9600 .
C5 H5C 0.9600 .
C6 P2 1.837(11) .
C6 H6A 0.9600 .
C6 H6B 0.9600 .
C6 H6C 0.9600 .
C7 P3 1.838(10) .
C7 H7A 0.9600 .
C7 H7B 0.9600 .
C7 H7C 0.9600 .
C8 P3 1.834(11) .
C8 H8A 0.9600 .
C8 H8B 0.9600 .
C8 H8C 0.9600 .
C9 P3 1.813(11) .
C9 H9A 0.9600 .
C9 H9B 0.9600 .
C9 H9C 0.9600 .
C10 O1 1.096(10) .
C10 Ru1 1.838(10) .
C11 C12 1.318(10) .
C11 Ru1 2.085(6) .
C11 H11 0.9300 .
C12 C13 1.495(10) .
C12 H12 0.9300 .
C13 C14 1.369(10) .
C13 C18 1.427(11) .
C14 C15 1.430(9) .
C14 H14 0.9300 .
C15 C19 1.369(10) 3_567
C15 C16 1.445(10) .
C16 C19 1.390(10) .
C16 C17 1.425(10) .
C17 C18 1.350(11) .
C17 H17 0.9300 .
C18 H18 0.9300 .
C19 C15 1.370(10) 3_567
C19 H19 0.9300 .
C20 Cl3 1.711(14) .
C20 Cl2 1.728(15) .
C20 Cl4 1.730(13) .
C20 H20 0.9800 .
C21 Cl5 1.673(16) .
C21 Cl7 1.691(14) .
C21 Cl6 1.703(17) .
C21 H21 0.9800 .
Cl1 Ru1 2.480(2) .
P1 Ru1 2.353(2) .
P2 Ru1 2.403(2) .
P3 Ru1 2.361(2) .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
C20 H20 Cl1 0.98 2.61 3.540(12) 157.3 1_565
C21 H21 Cl1 0.98 2.63 3.544(14) 155.1 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
Ru1 C11 C12 C13 -176.8(6) . .
C11 C12 C13 C14 3.8(14) . .
C11 C12 C13 C18 -178.2(9) . .
C18 C13 C14 C15 1.8(12) . .
C12 C13 C14 C15 179.8(7) . .
C13 C14 C15 C19 -179.0(8) . 3_567
C13 C14 C15 C16 -0.6(11) . .
C19 C15 C16 C19 -2.1(12) 3_567 .
C14 C15 C16 C19 179.4(7) . .
C19 C15 C16 C17 178.0(7) 3_567 .
C14 C15 C16 C17 -0.5(10) . .
C19 C16 C17 C18 -179.6(9) . .
C15 C16 C17 C18 0.3(13) . .
C16 C17 C18 C13 1.0(15) . .
C14 C13 C18 C17 -2.0(14) . .
C12 C13 C18 C17 179.9(9) . .
C17 C16 C19 C15 -177.9(8) . 3_567
C15 C16 C19 C15 2.3(12) . 3_567
O1 C10 Ru1 C11 -60(57) . .
O1 C10 Ru1 P1 26(57) . .
O1 C10 Ru1 P3 -144(57) . .
O1 C10 Ru1 P2 121(57) . .
O1 C10 Ru1 Cl1 -70(58) . .
C12 C11 Ru1 C10 -7.0(8) . .
C12 C11 Ru1 P1 -101.0(8) . .
C12 C11 Ru1 P3 86.4(8) . .
C12 C11 Ru1 P2 104(11) . .
C12 C11 Ru1 Cl1 172.5(8) . .
C1 P1 Ru1 C10 137.9(6) . .
C3 P1 Ru1 C10 -103.3(7) . .
C2 P1 Ru1 C10 15.3(6) . .
C1 P1 Ru1 C11 -132.7(6) . .
C3 P1 Ru1 C11 -13.9(6) . .
C2 P1 Ru1 C11 104.7(6) . .
C1 P1 Ru1 P3 -94.9(7) . .
C3 P1 Ru1 P3 23.9(8) . .
C2 P1 Ru1 P3 142.5(7) . .
C1 P1 Ru1 P2 46.8(5) . .
C3 P1 Ru1 P2 165.6(6) . .
C2 P1 Ru1 P2 -75.8(6) . .
C1 P1 Ru1 Cl1 -45.4(5) . .
C3 P1 Ru1 Cl1 73.3(6) . .
C2 P1 Ru1 Cl1 -168.0(6) . .
C9 P3 Ru1 C10 113.1(6) . .
C8 P3 Ru1 C10 -7.2(6) . .
C7 P3 Ru1 C10 -129.8(6) . .
C9 P3 Ru1 C11 23.8(6) . .
C8 P3 Ru1 C11 -96.5(6) . .
C7 P3 Ru1 C11 140.9(6) . .
C9 P3 Ru1 P1 -14.2(7) . .
C8 P3 Ru1 P1 -134.5(7) . .
C7 P3 Ru1 P1 102.9(7) . .
C9 P3 Ru1 P2 -155.8(5) . .
C8 P3 Ru1 P2 83.9(5) . .
C7 P3 Ru1 P2 -38.7(5) . .
C9 P3 Ru1 Cl1 -63.7(5) . .
C8 P3 Ru1 Cl1 176.0(5) . .
C7 P3 Ru1 Cl1 53.4(5) . .
C5 P2 Ru1 C10 172.8(7) . .
C4 P2 Ru1 C10 52.5(6) . .
C6 P2 Ru1 C10 -62.0(6) . .
C5 P2 Ru1 C11 61(11) . .
C4 P2 Ru1 C11 -59(11) . .
C6 P2 Ru1 C11 -173(11) . .
C5 P2 Ru1 P1 -93.1(6) . .
C4 P2 Ru1 P1 146.6(5) . .
C6 P2 Ru1 P1 32.1(6) . .
C5 P2 Ru1 P3 79.5(6) . .
C4 P2 Ru1 P3 -40.9(5) . .
C6 P2 Ru1 P3 -155.4(6) . .
C5 P2 Ru1 Cl1 -6.5(6) . .
C4 P2 Ru1 Cl1 -126.9(5) . .
C6 P2 Ru1 Cl1 118.6(6) . .
