#------------------------------------------------------------------------------
#$Date: 2016-03-21 07:12:46 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178553 $
#$URL: svn://www.crystallography.net/cod/cif/4/06/61/4066187.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4066187
loop_
_publ_author_name
'Štěpnička, Petr'
'Schulz, Jiří'
'Klemann, Thorsten'
'Siemeling, Ulrich'
'Císařová, Ivana'
_publ_section_title
;
 Synthesis, Structural Characterization, and Catalytic Evaluation of
 Palladium Complexes with Homologous Ferrocene-Based Pyridylphosphine
 Ligands
;
_journal_issue                   14
_journal_name_full               Organometallics
_journal_page_first              3187
_journal_paper_doi               10.1021/om100339p
_journal_volume                  29
_journal_year                    2010
_chemical_formula_moiety         'C37 H36 Fe N2 P Pd, F6 Sb'
_chemical_formula_sum            'C37 H36 F6 Fe N2 P Pd Sb'
_chemical_formula_weight         937.65
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 126.225(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   24.1524(12)
_cell_length_b                   18.5909(8)
_cell_length_c                   19.7994(11)
_cell_measurement_reflns_used    46205
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      2.2
_cell_volume                     7171.8(7)
_computing_cell_refinement
'Dirax/lsq (Duisenberg & Schreurs, 1989-2000)'
_computing_data_collection       'Collect (Nonius BV, 1997-2000)'
_computing_data_reduction        'EvalCCD (Duisenberg & Schreurs 1990-2000)'
_computing_molecular_graphics    'PLATON (Spek, 2001)'
_computing_publication_material  'PLATON (Spek, 2001)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SIR97 (Altomare et al., 1994)'
_diffrn_ambient_temperature      150(2)
_diffrn_detector_area_resol_mean 9.091
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  KappaCCD
_diffrn_measurement_method       'ω and π scans to fill the Ewald sphere'
_diffrn_radiation_monochromator  'horizontally mounted graphite crystal'
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0899
_diffrn_reflns_av_sigmaI/netI    0.0669
_diffrn_reflns_limit_h_max       31
_diffrn_reflns_limit_h_min       -31
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            46292
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         2.19
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.749
_exptl_absorpt_correction_T_max  0.860
_exptl_absorpt_correction_T_min  0.643
_exptl_absorpt_correction_type   integration
_exptl_absorpt_process_details
;
Gaussian integration (Coppens, 1970)
;
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.737
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             3712
_exptl_crystal_size_max          0.36
_exptl_crystal_size_mid          0.26
_exptl_crystal_size_min          0.22
_refine_diff_density_max         1.201
_refine_diff_density_min         -1.105
_refine_diff_density_rms         0.193
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.043
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     446
_refine_ls_number_reflns         8215
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.043
_refine_ls_R_factor_all          0.0894
_refine_ls_R_factor_gt           0.0428
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0261P)²+47.4094P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0793
_refine_ls_wR_factor_ref         0.0961
_reflns_number_gt                5601
_reflns_number_total             8215
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om100339p_si_002.cif
_cod_data_source_block           ps318
_cod_depositor_comments
;
The following automatic conversions were performed:
'_atom_site_symetry_multiplicity' tag replaced with
'_atom_site_symmetry_multiplicity'.

Automatic conversion script
Id: cif_correct_tags 1440 2010-10-19 06:21:57Z saulius 
;
_cod_original_cell_volume        7171.8(6)
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               4066187
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Pd Pd 0.179059(16) 0.256376(18) 0.21820(2) 0.01832(9) Uani 1 1 d .
Fe Fe 0.16383(4) 0.05636(4) 0.07750(4) 0.02774(17) Uani 1 1 d .
P P 0.26119(6) 0.19064(6) 0.22627(7) 0.0207(2) Uani 1 1 d .
N1 N 0.11196(18) 0.2533(2) 0.0844(2) 0.0270(9) Uani 1 1 d .
N2 N 0.10728(19) 0.3234(2) 0.2193(2) 0.0257(9) Uani 1 1 d .
C1 C 0.2396(2) 0.1302(2) 0.1428(3) 0.0234(10) Uani 1 1 d .
C2 C 0.2679(2) 0.0597(3) 0.1549(3) 0.0353(12) Uani 1 1 d .
H2 H 0.2958 0.0359 0.2058 0.042 Uiso 1 1 calc R
C3 C 0.2461(3) 0.0325(3) 0.0763(3) 0.0403(13) Uani 1 1 d .
H3 H 0.2574 -0.0123 0.0667 0.048 Uiso 1 1 calc R
C4 C 0.2044(3) 0.0844(3) 0.0146(3) 0.0342(12) Uani 1 1 d .
H4 H 0.1832 0.0797 -0.0425 0.041 Uiso 1 1 calc R
C5 C 0.2003(2) 0.1453(3) 0.0551(3) 0.0257(10) Uani 1 1 d .
H5 H 0.1763 0.1875 0.0291 0.031 Uiso 1 1 calc R
C6 C 0.0769(3) 0.0762(3) 0.0699(4) 0.0398(13) Uani 1 1 d .
C7 C 0.1188(3) 0.0264(3) 0.1337(4) 0.0501(17) Uani 1 1 d .
H7 H 0.1371 0.0324 0.1899 0.060 Uiso 1 1 calc R
C8 C 0.1290(3) -0.0344(3) 0.0992(4) 0.0511(16) Uani 1 1 d .
H8 H 0.1554 -0.0747 0.1283 0.061 Uiso 1 1 calc R
C9 C 0.0918(3) -0.0223(3) 0.0128(4) 0.0419(14) Uani 1 1 d .
H9 H 0.0888 -0.0537 -0.0258 0.050 Uiso 1 1 calc R
C10 C 0.0597(3) 0.0456(3) -0.0056(3) 0.0384(13) Uani 1 1 d .
H10 H 0.0321 0.0666 -0.0584 0.046 Uiso 1 1 calc R
C11 C 0.0527(3) 0.1465(3) 0.0816(4) 0.0442(15) Uani 1 1 d .
H11A H 0.0050 0.1417 0.0604 0.053 Uiso 1 1 calc R
H11B H 0.0790 0.1568 0.1411 0.053 Uiso 1 1 calc R
C12 C 0.0592(2) 0.2079(3) 0.0392(3) 0.0382(14) Uani 1 1 d .
C13 C 0.1206(3) 0.3078(3) 0.0467(3) 0.0406(13) Uani 1 1 d .
H13 H 0.1580 0.3382 0.0797 0.049 Uiso 1 1 calc R
C14 C 0.0774(4) 0.3209(4) -0.0375(4) 0.065(2) Uani 1 1 d .
H14 H 0.0854 0.3585 -0.0616 0.079 Uiso 1 1 calc R
C15 C 0.0225(4) 0.2768(5) -0.0844(4) 0.073(3) Uani 1 1 d .
H15 H -0.0085 0.2850 -0.1416 0.087 Uiso 1 1 calc R
C16 C 0.0118(3) 0.2201(4) -0.0484(4) 0.060(2) Uani 1 1 d .
H16 H -0.0261 0.1901 -0.0811 0.072 Uiso 1 1 calc R
C17 C 0.3083(2) 0.1315(3) 0.3171(3) 0.0262(10) Uani 1 1 d .
C18 C 0.3772(3) 0.1142(3) 0.3567(3) 0.0352(12) Uani 1 1 d .
H18 H 0.4008 0.1333 0.3370 0.042 Uiso 1 1 calc R
C19 C 0.4109(3) 0.0682(3) 0.4257(3) 0.0463(15) Uani 1 1 d .
H19 H 0.4568 0.0568 0.4520 0.056 Uiso 1 1 calc R
C20 C 0.3762(3) 0.0401(3) 0.4547(4) 0.0496(16) Uani 1 1 d .
H20 H 0.3992 0.0106 0.5017 0.060 Uiso 1 1 calc R
C21 C 0.3071(3) 0.0550(3) 0.4146(3) 0.0434(14) Uani 1 1 d .
H21 H 0.2834 0.0338 0.4330 0.052 Uiso 1 1 calc R
C22 C 0.2736(3) 0.1021(3) 0.3466(3) 0.0323(11) Uani 1 1 d .
H22 H 0.2278 0.1137 0.3210 0.039 Uiso 1 1 calc R
C23 C 0.3204(2) 0.2509(3) 0.2251(3) 0.0248(10) Uani 1 1 d .
C24 C 0.3225(2) 0.3237(3) 0.2428(3) 0.0323(12) Uani 1 1 d .
H24 H 0.2961 0.3409 0.2594 0.039 Uiso 1 1 calc R
C25 C 0.3633(3) 0.3704(3) 0.2361(3) 0.0423(14) Uani 1 1 d .
H25 H 0.3644 0.4188 0.2489 0.051 Uiso 1 1 calc R
C26 C 0.4023(3) 0.3469(3) 0.2110(3) 0.0394(13) Uani 1 1 d .
H26 H 0.4296 0.3788 0.2063 0.047 Uiso 1 1 calc R
C27 C 0.4003(3) 0.2750(3) 0.1928(3) 0.0406(13) Uani 1 1 d .
H27 H 0.4265 0.2584 0.1757 0.049 Uiso 1 1 calc R
C28 C 0.3601(2) 0.2269(3) 0.1995(3) 0.0327(12) Uani 1 1 d .
H28 H 0.3594 0.1786 0.1868 0.039 Uiso 1 1 calc R
C29 C 0.2373(2) 0.2787(2) 0.3423(3) 0.0233(10) Uani 1 1 d .
C30 C 0.1986(2) 0.3074(2) 0.3673(3) 0.0270(10) Uani 1 1 d .
C31 C 0.2297(3) 0.3334(3) 0.4480(3) 0.0324(12) Uani 1 1 d .
H31 H 0.2028 0.3533 0.4627 0.039 Uiso 1 1 calc R
C32 C 0.3003(3) 0.3299(3) 0.5066(3) 0.0365(13) Uani 1 1 d .
H32 H 0.3210 0.3463 0.5609 0.044 Uiso 1 1 calc R
C33 C 0.3395(3) 0.3019(3) 0.4832(3) 0.0346(12) Uani 1 1 d .
H33 H 0.3870 0.3001 0.5218 0.041 Uiso 1 1 calc R
C34 C 0.3087(2) 0.2761(3) 0.4021(3) 0.0287(11) Uani 1 1 d .
H34 H 0.3359 0.2570 0.3875 0.034 Uiso 1 1 calc R
C35 C 0.1224(2) 0.3104(3) 0.3033(3) 0.0294(11) Uani 1 1 d .
H35A H 0.1019 0.2654 0.3028 0.035 Uiso 1 1 calc R
H35B H 0.1033 0.3489 0.3167 0.035 Uiso 1 1 calc R
C36 C 0.0330(2) 0.3126(3) 0.1542(3) 0.0388(13) Uani 1 1 d .
H36A H 0.0074 0.3438 0.1650 0.058 Uiso 1 1 calc R
H36B H 0.0212 0.2635 0.1550 0.058 Uiso 1 1 calc R
H36C H 0.0222 0.3236 0.1002 0.058 Uiso 1 1 calc R
C37 C 0.1248(3) 0.3992(3) 0.2147(3) 0.0330(12) Uani 1 1 d .
H37A H 0.1161 0.4074 0.1613 0.049 Uiso 1 1 calc R
H37B H 0.1724 0.4077 0.2584 0.049 Uiso 1 1 calc R
H37C H 0.0972 0.4312 0.2213 0.049 Uiso 1 1 calc R
Sb1 Sb 0.5000 0.04065(2) 0.2500 0.02640(12) Uani 1 2 d S
F11 F 0.5154(2) 0.04141(19) 0.1682(2) 0.0635(11) Uani 1 1 d .
F12 F 0.5000 -0.0591(2) 0.2500 0.0677(17) Uani 1 2 d S
F13 F 0.40674(18) 0.0413(3) 0.1674(3) 0.0955(16) Uani 1 1 d .
F14 F 0.5000 0.1407(3) 0.2500 0.0714(16) Uani 1 2 d S
Sb2 Sb -0.01083(15) 0.07429(4) 0.2444(3) 0.0354(6) Uani 0.50 1 d P
F21 F -0.0007(5) 0.0033(5) 0.3169(5) 0.072(2) Uiso 0.50 1 d P
F22 F 0.0219(5) 0.1413(6) 0.3312(7) 0.0492(13) Uiso 0.50 1 d P
F23 F -0.0484(5) 0.0038(6) 0.1628(6) 0.093(3) Uiso 0.50 1 d P
F24 F -0.0940(4) 0.0990(5) 0.2221(5) 0.068(2) Uiso 0.50 1 d P
F25 F 0.0774(5) 0.0546(6) 0.2709(6) 0.082(3) Uiso 0.50 1 d P
F26 F -0.0353(5) 0.1442(6) 0.1685(7) 0.0492(13) Uiso 0.50 1 d P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Fe Fe 0.3463 0.8444 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
1 0 -1 0.080
0 -1 -1 0.046
-1 1 1 0.100
-1 0 0 0.083
-1 -1 0 0.095
1 1 -1 0.166
-1 0 1 0.102
4 -2 5 0.088
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C29 Pd N1 169.36(17) . .
C29 Pd N2 81.65(16) . .
N1 Pd N2 90.15(14) . .
C29 Pd P 94.25(13) . .
N1 Pd P 93.68(10) . .
N2 Pd P 175.44(11) . .
C1 Fe C2 41.32(19) . .
C1 Fe C7 114.1(2) . .
C2 Fe C7 114.7(3) . .
C1 Fe C8 139.0(2) . .
C2 Fe C8 110.3(3) . .
C7 Fe C8 40.6(2) . .
C1 Fe C5 41.17(18) . .
C2 Fe C5 68.8(2) . .
C7 Fe C5 141.0(2) . .
C8 Fe C5 178.3(2) . .
C1 Fe C9 176.5(2) . .
C2 Fe C9 135.3(2) . .
C7 Fe C9 67.4(2) . .
C8 Fe C9 40.2(2) . .
C5 Fe C9 139.5(2) . .
C1 Fe C10 142.9(2) . .
C2 Fe C10 175.0(2) . .
C7 Fe C10 67.3(2) . .
C8 Fe C10 68.0(3) . .
C5 Fe C10 112.8(2) . .
C9 Fe C10 40.4(2) . .
C1 Fe C6 115.17(19) . .
C2 Fe C6 144.0(2) . .
C7 Fe C6 40.1(2) . .
C8 Fe C6 68.4(3) . .
C5 Fe C6 113.2(2) . .
C9 Fe C6 68.1(2) . .
C10 Fe C6 40.5(2) . .
C1 Fe C3 68.8(2) . .
C2 Fe C3 40.4(2) . .
C7 Fe C3 141.3(3) . .
C8 Fe C3 110.3(3) . .
C5 Fe C3 68.1(2) . .
C9 Fe C3 108.0(2) . .
C10 Fe C3 135.1(2) . .
C6 Fe C3 175.5(2) . .
C1 Fe C4 68.93(19) . .
C2 Fe C4 68.2(2) . .
C7 Fe C4 176.8(2) . .
C8 Fe C4 137.8(2) . .
C5 Fe C4 40.66(19) . .
C9 Fe C4 109.6(2) . .
C10 Fe C4 109.7(2) . .
C6 Fe C4 138.2(2) . .
C3 Fe C4 40.1(2) . .
C1 P C17 101.7(2) . .
C1 P C23 100.0(2) . .
C17 P C23 110.2(2) . .
C1 P Pd 120.53(15) . .
C17 P Pd 114.00(16) . .
C23 P Pd 109.25(16) . .
C12 N1 C13 120.2(5) . .
C12 N1 Pd 124.8(4) . .
C13 N1 Pd 114.5(3) . .
C36 N2 C37 108.5(4) . .
C36 N2 C35 108.7(4) . .
C37 N2 C35 109.3(4) . .
C36 N2 Pd 118.9(3) . .
C37 N2 Pd 106.8(3) . .
C35 N2 Pd 104.4(3) . .
C5 C1 C2 106.9(4) . .
C5 C1 P 128.0(4) . .
C2 C1 P 124.6(4) . .
C5 C1 Fe 69.9(3) . .
C2 C1 Fe 69.4(3) . .
P C1 Fe 132.0(2) . .
C3 C2 C1 108.3(5) . .
C3 C2 Fe 70.6(3) . .
C1 C2 Fe 69.3(3) . .
C3 C2 H2 125.8 . .
C1 C2 H2 125.8 . .
Fe C2 H2 125.9 . .
C4 C3 C2 108.7(5) . .
C4 C3 Fe 70.1(3) . .
C2 C3 Fe 69.0(3) . .
C4 C3 H3 125.7 . .
C2 C3 H3 125.7 . .
Fe C3 H3 126.8 . .
C3 C4 C5 108.0(4) . .
C3 C4 Fe 69.8(3) . .
C5 C4 Fe 69.2(3) . .
C3 C4 H4 126.0 . .
C5 C4 H4 126.0 . .
Fe C4 H4 126.6 . .
C4 C5 C1 108.1(4) . .
C4 C5 Fe 70.2(3) . .
C1 C5 Fe 68.9(3) . .
C4 C5 H5 126.0 . .
C1 C5 H5 126.0 . .
Fe C5 H5 126.6 . .
C7 C6 C10 106.9(5) . .
C7 C6 C11 125.1(5) . .
C10 C6 C11 127.9(6) . .
C7 C6 Fe 69.6(3) . .
C10 C6 Fe 69.6(3) . .
C11 C6 Fe 128.3(4) . .
C6 C7 C8 109.4(5) . .
C6 C7 Fe 70.3(3) . .
C8 C7 Fe 69.7(3) . .
C6 C7 H7 125.3 . .
C8 C7 H7 125.3 . .
Fe C7 H7 126.2 . .
C9 C8 C7 107.0(6) . .
C9 C8 Fe 70.0(3) . .
C7 C8 Fe 69.7(3) . .
C9 C8 H8 126.5 . .
C7 C8 H8 126.5 . .
Fe C8 H8 125.4 . .
C8 C9 C10 108.4(5) . .
C8 C9 Fe 69.8(3) . .
C10 C9 Fe 69.9(3) . .
C8 C9 H9 125.8 . .
C10 C9 H9 125.8 . .
Fe C9 H9 126.1 . .
C9 C10 C6 108.3(5) . .
C9 C10 Fe 69.7(3) . .
C6 C10 Fe 69.9(3) . .
C9 C10 H10 125.9 . .
C6 C10 H10 125.9 . .
Fe C10 H10 126.0 . .
C12 C11 C6 113.7(4) . .
C12 C11 H11A 108.8 . .
C6 C11 H11A 108.8 . .
C12 C11 H11B 108.8 . .
C6 C11 H11B 108.8 . .
H11A C11 H11B 107.7 . .
N1 C12 C16 118.6(6) . .
N1 C12 C11 119.1(5) . .
C16 C12 C11 122.4(6) . .
N1 C13 C14 123.6(6) . .
N1 C13 H13 118.2 . .
C14 C13 H13 118.2 . .
C15 C14 C13 117.5(7) . .
C15 C14 H14 121.3 . .
C13 C14 H14 121.3 . .
C14 C15 C16 120.9(6) . .
C14 C15 H15 119.5 . .
C16 C15 H15 119.5 . .
C15 C16 C12 119.3(6) . .
C15 C16 H16 120.4 . .
C12 C16 H16 120.4 . .
C22 C17 C18 119.4(5) . .
C22 C17 P 118.3(4) . .
C18 C17 P 122.3(4) . .
C19 C18 C17 120.2(5) . .
C19 C18 H18 119.9 . .
C17 C18 H18 119.9 . .
C20 C19 C18 119.9(5) . .
C20 C19 H19 120.0 . .
C18 C19 H19 120.0 . .
C19 C20 C21 120.7(5) . .
C19 C20 H20 119.7 . .
C21 C20 H20 119.7 . .
C20 C21 C22 119.6(5) . .
C20 C21 H21 120.2 . .
C22 C21 H21 120.2 . .
C17 C22 C21 120.2(5) . .
C17 C22 H22 119.9 . .
C21 C22 H22 119.9 . .
C24 C23 C28 118.2(4) . .
C24 C23 P 120.3(3) . .
C28 C23 P 121.3(4) . .
C25 C24 C23 120.7(5) . .
C25 C24 H24 119.7 . .
C23 C24 H24 119.7 . .
C26 C25 C24 121.2(5) . .
C26 C25 H25 119.4 . .
C24 C25 H25 119.4 . .
C25 C26 C27 118.6(5) . .
C25 C26 H26 120.7 . .
C27 C26 H26 120.7 . .
C26 C27 C28 121.4(5) . .
C26 C27 H27 119.3 . .
C28 C27 H27 119.3 . .
C27 C28 C23 120.0(5) . .
C27 C28 H28 120.0 . .
C23 C28 H28 120.0 . .
C30 C29 C34 117.5(4) . .
C30 C29 Pd 112.2(3) . .
C34 C29 Pd 130.0(4) . .
C31 C30 C29 121.4(5) . .
C31 C30 C35 121.2(4) . .
C29 C30 C35 117.4(4) . .
C32 C31 C30 120.5(5) . .
C32 C31 H31 119.8 . .
C30 C31 H31 119.8 . .
C33 C32 C31 119.1(5) . .
C33 C32 H32 120.5 . .
C31 C32 H32 120.5 . .
C32 C33 C34 120.7(5) . .
C32 C33 H33 119.6 . .
C34 C33 H33 119.6 . .
C33 C34 C29 120.9(5) . .
C33 C34 H34 119.6 . .
C29 C34 H34 119.6 . .
N2 C35 C30 108.5(4) . .
N2 C35 H35A 110.0 . .
C30 C35 H35A 110.0 . .
N2 C35 H35B 110.0 . .
C30 C35 H35B 110.0 . .
H35A C35 H35B 108.4 . .
N2 C36 H36A 109.5 . .
N2 C36 H36B 109.5 . .
H36A C36 H36B 109.5 . .
N2 C36 H36C 109.5 . .
H36A C36 H36C 109.5 . .
H36B C36 H36C 109.5 . .
N2 C37 H37A 109.5 . .
N2 C37 H37B 109.5 . .
H37A C37 H37B 109.5 . .
N2 C37 H37C 109.5 . .
H37A C37 H37C 109.5 . .
H37B C37 H37C 109.5 . .
F13 Sb1 F13 179.3(3) . 2_655
F13 Sb1 F12 90.36(17) . .
F13 Sb1 F12 90.36(17) 2_655 .
F13 Sb1 F14 89.64(17) . .
F13 Sb1 F14 89.64(17) 2_655 .
F12 Sb1 F14 180.000(1) . .
F13 Sb1 F11 90.2(2) . 2_655
F13 Sb1 F11 89.8(2) 2_655 2_655
F12 Sb1 F11 90.43(11) . 2_655
F14 Sb1 F11 89.57(11) . 2_655
F13 Sb1 F11 89.8(2) . .
F13 Sb1 F11 90.2(2) 2_655 .
F12 Sb1 F11 90.43(11) . .
F14 Sb1 F11 89.57(11) . .
F11 Sb1 F11 179.1(2) 2_655 .
Sb2 Sb2 F25 159.5(12) 2 2
Sb2 Sb2 F26 97.5(10) 2 .
F25 Sb2 F26 103.0(5) 2 .
Sb2 Sb2 F24 160.6(11) 2 .
F25 Sb2 F24 28.6(4) 2 .
F26 Sb2 F24 81.2(4) . .
Sb2 Sb2 F22 88.2(11) 2 2
F25 Sb2 F22 112.3(5) 2 2
F26 Sb2 F22 10.2(5) . 2
F24 Sb2 F22 91.3(4) . 2
Sb2 Sb2 F23 105.7(11) 2 .
F25 Sb2 F23 74.7(5) 2 .
F26 Sb2 F23 91.9(5) . .
F24 Sb2 F23 93.7(4) . .
F22 Sb2 F23 90.5(5) 2 .
Sb2 Sb2 F21 92.0(11) 2 .
F25 Sb2 F21 67.5(5) 2 .
F26 Sb2 F21 170.4(4) . .
F24 Sb2 F21 89.4(4) . .
F22 Sb2 F21 177.3(5) 2 .
F23 Sb2 F21 86.8(4) . .
Sb2 Sb2 F22 78.6(11) 2 .
F25 Sb2 F22 99.6(5) 2 .
F26 Sb2 F22 92.2(2) . .
F24 Sb2 F22 82.2(4) . .
F22 Sb2 F22 94.3(7) 2 .
F23 Sb2 F22 173.7(5) . .
F21 Sb2 F22 88.4(5) . .
Sb2 Sb2 F25 15.9(10) 2 .
F25 Sb2 F25 154.6(7) 2 .
F26 Sb2 F25 97.5(4) . .
F24 Sb2 F25 176.3(5) . .
F22 Sb2 F25 87.4(4) 2 .
F23 Sb2 F25 89.8(5) . .
F21 Sb2 F25 92.1(4) . .
F22 Sb2 F25 94.5(4) . .
Sb2 Sb2 F26 69.6(10) 2 2
F25 Sb2 F26 109.5(5) 2 2
F26 Sb2 F26 89.5(7) . 2
F24 Sb2 F26 91.1(4) . 2
F22 Sb2 F26 90.0(2) 2 2
F23 Sb2 F26 175.2(5) . 2
F21 Sb2 F26 92.6(5) . 2
F22 Sb2 F26 9.8(5) . 2
F25 Sb2 F26 85.5(4) . 2
Sb2 Sb2 F21 75.0(10) 2 2
F25 Sb2 F21 104.1(5) 2 2
F26 Sb2 F21 93.9(5) . 2
F24 Sb2 F21 124.3(4) . 2
F22 Sb2 F21 87.5(5) 2 2
F23 Sb2 F21 30.7(3) . 2
F21 Sb2 F21 89.9(5) . 2
F22 Sb2 F21 153.4(4) . 2
F25 Sb2 F21 59.1(4) . 2
F26 Sb2 F21 144.5(4) 2 2
Sb2 Sb2 F23 62.4(10) 2 2
F25 Sb2 F23 97.1(5) 2 2
F26 Sb2 F23 159.9(5) . 2
F24 Sb2 F23 117.9(5) . 2
F22 Sb2 F23 150.2(4) 2 2
F23 Sb2 F23 93.0(6) . 2
F21 Sb2 F23 29.7(3) . 2
F22 Sb2 F23 84.8(5) . 2
F25 Sb2 F23 63.1(4) . 2
F26 Sb2 F23 84.1(5) 2 2
F21 Sb2 F23 80.7(3) 2 2
F23 F21 Sb2 83.5(8) 2 .
F23 F21 Sb2 70.6(8) 2 2
F26 F22 Sb2 78(4) 2 2
F26 F22 Sb2 90(4) 2 .
F21 F23 Sb2 78.7(8) 2 .
F21 F23 Sb2 66.8(8) 2 2
F25 F24 Sb2 53.7(8) 2 .
F25 F24 Sb2 56.2(8) 2 2
F24 F25 Sb2 97.7(10) 2 2
F24 F25 Sb2 101.0(10) 2 .
F22 F26 Sb2 92(4) 2 .
F22 F26 Sb2 80(4) 2 2
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pd C29 2.026(4) .
Pd N1 2.139(4) .
Pd N2 2.145(4) .
Pd P 2.2539(12) .
Fe C1 2.027(5) .
Fe C2 2.029(5) .
Fe C7 2.039(6) .
Fe C8 2.041(6) .
Fe C5 2.041(5) .
Fe C9 2.043(5) .
Fe C10 2.044(5) .
Fe C6 2.049(5) .
Fe C3 2.050(5) .
Fe C4 2.054(5) .
P C1 1.802(4) .
P C17 1.822(5) .
P C23 1.828(5) .
N1 C12 1.337(6) .
N1 C13 1.346(7) .
N2 C36 1.479(6) .
N2 C37 1.489(6) .
N2 C35 1.496(6) .
C1 C5 1.431(6) .
C1 C2 1.431(6) .
C2 C3 1.409(7) .
C2 H2 0.9300 .
C3 C4 1.408(8) .
C3 H3 0.9300 .
C4 C5 1.423(7) .
C4 H4 0.9300 .
C5 H5 0.9300 .
C6 C7 1.401(9) .
C6 C10 1.415(7) .
C6 C11 1.504(8) .
C7 C8 1.415(8) .
C7 H7 0.9300 .
C8 C9 1.403(8) .
C8 H8 0.9300 .
C9 C10 1.412(8) .
C9 H9 0.9300 .
C10 H10 0.9300 .
C11 C12 1.480(8) .
C11 H11A 0.9700 .
C11 H11B 0.9700 .
C12 C16 1.423(8) .
C13 C14 1.367(8) .
C13 H13 0.9300 .
C14 C15 1.355(11) .
C14 H14 0.9300 .
C15 C16 1.381(11) .
C15 H15 0.9300 .
C16 H16 0.9300 .
C17 C22 1.386(7) .
C17 C18 1.396(7) .
C18 C19 1.394(7) .
C18 H18 0.9300 .
C19 C20 1.368(9) .
C19 H19 0.9300 .
C20 C21 1.388(8) .
C20 H20 0.9300 .
C21 C22 1.394(7) .
C21 H21 0.9300 .
C22 H22 0.9300 .
C23 C24 1.391(7) .
C23 C28 1.395(6) .
C24 C25 1.378(7) .
C24 H24 0.9300 .
C25 C26 1.372(8) .
C25 H25 0.9300 .
C26 C27 1.379(8) .
C26 H26 0.9300 .
C27 C28 1.383(7) .
C27 H27 0.9300 .
C28 H28 0.9300 .
C29 C30 1.395(6) .
C29 C34 1.401(6) .
C30 C31 1.390(7) .
C30 C35 1.497(7) .
C31 C32 1.386(7) .
C31 H31 0.9300 .
C32 C33 1.379(7) .
C32 H32 0.9300 .
C33 C34 1.395(7) .
C33 H33 0.9300 .
C34 H34 0.9300 .
C35 H35A 0.9700 .
C35 H35B 0.9700 .
C36 H36A 0.9600 .
C36 H36B 0.9600 .
C36 H36C 0.9600 .
C37 H37A 0.9600 .
C37 H37B 0.9600 .
C37 H37C 0.9600 .
Sb1 F13 1.842(4) .
Sb1 F13 1.842(4) 2_655
Sb1 F12 1.854(4) .
Sb1 F14 1.859(5) .
Sb1 F11 1.865(3) 2_655
Sb1 F11 1.865(3) .
Sb2 Sb2 0.431(5) 2
Sb2 F25 1.496(10) 2
Sb2 F26 1.802(11) .
Sb2 F24 1.841(9) .
Sb2 F22 1.843(11) 2
Sb2 F23 1.849(11) .
Sb2 F21 1.858(9) .
Sb2 F22 1.879(11) .
Sb2 F25 1.906(9) .
Sb2 F26 1.906(11) 2
Sb2 F21 1.922(9) 2
Sb2 F23 2.008(11) 2
F21 F23 1.001(10) 2
F21 Sb2 1.922(9) 2
F22 F26 0.325(16) 2
F22 Sb2 1.843(11) 2
F23 F21 1.001(10) 2
F23 Sb2 2.008(11) 2
F24 F25 0.890(10) 2
F24 Sb2 2.252(9) 2
F25 F24 0.890(10) 2
F25 Sb2 1.496(10) 2
F26 F22 0.325(16) 2
F26 Sb2 1.906(11) 2
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
C29 Pd P C1 162.6(2)
N1 Pd P C1 -24.5(2)
C29 Pd P C17 41.2(2)
N1 Pd P C17 -145.9(2)
C29 Pd P C23 -82.57(19)
N1 Pd P C23 90.32(19)
C29 Pd N1 C12 -123.6(9)
N2 Pd N1 C12 -84.1(4)
P Pd N1 C12 98.3(4)
C29 Pd N1 C13 47.9(10)
N2 Pd N1 C13 87.4(3)
P Pd N1 C13 -90.2(3)
C29 Pd N2 C36 -152.8(4)
N1 Pd N2 C36 34.0(4)
C29 Pd N2 C37 84.2(3)
N1 Pd N2 C37 -89.0(3)
C29 Pd N2 C35 -31.5(3)
N1 Pd N2 C35 155.3(3)
C17 P C1 C5 177.9(4)
C23 P C1 C5 -68.9(4)
Pd P C1 C5 50.7(5)
C17 P C1 C2 -11.6(5)
C23 P C1 C2 101.7(4)
Pd P C1 C2 -138.7(4)
C17 P C1 Fe 81.1(3)
C23 P C1 Fe -165.7(3)
Pd P C1 Fe -46.1(4)
C2 Fe C1 C5 117.9(4)
C7 Fe C1 C5 -141.4(3)
C8 Fe C1 C5 177.4(3)
C10 Fe C1 C5 -57.7(4)
C6 Fe C1 C5 -97.1(3)
C3 Fe C1 C5 80.6(3)
C4 Fe C1 C5 37.4(3)
C7 Fe C1 C2 100.7(4)
C8 Fe C1 C2 59.5(5)
C5 Fe C1 C2 -117.9(4)
C10 Fe C1 C2 -175.6(4)
C6 Fe C1 C2 145.0(3)
C3 Fe C1 C2 -37.3(3)
C4 Fe C1 C2 -80.5(3)
C2 Fe C1 P -118.5(5)
C7 Fe C1 P -17.8(4)
C8 Fe C1 P -59.0(5)
C5 Fe C1 P 123.6(4)
C10 Fe C1 P 65.9(5)
C6 Fe C1 P 26.5(4)
C3 Fe C1 P -155.8(4)
C4 Fe C1 P 161.0(4)
C5 C1 C2 C3 -0.2(6)
P C1 C2 C3 -172.4(4)
Fe C1 C2 C3 60.0(4)
C5 C1 C2 Fe -60.2(3)
P C1 C2 Fe 127.6(4)
C1 Fe C2 C3 -119.3(5)
C7 Fe C2 C3 141.6(3)
C8 Fe C2 C3 97.8(4)
C5 Fe C2 C3 -80.7(3)
C9 Fe C2 C3 59.4(5)
C6 Fe C2 C3 178.6(4)
C4 Fe C2 C3 -36.8(3)
C7 Fe C2 C1 -99.1(3)
C8 Fe C2 C1 -142.9(3)
C5 Fe C2 C1 38.6(3)
C9 Fe C2 C1 178.7(3)
C6 Fe C2 C1 -62.0(5)
C3 Fe C2 C1 119.3(5)
C4 Fe C2 C1 82.5(3)
C1 C2 C3 C4 -0.2(6)
Fe C2 C3 C4 59.0(4)
C1 C2 C3 Fe -59.2(4)
C1 Fe C3 C4 -82.1(3)
C2 Fe C3 C4 -120.2(5)
C7 Fe C3 C4 175.4(3)
C8 Fe C3 C4 141.9(3)
C5 Fe C3 C4 -37.7(3)
C9 Fe C3 C4 99.3(3)
C10 Fe C3 C4 63.2(5)
C1 Fe C3 C2 38.1(3)
C7 Fe C3 C2 -64.4(5)
C8 Fe C3 C2 -97.9(4)
C5 Fe C3 C2 82.6(3)
C9 Fe C3 C2 -140.5(3)
C10 Fe C3 C2 -176.6(3)
C4 Fe C3 C2 120.2(5)
C2 C3 C4 C5 0.4(6)
Fe C3 C4 C5 58.8(3)
C2 C3 C4 Fe -58.4(4)
C1 Fe C4 C3 81.7(3)
C2 Fe C4 C3 37.1(3)
C8 Fe C4 C3 -59.5(5)
C5 Fe C4 C3 119.5(4)
C9 Fe C4 C3 -95.0(4)
C10 Fe C4 C3 -138.0(3)
C6 Fe C4 C3 -173.7(3)
C1 Fe C4 C5 -37.9(3)
C2 Fe C4 C5 -82.4(3)
C8 Fe C4 C5 -179.0(3)
C9 Fe C4 C5 145.5(3)
C10 Fe C4 C5 102.5(3)
C6 Fe C4 C5 66.8(4)
C3 Fe C4 C5 -119.5(4)
C3 C4 C5 C1 -0.5(6)
Fe C4 C5 C1 58.6(3)
C3 C4 C5 Fe -59.2(4)
C2 C1 C5 C4 0.4(5)
P C1 C5 C4 172.3(4)
Fe C1 C5 C4 -59.4(3)
C2 C1 C5 Fe 59.8(3)
P C1 C5 Fe -128.3(4)
C1 Fe C5 C4 119.5(4)
C2 Fe C5 C4 80.8(3)
C7 Fe C5 C4 -175.7(4)
C9 Fe C5 C4 -55.2(4)
C10 Fe C5 C4 -94.1(3)
C6 Fe C5 C4 -138.2(3)
C3 Fe C5 C4 37.2(3)
C2 Fe C5 C1 -38.8(3)
C7 Fe C5 C1 64.8(4)
C9 Fe C5 C1 -174.8(3)
C10 Fe C5 C1 146.4(3)
C6 Fe C5 C1 102.3(3)
C3 Fe C5 C1 -82.4(3)
C4 Fe C5 C1 -119.5(4)
C1 Fe C6 C7 -98.2(3)
C2 Fe C6 C7 -58.1(5)
C8 Fe C6 C7 37.1(3)
C5 Fe C6 C7 -143.5(3)
C9 Fe C6 C7 80.5(4)
C10 Fe C6 C7 118.0(5)
C4 Fe C6 C7 175.8(3)
C1 Fe C6 C10 143.8(3)
C2 Fe C6 C10 -176.1(4)
C7 Fe C6 C10 -118.0(5)
C8 Fe C6 C10 -80.9(4)
C5 Fe C6 C10 98.5(4)
C9 Fe C6 C10 -37.5(3)
C4 Fe C6 C10 57.8(5)
C1 Fe C6 C11 20.9(6)
C2 Fe C6 C11 61.1(7)
C7 Fe C6 C11 119.2(7)
C8 Fe C6 C11 156.2(6)
C5 Fe C6 C11 -24.4(6)
C9 Fe C6 C11 -160.3(6)
C10 Fe C6 C11 -122.8(7)
C4 Fe C6 C11 -65.0(6)
C10 C6 C7 C8 0.9(6)
C11 C6 C7 C8 177.9(5)
Fe C6 C7 C8 -58.9(4)
C10 C6 C7 Fe 59.9(4)
C11 C6 C7 Fe -123.1(5)
C1 Fe C7 C6 101.0(3)
C2 Fe C7 C6 146.6(3)
C8 Fe C7 C6 -120.5(5)
C5 Fe C7 C6 60.3(5)
C9 Fe C7 C6 -82.4(4)
C10 Fe C7 C6 -38.4(3)
C3 Fe C7 C6 -173.3(3)
C1 Fe C7 C8 -138.4(4)
C2 Fe C7 C8 -92.8(4)
C5 Fe C7 C8 -179.2(4)
C9 Fe C7 C8 38.2(4)
C10 Fe C7 C8 82.2(4)
C6 Fe C7 C8 120.5(5)
C3 Fe C7 C8 -52.7(5)
C6 C7 C8 C9 -1.1(7)
Fe C7 C8 C9 -60.3(4)
C6 C7 C8 Fe 59.3(4)
C1 Fe C8 C9 -174.8(3)
C2 Fe C8 C9 -137.5(4)
C7 Fe C8 C9 117.8(6)
C10 Fe C8 C9 37.5(3)
C6 Fe C8 C9 81.2(4)
C3 Fe C8 C9 -94.2(4)
C4 Fe C8 C9 -58.0(5)
C1 Fe C8 C7 67.4(5)
C2 Fe C8 C7 104.7(4)
C9 Fe C8 C7 -117.8(6)
C10 Fe C8 C7 -80.3(4)
C6 Fe C8 C7 -36.6(4)
C3 Fe C8 C7 148.0(4)
C4 Fe C8 C7 -175.8(4)
C7 C8 C9 C10 0.7(7)
Fe C8 C9 C10 -59.4(4)
C7 C8 C9 Fe 60.1(4)
C2 Fe C9 C8 64.4(5)
C7 Fe C9 C8 -38.6(4)
C5 Fe C9 C8 177.4(4)
C10 Fe C9 C8 -119.6(5)
C6 Fe C9 C8 -82.0(4)
C3 Fe C9 C8 100.3(4)
C4 Fe C9 C8 142.8(4)
C2 Fe C9 C10 -176.0(3)
C7 Fe C9 C10 81.0(4)
C8 Fe C9 C10 119.6(5)
C5 Fe C9 C10 -63.0(5)
C6 Fe C9 C10 37.5(3)
C3 Fe C9 C10 -140.1(3)
C4 Fe C9 C10 -97.6(3)
C8 C9 C10 C6 -0.2(6)
Fe C9 C10 C6 -59.5(4)
C8 C9 C10 Fe 59.4(4)
C7 C6 C10 C9 -0.5(6)
C11 C6 C10 C9 -177.4(5)
Fe C6 C10 C9 59.4(4)
C7 C6 C10 Fe -59.9(4)
C11 C6 C10 Fe 123.2(5)
C1 Fe C10 C9 178.2(3)
C7 Fe C10 C9 -81.3(4)
C8 Fe C10 C9 -37.3(3)
C5 Fe C10 C9 141.1(3)
C6 Fe C10 C9 -119.4(5)
C3 Fe C10 C9 59.8(5)
C4 Fe C10 C9 97.4(4)
C1 Fe C10 C6 -62.4(5)
C7 Fe C10 C6 38.1(3)
C8 Fe C10 C6 82.1(4)
C5 Fe C10 C6 -99.5(4)
C9 Fe C10 C6 119.4(5)
C3 Fe C10 C6 179.2(4)
C4 Fe C10 C6 -143.2(3)
C7 C6 C11 C12 134.7(6)
C10 C6 C11 C12 -48.9(7)
Fe C6 C11 C12 44.1(7)
C13 N1 C12 C16 -2.0(7)
Pd N1 C12 C16 169.0(3)
C13 N1 C12 C11 177.3(4)
Pd N1 C12 C11 -11.7(6)
C6 C11 C12 N1 -101.1(5)
C6 C11 C12 C16 78.2(6)
C12 N1 C13 C14 0.6(7)
Pd N1 C13 C14 -171.3(4)
N1 C13 C14 C15 1.2(9)
C13 C14 C15 C16 -1.5(9)
C14 C15 C16 C12 0.1(9)
N1 C12 C16 C15 1.7(8)
C11 C12 C16 C15 -177.5(5)
C1 P C17 C22 -98.4(4)
C23 P C17 C22 156.2(4)
Pd P C17 C22 32.9(4)
C1 P C17 C18 80.6(4)
C23 P C17 C18 -24.8(5)
Pd P C17 C18 -148.1(4)
C22 C17 C18 C19 -0.6(8)
P C17 C18 C19 -179.5(4)
C17 C18 C19 C20 0.0(9)
C18 C19 C20 C21 1.9(9)
C19 C20 C21 C22 -3.2(9)
C18 C17 C22 C21 -0.7(7)
P C17 C22 C21 178.3(4)
C20 C21 C22 C17 2.5(8)
C1 P C23 C24 145.1(4)
C17 P C23 C24 -108.3(4)
Pd P C23 C24 17.7(4)
C1 P C23 C28 -29.2(4)
C17 P C23 C28 77.4(4)
Pd P C23 C28 -156.6(3)
C28 C23 C24 C25 -0.8(7)
P C23 C24 C25 -175.2(4)
C23 C24 C25 C26 0.8(8)
C24 C25 C26 C27 -0.4(9)
C25 C26 C27 C28 0.0(8)
C26 C27 C28 C23 0.0(8)
C24 C23 C28 C27 0.4(7)
P C23 C28 C27 174.8(4)
N1 Pd C29 C30 55.0(10)
N2 Pd C29 C30 15.0(3)
P Pd C29 C30 -167.0(3)
N1 Pd C29 C34 -118.1(9)
N2 Pd C29 C34 -158.1(5)
P Pd C29 C34 19.9(4)
C34 C29 C30 C31 0.8(7)
Pd C29 C30 C31 -173.2(4)
C34 C29 C30 C35 179.7(4)
Pd C29 C30 C35 5.7(5)
C29 C30 C31 C32 -1.4(7)
C35 C30 C31 C32 179.7(4)
C30 C31 C32 C33 1.5(7)
C31 C32 C33 C34 -1.1(8)
C32 C33 C34 C29 0.5(8)
C30 C29 C34 C33 -0.4(7)
Pd C29 C34 C33 172.4(4)
C36 N2 C35 C30 169.3(4)
C37 N2 C35 C30 -72.5(5)
Pd N2 C35 C30 41.4(4)
C31 C30 C35 N2 145.4(4)
C29 C30 C35 N2 -33.4(6)
