#------------------------------------------------------------------------------
#$Date: 2016-03-21 07:18:36 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178558 $
#$URL: svn://www.crystallography.net/cod/cif/4/06/66/4066634.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4066634
loop_
_publ_author_name
'Chen, Dafa'
'Zhang, Xi'
'Xu, Shansheng'
'Song, Haibin'
'Wang, Baiquan'
_publ_section_title
;
 Pyridyl-Substituted Indenyl Ruthenium Complexes: Synthesis, Structures,
 and Reactivities
;
_journal_issue                   15
_journal_name_full               Organometallics
_journal_page_first              3418
_journal_paper_doi               10.1021/om100556y
_journal_volume                  29
_journal_year                    2010
_chemical_formula_sum            'C24 H16 N O2 Ru'
_chemical_formula_weight         451.45
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 112.454(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   16.451(3)
_cell_length_b                   14.350(2)
_cell_length_c                   17.250(3)
_cell_measurement_reflns_used    3111
_cell_measurement_temperature    294(2)
_cell_measurement_theta_max      24.71
_cell_measurement_theta_min      2.60
_cell_volume                     3763.5(11)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      294(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0437
_diffrn_reflns_av_sigmaI/netI    0.0542
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            10713
_diffrn_reflns_theta_full        26.40
_diffrn_reflns_theta_max         26.40
_diffrn_reflns_theta_min         1.95
_exptl_absorpt_coefficient_mu    0.853
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.798474
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_density_diffrn    1.594
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1816
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.10
_refine_diff_density_max         0.419
_refine_diff_density_min         -0.382
_refine_diff_density_rms         0.077
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.003
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     253
_refine_ls_number_reflns         3858
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.003
_refine_ls_R_factor_all          0.0581
_refine_ls_R_factor_gt           0.0328
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0316P)²+1.0062P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0666
_refine_ls_wR_factor_ref         0.0751
_reflns_number_gt                2803
_reflns_number_total             3858
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om100556y_si_001.cif
_cod_data_source_block           070522a
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'MULTI-SCAN'
changed to 'multi-scan' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.1 from
2010-06-29.

'_refine_ls_hydrogen_treatment' value 'CONSTR' changed
to 'constr' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'NONE' was changed to '?' - the
value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_cell_volume        3763.5(10)
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               4066634
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ru1 Ru 0.562300(16) 0.429613(17) 0.830386(16) 0.02926(9) Uani 1 1 d .
O1 O 0.58264(17) 0.63690(18) 0.85469(17) 0.0598(7) Uani 1 1 d .
O2 O 0.37442(15) 0.45710(17) 0.81122(16) 0.0488(7) Uani 1 1 d .
N1 N 0.43230(19) 0.1917(2) 0.8409(2) 0.0488(8) Uani 1 1 d .
C1 C 0.5734(2) 0.5581(2) 0.8444(2) 0.0372(8) Uani 1 1 d .
C2 C 0.4277(2) 0.4469(2) 0.7825(2) 0.0344(8) Uani 1 1 d .
C3 C 0.6784(2) 0.3277(2) 0.8833(2) 0.0333(7) Uani 1 1 d .
C4 C 0.5982(2) 0.2760(2) 0.8541(2) 0.0364(8) Uani 1 1 d .
H4 H 0.5825 0.2272 0.8112 0.044 Uiso 1 1 calc R
C5 C 0.5493(2) 0.3000(2) 0.9041(2) 0.0365(8) Uani 1 1 d .
C6 C 0.5951(2) 0.3710(2) 0.9595(2) 0.0362(8) Uani 1 1 d .
H6 H 0.5780 0.3985 1.0031 0.043 Uiso 1 1 calc R
C7 C 0.6765(2) 0.3890(2) 0.9485(2) 0.0340(8) Uani 1 1 d .
C8 C 0.7470(2) 0.4486(2) 1.0065(2) 0.0389(8) Uani 1 1 d .
C9 C 0.7262(2) 0.5258(3) 1.0441(2) 0.0491(9) Uani 1 1 d .
H9 H 0.6675 0.5428 1.0288 0.059 Uiso 1 1 calc R
C10 C 0.7904(3) 0.5774(3) 1.1032(2) 0.0591(11) Uani 1 1 d .
H10 H 0.7752 0.6285 1.1279 0.071 Uiso 1 1 calc R
C11 C 0.8776(3) 0.5534(3) 1.1258(3) 0.0647(12) Uani 1 1 d .
H11 H 0.9215 0.5884 1.1654 0.078 Uiso 1 1 calc R
C12 C 0.8989(2) 0.4777(3) 1.0894(3) 0.0596(11) Uani 1 1 d .
H12 H 0.9577 0.4616 1.1045 0.072 Uiso 1 1 calc R
C13 C 0.8353(2) 0.4252(2) 1.0313(2) 0.0466(9) Uani 1 1 d .
H13 H 0.8513 0.3733 1.0081 0.056 Uiso 1 1 calc R
C14 C 0.7519(2) 0.3136(2) 0.8541(2) 0.0355(8) Uani 1 1 d .
C15 C 0.7982(2) 0.3872(2) 0.8395(2) 0.0423(9) Uani 1 1 d .
H15 H 0.7803 0.4479 0.8435 0.051 Uiso 1 1 calc R
C16 C 0.8699(2) 0.3724(3) 0.8193(3) 0.0549(11) Uani 1 1 d .
H16 H 0.9011 0.4228 0.8107 0.066 Uiso 1 1 calc R
C17 C 0.8959(2) 0.2829(3) 0.8116(2) 0.0564(11) Uani 1 1 d .
H17 H 0.9447 0.2726 0.7981 0.068 Uiso 1 1 calc R
C18 C 0.8495(3) 0.2094(3) 0.8238(2) 0.0556(10) Uani 1 1 d .
H18 H 0.8661 0.1489 0.8173 0.067 Uiso 1 1 calc R
C19 C 0.7782(2) 0.2241(2) 0.8459(2) 0.0437(9) Uani 1 1 d .
H19 H 0.7478 0.1736 0.8552 0.052 Uiso 1 1 calc R
C20 C 0.4681(2) 0.2534(2) 0.9022(2) 0.0388(8) Uani 1 1 d .
C21 C 0.4350(2) 0.2715(3) 0.9634(3) 0.0547(10) Uani 1 1 d .
H21 H 0.4618 0.3152 1.0052 0.066 Uiso 1 1 calc R
C22 C 0.3617(3) 0.2237(3) 0.9612(3) 0.0739(14) Uani 1 1 d .
H22 H 0.3378 0.2351 1.0012 0.089 Uiso 1 1 calc R
C23 C 0.3249(3) 0.1596(3) 0.9001(3) 0.0685(13) Uani 1 1 d .
H23 H 0.2760 0.1257 0.8982 0.082 Uiso 1 1 calc R
C24 C 0.3607(3) 0.1451(3) 0.8405(3) 0.0609(11) Uani 1 1 d .
H24 H 0.3344 0.1016 0.7984 0.073 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 Ru1 C2 87.95(13) . 2_656
C1 Ru1 C2 88.25(13) . .
C2 Ru1 C2 93.96(12) 2_656 .
C1 Ru1 C6 105.52(13) . .
C2 Ru1 C6 156.94(12) 2_656 .
C2 Ru1 C6 104.88(12) . .
C1 Ru1 C7 97.57(13) . .
C2 Ru1 C7 123.56(12) 2_656 .
C2 Ru1 C7 142.08(12) . .
C6 Ru1 C7 37.46(10) . .
C1 Ru1 C4 158.46(14) . .
C2 Ru1 C4 100.36(12) 2_656 .
C2 Ru1 C4 110.71(12) . .
C6 Ru1 C4 60.79(12) . .
C7 Ru1 C4 61.26(12) . .
C1 Ru1 C3 123.64(13) . .
C2 Ru1 C3 95.70(12) 2_656 .
C2 Ru1 C3 146.88(11) . .
C6 Ru1 C3 61.28(11) . .
C7 Ru1 C3 36.78(11) . .
C4 Ru1 C3 36.30(11) . .
C1 Ru1 C5 138.77(13) . .
C2 Ru1 C5 133.23(12) 2_656 .
C2 Ru1 C5 90.38(12) . .
C6 Ru1 C5 35.85(11) . .
C7 Ru1 C5 60.99(11) . .
C4 Ru1 C5 36.28(10) . .
C3 Ru1 C5 60.40(11) . .
C1 Ru1 Ru1 97.46(10) . 2_656
C2 Ru1 Ru1 48.29(9) 2_656 2_656
C2 Ru1 Ru1 47.36(9) . 2_656
C6 Ru1 Ru1 143.62(8) . 2_656
C7 Ru1 Ru1 162.52(9) . 2_656
C4 Ru1 Ru1 102.91(9) . 2_656
C3 Ru1 Ru1 125.94(8) . 2_656
C5 Ru1 Ru1 111.45(9) . 2_656
C20 N1 C24 116.9(3) . .
O1 C1 Ru1 178.0(3) . .
O2 C2 Ru1 140.3(3) . 2_656
O2 C2 Ru1 135.2(3) . .
Ru1 C2 Ru1 84.35(12) 2_656 .
C4 C3 C7 107.6(3) . .
C4 C3 C14 124.7(3) . .
C7 C3 C14 127.6(3) . .
C4 C3 Ru1 71.03(17) . .
C7 C3 Ru1 70.03(17) . .
C14 C3 Ru1 127.6(2) . .
C3 C4 C5 108.6(3) . .
C3 C4 Ru1 72.67(18) . .
C5 C4 Ru1 73.05(18) . .
C3 C4 H4 125.5 . .
C5 C4 H4 125.5 . .
Ru1 C4 H4 125.5 . .
C6 C5 C4 107.9(3) . .
C6 C5 C20 125.9(3) . .
C4 C5 C20 126.1(3) . .
C6 C5 Ru1 69.61(18) . .
C4 C5 Ru1 70.67(17) . .
C20 C5 Ru1 128.5(2) . .
C5 C6 C7 108.9(3) . .
C5 C6 Ru1 74.54(19) . .
C7 C6 Ru1 71.72(18) . .
C5 C6 H6 125.4 . .
C7 C6 H6 125.4 . .
Ru1 C6 H6 125.4 . .
C3 C7 C6 106.9(3) . .
C3 C7 C8 129.6(3) . .
C6 C7 C8 122.8(3) . .
C3 C7 Ru1 73.19(18) . .
C6 C7 Ru1 70.82(18) . .
C8 C7 Ru1 128.9(2) . .
C13 C8 C9 117.6(3) . .
C13 C8 C7 121.8(3) . .
C9 C8 C7 120.4(3) . .
C10 C9 C8 121.3(4) . .
C10 C9 H9 119.4 . .
C8 C9 H9 119.4 . .
C9 C10 C11 119.9(4) . .
C9 C10 H10 120.1 . .
C11 C10 H10 120.1 . .
C12 C11 C10 119.4(4) . .
C12 C11 H11 120.3 . .
C10 C11 H11 120.3 . .
C11 C12 C13 121.1(4) . .
C11 C12 H12 119.4 . .
C13 C12 H12 119.4 . .
C12 C13 C8 120.7(4) . .
C12 C13 H13 119.6 . .
C8 C13 H13 119.6 . .
C19 C14 C15 118.5(3) . .
C19 C14 C3 119.2(3) . .
C15 C14 C3 122.2(3) . .
C16 C15 C14 121.1(3) . .
C16 C15 H15 119.4 . .
C14 C15 H15 119.4 . .
C15 C16 C17 119.9(3) . .
C15 C16 H16 120.0 . .
C17 C16 H16 120.0 . .
C18 C17 C16 119.6(3) . .
C18 C17 H17 120.2 . .
C16 C17 H17 120.2 . .
C17 C18 C19 120.5(3) . .
C17 C18 H18 119.7 . .
C19 C18 H18 119.7 . .
C14 C19 C18 120.3(3) . .
C14 C19 H19 119.9 . .
C18 C19 H19 119.9 . .
N1 C20 C21 123.1(3) . .
N1 C20 C5 116.0(3) . .
C21 C20 C5 120.8(3) . .
C22 C21 C20 118.8(4) . .
C22 C21 H21 120.6 . .
C20 C21 H21 120.6 . .
C23 C22 C21 119.1(4) . .
C23 C22 H22 120.4 . .
C21 C22 H22 120.4 . .
C22 C23 C24 119.3(4) . .
C22 C23 H23 120.3 . .
C24 C23 H23 120.3 . .
N1 C24 C23 122.7(4) . .
N1 C24 H24 118.6 . .
C23 C24 H24 118.6 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ru1 C1 1.859(3) .
Ru1 C2 2.031(3) 2_656
Ru1 C2 2.061(3) .
Ru1 C6 2.246(3) .
Ru1 C7 2.258(3) .
Ru1 C4 2.278(3) .
Ru1 C3 2.300(3) .
Ru1 C5 2.309(3) .
Ru1 Ru1 2.7478(6) 2_656
O1 C1 1.146(4) .
O2 C2 1.169(3) .
N1 C20 1.332(4) .
N1 C24 1.352(4) .
C2 Ru1 2.031(3) 2_656
C3 C4 1.426(4) .
C3 C7 1.438(4) .
C3 C14 1.491(4) .
C4 C5 1.429(4) .
C4 H4 0.9800 .
C5 C6 1.403(4) .
C5 C20 1.483(4) .
C6 C7 1.446(4) .
C6 H6 0.9800 .
C7 C8 1.479(5) .
C8 C13 1.389(4) .
C8 C9 1.392(5) .
C9 C10 1.371(5) .
C9 H9 0.9300 .
C10 C11 1.379(5) .
C10 H10 0.9300 .
C11 C12 1.365(5) .
C11 H11 0.9300 .
C12 C13 1.366(5) .
C12 H12 0.9300 .
C13 H13 0.9300 .
C14 C19 1.379(4) .
C14 C15 1.381(4) .
C15 C16 1.369(4) .
C15 H15 0.9300 .
C16 C17 1.375(5) .
C16 H16 0.9300 .
C17 C18 1.365(5) .
C17 H17 0.9300 .
C18 C19 1.380(5) .
C18 H18 0.9300 .
C19 H19 0.9300 .
C20 C21 1.385(4) .
C21 C22 1.375(5) .
C21 H21 0.9300 .
C22 C23 1.355(6) .
C22 H22 0.9300 .
C23 C24 1.381(5) .
C23 H23 0.9300 .
C24 H24 0.9300 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C2 Ru1 C1 O1 -104(9) 2_656 .
C2 Ru1 C1 O1 162(9) . .
C6 Ru1 C1 O1 57(9) . .
C7 Ru1 C1 O1 20(9) . .
C4 Ru1 C1 O1 10(9) . .
C3 Ru1 C1 O1 -8(9) . .
C5 Ru1 C1 O1 74(9) . .
Ru1 Ru1 C1 O1 -151(9) 2_656 .
C1 Ru1 C2 O2 -81.4(4) . .
C2 Ru1 C2 O2 -169.2(3) 2_656 .
C6 Ru1 C2 O2 24.2(4) . .
C7 Ru1 C2 O2 18.7(5) . .
C4 Ru1 C2 O2 88.2(4) . .
C3 Ru1 C2 O2 84.1(4) . .
C5 Ru1 C2 O2 57.4(4) . .
Ru1 Ru1 C2 O2 176.8(4) 2_656 .
C1 Ru1 C2 Ru1 101.81(12) . 2_656
C2 Ru1 C2 Ru1 13.98(16) 2_656 2_656
C6 Ru1 C2 Ru1 -152.60(11) . 2_656
C7 Ru1 C2 Ru1 -158.10(15) . 2_656
C4 Ru1 C2 Ru1 -88.66(12) . 2_656
C3 Ru1 C2 Ru1 -92.8(2) . 2_656
C5 Ru1 C2 Ru1 -119.41(11) . 2_656
C1 Ru1 C3 C4 168.92(19) . .
C2 Ru1 C3 C4 -99.74(19) 2_656 .
C2 Ru1 C3 C4 6.5(3) . .
C6 Ru1 C3 C4 78.8(2) . .
C7 Ru1 C3 C4 117.7(3) . .
C5 Ru1 C3 C4 37.55(18) . .
Ru1 Ru1 C3 C4 -58.63(19) 2_656 .
C1 Ru1 C3 C7 51.3(2) . .
C2 Ru1 C3 C7 142.58(18) 2_656 .
C2 Ru1 C3 C7 -111.1(3) . .
C6 Ru1 C3 C7 -38.86(17) . .
C4 Ru1 C3 C7 -117.7(3) . .
C5 Ru1 C3 C7 -80.12(19) . .
Ru1 Ru1 C3 C7 -176.30(14) 2_656 .
C1 Ru1 C3 C14 -71.4(3) . .
C2 Ru1 C3 C14 20.0(3) 2_656 .
C2 Ru1 C3 C14 126.2(3) . .
C6 Ru1 C3 C14 -161.5(3) . .
C7 Ru1 C3 C14 -122.6(4) . .
C4 Ru1 C3 C14 119.7(4) . .
C5 Ru1 C3 C14 157.3(3) . .
Ru1 Ru1 C3 C14 61.1(3) 2_656 .
C7 C3 C4 C5 -3.9(3) . .
C14 C3 C4 C5 172.2(3) . .
Ru1 C3 C4 C5 -64.7(2) . .
C7 C3 C4 Ru1 60.8(2) . .
C14 C3 C4 Ru1 -123.1(3) . .
C1 Ru1 C4 C3 -25.8(4) . .
C2 Ru1 C4 C3 85.5(2) 2_656 .
C2 Ru1 C4 C3 -176.20(18) . .
C6 Ru1 C4 C3 -80.3(2) . .
C7 Ru1 C4 C3 -37.21(17) . .
C5 Ru1 C4 C3 -116.4(3) . .
Ru1 Ru1 C4 C3 134.83(17) 2_656 .
C1 Ru1 C4 C5 90.6(4) . .
C2 Ru1 C4 C5 -158.1(2) 2_656 .
C2 Ru1 C4 C5 -59.8(2) . .
C6 Ru1 C4 C5 36.13(19) . .
C7 Ru1 C4 C5 79.2(2) . .
C3 Ru1 C4 C5 116.4(3) . .
Ru1 Ru1 C4 C5 -108.77(19) 2_656 .
C3 C4 C5 C6 4.5(4) . .
Ru1 C4 C5 C6 -59.9(2) . .
C3 C4 C5 C20 -171.5(3) . .
Ru1 C4 C5 C20 124.1(3) . .
C3 C4 C5 Ru1 64.5(2) . .
C1 Ru1 C5 C6 -27.6(3) . .
C2 Ru1 C5 C6 148.8(2) 2_656 .
C2 Ru1 C5 C6 -115.42(19) . .
C7 Ru1 C5 C6 38.52(18) . .
C4 Ru1 C5 C6 118.5(3) . .
C3 Ru1 C5 C6 80.9(2) . .
Ru1 Ru1 C5 C6 -158.93(15) 2_656 .
C1 Ru1 C5 C4 -146.2(2) . .
C2 Ru1 C5 C4 30.3(3) 2_656 .
C2 Ru1 C5 C4 126.1(2) . .
C6 Ru1 C5 C4 -118.5(3) . .
C7 Ru1 C5 C4 -80.0(2) . .
C3 Ru1 C5 C4 -37.57(19) . .
Ru1 Ru1 C5 C4 82.6(2) 2_656 .
C1 Ru1 C5 C20 92.6(3) . .
C2 Ru1 C5 C20 -90.9(3) 2_656 .
C2 Ru1 C5 C20 4.8(3) . .
C6 Ru1 C5 C20 120.3(4) . .
C7 Ru1 C5 C20 158.8(3) . .
C4 Ru1 C5 C20 -121.2(4) . .
C3 Ru1 C5 C20 -158.8(3) . .
Ru1 Ru1 C5 C20 -38.7(3) 2_656 .
C4 C5 C6 C7 -3.4(4) . .
C20 C5 C6 C7 172.6(3) . .
Ru1 C5 C6 C7 -64.0(2) . .
C4 C5 C6 Ru1 60.6(2) . .
C20 C5 C6 Ru1 -123.4(3) . .
C1 Ru1 C6 C5 161.50(18) . .
C2 Ru1 C6 C5 -74.6(4) 2_656 .
C2 Ru1 C6 C5 69.14(19) . .
C7 Ru1 C6 C5 -116.4(3) . .
C4 Ru1 C6 C5 -36.56(18) . .
C3 Ru1 C6 C5 -78.27(19) . .
Ru1 Ru1 C6 C5 34.3(2) 2_656 .
C1 Ru1 C6 C7 -82.1(2) . .
C2 Ru1 C6 C7 41.8(4) 2_656 .
C2 Ru1 C6 C7 -174.44(19) . .
C4 Ru1 C6 C7 79.9(2) . .
C3 Ru1 C6 C7 38.15(18) . .
C5 Ru1 C6 C7 116.4(3) . .
Ru1 Ru1 C6 C7 150.76(15) 2_656 .
C4 C3 C7 C6 1.8(3) . .
C14 C3 C7 C6 -174.2(3) . .
Ru1 C3 C7 C6 63.2(2) . .
C4 C3 C7 C8 171.5(3) . .
C14 C3 C7 C8 -4.4(5) . .
Ru1 C3 C7 C8 -127.0(3) . .
C4 C3 C7 Ru1 -61.5(2) . .
C14 C3 C7 Ru1 122.6(3) . .
C5 C6 C7 C3 1.0(4) . .
Ru1 C6 C7 C3 -64.8(2) . .
C5 C6 C7 C8 -169.6(3) . .
Ru1 C6 C7 C8 124.6(3) . .
C5 C6 C7 Ru1 65.8(2) . .
C1 Ru1 C7 C3 -139.08(18) . .
C2 Ru1 C7 C3 -46.5(2) 2_656 .
C2 Ru1 C7 C3 124.0(2) . .
C6 Ru1 C7 C3 115.2(3) . .
C4 Ru1 C7 C3 36.72(16) . .
C5 Ru1 C7 C3 78.38(19) . .
Ru1 Ru1 C7 C3 10.0(4) 2_656 .
C1 Ru1 C7 C6 105.7(2) . .
C2 Ru1 C7 C6 -161.74(18) 2_656 .
C2 Ru1 C7 C6 8.8(3) . .
C4 Ru1 C7 C6 -78.5(2) . .
C3 Ru1 C7 C6 -115.2(3) . .
C5 Ru1 C7 C6 -36.85(18) . .
Ru1 Ru1 C7 C6 -105.2(3) 2_656 .
C1 Ru1 C7 C8 -11.4(3) . .
C2 Ru1 C7 C8 81.2(3) 2_656 .
C2 Ru1 C7 C8 -108.3(3) . .
C6 Ru1 C7 C8 -117.1(4) . .
C4 Ru1 C7 C8 164.4(3) . .
C3 Ru1 C7 C8 127.7(3) . .
C5 Ru1 C7 C8 -153.9(3) . .
Ru1 Ru1 C7 C8 137.7(3) 2_656 .
C3 C7 C8 C13 -28.9(5) . .
C6 C7 C8 C13 139.4(3) . .
Ru1 C7 C8 C13 -129.6(3) . .
C3 C7 C8 C9 157.1(3) . .
C6 C7 C8 C9 -34.6(5) . .
Ru1 C7 C8 C9 56.4(4) . .
C13 C8 C9 C10 0.4(5) . .
C7 C8 C9 C10 174.6(3) . .
C8 C9 C10 C11 0.5(6) . .
C9 C10 C11 C12 -0.6(6) . .
C10 C11 C12 C13 -0.2(7) . .
C11 C12 C13 C8 1.2(6) . .
C9 C8 C13 C12 -1.2(5) . .
C7 C8 C13 C12 -175.3(3) . .
C4 C3 C14 C19 -44.3(5) . .
C7 C3 C14 C19 131.0(4) . .
Ru1 C3 C14 C19 -136.2(3) . .
C4 C3 C14 C15 139.6(3) . .
C7 C3 C14 C15 -45.1(5) . .
Ru1 C3 C14 C15 47.6(5) . .
C19 C14 C15 C16 -1.6(6) . .
C3 C14 C15 C16 174.6(3) . .
C14 C15 C16 C17 1.3(6) . .
C15 C16 C17 C18 0.3(6) . .
C16 C17 C18 C19 -1.6(6) . .
C15 C14 C19 C18 0.3(6) . .
C3 C14 C19 C18 -176.0(3) . .
C17 C18 C19 C14 1.3(6) . .
C24 N1 C20 C21 -0.5(5) . .
C24 N1 C20 C5 176.8(3) . .
C6 C5 C20 N1 175.9(3) . .
C4 C5 C20 N1 -8.8(5) . .
Ru1 C5 C20 N1 84.4(4) . .
C6 C5 C20 C21 -6.7(5) . .
C4 C5 C20 C21 168.6(3) . .
Ru1 C5 C20 C21 -98.2(4) . .
N1 C20 C21 C22 0.1(6) . .
C5 C20 C21 C22 -177.1(3) . .
C20 C21 C22 C23 0.8(6) . .
C21 C22 C23 C24 -1.2(7) . .
C20 N1 C24 C23 0.0(5) . .
C22 C23 C24 N1 0.8(6) . .
