#------------------------------------------------------------------------------
#$Date: 2016-02-16 22:30:59 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176467 $
#$URL: svn://www.crystallography.net/cod/cif/4/07/13/4071333.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4071333
loop_
_publ_author_name
'Yang, Liangru'
'Krüger, Anneke'
'Neels, Antonia'
'Albrecht, Martin'
_publ_section_title
;
 Rhodium(III) Complexes Containing C4-Bound N-Heterocyclic Carbenes:
 Synthesis, Coordination Chemistry, and Catalytic Activity in Transfer
 Hydrogenation
;
_journal_issue                   13
_journal_name_full               Organometallics
_journal_page_first              3161
_journal_paper_doi               10.1021/om800110c
_journal_volume                  27
_journal_year                    2008
_chemical_formula_sum            'C148.5 H171 Cl16.5 N12 O1.5 P3 Rh3'
_chemical_formula_weight         3134.54
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                94.133(12)
_cell_angle_beta                 101.237(10)
_cell_angle_gamma                103.493(10)
_cell_formula_units_Z            2
_cell_length_a                   15.964(2)
_cell_length_b                   19.617(3)
_cell_length_c                   25.720(4)
_cell_measurement_reflns_used    13742
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      21.74
_cell_measurement_theta_min      1.08
_cell_volume                     7624(2)
_computing_cell_refinement       'STOE X-AREA'
_computing_data_collection       'STOE X-AREA'
_computing_data_reduction        'STOE X-RED'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_detector_area_resol_mean 6.67
_diffrn_measured_fraction_theta_full 0.988
_diffrn_measured_fraction_theta_max 0.988
_diffrn_measurement_device_type  'STOE IPDS 2'
_diffrn_measurement_method       'rotation method'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.2473
_diffrn_reflns_av_sigmaI/netI    0.4111
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            70205
_diffrn_reflns_theta_full        25.20
_diffrn_reflns_theta_max         25.20
_diffrn_reflns_theta_min         1.27
_exptl_absorpt_coefficient_mu    0.695
_exptl_absorpt_correction_T_max  0.912
_exptl_absorpt_correction_T_min  0.834
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'MULABS, (PLATON03, Speck, 2003)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.366
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             3237
_exptl_crystal_size_max          0.45
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.05
_refine_diff_density_max         1.533
_refine_diff_density_min         -0.845
_refine_diff_density_rms         0.130
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.821
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1400
_refine_ls_number_reflns         27138
_refine_ls_number_restraints     15
_refine_ls_restrained_S_all      0.821
_refine_ls_R_factor_all          0.2865
_refine_ls_R_factor_gt           0.1008
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0886P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2116
_refine_ls_wR_factor_ref         0.2790
_reflns_number_gt                7263
_reflns_number_total             27138
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om800110c-file013.cif
_cod_data_source_block           compound-6
_cod_original_cell_volume        7623.6(19)
_cod_original_formula_sum        'C148.50 H171 Cl16.50 N12 O1.50 P3 Rh3'
_cod_database_code               4071333
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C -0.3328(10) -0.4068(8) 0.1225(6) 0.045(4) Uani 1 1 d . . .
C2 C -0.3612(10) -0.3856(7) 0.0720(6) 0.045(4) Uani 1 1 d . . .
H2A H -0.3281 -0.3797 0.0450 0.054 Uiso 1 1 calc R . .
C3 C -0.4712(10) -0.3875(8) 0.1138(6) 0.043(4) Uani 1 1 d . . .
C4 C -0.4134(10) -0.4404(8) 0.1937(6) 0.0514(14) Uani 1 1 d . . .
H4A H -0.4257 -0.4923 0.1856 0.062 Uiso 1 1 calc R . .
H4B H -0.4635 -0.4291 0.2070 0.062 Uiso 1 1 calc R . .
C5 C -0.3292(11) -0.3994(8) 0.2895(7) 0.0514(14) Uani 1 1 d . . .
C6 C -0.1937(11) -0.4022(8) 0.2763(6) 0.0514(14) Uani 1 1 d . . .
H6A H -0.1324 -0.4000 0.2847 0.062 Uiso 1 1 calc R . .
C7 C -0.2471(11) -0.4166(8) 0.2255(6) 0.0514(14) Uani 1 1 d . . .
C8 C -0.4894(11) -0.3417(9) 0.0236(6) 0.057(5) Uani 1 1 d . . .
H8A H -0.4455 -0.3032 0.0135 0.069 Uiso 1 1 calc R . .
H8B H -0.5338 -0.3209 0.0361 0.069 Uiso 1 1 calc R . .
C9 C -0.5345(11) -0.3962(9) -0.0251(7) 0.060(5) Uani 1 1 d . . .
H9A H -0.5772 -0.4347 -0.0141 0.072 Uiso 1 1 calc R . .
H9B H -0.5687 -0.3735 -0.0518 0.072 Uiso 1 1 calc R . .
C10 C -0.4751(14) -0.4280(10) -0.0514(7) 0.073(6) Uani 1 1 d . . .
H10A H -0.4402 -0.4498 -0.0243 0.088 Uiso 1 1 calc R . .
H10B H -0.5123 -0.4666 -0.0790 0.088 Uiso 1 1 calc R . .
C11 C -0.4134(16) -0.3811(13) -0.0766(8) 0.103(8) Uani 1 1 d . . .
H11A H -0.3782 -0.4082 -0.0923 0.155 Uiso 1 1 calc R . .
H11B H -0.3742 -0.3434 -0.0496 0.155 Uiso 1 1 calc R . .
H11C H -0.4466 -0.3604 -0.1046 0.155 Uiso 1 1 calc R . .
C12 C -0.5562(11) -0.3879(7) 0.1253(6) 0.047(4) Uani 1 1 d . . .
C13 C -0.6349(11) -0.4279(7) 0.0954(6) 0.044(4) Uani 1 1 d . . .
H13A H -0.6351 -0.4552 0.0633 0.053 Uiso 1 1 calc R . .
C14 C -0.7113(11) -0.4302(9) 0.1093(7) 0.054(5) Uani 1 1 d . . .
H14A H -0.7650 -0.4592 0.0880 0.065 Uiso 1 1 calc R . .
C15 C -0.7107(13) -0.3887(9) 0.1565(7) 0.063(5) Uani 1 1 d . . .
H15A H -0.7641 -0.3906 0.1681 0.076 Uiso 1 1 calc R . .
C16 C -0.6329(13) -0.3456(8) 0.1856(7) 0.061(5) Uani 1 1 d . . .
H16A H -0.6333 -0.3160 0.2165 0.073 Uiso 1 1 calc R . .
C17 C -0.5573(12) -0.3446(9) 0.1716(7) 0.057(5) Uani 1 1 d . . .
H17A H -0.5038 -0.3148 0.1925 0.069 Uiso 1 1 calc R . .
C18 C -0.4020(10) -0.3948(8) 0.3128(6) 0.0514(14) Uani 1 1 d . . .
C19 C -0.4297(10) -0.4459(8) 0.3439(6) 0.0514(14) Uani 1 1 d . . .
H19A H -0.4002 -0.4825 0.3495 0.062 Uiso 1 1 calc R . .
C20 C -0.5000(10) -0.4441(8) 0.3671(6) 0.0514(14) Uani 1 1 d . . .
H20A H -0.5211 -0.4809 0.3870 0.062 Uiso 1 1 calc R . .
C21 C -0.5420(10) -0.3862(8) 0.3613(6) 0.0514(14) Uani 1 1 d . . .
H21A H -0.5887 -0.3826 0.3785 0.062 Uiso 1 1 calc R . .
C22 C -0.5115(10) -0.3379(8) 0.3305(6) 0.0514(14) Uani 1 1 d . . .
H22A H -0.5400 -0.3008 0.3248 0.062 Uiso 1 1 calc R . .
C23 C -0.4404(10) -0.3388(8) 0.3063(6) 0.0514(14) Uani 1 1 d . . .
H23A H -0.4193 -0.3023 0.2862 0.062 Uiso 1 1 calc R . .
C24 C -0.2091(14) -0.3713(12) 0.3721(7) 0.091(4) Uani 1 1 d . . .
H24A H -0.1537 -0.3335 0.3786 0.109 Uiso 1 1 calc R . .
H24B H -0.2527 -0.3523 0.3872 0.109 Uiso 1 1 calc R . .
C25 C -0.1921(14) -0.4319(12) 0.3999(7) 0.091(4) Uani 1 1 d . . .
H25A H -0.1421 -0.4463 0.3889 0.109 Uiso 1 1 calc R . .
H25B H -0.2448 -0.4724 0.3891 0.109 Uiso 1 1 calc R . .
C26 C -0.1707(14) -0.4143(13) 0.4606(7) 0.091(4) Uani 1 1 d . . .
H26A H -0.1500 -0.4531 0.4772 0.109 Uiso 1 1 calc R . .
H26B H -0.1222 -0.3707 0.4711 0.109 Uiso 1 1 calc R . .
C27 C -0.2492(14) -0.4039(12) 0.4810(7) 0.091(4) Uani 1 1 d . . .
H27A H -0.2323 -0.3914 0.5198 0.137 Uiso 1 1 calc R . .
H27B H -0.2963 -0.4477 0.4721 0.137 Uiso 1 1 calc R . .
H27C H -0.2701 -0.3658 0.4643 0.137 Uiso 1 1 calc R . .
C28 C -0.0845(9) -0.2857(7) 0.2230(6) 0.041(4) Uani 1 1 d . . .
C29 C -0.0083(10) -0.3033(8) 0.2513(7) 0.053(5) Uani 1 1 d . . .
H29A H 0.0172 -0.3349 0.2338 0.063 Uiso 1 1 calc R . .
C30 C 0.0292(12) -0.2757(9) 0.3033(7) 0.064(5) Uani 1 1 d . . .
H30A H 0.0800 -0.2884 0.3214 0.076 Uiso 1 1 calc R . .
C31 C -0.0070(11) -0.2288(9) 0.3299(7) 0.063(5) Uani 1 1 d . . .
H31A H 0.0193 -0.2100 0.3661 0.076 Uiso 1 1 calc R . .
C32 C -0.0814(11) -0.2096(8) 0.3037(7) 0.065(6) Uani 1 1 d . . .
H32A H -0.1052 -0.1771 0.3215 0.078 Uiso 1 1 calc R . .
C33 C -0.1219(12) -0.2395(9) 0.2494(6) 0.061(5) Uani 1 1 d . . .
H33A H -0.1737 -0.2280 0.2315 0.073 Uiso 1 1 calc R . .
C34 C -0.0302(11) -0.3247(9) 0.1322(6) 0.053(5) Uani 1 1 d . . .
C35 C -0.0054(11) -0.3844(9) 0.1148(7) 0.054(5) Uani 1 1 d . . .
H35A H -0.0402 -0.4307 0.1153 0.065 Uiso 1 1 calc R . .
C36 C 0.0751(12) -0.3727(10) 0.0962(7) 0.065(6) Uani 1 1 d . . .
H36A H 0.0922 -0.4126 0.0829 0.078 Uiso 1 1 calc R . .
C37 C 0.1281(12) -0.3075(12) 0.0965(7) 0.073(6) Uani 1 1 d . . .
H37A H 0.1801 -0.3018 0.0828 0.087 Uiso 1 1 calc R . .
C38 C 0.1038(12) -0.2483(10) 0.1179(7) 0.063(5) Uani 1 1 d . . .
H38A H 0.1408 -0.2020 0.1203 0.075 Uiso 1 1 calc R . .
C39 C 0.0245(11) -0.2588(10) 0.1354(8) 0.068(5) Uani 1 1 d . . .
H39A H 0.0083 -0.2191 0.1498 0.081 Uiso 1 1 calc R . .
C40 C -0.1787(10) -0.2735(8) 0.1145(6) 0.044(4) Uani 1 1 d . . .
C41 C -0.1610(11) -0.2654(9) 0.0632(6) 0.054(5) Uani 1 1 d . . .
H41A H -0.1176 -0.2859 0.0527 0.065 Uiso 1 1 calc R . .
C42 C -0.2053(12) -0.2281(10) 0.0274(8) 0.070(6) Uani 1 1 d . . .
H42A H -0.1942 -0.2246 -0.0074 0.084 Uiso 1 1 calc R . .
C43 C -0.2641(14) -0.1974(9) 0.0441(8) 0.069(6) Uani 1 1 d . . .
H43A H -0.2915 -0.1698 0.0208 0.083 Uiso 1 1 calc R . .
C44 C -0.2877(12) -0.2036(8) 0.0938(8) 0.066(5) Uani 1 1 d . . .
H44A H -0.3301 -0.1817 0.1040 0.080 Uiso 1 1 calc R . .
C45 C -0.2439(11) -0.2450(8) 0.1282(7) 0.057(5) Uani 1 1 d . . .
H45A H -0.2601 -0.2529 0.1614 0.068 Uiso 1 1 calc R . .
C46 C -0.2289(10) -0.0744(8) 0.2732(6) 0.041(4) Uiso 1 1 d . . .
C47 C -0.1967(10) -0.0689(7) 0.2263(8) 0.061(6) Uani 1 1 d . . .
H47A H -0.2347 -0.0840 0.1921 0.073 Uiso 1 1 calc R . .
C48 C -0.0757(12) -0.0195(8) 0.2871(6) 0.049(5) Uani 1 1 d . . .
C49 C -0.1402(10) -0.0331(8) 0.3653(6) 0.044(4) Uani 1 1 d . . .
H49A H -0.1375 -0.0795 0.3773 0.053 Uiso 1 1 calc R . .
H49B H -0.0850 0.0020 0.3835 0.053 Uiso 1 1 calc R . .
C50 C -0.2061(10) 0.0307(8) 0.4254(6) 0.049(4) Uani 1 1 d . . .
C51 C -0.3459(11) -0.0144(8) 0.3876(6) 0.052(4) Uani 1 1 d . . .
H51A H -0.4084 -0.0242 0.3821 0.062 Uiso 1 1 calc R . .
C52 C -0.3015(10) -0.0411(7) 0.3545(6) 0.043(4) Uani 1 1 d . . .
C53 C -0.0553(18) -0.0180(13) 0.1907(11) 0.124(5) Uani 1 1 d . . .
H53A H -0.0872 0.0088 0.1662 0.149 Uiso 1 1 calc R . .
H53B H 0.0035 0.0131 0.2077 0.149 Uiso 1 1 calc R . .
C54 C -0.0450(18) -0.0796(13) 0.1608(11) 0.124(5) Uani 1 1 d . B .
H54A H -0.1044 -0.1110 0.1457 0.149 Uiso 1 1 calc R . .
H54B H -0.0127 -0.1054 0.1860 0.149 Uiso 1 1 calc R . .
C55 C 0.0041(19) -0.0656(14) 0.1144(12) 0.124(5) Uani 1 1 d . . .
H55A H 0.0004 -0.1111 0.0936 0.149 Uiso 0.50 1 calc PR A 1
H55B H -0.0246 -0.0368 0.0901 0.149 Uiso 0.50 1 calc PR A 1
H55C H 0.0674 -0.0505 0.1285 0.149 Uiso 0.50 1 d PR A 2
H55D H -0.0088 -0.1083 0.0897 0.149 Uiso 0.50 1 d PR A 2
C56 C 0.089(3) -0.032(3) 0.134(2) 0.124(5) Uani 0.50 1 d P B 1
H56A H 0.1185 -0.0235 0.1038 0.186 Uiso 0.50 1 calc PR B 1
H56B H 0.1174 -0.0606 0.1571 0.186 Uiso 0.50 1 calc PR B 1
H56C H 0.0924 0.0136 0.1536 0.186 Uiso 0.50 1 calc PR B 1
C56A C -0.023(4) -0.017(3) 0.090(2) 0.124(5) Uani 0.50 1 d P B 2
H56D H 0.0063 -0.0066 0.0608 0.186 Uiso 0.50 1 calc PR B 2
H56E H -0.0096 0.0262 0.1158 0.186 Uiso 0.50 1 calc PR B 2
H56F H -0.0872 -0.0326 0.0765 0.186 Uiso 0.50 1 calc PR B 2
C57 C 0.0153(11) 0.0085(9) 0.3140(7) 0.062(2) Uani 1 1 d . . .
C58 C 0.0763(11) -0.0325(9) 0.3116(7) 0.062(2) Uani 1 1 d . . .
H58A H 0.0595 -0.0766 0.2896 0.075 Uiso 1 1 calc R . .
C59 C 0.1623(11) -0.0067(9) 0.3425(7) 0.062(2) Uani 1 1 d . . .
H59A H 0.2029 -0.0353 0.3429 0.075 Uiso 1 1 calc R . .
C60 C 0.1898(11) 0.0594(9) 0.3723(7) 0.062(2) Uani 1 1 d . . .
H60A H 0.2488 0.0761 0.3924 0.075 Uiso 1 1 calc R . .
C61 C 0.1310(10) 0.1007(9) 0.3727(7) 0.062(2) Uani 1 1 d . . .
H61A H 0.1505 0.1467 0.3920 0.075 Uiso 1 1 calc R . .
C62 C 0.0434(11) 0.0762(9) 0.3451(7) 0.062(2) Uani 1 1 d . . .
H62A H 0.0028 0.1043 0.3470 0.075 Uiso 1 1 calc R . .
C63 C -0.1222(11) 0.0654(8) 0.4642(6) 0.047(4) Uani 1 1 d . . .
C64 C -0.0556(11) 0.1100(9) 0.4488(7) 0.055(5) Uani 1 1 d . . .
H64A H -0.0631 0.1213 0.4132 0.066 Uiso 1 1 calc R . .
C65 C 0.0242(10) 0.1396(8) 0.4855(7) 0.057(5) Uani 1 1 d . . .
H65A H 0.0708 0.1706 0.4744 0.068 Uiso 1 1 calc R . .
C66 C 0.0363(13) 0.1242(9) 0.5379(8) 0.069(6) Uani 1 1 d . . .
H66A H 0.0912 0.1426 0.5625 0.083 Uiso 1 1 calc R . .
C67 C -0.0348(13) 0.0810(10) 0.5530(7) 0.067(6) Uani 1 1 d . . .
H67A H -0.0291 0.0742 0.5896 0.081 Uiso 1 1 calc R . .
C68 C -0.1104(11) 0.0486(8) 0.5193(6) 0.054(5) Uani 1 1 d . . .
H68A H -0.1552 0.0157 0.5305 0.065 Uiso 1 1 calc R . .
C69 C -0.3103(12) 0.0698(10) 0.4741(7) 0.064(5) Uani 1 1 d . . .
H69A H -0.2559 0.1035 0.4951 0.077 Uiso 1 1 calc R . .
H69B H -0.3505 0.0978 0.4580 0.077 Uiso 1 1 calc R . .
C70 C -0.3524(12) 0.0272(10) 0.5105(7) 0.064(5) Uani 1 1 d . . .
H70A H -0.3132 -0.0019 0.5262 0.076 Uiso 1 1 calc R . .
H70B H -0.4081 -0.0053 0.4900 0.076 Uiso 1 1 calc R . .
C71 C -0.3725(13) 0.0706(10) 0.5552(7) 0.072(5) Uani 1 1 d . . .
H71A H -0.4147 0.0974 0.5396 0.086 Uiso 1 1 calc R . .
H71B H -0.3174 0.1053 0.5742 0.086 Uiso 1 1 calc R . .
C72 C -0.4119(13) 0.0258(13) 0.5962(8) 0.094(7) Uani 1 1 d . . .
H72A H -0.4247 0.0570 0.6235 0.140 Uiso 1 1 calc R . .
H72B H -0.3694 0.0010 0.6132 0.140 Uiso 1 1 calc R . .
H72C H -0.4666 -0.0086 0.5778 0.140 Uiso 1 1 calc R . .
C73 C -0.4329(11) 0.0347(9) 0.2762(7) 0.059(2) Uani 1 1 d . . .
C74 C -0.5149(12) 0.0357(9) 0.2799(7) 0.059(2) Uani 1 1 d . . .
H74A H -0.5627 -0.0014 0.2603 0.071 Uiso 1 1 calc R . .
C75 C -0.5340(12) 0.0903(8) 0.3123(7) 0.059(2) Uani 1 1 d . . .
H75A H -0.5926 0.0903 0.3146 0.071 Uiso 1 1 calc R . .
C76 C -0.4611(11) 0.1435(9) 0.3402(7) 0.059(2) Uani 1 1 d . . .
H76A H -0.4707 0.1815 0.3614 0.071 Uiso 1 1 calc R . .
C77 C -0.3791(12) 0.1427(9) 0.3380(7) 0.059(2) Uani 1 1 d . . .
H77A H -0.3318 0.1795 0.3583 0.071 Uiso 1 1 calc R . .
C78 C -0.3603(12) 0.0895(8) 0.3070(7) 0.059(2) Uani 1 1 d . . .
H78A H -0.3011 0.0895 0.3061 0.071 Uiso 1 1 calc R . .
C79 C -0.3509(11) 0.0002(8) 0.1886(7) 0.054(5) Uani 1 1 d . . .
C80 C -0.3649(11) -0.0366(8) 0.1370(6) 0.056(5) Uani 1 1 d . . .
H80A H -0.4084 -0.0803 0.1279 0.067 Uiso 1 1 calc R . .
C81 C -0.3188(12) -0.0125(10) 0.0996(7) 0.068(6) Uani 1 1 d . . .
H81A H -0.3319 -0.0393 0.0655 0.081 Uiso 1 1 calc R . .
C82 C -0.2547(13) 0.0491(10) 0.1102(7) 0.069(6) Uani 1 1 d . . .
H82A H -0.2231 0.0651 0.0838 0.083 Uiso 1 1 calc R . .
C83 C -0.2361(13) 0.0876(10) 0.1593(7) 0.066(5) Uani 1 1 d . . .
H83A H -0.1907 0.1302 0.1671 0.079 Uiso 1 1 calc R . .
C84 C -0.2825(11) 0.0656(8) 0.1979(7) 0.057(5) Uani 1 1 d . . .
H84A H -0.2691 0.0942 0.2313 0.069 Uiso 1 1 calc R . .
C85 C -0.5189(11) -0.0759(8) 0.1929(6) 0.054(5) Uani 1 1 d . . .
C86 C -0.5595(10) -0.1461(8) 0.1855(7) 0.058(5) Uani 1 1 d . . .
H86A H -0.5352 -0.1770 0.2071 0.070 Uiso 1 1 calc R . .
C87 C -0.6395(12) -0.1739(9) 0.1451(7) 0.073(6) Uani 1 1 d . . .
H87A H -0.6693 -0.2225 0.1404 0.088 Uiso 1 1 calc R . .
C88 C -0.6723(13) -0.1260(12) 0.1124(8) 0.080(6) Uani 1 1 d . . .
H88A H -0.7222 -0.1427 0.0836 0.096 Uiso 1 1 calc R . .
C89 C -0.6296(12) -0.0541(10) 0.1235(7) 0.068(6) Uani 1 1 d . . .
H89A H -0.6550 -0.0212 0.1049 0.081 Uiso 1 1 calc R . .
C90 C -0.5511(12) -0.0300(9) 0.1609(6) 0.066(5) Uani 1 1 d . . .
H90A H -0.5194 0.0182 0.1647 0.079 Uiso 1 1 calc R . .
C91 C 0.1552(12) -0.2661(8) -0.2428(6) 0.047(4) Uani 1 1 d . . .
C92 C 0.2433(11) -0.2537(7) -0.2434(6) 0.040(4) Uani 1 1 d . . .
H92A H 0.2691 -0.2423 -0.2730 0.048 Uiso 1 1 calc R . .
C93 C 0.2333(12) -0.2764(8) -0.1624(7) 0.052(5) Uani 1 1 d . . .
C94 C 0.0768(11) -0.2875(8) -0.1714(7) 0.060(5) Uani 1 1 d . . .
H94A H 0.0666 -0.2399 -0.1657 0.072 Uiso 1 1 calc R . .
H94B H 0.0871 -0.3049 -0.1361 0.072 Uiso 1 1 calc R . .
C95 C -0.0703(11) -0.3785(8) -0.1879(6) 0.051(4) Uani 1 1 d . . .
C96 C -0.1106(10) -0.3732(9) -0.2767(6) 0.050(4) Uani 1 1 d . . .
H96A H -0.1473 -0.3812 -0.3116 0.061 Uiso 1 1 calc R . .
C97 C -0.0267(11) -0.3287(8) -0.2608(6) 0.051(4) Uani 1 1 d . . .
C98 C 0.3847(13) -0.2581(11) -0.1799(9) 0.092(4) Uani 1 1 d . . .
H98A H 0.4012 -0.2731 -0.1442 0.111 Uiso 1 1 calc R . .
H98B H 0.3958 -0.2921 -0.2064 0.111 Uiso 1 1 calc R . .
C99 C 0.4413(13) -0.1879(11) -0.1810(9) 0.092(4) Uani 1 1 d . D .
H99A H 0.4320 -0.1543 -0.1534 0.111 Uiso 1 1 calc R . .
H99B H 0.4232 -0.1720 -0.2162 0.111 Uiso 1 1 calc R . .
C100 C 0.5397(13) -0.1854(12) -0.1713(9) 0.092(4) Uani 1 1 d . . .
H10E H 0.5748 -0.1361 -0.1694 0.111 Uiso 0.50 1 calc PR C 1
H10F H 0.5585 -0.2034 -0.1371 0.111 Uiso 0.50 1 calc PR C 1
H10G H 0.5710 -0.1401 -0.1793 0.111 Uiso 0.50 1 d PR C 2
H10H H 0.5478 -0.2218 -0.1960 0.111 Uiso 0.50 1 d PR C 2
C101 C 0.553(3) -0.225(2) -0.2116(18) 0.092(4) Uani 0.50 1 d P D 1
H10I H 0.6162 -0.2206 -0.2080 0.139 Uiso 0.50 1 calc PR D 1
H10K H 0.5287 -0.2102 -0.2455 0.139 Uiso 0.50 1 calc PR D 1
H10L H 0.5231 -0.2750 -0.2108 0.139 Uiso 0.50 1 calc PR D 1
C201 C 0.581(3) -0.195(2) -0.1152(17) 0.092(4) Uani 0.50 1 d P D 2
H20B H 0.6439 -0.1909 -0.1120 0.139 Uiso 0.50 1 calc PR D 2
H20C H 0.5523 -0.2420 -0.1073 0.139 Uiso 0.50 1 calc PR D 2
H20D H 0.5725 -0.1588 -0.0898 0.139 Uiso 0.50 1 calc PR D 2
C102 C 0.2548(11) -0.2823(9) -0.1020(6) 0.054(5) Uani 1 1 d . . .
C103 C 0.3050(13) -0.2213(9) -0.0691(6) 0.069(6) Uani 1 1 d . . .
H103 H 0.3217 -0.1784 -0.0837 0.083 Uiso 1 1 calc R . .
C104 C 0.3306(14) -0.2236(11) -0.0146(8) 0.083(7) Uani 1 1 d . . .
H104 H 0.3663 -0.1826 0.0082 0.099 Uiso 1 1 calc R . .
C105 C 0.3028(11) -0.2877(9) 0.0065(7) 0.055(5) Uani 1 1 d . . .
H105 H 0.3195 -0.2897 0.0437 0.066 Uiso 1 1 calc R . .
C106 C 0.2519(10) -0.3468(8) -0.0266(6) 0.044(4) Uani 1 1 d . . .
H106 H 0.2322 -0.3892 -0.0119 0.053 Uiso 1 1 calc R . .
C107 C 0.2284(10) -0.3454(8) -0.0818(6) 0.049(4) Uani 1 1 d . . .
H107 H 0.1952 -0.3869 -0.1049 0.058 Uiso 1 1 calc R . .
C108 C -0.0712(11) -0.3943(8) -0.1341(6) 0.048(4) Uani 1 1 d . . .
C109 C -0.0077(10) -0.4259(7) -0.1075(6) 0.047(4) Uani 1 1 d . . .
H109 H 0.0339 -0.4393 -0.1253 0.057 Uiso 1 1 calc R . .
C110 C -0.0065(12) -0.4373(9) -0.0543(7) 0.061(5) Uani 1 1 d . . .
H110 H 0.0388 -0.4548 -0.0343 0.074 Uiso 1 1 calc R . .
C111 C -0.0722(12) -0.4227(9) -0.0318(7) 0.060(5) Uani 1 1 d . . .
H111 H -0.0732 -0.4337 0.0035 0.072 Uiso 1 1 calc R . .
C112 C -0.1379(11) -0.3929(9) -0.0572(7) 0.056(5) Uani 1 1 d . . .
H112 H -0.1821 -0.3828 -0.0401 0.067 Uiso 1 1 calc R . .
C113 C -0.1346(11) -0.3788(8) -0.1091(7) 0.049(4) Uani 1 1 d . . .
H113 H -0.1774 -0.3578 -0.1280 0.059 Uiso 1 1 calc R . .
C114 C -0.2202(14) -0.4552(13) -0.2357(10) 0.117(5) Uani 1 1 d D . .
H11G H -0.2177 -0.4790 -0.2029 0.140 Uiso 1 1 calc R . .
H11H H -0.2345 -0.4917 -0.2669 0.140 Uiso 1 1 calc R . .
C115 C -0.2916(13) -0.4129(13) -0.2402(9) 0.117(5) Uani 1 1 d D . .
H11I H -0.2655 -0.3672 -0.2171 0.140 Uiso 1 1 calc R . .
H11J H -0.3051 -0.4022 -0.2775 0.140 Uiso 1 1 calc R . .
C116 C -0.3735(13) -0.4447(13) -0.2264(10) 0.117(5) Uani 1 1 d D . .
H11K H -0.3606 -0.4512 -0.1881 0.140 Uiso 1 1 calc R . .
H11L H -0.3967 -0.4924 -0.2469 0.140 Uiso 1 1 calc R . .
C117 C -0.4428(14) -0.4080(13) -0.2353(9) 0.117(5) Uani 1 1 d D . .
H11M H -0.4942 -0.4345 -0.2234 0.175 Uiso 1 1 calc R . .
H11N H -0.4596 -0.4039 -0.2734 0.175 Uiso 1 1 calc R . .
H11O H -0.4216 -0.3608 -0.2150 0.175 Uiso 1 1 calc R . .
C118 C -0.0141(10) -0.4369(7) -0.3575(6) 0.047(4) Uani 1 1 d . . .
C119 C -0.0971(11) -0.4497(8) -0.3941(6) 0.053(5) Uani 1 1 d . . .
H119 H -0.1037 -0.4166 -0.4188 0.064 Uiso 1 1 calc R . .
C120 C -0.1675(12) -0.5052(9) -0.3965(7) 0.065(5) Uani 1 1 d . . .
H120 H -0.2203 -0.5124 -0.4230 0.079 Uiso 1 1 calc R . .
C121 C -0.1584(14) -0.5512(10) -0.3577(8) 0.084(7) Uani 1 1 d . . .
H121 H -0.2058 -0.5905 -0.3570 0.100 Uiso 1 1 calc R . .
C122 C -0.0806(13) -0.5389(10) -0.3210(8) 0.076(6) Uani 1 1 d . . .
H122 H -0.0755 -0.5706 -0.2950 0.091 Uiso 1 1 calc R . .
C123 C -0.0085(11) -0.4827(8) -0.3194(7) 0.063(5) Uani 1 1 d . . .
H123 H 0.0439 -0.4759 -0.2926 0.075 Uiso 1 1 calc R . .
C124 C 0.1765(10) -0.3724(8) -0.3412(6) 0.046(4) Uani 1 1 d . . .
C125 C 0.2390(13) -0.3392(8) -0.3671(6) 0.057(5) Uani 1 1 d . . .
H125 H 0.2206 -0.3122 -0.3943 0.069 Uiso 1 1 calc R . .
C126 C 0.3267(14) -0.3417(10) -0.3571(7) 0.074(6) Uani 1 1 d . . .
H126 H 0.3669 -0.3187 -0.3770 0.089 Uiso 1 1 calc R . .
C127 C 0.3536(13) -0.3822(9) -0.3139(7) 0.058(5) Uani 1 1 d . . .
H127 H 0.4126 -0.3866 -0.3054 0.069 Uiso 1 1 calc R . .
C128 C 0.2939(12) -0.4135(9) -0.2859(8) 0.061(5) Uani 1 1 d . . .
H128 H 0.3126 -0.4392 -0.2579 0.073 Uiso 1 1 calc R . .
C129 C 0.2067(11) -0.4092(8) -0.2970(6) 0.050(4) Uani 1 1 d . . .
H129 H 0.1672 -0.4300 -0.2760 0.060 Uiso 1 1 calc R . .
C130 C 0.0611(11) -0.3490(8) -0.4270(6) 0.052(4) Uani 1 1 d . . .
C131 C 0.0678(12) -0.4091(9) -0.4573(6) 0.063(5) Uani 1 1 d . . .
H131 H 0.0720 -0.4508 -0.4414 0.075 Uiso 1 1 calc R . .
C132 C 0.0682(13) -0.4067(10) -0.5098(8) 0.082(6) Uani 1 1 d . . .
H132 H 0.0739 -0.4470 -0.5302 0.099 Uiso 1 1 calc R . .
C133 C 0.0609(13) -0.3486(10) -0.5342(8) 0.078(6) Uani 1 1 d . . .
H133 H 0.0615 -0.3483 -0.5710 0.093 Uiso 1 1 calc R . .
C134 C 0.0526(13) -0.2907(11) -0.5050(7) 0.078(6) Uani 1 1 d . . .
H134 H 0.0482 -0.2500 -0.5221 0.094 Uiso 1 1 calc R . .
C135 C 0.0504(12) -0.2891(8) -0.4514(6) 0.061(5) Uani 1 1 d . . .
H135 H 0.0419 -0.2490 -0.4320 0.073 Uiso 1 1 calc R . .
C136 C -0.6355(18) 0.2106(19) 0.5515(11) 0.160(2) Uani 1 1 d . . .
H13B H -0.6252 0.2611 0.5461 0.192 Uiso 1 1 calc R . .
H13C H -0.6416 0.2074 0.5889 0.192 Uiso 1 1 calc R . .
C137 C -0.5608(19) 0.189(2) 0.5456(10) 0.160(2) Uani 1 1 d . . .
H13D H -0.5620 0.1446 0.5622 0.192 Uiso 1 1 calc R . .
H13E H -0.5083 0.2249 0.5660 0.192 Uiso 1 1 calc R . .
C138 C -0.672(2) -0.6873(18) 0.4119(15) 0.176(2) Uani 1 1 d . . .
H13F H -0.6143 -0.6906 0.4328 0.212 Uiso 1 1 calc R . .
H13G H -0.7159 -0.6971 0.4345 0.212 Uiso 1 1 calc R . .
C139 C -0.699(2) -0.7381(19) 0.3636(15) 0.176(2) Uani 1 1 d . . .
H13H H -0.7467 -0.7262 0.3375 0.212 Uiso 1 1 calc R . .
H13I H -0.7213 -0.7866 0.3722 0.212 Uiso 1 1 calc R . .
C140 C -0.182(4) -0.199(3) -0.216(2) 0.140(4) Uani 0.50 1 d P . .
H14B H -0.1340 -0.2148 -0.2278 0.168 Uiso 0.50 1 calc PR . .
H14C H -0.2381 -0.2327 -0.2347 0.168 Uiso 0.50 1 calc PR . .
C141 C -0.183(4) -0.137(3) -0.235(2) 0.140(4) Uani 0.50 1 d P . .
H14D H -0.2024 -0.1476 -0.2743 0.168 Uiso 0.50 1 calc PR . .
H14E H -0.1214 -0.1085 -0.2271 0.168 Uiso 0.50 1 calc PR . .
C142 C -0.233(2) -0.7737(13) -0.2505(11) 0.155(2) Uani 1 1 d D . .
H14F H -0.1684 -0.7696 -0.2394 0.186 Uiso 1 1 calc R . .
H14G H -0.2583 -0.7715 -0.2186 0.186 Uiso 1 1 calc R . .
C143 C -0.277(2) -0.8353(13) -0.2872(11) 0.155(2) Uani 1 1 d D . .
H14H H -0.2536 -0.8362 -0.3202 0.186 Uiso 1 1 calc R . .
H14I H -0.3415 -0.8414 -0.2964 0.186 Uiso 1 1 calc R . .
C149 C 0.4814(19) -0.0302(14) 0.0038(14) 0.068(3) Uani 0.50 1 d PD . .
H14J H 0.4168 -0.0401 -0.0098 0.082 Uiso 0.50 1 calc PR . .
H14K H 0.4933 -0.0355 0.0423 0.082 Uiso 0.50 1 calc PR . .
Cl1 Cl -0.2108(3) -0.46845(19) 0.06067(14) 0.0478(10) Uani 1 1 d . . .
Cl2 Cl -0.3266(3) -0.55754(19) 0.15048(15) 0.0471(10) Uani 1 1 d . . .
Cl3 Cl -0.1018(3) -0.4861(2) 0.19419(16) 0.0528(11) Uani 1 1 d . . .
Cl4 Cl -0.4822(3) -0.1520(2) 0.31490(16) 0.0547(11) Uani 1 1 d . . .
Cl5 Cl -0.2733(3) -0.1897(2) 0.33937(17) 0.0603(12) Uani 1 1 d . . .
Cl6 Cl -0.3751(3) -0.1964(2) 0.20940(17) 0.0606(12) Uani 1 1 d . . .
Cl7 Cl -0.0825(3) -0.2651(2) -0.36797(15) 0.0526(11) Uani 1 1 d . . .
Cl8 Cl 0.1476(3) -0.1805(2) -0.33886(16) 0.0567(12) Uani 1 1 d . . .
Cl9 Cl 0.0281(3) -0.1678(2) -0.24311(16) 0.0586(12) Uani 1 1 d . . .
Cl10 Cl -0.7335(5) 0.1663(5) 0.5105(3) 0.160(2) Uani 1 1 d . . .
Cl11 Cl -0.5456(5) 0.1725(5) 0.4770(3) 0.160(2) Uani 1 1 d . . .
Cl12 Cl -0.6628(7) -0.5999(5) 0.3915(4) 0.176(2) Uani 1 1 d . . .
Cl13 Cl -0.5997(7) -0.7304(5) 0.3372(4) 0.176(2) Uani 1 1 d . . .
Cl14 Cl -0.1711(10) -0.2068(7) -0.1510(6) 0.140(4) Uani 0.50 1 d P . .
Cl15 Cl -0.2420(10) -0.0868(7) -0.2157(6) 0.140(4) Uani 0.50 1 d P . .
Cl16 Cl -0.2573(6) -0.7057(4) -0.2957(4) 0.155(2) Uani 1 1 d D . .
Cl17 Cl -0.2433(6) -0.9029(4) -0.2418(4) 0.155(2) Uani 1 1 d D . .
Cl18 Cl 0.5293(6) -0.0919(5) -0.0341(4) 0.068(3) Uani 0.50 1 d PD . .
N1 N -0.4438(9) -0.3751(6) 0.0681(5) 0.047(3) Uani 1 1 d . . .
N2 N -0.4033(8) -0.4073(6) 0.1460(5) 0.048(4) Uani 1 1 d . . .
N3 N -0.3293(7) -0.4128(6) 0.2353(4) 0.036(3) Uani 1 1 d . . .
N4 N -0.2435(8) -0.3917(6) 0.3127(5) 0.048(3) Uani 1 1 d . . .
N5 N -0.1055(9) -0.0401(7) 0.2324(5) 0.054(4) Uani 1 1 d . . .
N6 N -0.1486(8) -0.0375(6) 0.3072(5) 0.039(3) Uani 1 1 d . . .
N7 N -0.2139(9) -0.0129(6) 0.3787(4) 0.044(3) Uani 1 1 d . . .
N8 N -0.2868(9) 0.0293(7) 0.4305(5) 0.047(3) Uani 1 1 d . . .
N9 N 0.2891(9) -0.2610(7) -0.1915(5) 0.044(3) Uani 1 1 d . . .
N10 N 0.1530(8) -0.2813(6) -0.1915(5) 0.039(3) Uani 1 1 d . . .
N11 N -0.0043(9) -0.3351(6) -0.2057(5) 0.048(4) Uani 1 1 d . . .
N12 N -0.1308(9) -0.4030(7) -0.2335(5) 0.055(4) Uani 1 1 d . . .
P1 P -0.1316(3) -0.3325(2) 0.15555(17) 0.0472(11) Uani 1 1 d . . .
P2 P -0.4089(3) -0.0378(2) 0.23765(18) 0.0496(12) Uani 1 1 d . . .
P3 P 0.0680(3) -0.3554(2) -0.35446(16) 0.0473(12) Uani 1 1 d . . .
Rh1 Rh -0.22679(8) -0.44001(6) 0.15319(5) 0.0428(4) Uani 1 1 d . . .
Rh2 Rh -0.34005(9) -0.10826(6) 0.28776(5) 0.0477(4) Uani 1 1 d . . .
Rh3 Rh 0.05042(9) -0.26570(6) -0.29936(5) 0.0453(4) Uani 1 1 d . . .
O1 O -0.3591(16) 0.3443(14) 0.5261(10) 0.188(6) Uani 1 1 d D . .
C145 C -0.284(2) 0.2710(19) 0.5560(13) 0.188(6) Uani 1 1 d D . .
H14L H -0.2499 0.2366 0.5508 0.282 Uiso 1 1 calc R . .
H14M H -0.3376 0.2478 0.5676 0.282 Uiso 1 1 calc R . .
H14N H -0.2485 0.3097 0.5833 0.282 Uiso 1 1 calc R . .
C146 C -0.310(2) 0.3001(19) 0.5038(13) 0.188(6) Uani 1 1 d D . .
H14O H -0.2584 0.3277 0.4917 0.226 Uiso 1 1 calc R . .
H14P H -0.3474 0.2633 0.4749 0.226 Uiso 1 1 calc R . .
C147 C -0.392(2) 0.3745(18) 0.4798(13) 0.188(6) Uani 1 1 d D . .
H14Q H -0.4388 0.3389 0.4542 0.226 Uiso 1 1 calc R . .
H14R H -0.3437 0.3939 0.4616 0.226 Uiso 1 1 calc R . .
C148 C -0.427(2) 0.4321(18) 0.5012(14) 0.188(6) Uani 1 1 d D . .
H14S H -0.4526 0.4552 0.4716 0.282 Uiso 1 1 calc R . .
H14T H -0.3797 0.4669 0.5261 0.282 Uiso 1 1 calc R . .
H14U H -0.4735 0.4119 0.5200 0.282 Uiso 1 1 calc R . .
O2 O -0.136(2) 0.099(2) 0.0018(12) 0.140(10) Uani 0.50 1 d PD . .
C151 C -0.090(4) 0.210(3) 0.0263(17) 0.140(10) Uani 0.50 1 d PD . .
H15B H -0.0437 0.2529 0.0421 0.209 Uiso 0.50 1 calc PR . .
H15C H -0.1410 0.2082 0.0429 0.209 Uiso 0.50 1 calc PR . .
H15D H -0.1085 0.2115 -0.0122 0.209 Uiso 0.50 1 calc PR . .
C152 C -0.057(3) 0.148(2) 0.0356(18) 0.140(10) Uani 0.50 1 d PD . .
H15E H -0.0474 0.1393 0.0735 0.168 Uiso 0.50 1 calc PR . .
H15F H -0.0026 0.1490 0.0220 0.168 Uiso 0.50 1 calc PR . .
C153 C -0.123(3) 0.031(2) 0.0063(18) 0.140(10) Uani 0.50 1 d PD . .
H15G H -0.1170 0.0225 0.0442 0.168 Uiso 0.50 1 calc PR . .
H15H H -0.0660 0.0296 -0.0035 0.168 Uiso 0.50 1 calc PR . .
C154 C -0.194(3) -0.029(3) -0.0272(17) 0.140(10) Uani 0.50 1 d PD . .
H15I H -0.1773 -0.0734 -0.0227 0.209 Uiso 0.50 1 calc PR . .
H15J H -0.2009 -0.0210 -0.0649 0.209 Uiso 0.50 1 calc PR . .
H15K H -0.2494 -0.0308 -0.0160 0.209 Uiso 0.50 1 calc PR . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
N2 C1 C2 102.5(13) .
N2 C1 Rh1 125.3(11) .
C2 C1 Rh1 131.9(13) .
N1 C2 C1 109.5(15) .
N1 C2 H2A 125.3 .
C1 C2 H2A 125.3 .
N1 C3 N2 105.2(14) .
N1 C3 C12 128.3(13) .
N2 C3 C12 126.2(15) .
N2 C4 N3 108.3(12) .
N2 C4 H4A 110.0 .
N3 C4 H4A 110.0 .
N2 C4 H4B 110.0 .
N3 C4 H4B 110.0 .
H4A C4 H4B 108.4 .
N4 C5 N3 102.0(14) .
N4 C5 C18 130.2(15) .
N3 C5 C18 127.9(14) .
N4 C6 C7 109.2(15) .
N4 C6 H6A 125.4 .
C7 C6 H6A 125.4 .
C6 C7 N3 102.3(14) .
C6 C7 Rh1 133.9(14) .
N3 C7 Rh1 123.8(10) .
N1 C8 C9 110.9(13) .
N1 C8 H8A 109.5 .
C9 C8 H8A 109.5 .
N1 C8 H8B 109.5 .
C9 C8 H8B 109.5 .
H8A C8 H8B 108.1 .
C10 C9 C8 115.9(14) .
C10 C9 H9A 108.3 .
C8 C9 H9A 108.3 .
C10 C9 H9B 108.3 .
C8 C9 H9B 108.3 .
H9A C9 H9B 107.4 .
C11 C10 C9 117.4(18) .
C11 C10 H10A 108.0 .
C9 C10 H10A 108.0 .
C11 C10 H10B 108.0 .
C9 C10 H10B 108.0 .
H10A C10 H10B 107.2 .
C10 C11 H11A 109.5 .
C10 C11 H11B 109.5 .
H11A C11 H11B 109.5 .
C10 C11 H11C 109.5 .
H11A C11 H11C 109.5 .
H11B C11 H11C 109.5 .
C13 C12 C17 118.1(17) .
C13 C12 C3 124.6(15) .
C17 C12 C3 117.3(14) .
C14 C13 C12 122.7(16) .
C14 C13 H13A 118.7 .
C12 C13 H13A 118.7 .
C13 C14 C15 118.3(15) .
C13 C14 H14A 120.8 .
C15 C14 H14A 120.8 .
C16 C15 C14 119.8(18) .
C16 C15 H15A 120.1 .
C14 C15 H15A 120.1 .
C17 C16 C15 121.1(19) .
C17 C16 H16A 119.5 .
C15 C16 H16A 119.5 .
C16 C17 C12 119.9(16) .
C16 C17 H17A 120.0 .
C12 C17 H17A 120.0 .
C19 C18 C23 121.3(17) .
C19 C18 C5 117.8(15) .
C23 C18 C5 120.8(16) .
C18 C19 C20 120.1(16) .
C18 C19 H19A 120.0 .
C20 C19 H19A 120.0 .
C19 C20 C21 120.2(16) .
C19 C20 H20A 119.9 .
C21 C20 H20A 119.9 .
C22 C21 C20 116.6(17) .
C22 C21 H21A 121.7 .
C20 C21 H21A 121.7 .
C21 C22 C23 124.1(16) .
C21 C22 H22A 117.9 .
C23 C22 H22A 117.9 .
C18 C23 C22 117.5(16) .
C18 C23 H23A 121.3 .
C22 C23 H23A 121.3 .
C25 C24 N4 112.3(16) .
C25 C24 H24A 109.1 .
N4 C24 H24A 109.1 .
C25 C24 H24B 109.1 .
N4 C24 H24B 109.1 .
H24A C24 H24B 107.9 .
C24 C25 C26 112.3(18) .
C24 C25 H25A 109.2 .
C26 C25 H25A 109.2 .
C24 C25 H25B 109.2 .
C26 C25 H25B 109.2 .
H25A C25 H25B 107.9 .
C27 C26 C25 111.9(16) .
C27 C26 H26A 109.2 .
C25 C26 H26A 109.2 .
C27 C26 H26B 109.2 .
C25 C26 H26B 109.2 .
H26A C26 H26B 107.9 .
C26 C27 H27A 109.5 .
C26 C27 H27B 109.5 .
H27A C27 H27B 109.5 .
C26 C27 H27C 109.5 .
H27A C27 H27C 109.5 .
H27B C27 H27C 109.5 .
C33 C28 C29 118.7(14) .
C33 C28 P1 125.1(11) .
C29 C28 P1 116.0(12) .
C30 C29 C28 121.5(15) .
C30 C29 H29A 119.3 .
C28 C29 H29A 119.3 .
C29 C30 C31 120.4(16) .
C29 C30 H30A 119.8 .
C31 C30 H30A 119.8 .
C32 C31 C30 120.3(16) .
C32 C31 H31A 119.9 .
C30 C31 H31A 119.9 .
C31 C32 C33 119.5(16) .
C31 C32 H32A 120.3 .
C33 C32 H32A 120.3 .
C28 C33 C32 119.7(15) .
C28 C33 H33A 120.2 .
C32 C33 H33A 120.2 .
C39 C34 C35 120.6(17) .
C39 C34 P1 118.3(14) .
C35 C34 P1 121.0(14) .
C34 C35 C36 116.8(16) .
C34 C35 H35A 121.6 .
C36 C35 H35A 121.6 .
C37 C36 C35 123.4(17) .
C37 C36 H36A 118.3 .
C35 C36 H36A 118.3 .
C36 C37 C38 118.2(18) .
C36 C37 H37A 120.9 .
C38 C37 H37A 120.9 .
C39 C38 C37 119.1(17) .
C39 C38 H38A 120.5 .
C37 C38 H38A 120.5 .
C34 C39 C38 121.8(18) .
C34 C39 H39A 119.1 .
C38 C39 H39A 119.1 .
C45 C40 C41 117.7(15) .
C45 C40 P1 120.9(12) .
C41 C40 P1 120.5(13) .
C42 C41 C40 122.3(17) .
C42 C41 H41A 118.9 .
C40 C41 H41A 118.9 .
C43 C42 C41 117.6(18) .
C43 C42 H42A 121.2 .
C41 C42 H42A 121.2 .
C42 C43 C44 124.4(17) .
C42 C43 H43A 117.8 .
C44 C43 H43A 117.8 .
C43 C44 C45 116.2(17) .
C43 C44 H44A 121.9 .
C45 C44 H44A 121.9 .
C40 C45 C44 121.7(17) .
C40 C45 H45A 119.2 .
C44 C45 H45A 119.2 .
C47 C46 N6 94.9(13) .
C47 C46 Rh2 134.4(11) .
N6 C46 Rh2 130.4(12) .
C46 C47 N5 116.9(15) .
C46 C47 H47A 121.6 .
N5 C47 H47A 121.6 .
N6 C48 N5 104.6(13) .
N6 C48 C57 130.1(15) .
N5 C48 C57 125.1(18) .
N7 C49 N6 109.4(11) .
N7 C49 H49A 109.8 .
N6 C49 H49A 109.8 .
N7 C49 H49B 109.8 .
N6 C49 H49B 109.8 .
H49A C49 H49B 108.2 .
N8 C50 N7 106.7(12) .
N8 C50 C63 127.4(15) .
N7 C50 C63 125.6(15) .
C52 C51 N8 110.1(14) .
C52 C51 H51A 124.9 .
N8 C51 H51A 124.9 .
C51 C52 N7 104.0(13) .
C51 C52 Rh2 133.2(12) .
N7 C52 Rh2 122.7(12) .
C54 C53 N5 110(2) .
C54 C53 H53A 109.7 .
N5 C53 H53A 109.7 .
C54 C53 H53B 109.7 .
N5 C53 H53B 109.7 .
H53A C53 H53B 108.2 .
C53 C54 C55 116(2) .
C53 C54 H54A 108.2 .
C55 C54 H54A 108.2 .
C53 C54 H54B 108.2 .
C55 C54 H54B 108.2 .
H54A C54 H54B 107.4 .
C56A C55 C56 100(4) .
C56A C55 C54 107(3) .
C56 C55 C54 111(3) .
C56A C55 H55A 119.7 .
C56 C55 H55A 109.5 .
C54 C55 H55A 109.5 .
C56A C55 H55B 12.5 .
C56 C55 H55B 109.5 .
C54 C55 H55B 109.5 .
H55A C55 H55B 108.1 .
C56A C55 H55C 110.4 .
C56 C55 H55C 11.6 .
C54 C55 H55C 110.2 .
H55A C55 H55C 99.5 .
H55B C55 H55C 119.4 .
C56A C55 H55D 110.1 .
C56 C55 H55D 117.8 .
C54 C55 H55D 110.3 .
H55A C55 H55D 10.7 .
H55B C55 H55D 98.2 .
H55C C55 H55D 108.6 .
C55 C56 H55C 26.9 .
C55 C56 H56A 109.5 .
H55C C56 H56A 107.4 .
C55 C56 H56B 109.5 .
H55C C56 H56B 85.8 .
H56A C56 H56B 109.5 .
C55 C56 H56C 109.5 .
H55C C56 H56C 131.7 .
H56A C56 H56C 109.5 .
H56B C56 H56C 109.5 .
C55 C56A H56D 109.5 .
C55 C56A H56E 109.5 .
H56D C56A H56E 109.5 .
C55 C56A H56F 109.5 .
H56D C56A H56F 109.5 .
H56E C56A H56F 109.5 .
C58 C57 C62 119.7(15) .
C58 C57 C48 119.8(15) .
C62 C57 C48 120.5(16) .
C59 C58 C57 118.4(16) .
C59 C58 H58A 120.8 .
C57 C58 H58A 120.8 .
C60 C59 C58 121.9(17) .
C60 C59 H59A 119.1 .
C58 C59 H59A 119.1 .
C61 C60 C59 119.5(16) .
C61 C60 H60A 120.3 .
C59 C60 H60A 120.3 .
C60 C61 C62 121.2(16) .
C60 C61 H61A 119.4 .
C62 C61 H61A 119.4 .
C61 C62 C57 119.3(16) .
C61 C62 H62A 120.4 .
C57 C62 H62A 120.4 .
C64 C63 C68 119.7(15) .
C64 C63 C50 121.0(14) .
C68 C63 C50 119.2(15) .
C63 C64 C65 120.0(16) .
C63 C64 H64A 120.0 .
C65 C64 H64A 120.0 .
C66 C65 C64 121.0(18) .
C66 C65 H65A 119.5 .
C64 C65 H65A 119.5 .
C65 C66 C67 117.5(16) .
C65 C66 H66A 121.2 .
C67 C66 H66A 121.2 .
C68 C67 C66 123.9(19) .
C68 C67 H67A 118.0 .
C66 C67 H67A 118.0 .
C67 C68 C63 117.5(17) .
C67 C68 H68A 121.2 .
C63 C68 H68A 121.2 .
C70 C69 N8 115.1(15) .
C70 C69 H69A 108.5 .
N8 C69 H69A 108.5 .
C70 C69 H69B 108.5 .
N8 C69 H69B 108.5 .
H69A C69 H69B 107.5 .
C69 C70 C71 113.4(16) .
C69 C70 H70A 108.9 .
C71 C70 H70A 108.9 .
C69 C70 H70B 108.9 .
C71 C70 H70B 108.9 .
H70A C70 H70B 107.7 .
C70 C71 C72 113.6(16) .
C70 C71 H71A 108.8 .
C72 C71 H71A 108.8 .
C70 C71 H71B 108.8 .
C72 C71 H71B 108.8 .
H71A C71 H71B 107.7 .
C71 C72 H72A 109.5 .
C71 C72 H72B 109.5 .
H72A C72 H72B 109.5 .
C71 C72 H72C 109.5 .
H72A C72 H72C 109.5 .
H72B C72 H72C 109.5 .
C74 C73 C78 118.9(16) .
C74 C73 P2 122.4(13) .
C78 C73 P2 118.5(13) .
C73 C74 C75 122.8(17) .
C73 C74 H74A 118.6 .
C75 C74 H74A 118.6 .
C76 C75 C74 116.1(16) .
C76 C75 H75A 122.0 .
C74 C75 H75A 122.0 .
C77 C76 C75 122.1(17) .
C77 C76 H76A 118.9 .
C75 C76 H76A 118.9 .
C76 C77 C78 122.0(17) .
C76 C77 H77A 119.0 .
C78 C77 H77A 119.0 .
C77 C78 C73 118.1(16) .
C77 C78 H78A 121.0 .
C73 C78 H78A 121.0 .
C80 C79 C84 113.2(17) .
C80 C79 P2 120.9(13) .
C84 C79 P2 125.6(13) .
C81 C80 C79 123.3(16) .
C81 C80 H80A 118.3 .
C79 C80 H80A 118.3 .
C82 C81 C80 121.4(18) .
C82 C81 H81A 119.3 .
C80 C81 H81A 119.3 .
C81 C82 C83 119(2) .
C81 C82 H82A 120.4 .
C83 C82 H82A 120.4 .
C82 C83 C84 121.2(18) .
C82 C83 H83A 119.4 .
C84 C83 H83A 119.4 .
C83 C84 C79 121.7(17) .
C83 C84 H84A 119.1 .
C79 C84 H84A 119.1 .
C86 C85 C90 121.1(14) .
C86 C85 P2 123.1(13) .
C90 C85 P2 115.1(12) .
C85 C86 C87 120.4(15) .
C85 C86 H86A 119.8 .
C87 C86 H86A 119.8 .
C88 C87 C86 118.0(16) .
C88 C87 H87A 121.0 .
C86 C87 H87A 121.0 .
C89 C88 C87 118.6(17) .
C89 C88 H88A 120.7 .
C87 C88 H88A 120.7 .
C90 C89 C88 121.4(17) .
C90 C89 H89A 119.3 .
C88 C89 H89A 119.3 .
C89 C90 C85 119.9(16) .
C89 C90 H90A 120.0 .
C85 C90 H90A 120.0 .
C92 C91 N10 103.1(12) .
C92 C91 Rh3 131.5(12) .
N10 C91 Rh3 125.4(13) .
C91 C92 N9 107.5(14) .
C91 C92 H92A 126.2 .
N9 C92 H92A 126.2 .
N9 C93 N10 108.8(16) .
N9 C93 C102 126.0(15) .
N10 C93 C102 125.0(18) .
N10 C94 N11 115.1(14) .
N10 C94 H94A 108.5 .
N11 C94 H94A 108.5 .
N10 C94 H94B 108.5 .
N11 C94 H94B 108.5 .
H94A C94 H94B 107.5 .
N12 C95 N11 101.7(14) .
N12 C95 C108 130.3(16) .
N11 C95 C108 127.9(14) .
N12 C96 C97 107.3(14) .
N12 C96 H96A 126.4 .
C97 C96 H96A 126.4 .
C96 C97 N11 102.8(14) .
C96 C97 Rh3 132.8(12) .
N11 C97 Rh3 124.4(11) .
C99 C98 N9 113.6(17) .
C99 C98 H98A 108.8 .
N9 C98 H98A 108.8 .
C99 C98 H98B 108.8 .
N9 C98 H98B 108.8 .
H98A C98 H98B 107.7 .
C98 C99 C100 113.8(18) .
C98 C99 H99A 108.8 .
C100 C99 H99A 108.8 .
C98 C99 H99B 108.8 .
C100 C99 H99B 108.8 .
H99A C99 H99B 107.7 .
C101 C100 C201 118(3) .
C101 C100 C99 108(2) .
C201 C100 C99 115(3) .
C101 C100 H10E 110.0 .
C201 C100 H10E 95.1 .
C99 C100 H10E 110.0 .
C101 C100 H10F 110.0 .
C201 C100 H10F 13.4 .
C99 C100 H10F 110.0 .
H10E C100 H10F 108.4 .
C101 C100 H10G 97.4 .
C201 C100 H10G 108.5 .
C99 C100 H10G 108.4 .
H10E C100 H10G 14.8 .
H10F C100 H10G 121.5 .
C101 C100 H10H 11.3 .
C201 C100 H10H 108.8 .
C99 C100 H10H 108.6 .
H10E C100 H10H 119.3 .
H10F C100 H10H 99.9 .
H10G C100 H10H 107.6 .
C100 C101 H10H 26.4 .
C100 C101 H10I 109.5 .
H10H C101 H10I 108.6 .
C100 C101 H10K 109.5 .
H10H C101 H10K 130.7 .
H10I C101 H10K 109.5 .
C100 C101 H10L 109.5 .
H10H C101 H10L 85.7 .
H10I C101 H10L 109.5 .
H10K C101 H10L 109.5 .
C100 C201 H20B 109.5 .
C100 C201 H20C 109.5 .
H20B C201 H20C 109.5 .
C100 C201 H20D 109.5 .
H20B C201 H20D 109.5 .
H20C C201 H20D 109.5 .
C107 C102 C103 121.7(15) .
C107 C102 C93 121.9(13) .
C103 C102 C93 116.4(15) .
C104 C103 C102 119.6(17) .
C104 C103 H103 120.2 .
C102 C103 H103 120.2 .
C103 C104 C105 119.1(17) .
C103 C104 H104 120.4 .
C105 C104 H104 120.4 .
C106 C105 C104 120.4(15) .
C106 C105 H105 119.8 .
C104 C105 H105 119.8 .
C105 C106 C107 120.7(15) .
C105 C106 H106 119.7 .
C107 C106 H106 119.7 .
C102 C107 C106 118.5(14) .
C102 C107 H107 120.7 .
C106 C107 H107 120.7 .
C113 C108 C109 120.1(15) .
C113 C108 C95 120.1(15) .
C109 C108 C95 119.7(16) .
C110 C109 C108 119.0(17) .
C110 C109 H109 120.5 .
C108 C109 H109 120.5 .
C111 C110 C109 118.3(16) .
C111 C110 H110 120.9 .
C109 C110 H110 120.9 .
C110 C111 C112 124.5(17) .
C110 C111 H111 117.7 .
C112 C111 H111 117.7 .
C113 C112 C111 115.6(17) .
C113 C112 H112 122.2 .
C111 C112 H112 122.2 .
C108 C113 C112 122.2(16) .
C108 C113 H113 118.9 .
C112 C113 H113 118.9 .
N12 C114 C115 108.0(18) .
N12 C114 H11G 110.1 .
C115 C114 H11G 110.1 .
N12 C114 H11H 110.1 .
C115 C114 H11H 110.1 .
H11G C114 H11H 108.4 .
C116 C115 C114 118(2) .
C116 C115 H11I 107.8 .
C114 C115 H11I 107.8 .
C116 C115 H11J 107.8 .
C114 C115 H11J 107.8 .
H11I C115 H11J 107.2 .
C115 C116 C117 118(2) .
C115 C116 H11K 107.9 .
C117 C116 H11K 107.9 .
C115 C116 H11L 107.9 .
C117 C116 H11L 107.9 .
H11K C116 H11L 107.2 .
C116 C117 H11M 109.5 .
C116 C117 H11N 109.5 .
H11M C117 H11N 109.5 .
C116 C117 H11O 109.5 .
H11M C117 H11O 109.5 .
H11N C117 H11O 109.5 .
C123 C118 C119 116.0(14) .
C123 C118 P3 123.2(11) .
C119 C118 P3 119.7(11) .
C120 C119 C118 125.4(16) .
C120 C119 H119 117.3 .
C118 C119 H119 117.3 .
C119 C120 C121 116.6(16) .
C119 C120 H120 121.7 .
C121 C120 H120 121.7 .
C122 C121 C120 119.2(19) .
C122 C121 H121 120.4 .
C120 C121 H121 120.4 .
C121 C122 C123 123.8(18) .
C121 C122 H122 118.1 .
C123 C122 H122 118.1 .
C118 C123 C122 118.8(15) .
C118 C123 H123 120.6 .
C122 C123 H123 120.6 .
C125 C124 C129 116.7(15) .
C125 C124 P3 119.6(13) .
C129 C124 P3 122.6(13) .
C124 C125 C126 125.7(17) .
C124 C125 H125 117.1 .
C126 C125 H125 117.1 .
C125 C126 C127 115.8(19) .
C125 C126 H126 122.1 .
C127 C126 H126 122.1 .
C128 C127 C126 120.0(17) .
C128 C127 H127 120.0 .
C126 C127 H127 120.0 .
C127 C128 C129 122.3(18) .
C127 C128 H128 118.9 .
C129 C128 H128 118.9 .
C128 C129 C124 119.3(17) .
C128 C129 H129 120.4 .
C124 C129 H129 120.4 .
C135 C130 C131 120.2(15) .
C135 C130 P3 124.1(12) .
C131 C130 P3 115.6(12) .
C132 C131 C130 118.7(17) .
C132 C131 H131 120.7 .
C130 C131 H131 120.7 .
C131 C132 C133 122(2) .
C131 C132 H132 118.8 .
C133 C132 H132 118.8 .
C132 C133 C134 119(2) .
C132 C133 H133 120.5 .
C134 C133 H133 120.5 .
C133 C134 C135 122.4(18) .
C133 C134 H134 118.8 .
C135 C134 H134 118.8 .
C134 C135 C130 117.2(16) .
C134 C135 H135 121.4 .
C130 C135 H135 121.4 .
C137 C136 Cl10 117(2) .
C137 C136 H13B 108.0 .
Cl10 C136 H13B 108.0 .
C137 C136 H13C 108.0 .
Cl10 C136 H13C 108.0 .
H13B C136 H13C 107.2 .
C136 C137 Cl11 117(2) .
C136 C137 H13D 108.0 .
Cl11 C137 H13D 108.0 .
C136 C137 H13E 108.0 .
Cl11 C137 H13E 108.0 .
H13D C137 H13E 107.3 .
C139 C138 Cl12 108(3) .
C139 C138 H13F 110.2 .
Cl12 C138 H13F 110.2 .
C139 C138 H13G 110.2 .
Cl12 C138 H13G 110.2 .
H13F C138 H13G 108.5 .
C138 C139 Cl13 104(3) .
C138 C139 H13H 110.9 .
Cl13 C139 H13H 110.9 .
C138 C139 H13I 110.9 .
Cl13 C139 H13I 110.9 .
H13H C139 H13I 108.9 .
C141 C140 Cl14 122(5) .
C141 C140 H14B 106.7 .
Cl14 C140 H14B 106.7 .
C141 C140 H14C 106.7 .
Cl14 C140 H14C 106.7 .
H14B C140 H14C 106.6 .
C140 C141 Cl15 122(5) .
C140 C141 H14D 106.9 .
Cl15 C141 H14D 106.9 .
C140 C141 H14E 106.9 .
Cl15 C141 H14E 106.9 .
H14D C141 H14E 106.7 .
C143 C142 Cl16 97.9(15) .
C143 C142 H14F 112.2 .
Cl16 C142 H14F 112.2 .
C143 C142 H14G 112.2 .
Cl16 C142 H14G 112.2 .
H14F C142 H14G 109.8 .
C142 C143 Cl17 96.8(14) .
C142 C143 H14H 112.4 .
Cl17 C143 H14H 112.4 .
C142 C143 H14I 112.4 .
Cl17 C143 H14I 112.4 .
H14H C143 H14I 110.0 .
C149 C149 Cl18 106(3) 2_655
C149 C149 H14J 110.6 2_655
Cl18 C149 H14J 110.6 .
C149 C149 H14K 110.6 2_655
Cl18 C149 H14K 110.6 .
H14J C149 H14K 108.8 .
C3 N1 C2 109.8(12) .
C3 N1 C8 125.0(13) .
C2 N1 C8 124.3(14) .
C1 N2 C3 113.0(14) .
C1 N2 C4 122.7(12) .
C3 N2 C4 122.8(14) .
C5 N3 C7 113.9(12) .
C5 N3 C4 122.0(13) .
C7 N3 C4 122.1(12) .
C5 N4 C6 112.5(13) .
C5 N4 C24 121.7(15) .
C6 N4 C24 125.7(14) .
C48 N5 C47 103.8(15) .
C48 N5 C53 125.7(17) .
C47 N5 C53 128.7(17) .
C48 N6 C46 119.3(13) .
C48 N6 C49 119.7(12) .
C46 N6 C49 119.5(13) .
C52 N7 C50 110.5(14) .
C52 N7 C49 126.7(13) .
C50 N7 C49 121.8(12) .
C50 N8 C51 108.6(14) .
C50 N8 C69 125.5(13) .
C51 N8 C69 125.9(14) .
C93 N9 C92 108.6(14) .
C93 N9 C98 129.6(15) .
C92 N9 C98 121.5(16) .
C93 N10 C91 111.9(15) .
C93 N10 C94 125.1(15) .
C91 N10 C94 121.9(13) .
C95 N11 C97 113.3(12) .
C95 N11 C94 125.7(13) .
C97 N11 C94 120.0(14) .
C95 N12 C96 114.6(14) .
C95 N12 C114 122.9(16) .
C96 N12 C114 122.3(14) .
C34 P1 C40 98.9(8) .
C34 P1 C28 98.6(7) .
C40 P1 C28 108.3(7) .
C34 P1 Rh1 121.3(6) .
C40 P1 Rh1 113.8(5) .
C28 P1 Rh1 114.0(5) .
C79 P2 C73 107.3(8) .
C79 P2 C85 98.4(7) .
C73 P2 C85 100.1(8) .
C79 P2 Rh2 114.2(5) .
C73 P2 Rh2 114.7(6) .
C85 P2 Rh2 120.0(5) .
C118 P3 C124 109.2(7) .
C118 P3 C130 100.4(7) .
C124 P3 C130 95.7(8) .
C118 P3 Rh3 112.8(6) .
C124 P3 Rh3 115.7(5) .
C130 P3 Rh3 120.9(5) .
C7 Rh1 C1 88.4(7) .
C7 Rh1 P1 93.1(5) .
C1 Rh1 P1 93.4(5) .
C7 Rh1 Cl3 89.5(5) .
C1 Rh1 Cl3 176.3(5) .
P1 Rh1 Cl3 89.64(15) .
C7 Rh1 Cl2 87.6(5) .
C1 Rh1 Cl2 87.8(5) .
P1 Rh1 Cl2 178.58(16) .
Cl3 Rh1 Cl2 89.11(13) .
C7 Rh1 Cl1 176.4(5) .
C1 Rh1 Cl1 88.2(5) .
P1 Rh1 Cl1 87.94(15) .
Cl3 Rh1 Cl1 93.97(14) .
Cl2 Rh1 Cl1 91.47(13) .
C46 Rh2 C52 88.7(7) .
C46 Rh2 P2 96.6(5) .
C52 Rh2 P2 95.8(4) .
C46 Rh2 Cl6 88.4(5) .
C52 Rh2 Cl6 174.0(4) .
P2 Rh2 Cl6 89.73(15) .
C46 Rh2 Cl5 85.7(5) .
C52 Rh2 Cl5 86.6(4) .
P2 Rh2 Cl5 176.71(15) .
Cl6 Rh2 Cl5 87.99(15) .
C46 Rh2 Cl4 175.4(5) .
C52 Rh2 Cl4 87.6(5) .
P2 Rh2 Cl4 86.46(16) .
Cl6 Rh2 Cl4 95.03(15) .
Cl5 Rh2 Cl4 91.37(15) .
C97 Rh3 C91 89.6(7) .
C97 Rh3 P3 95.0(5) .
C91 Rh3 P3 94.1(5) .
C97 Rh3 Cl8 174.5(5) .
C91 Rh3 Cl8 88.0(5) .
P3 Rh3 Cl8 90.13(16) .
C97 Rh3 Cl9 85.8(5) .
C91 Rh3 Cl9 88.0(4) .
P3 Rh3 Cl9 177.77(14) .
Cl8 Rh3 Cl9 89.13(16) .
C97 Rh3 Cl7 89.2(5) .
C91 Rh3 Cl7 178.4(5) .
P3 Rh3 Cl7 86.96(14) .
Cl8 Rh3 Cl7 93.14(14) .
Cl9 Rh3 Cl7 90.97(14) .
C147 O1 C146 100(3) .
C146 C145 H14L 109.5 .
C146 C145 H14M 109.5 .
H14L C145 H14M 109.5 .
C146 C145 H14N 109.5 .
H14L C145 H14N 109.5 .
H14M C145 H14N 109.5 .
O1 C146 C145 93(3) .
O1 C146 H14O 113.0 .
C145 C146 H14O 113.0 .
O1 C146 H14P 113.0 .
C145 C146 H14P 113.0 .
H14O C146 H14P 110.4 .
O1 C147 C148 104(3) .
O1 C147 H14Q 110.9 .
C148 C147 H14Q 110.9 .
O1 C147 H14R 110.9 .
C148 C147 H14R 110.9 .
H14Q C147 H14R 108.9 .
C147 C148 H14S 109.5 .
C147 C148 H14T 109.5 .
H14S C148 H14T 109.5 .
C147 C148 H14U 109.5 .
H14S C148 H14U 109.5 .
H14T C148 H14U 109.5 .
C153 O2 C152 106(3) .
C152 C151 H15B 109.5 .
C152 C151 H15C 109.5 .
H15B C151 H15C 109.5 .
C152 C151 H15D 109.5 .
H15B C151 H15D 109.5 .
H15C C151 H15D 109.5 .
C151 C152 O2 94(4) .
C151 C152 H15E 113.0 .
O2 C152 H15E 113.0 .
C151 C152 H15F 113.0 .
O2 C152 H15F 113.0 .
H15E C152 H15F 110.4 .
O2 C153 C154 116(4) .
O2 C153 H15G 108.3 .
C154 C153 H15G 108.3 .
O2 C153 H15H 108.3 .
C154 C153 H15H 108.3 .
H15G C153 H15H 107.4 .
C153 C154 H15I 109.5 .
C153 C154 H15J 109.5 .
H15I C154 H15J 109.5 .
C153 C154 H15K 109.5 .
H15I C154 H15K 109.5 .
H15J C154 H15K 109.5 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 N2 1.376(19) .
C1 C2 1.414(19) .
C1 Rh1 1.995(14) .
C2 N1 1.367(18) .
C2 H2A 0.9500 .
C3 N1 1.350(19) .
C3 N2 1.380(16) .
C3 C12 1.44(2) .
C4 N2 1.447(19) .
C4 N3 1.504(17) .
C4 H4A 0.9900 .
C4 H4B 0.9900 .
C5 N4 1.350(18) .
C5 N3 1.399(19) .
C5 C18 1.42(2) .
C6 N4 1.37(2) .
C6 C7 1.38(2) .
C6 H6A 0.9500 .
C7 N3 1.401(19) .
C7 Rh1 1.988(17) .
C8 N1 1.508(17) .
C8 C9 1.52(2) .
C8 H8A 0.9900 .
C8 H8B 0.9900 .
C9 C10 1.49(2) .
C9 H9A 0.9900 .
C9 H9B 0.9900 .
C10 C11 1.47(3) .
C10 H10A 0.9900 .
C10 H10B 0.9900 .
C11 H11A 0.9800 .
C11 H11B 0.9800 .
C11 H11C 0.9800 .
C12 C13 1.364(19) .
C12 C17 1.42(2) .
C13 C14 1.33(2) .
C13 H13A 0.9500 .
C14 C15 1.41(2) .
C14 H14A 0.9500 .
C15 C16 1.37(2) .
C15 H15A 0.9500 .
C16 C17 1.32(2) .
C16 H16A 0.9500 .
C17 H17A 0.9500 .
C18 C19 1.37(2) .
C18 C23 1.38(2) .
C19 C20 1.38(2) .
C19 H19A 0.9500 .
C20 C21 1.45(2) .
C20 H20A 0.9500 .
C21 C22 1.34(2) .
C21 H21A 0.9500 .
C22 C23 1.40(2) .
C22 H22A 0.9500 .
C23 H23A 0.9500 .
C24 C25 1.48(3) .
C24 N4 1.51(2) .
C24 H24A 0.9900 .
C24 H24B 0.9900 .
C25 C26 1.53(2) .
C25 H25A 0.9900 .
C25 H25B 0.9900 .
C26 C27 1.50(3) .
C26 H26A 0.9900 .
C26 H26B 0.9900 .
C27 H27A 0.9800 .
C27 H27B 0.9800 .
C27 H27C 0.9800 .
C28 C33 1.40(2) .
C28 C29 1.420(19) .
C28 P1 1.832(15) .
C29 C30 1.37(2) .
C29 H29A 0.9500 .
C30 C31 1.40(2) .
C30 H30A 0.9500 .
C31 C32 1.39(2) .
C31 H31A 0.9500 .
C32 C33 1.44(2) .
C32 H32A 0.9500 .
C33 H33A 0.9500 .
C34 C39 1.37(2) .
C34 C35 1.39(2) .
C34 P1 1.813(18) .
C35 C36 1.43(2) .
C35 H35A 0.9500 .
C36 C37 1.36(2) .
C36 H36A 0.9500 .
C37 C38 1.42(2) .
C37 H37A 0.9500 .
C38 C39 1.40(2) .
C38 H38A 0.9500 .
C39 H39A 0.9500 .
C40 C45 1.38(2) .
C40 C41 1.41(2) .
C40 P1 1.815(15) .
C41 C42 1.40(2) .
C41 H41A 0.9500 .
C42 C43 1.35(2) .
C42 H42A 0.9500 .
C43 C44 1.41(3) .
C43 H43A 0.9500 .
C44 C45 1.43(2) .
C44 H44A 0.9500 .
C45 H45A 0.9500 .
C46 C47 1.40(2) .
C46 N6 1.404(17) .
C46 Rh2 1.865(16) .
C47 N5 1.407(19) .
C47 H47A 0.9500 .
C48 N6 1.35(2) .
C48 N5 1.392(18) .
C48 C57 1.44(2) .
C49 N7 1.421(19) .
C49 N6 1.467(18) .
C49 H49A 0.9900 .
C49 H49B 0.9900 .
C50 N8 1.315(19) .
C50 N7 1.389(18) .
C50 C63 1.49(2) .
C51 C52 1.36(2) .
C51 N8 1.387(18) .
C51 H51A 0.9500 .
C52 N7 1.378(17) .
C52 Rh2 1.986(15) .
C53 C54 1.44(3) .
C53 N5 1.49(3) .
C53 H53A 0.9900 .
C53 H53B 0.9900 .
C54 C55 1.56(3) .
C54 H54A 0.9900 .
C54 H54B 0.9900 .
C55 C56A 1.29(5) .
C55 C56 1.33(5) .
C55 H55A 0.9900 .
C55 H55B 0.9900 .
C55 H55C 0.9700 .
C55 H55D 0.9700 .
C56 H55C 0.4310 .
C56 H56A 0.9800 .
C56 H56B 0.9800 .
C56 H56C 0.9800 .
C56A H56D 0.9800 .
C56A H56E 0.9800 .
C56A H56F 0.9800 .
C57 C58 1.41(2) .
C57 C62 1.43(2) .
C58 C59 1.40(2) .
C58 H58A 0.9500 .
C59 C60 1.39(2) .
C59 H59A 0.9500 .
C60 C61 1.38(2) .
C60 H60A 0.9500 .
C61 C62 1.39(2) .
C61 H61A 0.9500 .
C62 H62A 0.9500 .
C63 C64 1.35(2) .
C63 C68 1.47(2) .
C64 C65 1.40(2) .
C64 H64A 0.9500 .
C65 C66 1.39(2) .
C65 H65A 0.9500 .
C66 C67 1.39(3) .
C66 H66A 0.9500 .
C67 C68 1.33(2) .
C67 H67A 0.9500 .
C68 H68A 0.9500 .
C69 C70 1.46(2) .
C69 N8 1.49(2) .
C69 H69A 0.9900 .
C69 H69B 0.9900 .
C70 C71 1.51(2) .
C70 H70A 0.9900 .
C70 H70B 0.9900 .
C71 C72 1.55(3) .
C71 H71A 0.9900 .
C71 H71B 0.9900 .
C72 H72A 0.9800 .
C72 H72B 0.9800 .
C72 H72C 0.9800 .
C73 C74 1.34(2) .
C73 C78 1.44(2) .
C73 P2 1.831(17) .
C74 C75 1.43(2) .
C74 H74A 0.9500 .
C75 C76 1.40(2) .
C75 H75A 0.9500 .
C76 C77 1.32(2) .
C76 H76A 0.9500 .
C77 C78 1.39(2) .
C77 H77A 0.9500 .
C78 H78A 0.9500 .
C79 C80 1.41(2) .
C79 C84 1.45(2) .
C79 P2 1.810(19) .
C80 C81 1.37(2) .
C80 H80A 0.9500 .
C81 C82 1.36(2) .
C81 H81A 0.9500 .
C82 C83 1.37(2) .
C82 H82A 0.9500 .
C83 C84 1.38(2) .
C83 H83A 0.9500 .
C84 H84A 0.9500 .
C85 C86 1.36(2) .
C85 C90 1.38(2) .
C85 P2 1.855(15) .
C86 C87 1.44(2) .
C86 H86A 0.9500 .
C87 C88 1.43(2) .
C87 H87A 0.9500 .
C88 C89 1.40(2) .
C88 H88A 0.9500 .
C89 C90 1.38(2) .
C89 H89A 0.9500 .
C90 H90A 0.9500 .
C91 C92 1.37(2) .
C91 N10 1.379(18) .
C91 Rh3 1.994(15) .
C92 N9 1.425(17) .
C92 H92A 0.9500 .
C93 N9 1.27(2) .
C93 N10 1.331(18) .
C93 C102 1.54(2) .
C94 N10 1.40(2) .
C94 N11 1.482(17) .
C94 H94A 0.9900 .
C94 H94B 0.9900 .
C95 N12 1.340(18) .
C95 N11 1.37(2) .
C95 C108 1.44(2) .
C96 N12 1.352(19) .
C96 C97 1.38(2) .
C96 H96A 0.9500 .
C97 N11 1.416(18) .
C97 Rh3 1.992(16) .
C98 C99 1.47(3) .
C98 N9 1.48(2) .
C98 H98A 0.9900 .
C98 H98B 0.9900 .
C99 C100 1.53(3) .
C99 H99A 0.9900 .
C99 H99B 0.9900 .
C100 C101 1.33(4) .
C100 C201 1.51(4) .
C100 H10E 0.9900 .
C100 H10F 0.9900 .
C100 H10G 0.9700 .
C100 H10H 0.9700 .
C101 H10H 0.4271 .
C101 H10I 0.9800 .
C101 H10K 0.9800 .
C101 H10L 0.9800 .
C201 H20B 0.9800 .
C201 H20C 0.9800 .
C201 H20D 0.9800 .
C102 C107 1.38(2) .
C102 C103 1.39(2) .
C103 C104 1.39(2) .
C103 H103 0.9500 .
C104 C105 1.42(2) .
C104 H104 0.9500 .
C105 C106 1.37(2) .
C105 H105 0.9500 .
C106 C107 1.401(19) .
C106 H106 0.9500 .
C107 H107 0.9500 .
C108 C113 1.38(2) .
C108 C109 1.40(2) .
C109 C110 1.40(2) .
C109 H109 0.9500 .
C110 C111 1.37(2) .
C110 H110 0.9500 .
C111 C112 1.39(2) .
C111 H111 0.9500 .
C112 C113 1.39(2) .
C112 H112 0.9500 .
C113 H113 0.9500 .
C114 N12 1.54(3) .
C114 C115 1.551(17) .
C114 H11G 0.9900 .
C114 H11H 0.9900 .
C115 C116 1.433(17) .
C115 H11I 0.9900 .
C115 H11J 0.9900 .
C116 C117 1.447(17) .
C116 H11K 0.9900 .
C116 H11L 0.9900 .
C117 H11M 0.9800 .
C117 H11N 0.9800 .
C117 H11O 0.9800 .
C118 C123 1.38(2) .
C118 C119 1.424(19) .
C118 P3 1.801(14) .
C119 C120 1.36(2) .
C119 H119 0.9500 .
C120 C121 1.40(3) .
C120 H120 0.9500 .
C121 C122 1.36(2) .
C121 H121 0.9500 .
C122 C123 1.39(2) .
C122 H122 0.9500 .
C123 H123 0.9500 .
C124 C125 1.37(2) .
C124 C129 1.45(2) .
C124 P3 1.812(17) .
C125 C126 1.39(2) .
C125 H125 0.9500 .
C126 C127 1.47(2) .
C126 H126 0.9500 .
C127 C128 1.36(2) .
C127 H127 0.9500 .
C128 C129 1.39(2) .
C128 H128 0.9500 .
C129 H129 0.9500 .
C130 C135 1.40(2) .
C130 C131 1.40(2) .
C130 P3 1.862(16) .
C131 C132 1.36(2) .
C131 H131 0.9500 .
C132 C133 1.36(2) .
C132 H132 0.9500 .
C133 C134 1.36(2) .
C133 H133 0.9500 .
C134 C135 1.38(2) .
C134 H134 0.9500 .
C135 H135 0.9500 .
C136 C137 1.39(3) .
C136 Cl10 1.70(3) .
C136 H13B 0.9900 .
C136 H13C 0.9900 .
C137 Cl11 1.84(3) .
C137 H13D 0.9900 .
C137 H13E 0.9900 .
C138 C139 1.46(4) .
C138 Cl12 1.81(3) .
C138 H13F 0.9900 .
C138 H13G 0.9900 .
C139 Cl13 1.83(3) .
C139 H13H 0.9900 .
C139 H13I 0.9900 .
C140 C141 1.33(6) .
C140 Cl14 1.67(5) .
C140 H14B 0.9900 .
C140 H14C 0.9900 .
C141 Cl15 1.63(6) .
C141 H14D 0.9900 .
C141 H14E 0.9900 .
C142 C143 1.424(18) .
C142 Cl16 1.892(17) .
C142 H14F 0.9900 .
C142 H14G 0.9900 .
C143 Cl17 1.929(17) .
C143 H14H 0.9900 .
C143 H14I 0.9900 .
C149 C149 1.24(6) 2_655
C149 Cl18 1.883(18) .
C149 H14J 0.9900 .
C149 H14K 0.9900 .
Cl1 Rh1 2.480(4) .
Cl2 Rh1 2.465(4) .
Cl3 Rh1 2.464(4) .
Cl4 Rh2 2.483(5) .
Cl5 Rh2 2.449(4) .
Cl6 Rh2 2.444(4) .
Cl7 Rh3 2.485(4) .
Cl8 Rh3 2.425(5) .
Cl9 Rh3 2.455(4) .
P1 Rh1 2.282(5) .
P2 Rh2 2.279(4) .
P3 Rh3 2.283(4) .
O1 C147 1.432(18) .
O1 C146 1.456(18) .
C145 C146 1.517(19) .
C145 H14L 0.9800 .
C145 H14M 0.9800 .
C145 H14N 0.9800 .
C146 H14O 0.9900 .
C146 H14P 0.9900 .
C147 C148 1.495(18) .
C147 H14Q 0.9900 .
C147 H14R 0.9900 .
C148 H14S 0.9800 .
C148 H14T 0.9800 .
C148 H14U 0.9800 .
O2 C153 1.415(19) .
O2 C152 1.465(19) .
C151 C152 1.46(2) .
C151 H15B 0.9800 .
C151 H15C 0.9800 .
C151 H15D 0.9800 .
C152 H15E 0.9900 .
C152 H15F 0.9900 .
C153 C154 1.50(2) .
C153 H15G 0.9900 .
C153 H15H 0.9900 .
C154 H15I 0.9800 .
C154 H15J 0.9800 .
C154 H15K 0.9800 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
N2 C1 C2 N1 0.0(16)
Rh1 C1 C2 N1 173.1(11)
N4 C6 C7 N3 0.5(16)
N4 C6 C7 Rh1 -177.9(12)
N1 C8 C9 C10 -64(2)
C8 C9 C10 C11 -65(2)
N1 C3 C12 C13 55(2)
N2 C3 C12 C13 -117.9(17)
N1 C3 C12 C17 -126.6(17)
N2 C3 C12 C17 61(2)
C17 C12 C13 C14 -3(2)
C3 C12 C13 C14 175.5(15)
C12 C13 C14 C15 1(2)
C13 C14 C15 C16 2(2)
C14 C15 C16 C17 -3(2)
C15 C16 C17 C12 1(2)
C13 C12 C17 C16 2(2)
C3 C12 C17 C16 -176.5(15)
N4 C5 C18 C19 -67(2)
N3 C5 C18 C19 113.5(18)
N4 C5 C18 C23 110(2)
N3 C5 C18 C23 -70(2)
C23 C18 C19 C20 4(2)
C5 C18 C19 C20 -179.7(14)
C18 C19 C20 C21 -4(2)
C19 C20 C21 C22 3(2)
C20 C21 C22 C23 -3(2)
C19 C18 C23 C22 -3(2)
C5 C18 C23 C22 -179.8(14)
C21 C22 C23 C18 3(2)
N4 C24 C25 C26 -171.4(17)
C24 C25 C26 C27 68(3)
C33 C28 C29 C30 0(2)
P1 C28 C29 C30 -175.3(14)
C28 C29 C30 C31 0(3)
C29 C30 C31 C32 0(3)
C30 C31 C32 C33 1(3)
C29 C28 C33 C32 2(2)
P1 C28 C33 C32 175.9(13)
C31 C32 C33 C28 -2(3)
C39 C34 C35 C36 -6(2)
P1 C34 C35 C36 178.9(11)
C34 C35 C36 C37 2(2)
C35 C36 C37 C38 2(3)
C36 C37 C38 C39 -3(3)
C35 C34 C39 C38 5(3)
P1 C34 C39 C38 -179.6(13)
C37 C38 C39 C34 0(3)
C45 C40 C41 C42 2(2)
P1 C40 C41 C42 171.1(13)
C40 C41 C42 C43 2(3)
C41 C42 C43 C44 -4(3)
C42 C43 C44 C45 1(3)
C41 C40 C45 C44 -5(2)
P1 C40 C45 C44 -174.1(12)
C43 C44 C45 C40 4(2)
N6 C46 C47 N5 7.0(16)
Rh2 C46 C47 N5 -179.3(11)
N8 C51 C52 N7 0.3(17)
N8 C51 C52 Rh2 177.8(11)
N5 C53 C54 C55 178(2)
C53 C54 C55 C56A -41(4)
C53 C54 C55 C56 67(4)
N6 C48 C57 C58 113(2)
N5 C48 C57 C58 -60(2)
N6 C48 C57 C62 -64(2)
N5 C48 C57 C62 122.4(19)
C62 C57 C58 C59 3(3)
C48 C57 C58 C59 -173.8(17)
C57 C58 C59 C60 -4(3)
C58 C59 C60 C61 1(3)
C59 C60 C61 C62 2(3)
C60 C61 C62 C57 -3(3)
C58 C57 C62 C61 0(3)
C48 C57 C62 C61 177.2(17)
N8 C50 C63 C64 -128.5(18)
N7 C50 C63 C64 59(2)
N8 C50 C63 C68 54(2)
N7 C50 C63 C68 -119.0(18)
C68 C63 C64 C65 0(2)
C50 C63 C64 C65 -177.1(14)
C63 C64 C65 C66 0(3)
C64 C65 C66 C67 -3(3)
C65 C66 C67 C68 6(3)
C66 C67 C68 C63 -6(3)
C64 C63 C68 C67 3(2)
C50 C63 C68 C67 -179.5(15)
N8 C69 C70 C71 178.2(14)
C69 C70 C71 C72 -176.4(16)
C78 C73 C74 C75 2(3)
P2 C73 C74 C75 176.7(13)
C73 C74 C75 C76 0(3)
C74 C75 C76 C77 -2(3)
C75 C76 C77 C78 1(3)
C76 C77 C78 C73 1(3)
C74 C73 C78 C77 -2(3)
P2 C73 C78 C77 -177.2(13)
C84 C79 C80 C81 -1(2)
P2 C79 C80 C81 -175.7(14)
C79 C80 C81 C82 1(3)
C80 C81 C82 C83 0(3)
C81 C82 C83 C84 -1(3)
C82 C83 C84 C79 2(3)
C80 C79 C84 C83 -1(2)
P2 C79 C84 C83 174.2(14)
C90 C85 C86 C87 -2(3)
P2 C85 C86 C87 -171.9(14)
C85 C86 C87 C88 2(3)
C86 C87 C88 C89 -5(3)
C87 C88 C89 C90 8(3)
C88 C89 C90 C85 -8(3)
C86 C85 C90 C89 5(3)
P2 C85 C90 C89 175.6(15)
N10 C91 C92 N9 -1.1(15)
Rh3 C91 C92 N9 179.9(11)
N12 C96 C97 N11 -1.7(18)
N12 C96 C97 Rh3 -179.7(13)
N9 C98 C99 C100 -177.6(18)
C98 C99 C100 C101 65(3)
C98 C99 C100 C201 -69(3)
N9 C93 C102 C107 -116(2)
N10 C93 C102 C107 69(2)
N9 C93 C102 C103 61(2)
N10 C93 C102 C103 -113.0(19)
C107 C102 C103 C104 1(3)
C93 C102 C103 C104 -176.8(18)
C102 C103 C104 C105 -2(3)
C103 C104 C105 C106 1(3)
C104 C105 C106 C107 2(3)
C103 C102 C107 C106 1(3)
C93 C102 C107 C106 178.9(15)
C105 C106 C107 C102 -3(2)
N12 C95 C108 C113 -62(2)
N11 C95 C108 C113 120.1(18)
N12 C95 C108 C109 117.5(19)
N11 C95 C108 C109 -60(2)
C113 C108 C109 C110 -4(2)
C95 C108 C109 C110 176.5(14)
C108 C109 C110 C111 6(2)
C109 C110 C111 C112 -4(2)
C110 C111 C112 C113 1(2)
C109 C108 C113 C112 1(2)
C95 C108 C113 C112 -179.8(14)
C111 C112 C113 C108 1(2)
N12 C114 C115 C116 -161(2)
C114 C115 C116 C117 -175(2)
C123 C118 C119 C120 -5(3)
P3 C118 C119 C120 -172.7(15)
C118 C119 C120 C121 4(3)
C119 C120 C121 C122 -1(3)
C120 C121 C122 C123 0(3)
C119 C118 C123 C122 3(3)
P3 C118 C123 C122 170.9(15)
C121 C122 C123 C118 -1(3)
C129 C124 C125 C126 5(2)
P3 C124 C125 C126 173.3(13)
C124 C125 C126 C127 -2(3)
C125 C126 C127 C128 -1(2)
C126 C127 C128 C129 0(3)
C127 C128 C129 C124 2(2)
C125 C124 C129 C128 -5(2)
P3 C124 C129 C128 -173.1(11)
C135 C130 C131 C132 3(3)
P3 C130 C131 C132 -176.4(15)
C130 C131 C132 C133 -1(3)
C131 C132 C133 C134 0(3)
C132 C133 C134 C135 -1(3)
C133 C134 C135 C130 3(3)
C131 C130 C135 C134 -4(3)
P3 C130 C135 C134 175.6(14)
Cl10 C136 C137 Cl11 46(4)
Cl12 C138 C139 Cl13 76(2)
Cl14 C140 C141 Cl15 -46(7)
Cl16 C142 C143 Cl17 176.2(13)
N2 C3 N1 C2 -0.9(16)
C12 C3 N1 C2 -174.8(14)
N2 C3 N1 C8 -170.5(12)
C12 C3 N1 C8 16(2)
C1 C2 N1 C3 0.6(17)
C1 C2 N1 C8 170.3(13)
C9 C8 N1 C3 -108.4(17)
C9 C8 N1 C2 83.5(18)
C2 C1 N2 C3 -0.6(16)
Rh1 C1 N2 C3 -174.3(10)
C2 C1 N2 C4 166.1(12)
Rh1 C1 N2 C4 -8(2)
N1 C3 N2 C1 1.0(16)
C12 C3 N2 C1 174.9(14)
N1 C3 N2 C4 -165.7(13)
C12 C3 N2 C4 8(2)
N3 C4 N2 C1 51.8(18)
N3 C4 N2 C3 -142.9(13)
N4 C5 N3 C7 2.8(16)
C18 C5 N3 C7 -177.7(15)
N4 C5 N3 C4 166.7(12)
C18 C5 N3 C4 -14(2)
C6 C7 N3 C5 -2.1(16)
Rh1 C7 N3 C5 176.5(11)
C6 C7 N3 C4 -166.0(12)
Rh1 C7 N3 C4 12.6(19)
N2 C4 N3 C5 142.7(13)
N2 C4 N3 C7 -54.6(17)
N3 C5 N4 C6 -2.4(16)
C18 C5 N4 C6 178.2(16)
N3 C5 N4 C24 175.9(14)
C18 C5 N4 C24 -4(3)
C7 C6 N4 C5 1.2(18)
C7 C6 N4 C24 -176.9(15)
C25 C24 N4 C5 105(2)
C25 C24 N4 C6 -77(2)
N6 C48 N5 C47 0.1(14)
C57 C48 N5 C47 175.1(14)
N6 C48 N5 C53 165.7(17)
C57 C48 N5 C53 -19(3)
C46 C47 N5 C48 -4.9(17)
C46 C47 N5 C53 -170.0(18)
C54 C53 N5 C48 122(2)
C54 C53 N5 C47 -76(3)
N5 C48 N6 C46 4.9(17)
C57 C48 N6 C46 -169.8(15)
N5 C48 N6 C49 171.0(11)
C57 C48 N6 C49 -4(2)
C47 C46 N6 C48 -7.1(16)
Rh2 C46 N6 C48 178.8(11)
C47 C46 N6 C49 -173.3(12)
Rh2 C46 N6 C49 13(2)
N7 C49 N6 C48 145.7(13)
N7 C49 N6 C46 -48.2(17)
C51 C52 N7 C50 -0.5(16)
Rh2 C52 N7 C50 -178.3(10)
C51 C52 N7 C49 168.7(14)
Rh2 C52 N7 C49 -9(2)
N8 C50 N7 C52 0.5(16)
C63 C50 N7 C52 174.7(14)
N8 C50 N7 C49 -169.3(13)
C63 C50 N7 C49 5(2)
N6 C49 N7 C52 47.5(19)
N6 C49 N7 C50 -144.5(13)
N7 C50 N8 C51 -0.3(16)
C63 C50 N8 C51 -174.3(15)
N7 C50 N8 C69 -178.3(13)
C63 C50 N8 C69 8(2)
C52 C51 N8 C50 0.0(18)
C52 C51 N8 C69 178.0(14)
C70 C69 N8 C50 -112.8(18)
C70 C69 N8 C51 70(2)
N10 C93 N9 C92 1.1(17)
C102 C93 N9 C92 -173.9(13)
N10 C93 N9 C98 -171.9(15)
C102 C93 N9 C98 13(3)
C91 C92 N9 C93 0.0(16)
C91 C92 N9 C98 173.7(14)
C99 C98 N9 C93 -119(2)
C99 C98 N9 C92 69(2)
N9 C93 N10 C91 -1.9(17)
C102 C93 N10 C91 173.2(13)
N9 C93 N10 C94 -170.4(14)
C102 C93 N10 C94 5(2)
C92 C91 N10 C93 1.8(16)
Rh3 C91 N10 C93 -179.1(10)
C92 C91 N10 C94 170.7(12)
Rh3 C91 N10 C94 -10.2(19)
N11 C94 N10 C93 -142.1(13)
N11 C94 N10 C91 50.6(19)
N12 C95 N11 C97 4.6(17)
C108 C95 N11 C97 -177.1(15)
N12 C95 N11 C94 173.2(13)
C108 C95 N11 C94 -8(3)
C96 C97 N11 C95 -1.9(18)
Rh3 C97 N11 C95 176.3(11)
C96 C97 N11 C94 -171.3(14)
Rh3 C97 N11 C94 7(2)
N10 C94 N11 C95 143.5(15)
N10 C94 N11 C97 -48.6(19)
N11 C95 N12 C96 -5.9(18)
C108 C95 N12 C96 175.9(17)
N11 C95 N12 C114 -179.9(15)
C108 C95 N12 C114 2(3)
C97 C96 N12 C95 5(2)
C97 C96 N12 C114 179.1(16)
C115 C114 N12 C95 102(2)
C115 C114 N12 C96 -72(2)
C39 C34 P1 C40 55.9(14)
C35 C34 P1 C40 -128.4(13)
C39 C34 P1 C28 -54.2(14)
C35 C34 P1 C28 121.4(13)
C39 C34 P1 Rh1 -179.1(11)
C35 C34 P1 Rh1 -3.5(15)
C45 C40 P1 C34 -160.5(13)
C41 C40 P1 C34 30.6(14)
C45 C40 P1 C28 -58.3(14)
C41 C40 P1 C28 132.8(12)
C45 C40 P1 Rh1 69.5(13)
C41 C40 P1 Rh1 -99.4(12)
C33 C28 P1 C34 140.8(14)
C29 C28 P1 C34 -44.8(13)
C33 C28 P1 C40 38.4(16)
C29 C28 P1 C40 -147.2(12)
C33 C28 P1 Rh1 -89.3(14)
C29 C28 P1 Rh1 85.1(12)
C80 C79 P2 C73 -144.2(13)
C84 C79 P2 C73 41.3(15)
C80 C79 P2 C85 -40.8(14)
C84 C79 P2 C85 144.6(14)
C80 C79 P2 Rh2 87.5(13)
C84 C79 P2 Rh2 -87.1(14)
C74 C73 P2 C79 122.7(15)
C78 C73 P2 C79 -62.4(15)
C74 C73 P2 C85 20.5(17)
C78 C73 P2 C85 -164.5(13)
C74 C73 P2 Rh2 -109.3(15)
C78 C73 P2 Rh2 65.6(15)
C86 C85 P2 C79 120.0(17)
C90 C85 P2 C79 -50.3(16)
C86 C85 P2 C73 -130.6(17)
C90 C85 P2 C73 59.1(16)
C86 C85 P2 Rh2 -4.3(19)
C90 C85 P2 Rh2 -174.6(12)
C123 C118 P3 C124 48.3(18)
C119 C118 P3 C124 -144.5(14)
C123 C118 P3 C130 148.2(16)
C119 C118 P3 C130 -44.7(15)
C123 C118 P3 Rh3 -81.7(16)
C119 C118 P3 Rh3 85.4(14)
C125 C124 P3 C118 139.9(12)
C129 C124 P3 C118 -52.1(14)
C125 C124 P3 C130 36.7(13)
C129 C124 P3 C130 -155.2(12)
C125 C124 P3 Rh3 -91.7(13)
C129 C124 P3 Rh3 76.4(13)
C135 C130 P3 C118 128.6(15)
C131 C130 P3 C118 -51.7(15)
C135 C130 P3 C124 -120.7(16)
C131 C130 P3 C124 59.0(14)
C135 C130 P3 Rh3 3.9(18)
C131 C130 P3 Rh3 -176.4(11)
C6 C7 Rh1 C1 -158.2(17)
N3 C7 Rh1 C1 23.7(13)
C6 C7 Rh1 P1 -64.8(16)
N3 C7 Rh1 P1 117.0(12)
C6 C7 Rh1 Cl3 24.8(16)
N3 C7 Rh1 Cl3 -153.3(12)
C6 C7 Rh1 Cl2 113.9(16)
N3 C7 Rh1 Cl2 -64.2(12)
C6 C7 Rh1 Cl1 -171(6)
N3 C7 Rh1 Cl1 11(9)
N2 C1 Rh1 C7 -27.2(13)
C2 C1 Rh1 C7 161.0(15)
N2 C1 Rh1 P1 -120.1(12)
C2 C1 Rh1 P1 68.0(14)
N2 C1 Rh1 Cl3 26(8)
C2 C1 Rh1 Cl3 -145(6)
N2 C1 Rh1 Cl2 60.5(12)
C2 C1 Rh1 Cl2 -111.3(14)
N2 C1 Rh1 Cl1 152.0(12)
C2 C1 Rh1 Cl1 -19.8(14)
C34 P1 Rh1 C7 137.2(7)
C40 P1 Rh1 C7 -105.0(8)
C28 P1 Rh1 C7 19.8(7)
C34 P1 Rh1 C1 -134.2(7)
C40 P1 Rh1 C1 -16.5(8)
C28 P1 Rh1 C1 108.3(7)
C34 P1 Rh1 Cl3 47.8(6)
C40 P1 Rh1 Cl3 165.5(6)
C28 P1 Rh1 Cl3 -69.6(6)
C34 P1 Rh1 Cl2 19(6)
C40 P1 Rh1 Cl2 137(6)
C28 P1 Rh1 Cl2 -98(6)
C34 P1 Rh1 Cl1 -46.2(6)
C40 P1 Rh1 Cl1 71.5(6)
C28 P1 Rh1 Cl1 -163.6(6)
C47 C46 Rh2 C52 -152.1(16)
N6 C46 Rh2 C52 19.7(14)
C47 C46 Rh2 P2 -56.4(16)
N6 C46 Rh2 P2 115.4(13)
C47 C46 Rh2 Cl6 33.1(15)
N6 C46 Rh2 Cl6 -155.1(13)
C47 C46 Rh2 Cl5 121.3(16)
N6 C46 Rh2 Cl5 -67.0(13)
C47 C46 Rh2 Cl4 172(5)
N6 C46 Rh2 Cl4 -16(7)
C51 C52 Rh2 C46 161.3(16)
N7 C52 Rh2 C46 -21.6(12)
C51 C52 Rh2 P2 64.9(16)
N7 C52 Rh2 P2 -118.0(11)
C51 C52 Rh2 Cl6 -138(4)
N7 C52 Rh2 Cl6 40(6)
C51 C52 Rh2 Cl5 -112.9(15)
N7 C52 Rh2 Cl5 64.2(11)
C51 C52 Rh2 Cl4 -21.3(15)
N7 C52 Rh2 Cl4 155.8(11)
C79 P2 Rh2 C46 18.4(7)
C73 P2 Rh2 C46 -106.1(8)
C85 P2 Rh2 C46 134.7(8)
C79 P2 Rh2 C52 107.7(8)
C73 P2 Rh2 C52 -16.8(8)
C85 P2 Rh2 C52 -135.9(8)
C79 P2 Rh2 Cl6 -70.0(6)
C73 P2 Rh2 Cl6 165.5(6)
C85 P2 Rh2 Cl6 46.3(7)
C79 P2 Rh2 Cl5 -116(3)
C73 P2 Rh2 Cl5 119(3)
C85 P2 Rh2 Cl5 0(4)
C79 P2 Rh2 Cl4 -165.1(6)
C73 P2 Rh2 Cl4 70.4(6)
C85 P2 Rh2 Cl4 -48.7(7)
C96 C97 Rh3 C91 -159.9(17)
N11 C97 Rh3 C91 22.4(14)
C96 C97 Rh3 P3 -65.8(17)
N11 C97 Rh3 P3 116.5(13)
C96 C97 Rh3 Cl8 136(4)
N11 C97 Rh3 Cl8 -41(6)
C96 C97 Rh3 Cl9 112.1(17)
N11 C97 Rh3 Cl9 -65.6(13)
C96 C97 Rh3 Cl7 21.1(17)
N11 C97 Rh3 Cl7 -156.6(13)
C92 C91 Rh3 C97 156.7(15)
N10 C91 Rh3 C97 -22.1(13)
C92 C91 Rh3 P3 61.7(14)
N10 C91 Rh3 P3 -117.1(12)
C92 C91 Rh3 Cl8 -28.3(14)
N10 C91 Rh3 Cl8 152.9(12)
C92 C91 Rh3 Cl9 -117.5(14)
N10 C91 Rh3 Cl9 63.7(12)
C92 C91 Rh3 Cl7 -166(15)
N10 C91 Rh3 Cl7 16(17)
C118 P3 Rh3 C97 17.9(7)
C124 P3 Rh3 C97 -108.8(8)
C130 P3 Rh3 C97 136.6(8)
C118 P3 Rh3 C91 107.8(7)
C124 P3 Rh3 C91 -18.9(8)
C130 P3 Rh3 C91 -133.5(8)
C118 P3 Rh3 Cl8 -164.2(5)
C124 P3 Rh3 Cl8 69.1(6)
C130 P3 Rh3 Cl8 -45.5(6)
C118 P3 Rh3 Cl9 -93(5)
C124 P3 Rh3 Cl9 140(5)
C130 P3 Rh3 Cl9 25(5)
C118 P3 Rh3 Cl7 -71.1(5)
C124 P3 Rh3 Cl7 162.3(6)
C130 P3 Rh3 Cl7 47.6(6)
C147 O1 C146 C145 -178(3)
C146 O1 C147 C148 -169(3)
C153 O2 C152 C151 -176(4)
C152 O2 C153 C154 -177(4)
