#------------------------------------------------------------------------------
#$Date: 2016-02-16 22:30:59 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176467 $
#$URL: svn://www.crystallography.net/cod/cif/4/07/22/4072287.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4072287
loop_
_publ_author_name
'Wallenhorst, Carolin'
'Kehr, Gerald'
'Fröhlich, Roland'
'Erker, Gerhard'
_publ_section_title
;
 Unsymmetrical Bis(iminoethyl)pyridine Metal Complexes with a Pendant
 Alkenyl Substituent. Part B: Internal Olefin Coordination to
 Ruthenium†
;
_journal_issue                   24
_journal_name_full               Organometallics
_journal_page_first              6557
_journal_paper_doi               10.1021/om800727q
_journal_volume                  27
_journal_year                    2008
_chemical_formula_sum            'C27.5 H38 Cl3 N3 Ru'
_chemical_formula_weight         618.03
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 94.351(1)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   25.8516(5)
_cell_length_b                   10.8712(2)
_cell_length_c                   20.0594(3)
_cell_measurement_reflns_used    17305
_cell_measurement_temperature    198(2)
_cell_measurement_theta_max      27.88
_cell_measurement_theta_min      0.41
_cell_volume                     5621.20(17)
_computing_cell_refinement       'Collect (Nonius B.V., 1998)'
_computing_data_collection       'Collect (Nonius B.V., 1998)'
_computing_data_reduction        'Denzo-SMN (Otwinowski & Minor, 1997)'
_computing_molecular_graphics    'XP (BrukerAXS, 2000)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      198(2)
_diffrn_measured_fraction_theta_full 0.986
_diffrn_measured_fraction_theta_max 0.986
_diffrn_measurement_device_type  'Nonius Kappa CCD'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.145
_diffrn_reflns_av_sigmaI/netI    0.0383
_diffrn_reflns_limit_h_max       34
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            17305
_diffrn_reflns_theta_full        28.33
_diffrn_reflns_theta_max         28.33
_diffrn_reflns_theta_min         1.58
_exptl_absorpt_coefficient_mu    0.864
_exptl_absorpt_correction_T_max  0.9500
_exptl_absorpt_correction_T_min  0.6479
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SORTAV (Blessing, 1995 & 1997)'
_exptl_crystal_colour            black
_exptl_crystal_density_diffrn    1.461
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             2552
_exptl_crystal_size_max          0.55
_exptl_crystal_size_mid          0.45
_exptl_crystal_size_min          0.06
_refine_diff_density_max         1.209
_refine_diff_density_min         -0.818
_refine_diff_density_rms         0.101
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.146
_refine_ls_hydrogen_treatment    riding
_refine_ls_matrix_type           full
_refine_ls_number_parameters     318
_refine_ls_number_reflns         6927
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.146
_refine_ls_R_factor_all          0.0565
_refine_ls_R_factor_gt           0.0421
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0220P)²+28.7557P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0941
_refine_ls_wR_factor_ref         0.1000
_reflns_number_gt                5708
_reflns_number_total             6927
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om800727q_si_004.cif
_cod_data_source_block           erk4126
_cod_original_sg_symbol_H-M      C2/c
_cod_original_formula_sum        'C27.50 H38 Cl3 N3 Ru'
_cod_database_code               4072287
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ru Ru 0.136351(9) 0.77233(2) 0.133767(11) 0.01752(7) Uani 1 1 d .
Cl1 Cl 0.13085(3) 0.61271(7) 0.21582(4) 0.02575(17) Uani 1 1 d .
Cl2 Cl 0.14127(3) 0.91828(7) 0.04536(4) 0.02553(17) Uani 1 1 d .
N1 N 0.21242(9) 0.7692(2) 0.13459(12) 0.0178(5) Uani 1 1 d .
C2 C 0.24102(11) 0.8513(3) 0.17137(15) 0.0200(6) Uani 1 1 d .
C3 C 0.29463(12) 0.8579(3) 0.16832(16) 0.0255(7) Uani 1 1 d .
H3 H 0.3147 0.9153 0.1950 0.031 Uiso 1 1 calc R
C4 C 0.31803(12) 0.7793(3) 0.12567(17) 0.0279(7) Uani 1 1 d .
H4 H 0.3546 0.7813 0.1235 0.033 Uiso 1 1 calc R
C5 C 0.28835(13) 0.6977(3) 0.08604(16) 0.0268(7) Uani 1 1 d .
H5 H 0.3043 0.6448 0.0559 0.032 Uiso 1 1 calc R
C6 C 0.23487(12) 0.6939(3) 0.09084(14) 0.0209(6) Uani 1 1 d .
C7 C 0.20972(12) 0.9301(3) 0.21207(15) 0.0211(6) Uani 1 1 d .
C8 C 0.23706(13) 1.0239(3) 0.25623(18) 0.0330(8) Uani 1 1 d .
H8A H 0.2117 1.0689 0.2807 0.050 Uiso 1 1 calc R
H8B H 0.2555 1.0816 0.2289 0.050 Uiso 1 1 calc R
H8C H 0.2620 0.9827 0.2881 0.050 Uiso 1 1 calc R
N9 N 0.16023(10) 0.9114(2) 0.20486(12) 0.0192(5) Uani 1 1 d .
C10 C 0.12739(12) 0.9894(3) 0.24400(16) 0.0239(7) Uani 1 1 d .
C11 C 0.10970(14) 1.1019(3) 0.21744(17) 0.0296(7) Uani 1 1 d .
C12 C 0.07591(16) 1.1688(4) 0.2544(2) 0.0424(10) Uani 1 1 d .
H12 H 0.0626 1.2449 0.2373 0.051 Uiso 1 1 calc R
C13 C 0.06133(16) 1.1283(4) 0.3145(2) 0.0476(11) Uani 1 1 d .
H13 H 0.0376 1.1752 0.3380 0.057 Uiso 1 1 calc R
C14 C 0.08077(15) 1.0203(4) 0.34120(19) 0.0417(10) Uani 1 1 d .
H14 H 0.0711 0.9946 0.3838 0.050 Uiso 1 1 calc R
C15 C 0.11448(13) 0.9471(3) 0.30704(17) 0.0290(7) Uani 1 1 d .
C16 C 0.12646(15) 1.1532(3) 0.15221(17) 0.0338(8) Uani 1 1 d .
H16 H 0.1469 1.0881 0.1307 0.041 Uiso 1 1 calc R
C17 C 0.16172(19) 1.2662(4) 0.1643(2) 0.0492(11) Uani 1 1 d .
H17A H 0.1420 1.3331 0.1831 0.074 Uiso 1 1 calc R
H17B H 0.1744 1.2929 0.1218 0.074 Uiso 1 1 calc R
H17C H 0.1912 1.2446 0.1957 0.074 Uiso 1 1 calc R
C18 C 0.08043(18) 1.1879(4) 0.1031(2) 0.0501(11) Uani 1 1 d .
H18A H 0.0574 1.1168 0.0960 0.075 Uiso 1 1 calc R
H18B H 0.0932 1.2129 0.0604 0.075 Uiso 1 1 calc R
H18C H 0.0613 1.2562 0.1216 0.075 Uiso 1 1 calc R
C19 C 0.13626(15) 0.8295(3) 0.33852(17) 0.0339(8) Uani 1 1 d .
H19 H 0.1522 0.7813 0.3029 0.041 Uiso 1 1 calc R
C20 C 0.0947(2) 0.7492(5) 0.3667(2) 0.0571(13) Uani 1 1 d .
H20A H 0.0810 0.7906 0.4051 0.086 Uiso 1 1 calc R
H20B H 0.1098 0.6700 0.3810 0.086 Uiso 1 1 calc R
H20C H 0.0664 0.7354 0.3321 0.086 Uiso 1 1 calc R
C21 C 0.17907(19) 0.8581(4) 0.3936(2) 0.0529(11) Uani 1 1 d .
H21A H 0.2061 0.9078 0.3749 0.079 Uiso 1 1 calc R
H21B H 0.1942 0.7809 0.4112 0.079 Uiso 1 1 calc R
H21C H 0.1642 0.9037 0.4297 0.079 Uiso 1 1 calc R
C22 C 0.19735(13) 0.6119(3) 0.05549(15) 0.0223(6) Uani 1 1 d .
C23 C 0.21587(15) 0.5143(3) 0.00973(17) 0.0315(8) Uani 1 1 d .
H23A H 0.2229 0.4382 0.0351 0.047 Uiso 1 1 calc R
H23B H 0.2477 0.5421 -0.0091 0.047 Uiso 1 1 calc R
H23C H 0.1891 0.4989 -0.0265 0.047 Uiso 1 1 calc R
N24 N 0.14949(10) 0.6267(2) 0.06929(13) 0.0219(5) Uani 1 1 d .
C25 C 0.11056(14) 0.5333(3) 0.04746(18) 0.0320(8) Uani 1 1 d .
H25A H 0.0882 0.5174 0.0845 0.038 Uiso 1 1 calc R
H25B H 0.1287 0.4556 0.0383 0.038 Uiso 1 1 calc R
C26 C 0.07643(16) 0.5690(4) -0.01428(19) 0.0438(10) Uani 1 1 d .
H26A H 0.0952 0.5482 -0.0540 0.053 Uiso 1 1 calc R
H26B H 0.0448 0.5173 -0.0159 0.053 Uiso 1 1 calc R
C27 C 0.06039(19) 0.6968(4) -0.0199(2) 0.0493(11) Uani 1 1 d .
H27A H 0.0386 0.7053 -0.0624 0.059 Uiso 1 1 calc R
H27B H 0.0920 0.7464 -0.0245 0.059 Uiso 1 1 calc R
C28 C 0.03063(14) 0.7573(4) 0.03514(18) 0.0354(8) Uani 1 1 d .
H28A H 0.0293 0.8469 0.0264 0.043 Uiso 1 1 calc R
H28B H -0.0055 0.7266 0.0304 0.043 Uiso 1 1 calc R
C29 C 0.05121(12) 0.7385(3) 0.10757(16) 0.0270(7) Uani 1 1 d .
H29 H 0.0605 0.6576 0.1217 0.032 Uiso 1 1 calc R
C30 C 0.05696(12) 0.8306(3) 0.15291(17) 0.0281(7) Uani 1 1 d .
H30A H 0.0480 0.9125 0.1402 0.034 Uiso 1 1 calc R
H30B H 0.0700 0.8134 0.1975 0.034 Uiso 1 1 calc R
Cl11 Cl 0.01451(5) 0.54862(9) -0.17844(5) 0.0473(3) Uani 1 1 d .
C100 C 0.0000 0.4582(4) -0.2500 0.0276(10) Uani 1 2 d S
H10A H -0.0300 0.4046 -0.2427 0.033 Uiso 0.50 1 calc PR
H10B H 0.0300 0.4046 -0.2573 0.033 Uiso 0.50 1 calc PR
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_3
N1 Ru N24 77.43(10) .
N1 Ru N9 76.62(10) .
N24 Ru N9 153.81(10) .
N1 Ru C30 161.01(12) .
N24 Ru C30 121.46(12) .
N9 Ru C30 84.62(11) .
N1 Ru C29 163.29(11) .
N24 Ru C29 86.20(11) .
N9 Ru C29 119.90(11) .
C30 Ru C29 35.28(13) .
N1 Ru Cl2 84.74(7) .
N24 Ru Cl2 91.35(7) .
N9 Ru Cl2 89.80(7) .
C30 Ru Cl2 92.36(10) .
C29 Ru Cl2 92.37(9) .
N1 Ru Cl1 95.32(7) .
N24 Ru Cl1 84.12(7) .
N9 Ru Cl1 94.76(7) .
C30 Ru Cl1 89.08(10) .
C29 Ru Cl1 86.24(9) .
Cl2 Ru Cl1 175.33(3) .
C2 N1 C6 120.6(3) .
C2 N1 Ru 120.1(2) .
C6 N1 Ru 118.7(2) .
N1 C2 C3 121.2(3) .
N1 C2 C7 112.9(3) .
C3 C2 C7 125.9(3) .
C4 C3 C2 118.6(3) .
C3 C4 C5 120.2(3) .
C4 C5 C6 119.3(3) .
N1 C6 C5 120.0(3) .
N1 C6 C22 112.3(3) .
C5 C6 C22 127.6(3) .
N9 C7 C2 115.4(3) .
N9 C7 C8 126.4(3) .
C2 C7 C8 118.2(3) .
C7 N9 C10 117.2(3) .
C7 N9 Ru 114.8(2) .
C10 N9 Ru 128.01(19) .
C11 C10 C15 122.4(3) .
C11 C10 N9 119.2(3) .
C15 C10 N9 118.5(3) .
C12 C11 C10 117.0(3) .
C12 C11 C16 120.0(3) .
C10 C11 C16 123.0(3) .
C13 C12 C11 121.9(4) .
C12 C13 C14 120.3(3) .
C13 C14 C15 121.4(4) .
C14 C15 C10 116.9(3) .
C14 C15 C19 120.1(3) .
C10 C15 C19 123.0(3) .
C11 C16 C18 112.7(3) .
C11 C16 C17 111.3(3) .
C18 C16 C17 109.1(3) .
C15 C19 C20 112.8(4) .
C15 C19 C21 110.8(3) .
C20 C19 C21 109.8(3) .
N24 C22 C6 115.4(3) .
N24 C22 C23 124.7(3) .
C6 C22 C23 119.7(3) .
C22 N24 C25 119.5(3) .
C22 N24 Ru 115.4(2) .
C25 N24 Ru 124.6(2) .
N24 C25 C26 114.1(3) .
C27 C26 C25 117.0(3) .
C26 C27 C28 120.5(4) .
C29 C28 C27 118.0(3) .
C30 C29 C28 123.7(3) .
C30 C29 Ru 70.55(18) .
C28 C29 Ru 117.7(2) .
C29 C30 Ru 74.17(19) .
Cl11 C100 Cl11 111.9(3) 2_554
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ru N1 1.966(2) .
Ru N24 2.088(3) .
Ru N9 2.137(2) .
Ru C30 2.209(3) .
Ru C29 2.254(3) .
Ru Cl2 2.3901(8) .
Ru Cl1 2.4034(8) .
N1 C2 1.343(4) .
N1 C6 1.362(4) .
C2 C3 1.394(4) .
C2 C7 1.468(4) .
C3 C4 1.381(5) .
C4 C5 1.384(5) .
C5 C6 1.394(4) .
C6 C22 1.461(5) .
C7 N9 1.293(4) .
C7 C8 1.493(5) .
N9 C10 1.469(4) .
C10 C11 1.397(5) .
C10 C15 1.410(5) .
C11 C12 1.393(5) .
C11 C16 1.516(5) .
C12 C13 1.363(6) .
C13 C14 1.370(6) .
C14 C15 1.398(5) .
C15 C19 1.515(5) .
C16 C18 1.533(5) .
C16 C17 1.537(6) .
C19 C20 1.527(5) .
C19 C21 1.534(6) .
C22 N24 1.298(4) .
C22 C23 1.505(4) .
N24 C25 1.473(4) .
C25 C26 1.516(5) .
C26 C27 1.453(6) .
C27 C28 1.540(6) .
C28 C29 1.523(5) .
C29 C30 1.353(5) .
Cl11 C100 1.757(3) .
C100 Cl11 1.757(3) 2_554
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
N24 Ru N1 C2 179.5(2)
N9 Ru N1 C2 -4.1(2)
C30 Ru N1 C2 5.0(5)
C29 Ru N1 C2 167.6(4)
Cl2 Ru N1 C2 87.0(2)
Cl1 Ru N1 C2 -97.7(2)
N24 Ru N1 C6 8.1(2)
N9 Ru N1 C6 -175.5(2)
C30 Ru N1 C6 -166.4(3)
C29 Ru N1 C6 -3.8(5)
Cl2 Ru N1 C6 -84.5(2)
Cl1 Ru N1 C6 90.9(2)
C6 N1 C2 C3 -3.1(4)
Ru N1 C2 C3 -174.4(2)
C6 N1 C2 C7 175.9(3)
Ru N1 C2 C7 4.7(3)
N1 C2 C3 C4 1.1(5)
C7 C2 C3 C4 -177.9(3)
C2 C3 C4 C5 1.2(5)
C3 C4 C5 C6 -1.4(5)
C2 N1 C6 C5 2.9(4)
Ru N1 C6 C5 174.2(2)
C2 N1 C6 C22 -179.7(3)
Ru N1 C6 C22 -8.3(3)
C4 C5 C6 N1 -0.6(5)
C4 C5 C6 C22 -177.6(3)
N1 C2 C7 N9 -2.0(4)
C3 C2 C7 N9 177.0(3)
N1 C2 C7 C8 178.9(3)
C3 C2 C7 C8 -2.1(5)
C2 C7 N9 C10 -179.2(3)
C8 C7 N9 C10 -0.3(5)
C2 C7 N9 Ru -1.2(3)
C8 C7 N9 Ru 177.8(3)
N1 Ru N9 C7 2.7(2)
N24 Ru N9 C7 10.7(4)
C30 Ru N9 C7 -174.3(2)
C29 Ru N9 C7 -174.5(2)
Cl2 Ru N9 C7 -81.9(2)
Cl1 Ru N9 C7 97.1(2)
N1 Ru N9 C10 -179.5(3)
N24 Ru N9 C10 -171.5(2)
C30 Ru N9 C10 3.5(3)
C29 Ru N9 C10 3.3(3)
Cl2 Ru N9 C10 95.9(2)
Cl1 Ru N9 C10 -85.1(2)
C7 N9 C10 C11 88.2(4)
Ru N9 C10 C11 -89.6(3)
C7 N9 C10 C15 -92.4(4)
Ru N9 C10 C15 89.8(3)
C15 C10 C11 C12 -3.5(5)
N9 C10 C11 C12 175.9(3)
C15 C10 C11 C16 175.2(3)
N9 C10 C11 C16 -5.4(5)
C10 C11 C12 C13 1.3(6)
C16 C11 C12 C13 -177.5(4)
C11 C12 C13 C14 1.5(7)
C12 C13 C14 C15 -2.0(6)
C13 C14 C15 C10 -0.1(6)
C13 C14 C15 C19 178.6(4)
C11 C10 C15 C14 3.0(5)
N9 C10 C15 C14 -176.4(3)
C11 C10 C15 C19 -175.8(3)
N9 C10 C15 C19 4.9(5)
C12 C11 C16 C18 -54.3(5)
C10 C11 C16 C18 127.0(4)
C12 C11 C16 C17 68.6(5)
C10 C11 C16 C17 -110.1(4)
C14 C15 C19 C20 48.1(5)
C10 C15 C19 C20 -133.2(4)
C14 C15 C19 C21 -75.4(4)
C10 C15 C19 C21 103.2(4)
N1 C6 C22 N24 2.4(4)
C5 C6 C22 N24 179.5(3)
N1 C6 C22 C23 -174.4(3)
C5 C6 C22 C23 2.7(5)
C6 C22 N24 C25 -167.4(3)
C23 C22 N24 C25 9.2(5)
C6 C22 N24 Ru 4.1(3)
C23 C22 N24 Ru -179.3(2)
N1 Ru N24 C22 -6.5(2)
N9 Ru N24 C22 -14.5(4)
C30 Ru N24 C22 171.4(2)
C29 Ru N24 C22 170.0(2)
Cl2 Ru N24 C22 77.8(2)
Cl1 Ru N24 C22 -103.3(2)
N1 Ru N24 C25 164.5(3)
N9 Ru N24 C25 156.5(2)
C30 Ru N24 C25 -17.6(3)
C29 Ru N24 C25 -18.9(3)
Cl2 Ru N24 C25 -111.2(2)
Cl1 Ru N24 C25 67.7(2)
C22 N24 C25 C26 -101.7(4)
Ru N24 C25 C26 87.6(3)
N24 C25 C26 C27 -38.4(5)
C25 C26 C27 C28 -57.3(6)
C26 C27 C28 C29 47.1(6)
C27 C28 C29 C30 133.1(4)
C27 C28 C29 Ru 48.9(5)
N1 Ru C29 C30 -170.3(3)
N24 Ru C29 C30 178.1(2)
N9 Ru C29 C30 0.4(3)
Cl2 Ru C29 C30 -90.7(2)
Cl1 Ru C29 C30 93.7(2)
N1 Ru C29 C28 -51.7(6)
N24 Ru C29 C28 -63.3(3)
N9 Ru C29 C28 119.0(3)
C30 Ru C29 C28 118.6(4)
Cl2 Ru C29 C28 27.9(3)
Cl1 Ru C29 C28 -147.7(3)
C28 C29 C30 Ru -110.9(3)
N1 Ru C30 C29 171.4(3)
N24 Ru C30 C29 -2.3(3)
N9 Ru C30 C29 -179.7(2)
Cl2 Ru C30 C29 90.8(2)
Cl1 Ru C30 C29 -84.8(2)
