#------------------------------------------------------------------------------
#$Date: 2016-02-16 22:30:59 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176467 $
#$URL: svn://www.crystallography.net/cod/cif/4/07/51/4075148.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4075148
loop_
_publ_author_name
'Amitsuka, Takahiko'
'Seino, Hidetake'
'Hidai, Masanobu'
'Mizobe, Yasushi'
_publ_section_title
;
 Mixed-Metal Sulfido Clusters Containing Noble Metals and Group 15 Metals.
 Stepwise Construction of Bimetallic and Trimetallic Ru2MS2(M = Sb, Bi),
 Ru2PdSbS2, and Ru2Pd2SbS2Cores
;
_journal_issue                   12
_journal_name_full               Organometallics
_journal_page_first              3034
_journal_paper_doi               10.1021/om060071s
_journal_volume                  25
_journal_year                    2006
_chemical_formula_moiety         'C22 H35 Bi Cl4 S2 Ru2 '
_chemical_formula_sum            'C22 H35 Bi Cl4 Ru2 S2'
_chemical_formula_weight         916.57
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90
_cell_angle_beta                 97.8019(7)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   10.454(2)
_cell_length_b                   23.873(4)
_cell_length_c                   11.819(2)
_cell_measurement_reflns_used    7695
_cell_measurement_temperature    293.1
_cell_measurement_theta_max      27.9
_cell_measurement_theta_min      3.2
_cell_volume                     2922.3(9)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.6.0'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    'DIRDIF99 (PATTY)'
_diffrn_detector_area_resol_mean 7.31
_diffrn_measured_fraction_theta_full 0.9941
_diffrn_measured_fraction_theta_max 0.9941
_diffrn_measurement_device_type  'Rigaku Mercury'
_diffrn_measurement_method       ω
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.033
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_k_max       31
_diffrn_reflns_limit_k_min       -30
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            24348
_diffrn_reflns_theta_full        27.88
_diffrn_reflns_theta_max         27.88
_exptl_absorpt_coefficient_mu    7.535
_exptl_absorpt_correction_T_max  0.471
_exptl_absorpt_correction_T_min  0.220
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Jacobson, R. (1998) Private communication'
_exptl_crystal_colour            brown
_exptl_crystal_density_diffrn    2.083
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       platelet
_exptl_crystal_F_000             1752.00
_exptl_crystal_size_max          0.50
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.10
_refine_diff_density_max         2.09
_refine_diff_density_min         -0.93
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.000
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     318
_refine_ls_number_reflns         6940
_refine_ls_R_factor_gt           0.0280
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[0.0010Fo² + 0.2300σ(Fo²) + 0.0200]/(4Fo²)'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0980
_reflns_number_gt                5005
_reflns_number_total             6940
_reflns_threshold_expression     F²>2.0σ(F²)
_cod_data_source_file            om060071ssi20060417_110316.cif
_cod_data_source_block           '__[(Cp^RuCl)2(SH)(SBiCl2)]_(3b)'
_cod_original_cell_volume        2922.4(9)
_cod_original_formula_sum        'C22 H35 Bi Cl4 S2 Ru2 '
_cod_database_code               4075148
loop_
_symmetry_equiv_pos_site_id
_symmetry_equiv_pos_as_xyz
1 +X,+Y,+Z
2 1/2-X,1/2+Y,1/2-Z
3 -X,-Y,-Z
4 1/2+X,1/2-Y,1/2+Z
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Bi(1) Bi 0.11806(2) 0.083430(10) 0.52118(2) 0.03944(6) Uani 1.00 1 d .
Ru(1) Ru 0.29054(4) 0.105510(10) 0.25742(3) 0.03039(10) Uani 1.00 1 d .
Ru(2) Ru 0.34904(3) 0.193020(10) 0.42057(4) 0.03074(10) Uani 1.00 1 d .
Cl(1) Cl 0.06258(12) 0.09654(6) 0.27947(13) 0.0477(4) Uani 1.00 1 d .
Cl(2) Cl 0.13393(12) 0.20258(6) 0.4784(1) 0.0490(4) Uani 1.00 1 d .
Cl(3) Cl 0.1751(1) -0.02177(6) 0.5190(2) 0.0606(5) Uani 1.00 1 d .
Cl(4) Cl 0.2253(2) 0.09832(9) 0.7272(2) 0.0771(6) Uani 1.00 1 d .
S(1) S 0.34119(11) 0.09769(4) 0.45331(10) 0.0294(3) Uani 1.00 1 d .
S(2) S 0.2570(1) 0.20063(5) 0.23186(13) 0.0449(4) Uani 1.00 1 d .
C(1) C 0.4658(6) 0.0756(2) 0.1783(5) 0.042(1) Uani 1.00 1 d .
C(2) C 0.3705(6) 0.0974(2) 0.0923(5) 0.048(2) Uani 1.00 1 d .
C(3) C 0.2550(6) 0.0659(3) 0.0905(5) 0.050(2) Uani 1.00 1 d .
C(4) C 0.2799(5) 0.0228(2) 0.1769(5) 0.044(1) Uani 1.00 1 d .
C(5) C 0.4100(5) 0.0297(2) 0.2298(5) 0.043(1) Uani 1.00 1 d .
C(6) C 0.6084(6) 0.0872(3) 0.1897(6) 0.057(2) Uani 1.00 1 d .
C(7) C 0.6712(8) 0.0518(4) 0.1046(9) 0.091(3) Uani 1.00 1 d .
C(8) C 0.3945(8) 0.1445(3) 0.0123(6) 0.078(3) Uani 1.00 1 d .
C(9) C 0.1324(7) 0.0715(4) 0.0101(6) 0.077(3) Uani 1.00 1 d .
C(10) C 0.1907(7) -0.0239(3) 0.1976(7) 0.071(2) Uani 1.00 1 d .
C(11) C 0.4778(7) -0.0082(3) 0.3198(6) 0.064(2) Uani 1.00 1 d .
C(12) C 0.5583(5) 0.2016(2) 0.4672(6) 0.050(2) Uani 1.00 1 d .
C(13) C 0.5114(6) 0.2454(3) 0.3925(6) 0.056(2) Uani 1.00 1 d .
C(14) C 0.4250(6) 0.2778(2) 0.4487(7) 0.062(2) Uani 1.00 1 d .
C(15) C 0.4220(6) 0.2541(3) 0.5562(7) 0.068(2) Uani 1.00 1 d .
C(16) C 0.5023(6) 0.2076(3) 0.5688(6) 0.057(2) Uani 1.00 1 d .
C(17) C 0.6623(7) 0.1605(4) 0.4502(11) 0.122(4) Uani 1.00 1 d .
C(18) C 0.7943(7) 0.1800(4) 0.4997(12) 0.140(4) Uani 1.00 1 d .
C(19) C 0.5538(11) 0.2590(5) 0.2812(9) 0.139(5) Uani 1.00 1 d .
C(20) C 0.3558(10) 0.3311(3) 0.4043(13) 0.173(5) Uani 1.00 1 d .
C(21) C 0.3465(9) 0.2772(6) 0.6469(11) 0.169(5) Uani 1.00 1 d .
C(22) C 0.5288(13) 0.1727(5) 0.6742(9) 0.165(5) Uani 1.00 1 d .
H(1) H 0.6204 0.1254 0.1718 0.069 Uiso 1.00 1 c R
H(2) H 0.6470 0.0799 0.2657 0.069 Uiso 1.00 1 c R
H(3) H 0.6995 0.0179 0.1417 0.114 Uiso 1.00 1 c R
H(4) H 0.7430 0.0708 0.0810 0.114 Uiso 1.00 1 c R
H(5) H 0.6099 0.0437 0.0397 0.114 Uiso 1.00 1 c R
H(6) H 0.3193 0.1507 -0.0410 0.094 Uiso 1.00 1 c R
H(7) H 0.4646 0.1350 -0.0274 0.094 Uiso 1.00 1 c R
H(8) H 0.4150 0.1776 0.0556 0.094 Uiso 1.00 1 c R
H(9) H 0.0736 0.0428 0.0239 0.090 Uiso 1.00 1 c R
H(10) H 0.1515 0.0686 -0.0660 0.090 Uiso 1.00 1 c R
H(11) H 0.0948 0.1070 0.0207 0.090 Uiso 1.00 1 c R
H(12) H 0.2305 -0.0466 0.2583 0.085 Uiso 1.00 1 c R
H(13) H 0.1722 -0.0459 0.1304 0.085 Uiso 1.00 1 c R
H(14) H 0.1127 -0.0087 0.2175 0.085 Uiso 1.00 1 c R
H(15) H 0.5626 0.0056 0.3427 0.077 Uiso 1.00 1 c R
H(16) H 0.4823 -0.0451 0.2907 0.077 Uiso 1.00 1 c R
H(17) H 0.4315 -0.0086 0.3836 0.077 Uiso 1.00 1 c R
H(18) H 0.6447 0.1267 0.4877 0.141 Uiso 1.00 1 c R
H(19) H 0.6607 0.1535 0.3709 0.141 Uiso 1.00 1 c R
H(20) H 0.8313 0.1998 0.4424 0.163 Uiso 1.00 1 c R
H(21) H 0.8476 0.1490 0.5250 0.163 Uiso 1.00 1 c R
H(22) H 0.7873 0.2042 0.5623 0.163 Uiso 1.00 1 c R
H(23) H 0.6158 0.2317 0.2668 0.168 Uiso 1.00 1 c R
H(24) H 0.5921 0.2951 0.2835 0.168 Uiso 1.00 1 c R
H(25) H 0.4826 0.2578 0.2220 0.168 Uiso 1.00 1 c R
H(26) H 0.3772 0.3395 0.3305 0.191 Uiso 1.00 1 c R
H(27) H 0.3813 0.3614 0.4546 0.191 Uiso 1.00 1 c R
H(28) H 0.2652 0.3257 0.3996 0.191 Uiso 1.00 1 c R
H(29) H 0.2978 0.3096 0.6226 0.206 Uiso 1.00 1 c R
H(30) H 0.4067 0.2860 0.7121 0.206 Uiso 1.00 1 c R
H(31) H 0.2900 0.2485 0.6659 0.206 Uiso 1.00 1 c R
H(32) H 0.4789 0.1870 0.7292 0.185 Uiso 1.00 1 c R
H(33) H 0.6179 0.1745 0.7038 0.185 Uiso 1.00 1 c R
H(34) H 0.5053 0.1349 0.6573 0.185 Uiso 1.00 1 c R
H(35) H 0.133(5) 0.204(2) 0.242(4) 0.033(13) Uiso 1.00 1 c .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.003 0.002
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
H H 0.000 0.000
;
International Tables for Crystallography
(1992, Vol. C, Table 6.1.1.4)
;
S S 0.125 0.123
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
Cl Cl 0.148 0.159
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
Ru Ru -1.259 0.836
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
Bi Bi -4.108 10.257
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
Bi(1) Cl(1) Ru(1) 92.74(4)
Cl(2) Bi(1) Cl(1) 74.12(4)
Cl(3) Bi(1) Cl(1) 96.46(5)
Cl(4) Bi(1) Cl(1) 159.85(6)
S(1) Bi(1) Cl(1) 75.21(4)
Bi(1) Cl(2) Ru(2) 91.93(4)
Cl(3) Bi(1) Cl(2) 159.11(5)
Cl(4) Bi(1) Cl(2) 90.10(6)
S(1) Bi(1) Cl(2) 75.03(4)
Cl(4) Bi(1) Cl(3) 94.16(6)
S(1) Bi(1) Cl(3) 84.61(4)
S(1) Bi(1) Cl(4) 88.84(6)
Bi(1) S(1) Ru(1) 103.14(4)
Bi(1) S(1) Ru(2) 103.60(4)
Cl(1) Ru(1) Ru(2) 96.60(4)
Ru(1) Ru(2) Cl(2) 97.83(4)
Ru(1) Ru(2) S(1) 51.90(3)
S(1) Ru(1) Ru(2) 51.91(3)
Ru(1) Ru(2) S(2) 51.89(3)
S(2) Ru(1) Ru(2) 51.95(4)
C(1) Ru(1) Ru(2) 113.3(1)
C(2) Ru(1) Ru(2) 125.7(2)
C(3) Ru(1) Ru(2) 157.9(2)
C(4) Ru(1) Ru(2) 161.5(1)
C(5) Ru(1) Ru(2) 128.0(1)
Ru(1) Ru(2) C(12) 110.7(2)
Ru(1) Ru(2) C(13) 114.8(2)
Ru(1) Ru(2) C(14) 145.3(2)
Ru(1) Ru(2) C(15) 171.3(2)
Ru(1) Ru(2) C(16) 135.2(2)
S(1) Ru(1) Cl(1) 88.87(5)
S(2) Ru(1) Cl(1) 88.11(5)
C(1) Ru(1) Cl(1) 150.0(1)
C(2) Ru(1) Cl(1) 124.9(2)
C(3) Ru(1) Cl(1) 90.6(2)
C(4) Ru(1) Cl(1) 88.5(2)
C(5) Ru(1) Cl(1) 121.0(1)
Ru(1) S(1) Ru(2) 76.19(4)
S(2) Ru(1) S(1) 102.73(5)
C(1) Ru(1) S(1) 107.3(1)
C(2) Ru(1) S(1) 143.7(2)
C(3) Ru(1) S(1) 149.5(2)
C(4) Ru(1) S(1) 110.7(1)
C(5) Ru(1) S(1) 91.4(1)
Ru(1) S(2) Ru(2) 76.17(4)
C(1) Ru(1) S(2) 111.7(1)
C(2) Ru(1) S(2) 92.3(2)
C(3) Ru(1) S(2) 107.7(2)
C(4) Ru(1) S(2) 146.3(1)
C(5) Ru(1) S(2) 148.2(2)
Ru(1) C(1) C(2) 69.8(3)
C(2) Ru(1) C(1) 36.7(2)
C(3) Ru(1) C(1) 62.6(2)
C(4) Ru(1) C(1) 62.3(2)
Ru(1) C(1) C(5) 70.4(3)
C(5) Ru(1) C(1) 36.5(2)
Ru(1) C(1) C(6) 138.4(4)
Ru(1) C(2) C(1) 73.5(3)
Ru(1) C(2) C(3) 68.9(3)
C(3) Ru(1) C(2) 37.5(2)
C(4) Ru(1) C(2) 62.9(2)
C(5) Ru(1) C(2) 61.4(2)
Ru(1) C(2) C(8) 126.5(5)
Ru(1) C(3) C(2) 73.5(3)
Ru(1) C(3) C(4) 71.2(3)
C(4) Ru(1) C(3) 38.8(2)
C(5) Ru(1) C(3) 63.1(2)
Ru(1) C(3) C(9) 124.3(5)
Ru(1) C(4) C(3) 70.1(3)
Ru(1) C(4) C(5) 73.5(3)
C(5) Ru(1) C(4) 37.5(2)
Ru(1) C(4) C(10) 126.7(5)
Ru(1) C(5) C(1) 73.1(3)
Ru(1) C(5) C(4) 69.0(3)
Ru(1) C(5) C(11) 127.0(4)
S(1) Ru(2) Cl(2) 89.44(5)
S(2) Ru(2) Cl(2) 89.09(5)
C(12) Ru(2) Cl(2) 147.6(2)
C(13) Ru(2) Cl(2) 139.2(2)
C(14) Ru(2) Cl(2) 101.5(2)
C(15) Ru(2) Cl(2) 88.6(2)
C(16) Ru(2) Cl(2) 110.8(2)
S(2) Ru(2) S(1) 102.66(4)
C(12) Ru(2) S(1) 96.1(1)
C(13) Ru(2) S(1) 129.7(2)
C(14) Ru(2) S(1) 155.2(2)
C(15) Ru(2) S(1) 122.8(2)
C(16) Ru(2) S(1) 93.4(2)
C(12) Ru(2) S(2) 120.4(2)
C(13) Ru(2) S(2) 92.2(2)
C(14) Ru(2) S(2) 99.7(2)
C(15) Ru(2) S(2) 134.5(2)
C(16) Ru(2) S(2) 154.7(2)
Ru(2) C(12) C(13) 70.3(3)
C(13) Ru(2) C(12) 37.8(2)
C(14) Ru(2) C(12) 63.0(2)
C(15) Ru(2) C(12) 61.6(2)
Ru(2) C(12) C(16) 73.1(3)
C(16) Ru(2) C(12) 37.2(3)
Ru(2) C(12) C(17) 128.6(4)
Ru(2) C(13) C(12) 71.9(3)
Ru(2) C(13) C(14) 71.4(3)
C(14) Ru(2) C(13) 38.1(3)
C(15) Ru(2) C(13) 62.2(3)
C(16) Ru(2) C(13) 62.5(2)
Ru(2) C(13) C(19) 126.7(6)
Ru(2) C(14) C(13) 70.4(3)
Ru(2) C(14) C(15) 73.1(4)
C(15) Ru(2) C(14) 36.9(3)
C(16) Ru(2) C(14) 61.9(2)
Ru(2) C(14) C(20) 125.2(5)
Ru(2) C(15) C(14) 70.0(4)
Ru(2) C(15) C(16) 72.3(4)
C(16) Ru(2) C(15) 36.3(2)
Ru(2) C(15) C(21) 125.9(5)
Ru(2) C(16) C(12) 69.7(3)
Ru(2) C(16) C(15) 71.4(4)
Ru(2) C(16) C(22) 126.8(6)
C(1) C(2) C(3) 109.2(5)
C(5) C(1) C(2) 107.4(5)
C(6) C(1) C(2) 126.0(5)
C(1) C(2) C(8) 124.0(6)
C(1) C(5) C(4) 109.0(5)
C(6) C(1) C(5) 124.3(5)
C(1) C(5) C(11) 126.0(5)
C(1) C(6) C(7) 110.5(6)
C(2) C(3) C(4) 107.1(5)
C(8) C(2) C(3) 126.7(6)
C(2) C(3) C(9) 128.0(6)
C(3) C(4) C(5) 107.2(5)
C(9) C(3) C(4) 124.7(6)
C(3) C(4) C(10) 126.1(5)
C(10) C(4) C(5) 126.4(5)
C(4) C(5) C(11) 124.9(5)
C(12) C(13) C(14) 107.4(6)
C(16) C(12) C(13) 107.9(5)
C(17) C(12) C(13) 126.6(7)
C(12) C(13) C(19) 126.7(7)
C(12) C(16) C(15) 107.7(6)
C(17) C(12) C(16) 125.0(7)
C(12) C(16) C(22) 126.9(7)
C(12) C(17) C(18) 113.1(7)
C(13) C(14) C(15) 107.4(5)
C(19) C(13) C(14) 125.6(7)
C(13) C(14) C(20) 126.7(8)
C(14) C(15) C(16) 109.5(7)
C(20) C(14) C(15) 125.8(8)
C(14) C(15) C(21) 125.1(7)
C(21) C(15) C(16) 125.4(8)
C(15) C(16) C(22) 125.3(8)
Ru(1) S(2) H(35) 100(2)
Ru(2) S(2) H(35) 101(2)
C(1) C(6) H(1) 108.3860
C(1) C(6) H(2) 109.9015
C(2) C(8) H(6) 109.7007
C(2) C(8) H(8) 109.1013
C(2) C(8) H(7) 109.6037
C(3) C(9) H(9) 110.2100
C(3) C(9) H(11) 109.3398
C(3) C(9) H(10) 108.8608
C(4) C(10) H(12) 109.3338
C(4) C(10) H(14) 109.4127
C(4) C(10) H(13) 109.6666
C(5) C(11) H(15) 109.1004
C(5) C(11) H(17) 109.0994
C(5) C(11) H(16) 110.2046
H(1) C(6) C(7) 107.6316
H(2) C(6) C(7) 110.9301
C(6) C(7) H(3) 107.5639
C(6) C(7) H(4) 110.9271
C(6) C(7) H(5) 109.8996
H(2) C(6) H(1) 109.4574
H(4) C(7) H(3) 109.4724
H(5) C(7) H(3) 109.4778
H(5) C(7) H(4) 109.4682
H(8) C(8) H(6) 109.4797
H(7) C(8) H(6) 109.4703
H(8) C(8) H(7) 109.4710
H(11) C(9) H(9) 109.4662
H(10) C(9) H(9) 109.4832
H(11) C(9) H(10) 109.4644
H(14) C(10) H(12) 109.4688
H(13) C(10) H(12) 109.4710
H(14) C(10) H(13) 109.4741
H(17) C(11) H(15) 109.4770
H(16) C(11) H(15) 109.4667
H(17) C(11) H(16) 109.4766
C(12) C(17) H(18) 107.5603
C(12) C(17) H(19) 109.3671
C(13) C(19) H(23) 107.5247
C(13) C(19) H(25) 110.4338
C(13) C(19) H(24) 110.4360
C(14) C(20) H(26) 109.3607
C(14) C(20) H(28) 109.2229
C(14) C(20) H(27) 109.8174
C(15) C(21) H(29) 112.9536
C(15) C(21) H(31) 107.7530
C(15) C(21) H(30) 107.6490
C(16) C(22) H(32) 108.2989
C(16) C(22) H(34) 109.9754
C(16) C(22) H(33) 110.1303
H(18) C(17) C(18) 107.9296
H(19) C(17) C(18) 109.3895
C(17) C(18) H(20) 108.6260
C(17) C(18) H(21) 110.5548
C(17) C(18) H(22) 109.2300
H(19) C(17) H(18) 109.4631
H(21) C(18) H(20) 109.4766
H(22) C(18) H(20) 109.4700
H(22) C(18) H(21) 109.4639
H(25) C(19) H(23) 109.4792
H(24) C(19) H(23) 109.4662
H(25) C(19) H(24) 109.4695
H(28) C(20) H(26) 109.4702
H(27) C(20) H(26) 109.4781
H(28) C(20) H(27) 109.4774
H(31) C(21) H(29) 109.4732
H(30) C(21) H(29) 109.4690
H(31) C(21) H(30) 109.4755
H(34) C(22) H(32) 109.4684
H(33) C(22) H(32) 109.4775
H(34) C(22) H(33) 109.4704
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
Bi(1) Cl(1) 2.854(2)
Bi(1) Cl(2) 2.898(1)
Bi(1) Cl(3) 2.582(1)
Bi(1) Cl(4) 2.564(2)
Bi(1) S(1) 2.590(1)
Ru(1) Ru(2) 2.8525(5)
Ru(1) Cl(1) 2.442(1)
Ru(1) S(1) 2.311(1)
Ru(1) S(2) 2.311(1)
Ru(1) C(1) 2.282(6)
Ru(1) C(2) 2.234(6)
Ru(1) C(3) 2.174(6)
Ru(1) C(4) 2.189(5)
Ru(1) C(5) 2.247(5)
Ru(2) Cl(2) 2.448(1)
Ru(2) S(1) 2.312(1)
Ru(2) S(2) 2.313(2)
Ru(2) C(12) 2.191(5)
Ru(2) C(13) 2.169(6)
Ru(2) C(14) 2.183(5)
Ru(2) C(15) 2.223(8)
Ru(2) C(16) 2.235(6)
C(1) C(2) 1.422(8)
C(1) C(5) 1.417(8)
C(1) C(6) 1.503(9)
C(2) C(3) 1.420(9)
C(2) C(8) 1.51(1)
C(3) C(4) 1.448(8)
C(3) C(9) 1.494(9)
C(4) C(5) 1.427(8)
C(4) C(10) 1.494(9)
C(5) C(11) 1.499(8)
C(6) C(7) 1.53(1)
C(12) C(13) 1.413(9)
C(12) C(16) 1.41(1)
C(12) C(17) 1.50(1)
C(13) C(14) 1.42(1)
C(13) C(19) 1.48(1)
C(14) C(15) 1.40(1)
C(14) C(20) 1.52(1)
C(15) C(16) 1.387(9)
C(15) C(21) 1.52(1)
C(16) C(22) 1.49(1)
C(17) C(18) 1.50(1)
C(18) C(17) 1.50(1)
S(2) H(35) 1.32(5)
C(6) H(1) 0.9500
C(6) H(2) 0.9500
C(7) H(3) 0.9499
C(7) H(4) 0.9500
C(7) H(5) 0.9500
C(8) H(6) 0.9500
C(8) H(7) 0.9500
C(8) H(8) 0.9501
C(9) H(9) 0.9500
C(9) H(10) 0.9500
C(9) H(11) 0.9499
C(10) H(12) 0.9499
C(10) H(13) 0.9500
C(10) H(14) 0.9500
C(11) H(15) 0.9500
C(11) H(16) 0.9499
C(11) H(17) 0.9500
C(17) H(18) 0.9500
C(17) H(19) 0.9499
C(18) H(20) 0.9500
C(18) H(21) 0.9499
C(18) H(22) 0.9500
C(19) H(23) 0.9500
C(19) H(24) 0.9500
C(19) H(25) 0.9500
C(20) H(26) 0.9500
C(20) H(27) 0.9500
C(20) H(28) 0.9500
C(21) H(29) 0.9499
C(21) H(30) 0.9500
C(21) H(31) 0.9500
C(22) H(32) 0.9499
C(22) H(33) 0.9500
C(22) H(34) 0.9499
H(20) C(18) 0.9500
H(21) C(18) 0.9499
H(22) C(18) 0.9500
loop_
_geom_contact_atom_site_label_1
_geom_contact_atom_site_label_2
_geom_contact_distance
_geom_contact_site_symmetry_2
Bi(1) Ru(1) 3.8436(5) .
Bi(1) Ru(2) 3.8560(4) .
Bi(1) Cl(3) 3.374(1) 55603
