#------------------------------------------------------------------------------
#$Date: 2016-03-21 10:29:19 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178653 $
#$URL: svn://www.crystallography.net/cod/cif/4/07/64/4076450.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4076450
loop_
_publ_author_name
'Lohan, Manja'
'Milde, Bianca'
'Heider, Silvio'
'Speck, J. Matthäus'
'Krauße, Sabrina'
'Schaarschmidt, Dieter'
'Rüffer, Tobias'
'Lang, Heinrich'
_publ_section_title
;
 Synthesis, Electrochemistry, Spectroelectrochemistry, and Solid-State
 Structures of Palladium Biferrocenylphosphines and Their Use in C,C
 Cross-Coupling Reactions
;
_journal_issue                   6
_journal_name_full               Organometallics
_journal_page_first              2310
_journal_paper_doi               10.1021/om201220w
_journal_volume                  31
_journal_year                    2012
_chemical_formula_moiety         'C64 H54 Cl2 Fe4 P2 Pd, 2(C H2 Cl2)'
_chemical_formula_sum            'C66 H58 Cl6 Fe4 P2 Pd'
_chemical_formula_weight         1455.56
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                95.707(8)
_cell_angle_beta                 97.126(8)
_cell_angle_gamma                113.675(9)
_cell_formula_units_Z            1
_cell_length_a                   9.8163(9)
_cell_length_b                   11.2358(12)
_cell_length_c                   14.9169(14)
_cell_measurement_reflns_used    8503
_cell_measurement_temperature    100
_cell_measurement_theta_max      28.6207
_cell_measurement_theta_min      2.7860
_cell_volume                     1474.8(3)
_computing_cell_refinement
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.32.5 (release 08-05-2007 CrysAlis171 .NET)
(compiled May  8 2007,13:10:02)
;
_computing_data_collection
;
CrysAlis CCD, Oxford Diffraction Ltd.,
Version 1.171.32.5 (release 08-05-2007 CrysAlis171 .NET)
(compiled May  8 2007,13:10:02)
;
_computing_data_reduction
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.32.5 (release 08-05-2007 CrysAlis171 .NET)
(compiled May  8 2007,13:10:02)
;
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'Oxford Gemini S'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0275
_diffrn_reflns_av_sigmaI/netI    0.0406
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            14551
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         2.79
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 50
_diffrn_standards_interval_time  10
_diffrn_standards_number         2
_exptl_absorpt_coefficient_mu    1.628
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.74925
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.32.5 (release 08-05-2007 CrysAlis171 .NET)
(compiled May  8 2007,13:10:02)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.639
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             736
_exptl_crystal_size_max          0.38
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.30
_refine_diff_density_max         0.679
_refine_diff_density_min         -0.638
_refine_diff_density_rms         0.077
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.993
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     386
_refine_ls_number_reflns         5747
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.993
_refine_ls_R_factor_all          0.0412
_refine_ls_R_factor_gt           0.0283
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0413P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0661
_refine_ls_wR_factor_ref         0.0699
_reflns_number_gt                4471
_reflns_number_total             5747
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om201220w_si_001.cif
_cod_data_source_block           exp_008
_cod_original_cell_volume        1474.8(2)
_cod_database_code               4076450
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.1773(3) 0.8193(2) 0.03074(19) 0.0241(6) Uani 1 1 d . . .
H1 H 0.2202 0.7937 -0.0155 0.029 Uiso 1 1 calc R . .
C2 C 0.0668(3) 0.8716(2) 0.01965(19) 0.0241(6) Uani 1 1 d . . .
H2 H 0.0243 0.8858 -0.0352 0.029 Uiso 1 1 calc R . .
C3 C 0.0337(3) 0.8978(3) 0.1073(2) 0.0301(7) Uani 1 1 d . . .
H3 H -0.0346 0.9327 0.1199 0.036 Uiso 1 1 calc R . .
C4 C 0.1209(3) 0.8624(3) 0.1720(2) 0.0335(7) Uani 1 1 d . . .
H4 H 0.1206 0.8696 0.2346 0.040 Uiso 1 1 calc R . .
C5 C 0.2096(3) 0.8136(3) 0.1248(2) 0.0294(7) Uani 1 1 d . . .
H5 H 0.2776 0.7831 0.1513 0.035 Uiso 1 1 calc R . .
C6 C 0.4578(2) 1.1247(2) 0.07312(17) 0.0194(6) Uani 1 1 d . . .
H6 H 0.5040 1.1032 0.0272 0.023 Uiso 1 1 calc R . .
C7 C 0.3504(3) 1.1800(2) 0.06251(18) 0.0220(6) Uani 1 1 d . . .
H7 H 0.3145 1.2010 0.0084 0.026 Uiso 1 1 calc R . .
C8 C 0.3075(3) 1.1976(2) 0.14833(18) 0.0235(6) Uani 1 1 d . . .
H8 H 0.2390 1.2323 0.1606 0.028 Uiso 1 1 calc R . .
C9 C 0.3879(3) 1.1528(2) 0.21230(18) 0.0225(6) Uani 1 1 d . . .
H9 H 0.3803 1.1528 0.2738 0.027 Uiso 1 1 calc R . .
C10 C 0.4821(2) 1.1078(2) 0.16669(17) 0.0176(5) Uani 1 1 d . . .
C11 C 0.5741(2) 1.0448(2) 0.20690(16) 0.0169(5) Uani 1 1 d . . .
C12 C 0.5781(2) 1.0146(2) 0.29763(17) 0.0175(5) Uani 1 1 d . . .
H12 H 0.5258 1.0340 0.3405 0.021 Uiso 1 1 calc R . .
C13 C 0.6753(2) 0.9499(2) 0.31163(17) 0.0174(5) Uani 1 1 d . . .
H13 H 0.6977 0.9198 0.3649 0.021 Uiso 1 1 calc R . .
C14 C 0.7321(3) 0.9397(2) 0.22974(17) 0.0182(5) Uani 1 1 d . . .
H14 H 0.7981 0.9011 0.2199 0.022 Uiso 1 1 calc R . .
C15 C 0.6711(2) 0.9985(2) 0.16518(17) 0.0177(5) Uani 1 1 d . . .
H15 H 0.6908 1.0055 0.1061 0.021 Uiso 1 1 calc R . .
C16 C 0.8676(3) 1.3290(2) 0.26946(17) 0.0214(6) Uani 1 1 d . . .
H16 H 0.8148 1.3675 0.2360 0.026 Uiso 1 1 calc R . .
C17 C 0.8652(2) 1.3123(2) 0.36230(17) 0.0180(5) Uani 1 1 d . . .
H17 H 0.8103 1.3382 0.4003 0.022 Uiso 1 1 calc R . .
C18 C 0.9621(2) 1.2486(2) 0.38787(16) 0.0148(5) Uani 1 1 d . . .
C19 C 1.0227(2) 1.2251(2) 0.30839(17) 0.0189(5) Uani 1 1 d . . .
H19 H 1.0877 1.1840 0.3047 0.023 Uiso 1 1 calc R . .
C20 C 0.9654(3) 1.2761(3) 0.23646(18) 0.0223(6) Uani 1 1 d . . .
H20 H 0.9880 1.2751 0.1777 0.027 Uiso 1 1 calc R . .
C21 C 0.8673(2) 1.2441(2) 0.55940(16) 0.0154(5) Uani 1 1 d . . .
C22 C 0.7125(3) 1.1707(2) 0.52735(17) 0.0202(6) Uani 1 1 d . . .
H22 H 0.6799 1.1021 0.4782 0.024 Uiso 1 1 calc R . .
C23 C 0.6077(3) 1.1987(3) 0.56766(18) 0.0235(6) Uani 1 1 d . . .
H23 H 0.5051 1.1515 0.5443 0.028 Uiso 1 1 calc R . .
C24 C 0.6556(3) 1.2977(3) 0.6433(2) 0.0293(7) Uani 1 1 d . . .
H24 H 0.5848 1.3149 0.6717 0.035 Uiso 1 1 calc R . .
C25 C 0.8066(3) 1.3697(3) 0.6761(2) 0.0298(7) Uani 1 1 d . . .
H25 H 0.8381 1.4361 0.7266 0.036 Uiso 1 1 calc R . .
C26 C 0.9133(3) 1.3442(2) 0.63427(18) 0.0216(6) Uani 1 1 d . . .
H26 H 1.0158 1.3944 0.6565 0.026 Uiso 1 1 calc R . .
C27 C 1.1823(2) 1.3357(2) 0.55652(17) 0.0167(5) Uani 1 1 d . . .
C28 C 1.2628(3) 1.4454(2) 0.51895(19) 0.0217(6) Uani 1 1 d . . .
H28 H 1.2257 1.4549 0.4609 0.026 Uiso 1 1 calc R . .
C29 C 1.3994(3) 1.5412(3) 0.5683(2) 0.0298(7) Uani 1 1 d . . .
H29 H 1.4540 1.6144 0.5429 0.036 Uiso 1 1 calc R . .
C30 C 1.4536(3) 1.5283(3) 0.6541(2) 0.0341(8) Uani 1 1 d . . .
H30 H 1.5448 1.5930 0.6867 0.041 Uiso 1 1 calc R . .
C31 C 1.3738(3) 1.4196(3) 0.6929(2) 0.0316(7) Uani 1 1 d . . .
H31 H 1.4104 1.4116 0.7516 0.038 Uiso 1 1 calc R . .
C32 C 1.2393(3) 1.3232(3) 0.64338(18) 0.0252(6) Uani 1 1 d . . .
H32 H 1.1864 1.2491 0.6685 0.030 Uiso 1 1 calc R . .
Cl1 Cl 1.20786(6) 1.07528(6) 0.42955(4) 0.02117(15) Uani 1 1 d . . .
Fe1 Fe 0.25857(4) 1.00358(3) 0.10816(2) 0.01719(10) Uani 1 1 d . . .
Fe2 Fe 0.79203(3) 1.13328(3) 0.28019(2) 0.01504(9) Uani 1 1 d . . .
Pd1 Pd 1.0000 1.0000 0.5000 0.01395(8) Uani 1 2 d S . .
P1 P 0.99987(6) 1.20781(6) 0.49920(4) 0.01454(14) Uani 1 1 d . . .
C33 C 0.1643(7) 0.4735(7) 0.9869(7) 0.080(2) Uani 0.636(5) 1 d P A 1
H33A H 0.0855 0.3845 0.9719 0.096 Uiso 0.636(5) 1 calc PR A 1
H33B H 0.1158 0.5336 0.9871 0.096 Uiso 0.636(5) 1 calc PR A 1
Cl2 Cl 0.2681(3) 0.4952(2) 1.09883(13) 0.0766(8) Uani 0.636(5) 1 d P A 1
Cl3 Cl 0.2712(4) 0.4997(4) 0.90640(19) 0.1379(16) Uani 0.636(5) 1 d P A 1
C34 C 0.3657(11) 0.5196(10) 0.9839(8) 0.065(4) Uani 0.364(5) 1 d P A 2
H34A H 0.3975 0.4490 0.9901 0.078 Uiso 0.364(5) 1 calc PR A 2
H34B H 0.4351 0.5807 0.9516 0.078 Uiso 0.364(5) 1 calc PR A 2
Cl5 Cl 0.1831(5) 0.4511(4) 0.9148(3) 0.1070(18) Uani 0.364(5) 1 d P A 2
Cl4 Cl 0.3834(10) 0.5938(9) 1.0827(3) 0.155(4) Uani 0.364(5) 1 d P A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Fe Fe 0.3463 0.8444 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C5 C1 C2 107.4(2) . .
C5 C1 Fe1 69.19(15) . .
C2 C1 Fe1 69.83(15) . .
C5 C1 H1 126.3 . .
C2 C1 H1 126.3 . .
Fe1 C1 H1 126.3 . .
C3 C2 C1 107.7(2) . .
C3 C2 Fe1 69.15(15) . .
C1 C2 Fe1 69.62(14) . .
C3 C2 H2 126.2 . .
C1 C2 H2 126.2 . .
Fe1 C2 H2 126.6 . .
C4 C3 C2 108.6(3) . .
C4 C3 Fe1 69.67(15) . .
C2 C3 Fe1 70.40(14) . .
C4 C3 H3 125.7 . .
C2 C3 H3 125.7 . .
Fe1 C3 H3 125.8 . .
C3 C4 C5 107.8(3) . .
C3 C4 Fe1 70.10(15) . .
C5 C4 Fe1 69.74(15) . .
C3 C4 H4 126.1 . .
C5 C4 H4 126.1 . .
Fe1 C4 H4 125.6 . .
C1 C5 C4 108.5(2) . .
C1 C5 Fe1 70.45(14) . .
C4 C5 Fe1 69.51(16) . .
C1 C5 H5 125.8 . .
C4 C5 H5 125.8 . .
Fe1 C5 H5 125.9 . .
C7 C6 C10 108.1(2) . .
C7 C6 Fe1 69.53(13) . .
C10 C6 Fe1 69.60(13) . .
C7 C6 H6 126.0 . .
C10 C6 H6 126.0 . .
Fe1 C6 H6 126.5 . .
C8 C7 C6 108.4(2) . .
C8 C7 Fe1 69.53(15) . .
C6 C7 Fe1 69.81(14) . .
C8 C7 H7 125.8 . .
C6 C7 H7 125.8 . .
Fe1 C7 H7 126.4 . .
C7 C8 C9 107.8(2) . .
C7 C8 Fe1 69.95(15) . .
C9 C8 Fe1 69.15(15) . .
C7 C8 H8 126.1 . .
C9 C8 H8 126.1 . .
Fe1 C8 H8 126.4 . .
C8 C9 C10 108.8(2) . .
C8 C9 Fe1 70.07(14) . .
C10 C9 Fe1 70.33(14) . .
C8 C9 H9 125.6 . .
C10 C9 H9 125.6 . .
Fe1 C9 H9 125.6 . .
C9 C10 C6 107.0(2) . .
C9 C10 C11 125.8(2) . .
C6 C10 C11 127.0(2) . .
C9 C10 Fe1 68.71(13) . .
C6 C10 Fe1 69.57(13) . .
C11 C10 Fe1 122.37(16) . .
C12 C11 C15 107.0(2) . .
C12 C11 C10 124.5(2) . .
C15 C11 C10 128.4(2) . .
C12 C11 Fe2 69.30(13) . .
C15 C11 Fe2 68.95(13) . .
C10 C11 Fe2 128.24(17) . .
C13 C12 C11 108.7(2) . .
C13 C12 Fe2 69.69(13) . .
C11 C12 Fe2 70.11(13) . .
C13 C12 H12 125.6 . .
C11 C12 H12 125.6 . .
Fe2 C12 H12 126.2 . .
C14 C13 C12 107.7(2) . .
C14 C13 Fe2 69.53(14) . .
C12 C13 Fe2 69.78(13) . .
C14 C13 H13 126.2 . .
C12 C13 H13 126.2 . .
Fe2 C13 H13 126.1 . .
C13 C14 C15 108.4(2) . .
C13 C14 Fe2 69.98(14) . .
C15 C14 Fe2 69.63(14) . .
C13 C14 H14 125.8 . .
C15 C14 H14 125.8 . .
Fe2 C14 H14 126.1 . .
C14 C15 C11 108.2(2) . .
C14 C15 Fe2 69.65(13) . .
C11 C15 Fe2 70.31(13) . .
C14 C15 H15 125.9 . .
C11 C15 H15 125.9 . .
Fe2 C15 H15 125.7 . .
C17 C16 C20 107.9(2) . .
C17 C16 Fe2 69.72(14) . .
C20 C16 Fe2 69.52(14) . .
C17 C16 H16 126.0 . .
C20 C16 H16 126.0 . .
Fe2 C16 H16 126.3 . .
C16 C17 C18 108.5(2) . .
C16 C17 Fe2 69.80(14) . .
C18 C17 Fe2 69.77(14) . .
C16 C17 H17 125.8 . .
C18 C17 H17 125.8 . .
Fe2 C17 H17 126.2 . .
C19 C18 C17 107.2(2) . .
C19 C18 P1 126.95(18) . .
C17 C18 P1 125.86(19) . .
C19 C18 Fe2 68.92(13) . .
C17 C18 Fe2 69.16(13) . .
P1 C18 Fe2 127.39(12) . .
C20 C19 C18 107.8(2) . .
C20 C19 Fe2 69.80(13) . .
C18 C19 Fe2 70.00(12) . .
C20 C19 H19 126.1 . .
C18 C19 H19 126.1 . .
Fe2 C19 H19 125.7 . .
C19 C20 C16 108.6(2) . .
C19 C20 Fe2 69.45(13) . .
C16 C20 Fe2 69.73(14) . .
C19 C20 H20 125.7 . .
C16 C20 H20 125.7 . .
Fe2 C20 H20 126.7 . .
C26 C21 C22 118.6(2) . .
C26 C21 P1 122.89(18) . .
C22 C21 P1 118.53(19) . .
C23 C22 C21 120.8(2) . .
C23 C22 H22 119.6 . .
C21 C22 H22 119.6 . .
C22 C23 C24 119.8(2) . .
C22 C23 H23 120.1 . .
C24 C23 H23 120.1 . .
C25 C24 C23 120.2(2) . .
C25 C24 H24 119.9 . .
C23 C24 H24 119.9 . .
C24 C25 C26 120.3(3) . .
C24 C25 H25 119.8 . .
C26 C25 H25 119.8 . .
C21 C26 C25 120.3(2) . .
C21 C26 H26 119.8 . .
C25 C26 H26 119.8 . .
C28 C27 C32 119.3(2) . .
C28 C27 P1 123.17(19) . .
C32 C27 P1 117.46(19) . .
C27 C28 C29 119.8(2) . .
C27 C28 H28 120.1 . .
C29 C28 H28 120.1 . .
C30 C29 C28 120.3(3) . .
C30 C29 H29 119.9 . .
C28 C29 H29 119.9 . .
C29 C30 C31 120.6(2) . .
C29 C30 H30 119.7 . .
C31 C30 H30 119.7 . .
C32 C31 C30 119.2(3) . .
C32 C31 H31 120.4 . .
C30 C31 H31 120.4 . .
C31 C32 C27 120.7(3) . .
C31 C32 H32 119.6 . .
C27 C32 H32 119.6 . .
C9 Fe1 C4 103.74(11) . .
C9 Fe1 C5 119.70(11) . .
C4 Fe1 C5 40.74(11) . .
C9 Fe1 C8 40.78(10) . .
C4 Fe1 C8 120.60(12) . .
C5 Fe1 C8 156.14(11) . .
C9 Fe1 C3 120.59(11) . .
C4 Fe1 C3 40.22(11) . .
C5 Fe1 C3 67.90(11) . .
C8 Fe1 C3 107.57(11) . .
C9 Fe1 C7 68.34(10) . .
C4 Fe1 C7 158.41(12) . .
C5 Fe1 C7 160.66(11) . .
C8 Fe1 C7 40.52(10) . .
C3 Fe1 C7 125.24(11) . .
C9 Fe1 C6 68.53(10) . .
C4 Fe1 C6 157.00(11) . .
C5 Fe1 C6 122.88(11) . .
C8 Fe1 C6 68.48(10) . .
C3 Fe1 C6 162.23(11) . .
C7 Fe1 C6 40.66(10) . .
C9 Fe1 C10 40.96(10) . .
C4 Fe1 C10 119.32(11) . .
C5 Fe1 C10 105.10(10) . .
C8 Fe1 C10 68.87(10) . .
C3 Fe1 C10 155.63(11) . .
C7 Fe1 C10 68.65(10) . .
C6 Fe1 C10 40.83(9) . .
C9 Fe1 C1 156.90(10) . .
C4 Fe1 C1 68.32(12) . .
C5 Fe1 C1 40.36(11) . .
C8 Fe1 C1 161.86(11) . .
C3 Fe1 C1 68.13(11) . .
C7 Fe1 C1 126.50(11) . .
C6 Fe1 C1 109.90(10) . .
C10 Fe1 C1 122.56(10) . .
C9 Fe1 C2 158.38(10) . .
C4 Fe1 C2 68.01(11) . .
C5 Fe1 C2 67.90(11) . .
C8 Fe1 C2 124.86(11) . .
C3 Fe1 C2 40.45(11) . .
C7 Fe1 C2 111.64(10) . .
C6 Fe1 C2 126.57(10) . .
C10 Fe1 C2 160.58(10) . .
C1 Fe1 C2 40.56(10) . .
C19 Fe2 C15 123.77(10) . .
C19 Fe2 C14 107.57(10) . .
C15 Fe2 C14 40.72(9) . .
C19 Fe2 C20 40.75(10) . .
C15 Fe2 C20 105.11(10) . .
C14 Fe2 C20 119.24(10) . .
C19 Fe2 C17 68.99(10) . .
C15 Fe2 C17 153.39(10) . .
C14 Fe2 C17 165.04(10) . .
C20 Fe2 C17 68.32(10) . .
C19 Fe2 C16 68.90(10) . .
C15 Fe2 C16 117.76(10) . .
C14 Fe2 C16 153.30(10) . .
C20 Fe2 C16 40.75(10) . .
C17 Fe2 C16 40.48(10) . .
C19 Fe2 C13 121.83(10) . .
C15 Fe2 C13 68.43(10) . .
C14 Fe2 C13 40.49(9) . .
C20 Fe2 C13 155.38(10) . .
C17 Fe2 C13 127.96(10) . .
C16 Fe2 C13 163.54(10) . .
C19 Fe2 C12 157.57(10) . .
C15 Fe2 C12 68.22(10) . .
C14 Fe2 C12 68.03(10) . .
C20 Fe2 C12 161.07(10) . .
C17 Fe2 C12 109.24(10) . .
C16 Fe2 C12 125.21(10) . .
C13 Fe2 C12 40.53(10) . .
C19 Fe2 C18 41.09(9) . .
C15 Fe2 C18 162.61(9) . .
C14 Fe2 C18 126.95(10) . .
C20 Fe2 C18 68.60(10) . .
C17 Fe2 C18 41.07(9) . .
C16 Fe2 C18 68.77(10) . .
C13 Fe2 C18 110.14(9) . .
C12 Fe2 C18 122.78(10) . .
C19 Fe2 C11 160.34(10) . .
C15 Fe2 C11 40.74(9) . .
C14 Fe2 C11 68.45(10) . .
C20 Fe2 C11 122.98(10) . .
C17 Fe2 C11 119.78(10) . .
C16 Fe2 C11 105.53(10) . .
C13 Fe2 C11 68.50(9) . .
C12 Fe2 C11 40.59(9) . .
C18 Fe2 C11 156.26(10) . .
Cl1 Pd1 Cl1 180.000(1) 2_776 .
Cl1 Pd1 P1 86.59(2) 2_776 2_776
Cl1 Pd1 P1 93.41(2) . 2_776
Cl1 Pd1 P1 93.41(2) 2_776 .
Cl1 Pd1 P1 86.59(2) . .
P1 Pd1 P1 180.0 2_776 .
C18 P1 C21 102.72(11) . .
C18 P1 C27 106.58(11) . .
C21 P1 C27 102.97(11) . .
C18 P1 Pd1 115.70(8) . .
C21 P1 Pd1 117.36(8) . .
C27 P1 Pd1 110.23(8) . .
Cl3 C33 Cl2 113.3(4) . .
Cl3 C33 H33A 108.9 . .
Cl2 C33 H33A 108.9 . .
Cl3 C33 H33B 108.9 . .
Cl2 C33 H33B 108.9 . .
H33A C33 H33B 107.7 . .
Cl4 C34 Cl5 117.1(8) . .
Cl4 C34 H34A 108.0 . .
Cl5 C34 H34A 108.0 . .
Cl4 C34 H34B 108.0 . .
Cl5 C34 H34B 108.0 . .
H34A C34 H34B 107.3 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 C5 1.413(4) .
C1 C2 1.426(4) .
C1 Fe1 2.056(3) .
C1 H1 0.9300 .
C2 C3 1.418(4) .
C2 Fe1 2.058(2) .
C2 H2 0.9300 .
C3 C4 1.402(4) .
C3 Fe1 2.042(2) .
C3 H3 0.9300 .
C4 C5 1.419(4) .
C4 Fe1 2.036(3) .
C4 H4 0.9300 .
C5 Fe1 2.039(3) .
C5 H5 0.9300 .
C6 C7 1.424(3) .
C6 C10 1.431(3) .
C6 Fe1 2.051(2) .
C6 H6 0.9300 .
C7 C8 1.416(4) .
C7 Fe1 2.047(2) .
C7 H7 0.9300 .
C8 C9 1.419(4) .
C8 Fe1 2.042(3) .
C8 H8 0.9300 .
C9 C10 1.428(3) .
C9 Fe1 2.030(2) .
C9 H9 0.9300 .
C10 C11 1.463(3) .
C10 Fe1 2.051(2) .
C11 C12 1.427(3) .
C11 C15 1.430(3) .
C11 Fe2 2.063(2) .
C12 C13 1.421(3) .
C12 Fe2 2.052(2) .
C12 H12 0.9300 .
C13 C14 1.417(3) .
C13 Fe2 2.051(2) .
C13 H13 0.9300 .
C14 C15 1.423(3) .
C14 Fe2 2.045(2) .
C14 H14 0.9300 .
C15 Fe2 2.045(2) .
C15 H15 0.9300 .
C16 C17 1.418(3) .
C16 C20 1.426(4) .
C16 Fe2 2.049(2) .
C16 H16 0.9300 .
C17 C18 1.440(3) .
C17 Fe2 2.048(2) .
C17 H17 0.9300 .
C18 C19 1.438(3) .
C18 P1 1.800(2) .
C18 Fe2 2.056(2) .
C19 C20 1.423(3) .
C19 Fe2 2.042(2) .
C19 H19 0.9300 .
C20 Fe2 2.046(2) .
C20 H20 0.9300 .
C21 C26 1.391(4) .
C21 C22 1.397(3) .
C21 P1 1.819(2) .
C22 C23 1.377(3) .
C22 H22 0.9300 .
C23 C24 1.389(4) .
C23 H23 0.9300 .
C24 C25 1.367(4) .
C24 H24 0.9300 .
C25 C26 1.391(4) .
C25 H25 0.9300 .
C26 H26 0.9300 .
C27 C28 1.387(3) .
C27 C32 1.390(3) .
C27 P1 1.820(2) .
C28 C29 1.392(4) .
C28 H28 0.9300 .
C29 C30 1.368(4) .
C29 H29 0.9300 .
C30 C31 1.387(4) .
C30 H30 0.9300 .
C31 C32 1.383(4) .
C31 H31 0.9300 .
C32 H32 0.9300 .
Cl1 Pd1 2.3035(6) .
Pd1 Cl1 2.3035(6) 2_776
Pd1 P1 2.3366(7) 2_776
Pd1 P1 2.3366(7) .
C33 Cl3 1.663(9) .
C33 Cl2 1.784(9) .
C33 H33A 0.9700 .
C33 H33B 0.9700 .
C34 Cl4 1.572(12) .
C34 Cl5 1.773(10) .
C34 H34A 0.9700 .
C34 H34B 0.9700 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
C5 C1 C2 C3 0.3(3) .
Fe1 C1 C2 C3 -58.89(18) .
C5 C1 C2 Fe1 59.20(16) .
C1 C2 C3 C4 -0.2(3) .
Fe1 C2 C3 C4 -59.40(18) .
C1 C2 C3 Fe1 59.18(17) .
C2 C3 C4 C5 0.0(3) .
Fe1 C3 C4 C5 -59.81(18) .
C2 C3 C4 Fe1 59.86(18) .
C2 C1 C5 C4 -0.3(3) .
Fe1 C1 C5 C4 59.31(18) .
C2 C1 C5 Fe1 -59.59(17) .
C3 C4 C5 C1 0.1(3) .
Fe1 C4 C5 C1 -59.89(17) .
C3 C4 C5 Fe1 60.04(18) .
C10 C6 C7 C8 -0.1(3) .
Fe1 C6 C7 C8 59.02(17) .
C10 C6 C7 Fe1 -59.10(16) .
C6 C7 C8 C9 -0.2(3) .
Fe1 C7 C8 C9 59.02(17) .
C6 C7 C8 Fe1 -59.19(17) .
C7 C8 C9 C10 0.4(3) .
Fe1 C8 C9 C10 59.89(17) .
C7 C8 C9 Fe1 -59.52(17) .
C8 C9 C10 C6 -0.4(3) .
Fe1 C9 C10 C6 59.31(15) .
C8 C9 C10 C11 -175.0(2) .
Fe1 C9 C10 C11 -115.3(2) .
C8 C9 C10 Fe1 -59.72(17) .
C7 C6 C10 C9 0.3(3) .
Fe1 C6 C10 C9 -58.76(16) .
C7 C6 C10 C11 174.8(2) .
Fe1 C6 C10 C11 115.8(2) .
C7 C6 C10 Fe1 59.06(16) .
C9 C10 C11 C12 2.5(4) .
C6 C10 C11 C12 -171.0(2) .
Fe1 C10 C11 C12 -83.3(3) .
C9 C10 C11 C15 -179.6(2) .
C6 C10 C11 C15 6.9(4) .
Fe1 C10 C11 C15 94.6(3) .
C9 C10 C11 Fe2 -87.2(3) .
C6 C10 C11 Fe2 99.2(3) .
Fe1 C10 C11 Fe2 -173.04(12) .
C15 C11 C12 C13 -0.3(3) .
C10 C11 C12 C13 177.9(2) .
Fe2 C11 C12 C13 -59.17(16) .
C15 C11 C12 Fe2 58.84(15) .
C10 C11 C12 Fe2 -122.9(2) .
C11 C12 C13 C14 0.0(3) .
Fe2 C12 C13 C14 -59.42(16) .
C11 C12 C13 Fe2 59.43(15) .
C12 C13 C14 C15 0.3(3) .
Fe2 C13 C14 C15 -59.25(16) .
C12 C13 C14 Fe2 59.58(16) .
C13 C14 C15 C11 -0.5(3) .
Fe2 C14 C15 C11 -60.00(16) .
C13 C14 C15 Fe2 59.47(16) .
C12 C11 C15 C14 0.5(3) .
C10 C11 C15 C14 -177.6(2) .
Fe2 C11 C15 C14 59.59(16) .
C12 C11 C15 Fe2 -59.06(15) .
C10 C11 C15 Fe2 122.8(2) .
C20 C16 C17 C18 0.0(3) .
Fe2 C16 C17 C18 59.25(16) .
C20 C16 C17 Fe2 -59.24(16) .
C16 C17 C18 C19 -0.6(3) .
Fe2 C17 C18 C19 58.62(15) .
C16 C17 C18 P1 178.96(16) .
Fe2 C17 C18 P1 -121.78(18) .
C16 C17 C18 Fe2 -59.26(16) .
C17 C18 C19 C20 1.0(3) .
P1 C18 C19 C20 -178.56(17) .
Fe2 C18 C19 C20 59.81(16) .
C17 C18 C19 Fe2 -58.77(15) .
P1 C18 C19 Fe2 121.63(18) .
C18 C19 C20 C16 -1.1(3) .
Fe2 C19 C20 C16 58.88(16) .
C18 C19 C20 Fe2 -59.94(16) .
C17 C16 C20 C19 0.7(3) .
Fe2 C16 C20 C19 -58.71(16) .
C17 C16 C20 Fe2 59.37(16) .
C26 C21 C22 C23 1.5(4) .
P1 C21 C22 C23 -176.69(19) .
C21 C22 C23 C24 -2.5(4) .
C22 C23 C24 C25 1.9(4) .
C23 C24 C25 C26 -0.3(4) .
C22 C21 C26 C25 0.2(4) .
P1 C21 C26 C25 178.3(2) .
C24 C25 C26 C21 -0.8(4) .
C32 C27 C28 C29 0.1(4) .
P1 C27 C28 C29 177.88(19) .
C27 C28 C29 C30 -0.7(4) .
C28 C29 C30 C31 0.3(4) .
C29 C30 C31 C32 0.8(4) .
C30 C31 C32 C27 -1.4(4) .
C28 C27 C32 C31 0.9(4) .
P1 C27 C32 C31 -177.0(2) .
C8 C9 Fe1 C4 -121.25(16) .
C10 C9 Fe1 C4 119.16(16) .
C8 C9 Fe1 C5 -161.92(15) .
C10 C9 Fe1 C5 78.49(17) .
C10 C9 Fe1 C8 -119.6(2) .
C8 C9 Fe1 C3 -81.47(18) .
C10 C9 Fe1 C3 158.94(15) .
C8 C9 Fe1 C7 37.64(15) .
C10 C9 Fe1 C7 -81.95(15) .
C8 C9 Fe1 C6 81.51(16) .
C10 C9 Fe1 C6 -38.08(14) .
C8 C9 Fe1 C10 119.6(2) .
C8 C9 Fe1 C1 172.1(2) .
C10 C9 Fe1 C1 52.5(3) .
C8 C9 Fe1 C2 -56.7(3) .
C10 C9 Fe1 C2 -176.2(3) .
C3 C4 Fe1 C9 121.47(18) .
C5 C4 Fe1 C9 -119.84(16) .
C3 C4 Fe1 C5 -118.7(2) .
C3 C4 Fe1 C8 81.0(2) .
C5 C4 Fe1 C8 -160.29(15) .
C5 C4 Fe1 C3 118.7(2) .
C3 C4 Fe1 C7 56.0(4) .
C5 C4 Fe1 C7 174.7(3) .
C3 C4 Fe1 C6 -171.4(3) .
C5 C4 Fe1 C6 -52.7(4) .
C3 C4 Fe1 C10 162.51(17) .
C5 C4 Fe1 C10 -78.81(18) .
C3 C4 Fe1 C1 -81.33(19) .
C5 C4 Fe1 C1 37.35(16) .
C3 C4 Fe1 C2 -37.49(18) .
C5 C4 Fe1 C2 81.20(17) .
C1 C5 Fe1 C9 -164.60(14) .
C4 C5 Fe1 C9 75.93(18) .
C1 C5 Fe1 C4 119.5(2) .
C1 C5 Fe1 C8 165.3(2) .
C4 C5 Fe1 C8 45.9(3) .
C1 C5 Fe1 C3 81.78(17) .
C4 C5 Fe1 C3 -37.69(17) .
C1 C5 Fe1 C7 -54.6(4) .
C4 C5 Fe1 C7 -174.1(3) .
C1 C5 Fe1 C6 -82.25(17) .
C4 C5 Fe1 C6 158.28(16) .
C1 C5 Fe1 C10 -122.90(15) .
C4 C5 Fe1 C10 117.63(17) .
C4 C5 Fe1 C1 -119.5(2) .
C1 C5 Fe1 C2 37.96(15) .
C4 C5 Fe1 C2 -81.50(17) .
C7 C8 Fe1 C9 119.1(2) .
C7 C8 Fe1 C4 -166.13(15) .
C9 C8 Fe1 C4 74.75(18) .
C7 C8 Fe1 C5 160.9(2) .
C9 C8 Fe1 C5 41.8(3) .
C7 C8 Fe1 C3 -124.13(16) .
C9 C8 Fe1 C3 116.75(16) .
C9 C8 Fe1 C7 -119.1(2) .
C7 C8 Fe1 C6 37.47(14) .
C9 C8 Fe1 C6 -81.65(15) .
C7 C8 Fe1 C10 81.45(15) .
C9 C8 Fe1 C10 -37.67(14) .
C7 C8 Fe1 C1 -50.9(4) .
C9 C8 Fe1 C1 -170.0(3) .
C7 C8 Fe1 C2 -82.92(17) .
C9 C8 Fe1 C2 157.96(15) .
C4 C3 Fe1 C9 -74.2(2) .
C2 C3 Fe1 C9 166.21(16) .
C2 C3 Fe1 C4 -119.6(3) .
C4 C3 Fe1 C5 38.17(18) .
C2 C3 Fe1 C5 -81.38(18) .
C4 C3 Fe1 C8 -116.89(18) .
C2 C3 Fe1 C8 123.55(17) .
C4 C3 Fe1 C7 -158.07(17) .
C2 C3 Fe1 C7 82.4(2) .
C4 C3 Fe1 C6 168.9(3) .
C2 C3 Fe1 C6 49.4(4) .
C4 C3 Fe1 C10 -39.4(4) .
C2 C3 Fe1 C10 -159.0(2) .
C4 C3 Fe1 C1 81.85(19) .
C2 C3 Fe1 C1 -37.71(16) .
C4 C3 Fe1 C2 119.6(3) .
C8 C7 Fe1 C9 -37.88(14) .
C6 C7 Fe1 C9 81.83(16) .
C8 C7 Fe1 C4 34.1(4) .
C6 C7 Fe1 C4 153.8(3) .
C8 C7 Fe1 C5 -156.4(3) .
C6 C7 Fe1 C5 -36.7(4) .
C6 C7 Fe1 C8 119.7(2) .
C8 C7 Fe1 C3 75.06(19) .
C6 C7 Fe1 C3 -165.23(16) .
C8 C7 Fe1 C6 -119.7(2) .
C8 C7 Fe1 C10 -82.06(15) .
C6 C7 Fe1 C10 37.66(14) .
C8 C7 Fe1 C1 162.51(14) .
C6 C7 Fe1 C1 -77.78(18) .
C8 C7 Fe1 C2 118.83(15) .
C6 C7 Fe1 C2 -121.46(15) .
C7 C6 Fe1 C9 -81.33(16) .
C10 C6 Fe1 C9 38.19(14) .
C7 C6 Fe1 C4 -155.5(3) .
C10 C6 Fe1 C4 -35.9(3) .
C7 C6 Fe1 C5 166.36(15) .
C10 C6 Fe1 C5 -74.12(18) .
C7 C6 Fe1 C8 -37.34(15) .
C10 C6 Fe1 C8 82.17(15) .
C7 C6 Fe1 C3 43.0(4) .
C10 C6 Fe1 C3 162.5(3) .
C10 C6 Fe1 C7 119.5(2) .
C7 C6 Fe1 C10 -119.5(2) .
C7 C6 Fe1 C1 123.33(16) .
C10 C6 Fe1 C1 -117.16(15) .
C7 C6 Fe1 C2 80.86(19) .
C10 C6 Fe1 C2 -159.63(15) .
C6 C10 Fe1 C9 -118.6(2) .
C11 C10 Fe1 C9 119.8(3) .
C9 C10 Fe1 C4 -76.62(18) .
C6 C10 Fe1 C4 164.75(16) .
C11 C10 Fe1 C4 43.1(3) .
C9 C10 Fe1 C5 -118.16(16) .
C6 C10 Fe1 C5 123.21(16) .
C11 C10 Fe1 C5 1.6(2) .
C9 C10 Fe1 C8 37.51(15) .
C6 C10 Fe1 C8 -81.12(16) .
C11 C10 Fe1 C8 157.3(2) .
C9 C10 Fe1 C3 -48.6(3) .
C6 C10 Fe1 C3 -167.2(3) .
C11 C10 Fe1 C3 71.2(4) .
C9 C10 Fe1 C7 81.13(16) .
C6 C10 Fe1 C7 -37.50(15) .
C11 C10 Fe1 C7 -159.1(2) .
C9 C10 Fe1 C6 118.6(2) .
C11 C10 Fe1 C6 -121.6(3) .
C9 C10 Fe1 C1 -158.33(15) .
C6 C10 Fe1 C1 83.03(17) .
C11 C10 Fe1 C1 -38.6(2) .
C9 C10 Fe1 C2 175.8(3) .
C6 C10 Fe1 C2 57.2(4) .
C11 C10 Fe1 C2 -64.4(4) .
C5 C1 Fe1 C9 36.0(3) .
C2 C1 Fe1 C9 154.8(2) .
C5 C1 Fe1 C4 -37.70(16) .
C2 C1 Fe1 C4 81.07(17) .
C2 C1 Fe1 C5 118.8(2) .
C5 C1 Fe1 C8 -160.8(3) .
C2 C1 Fe1 C8 -42.0(4) .
C5 C1 Fe1 C3 -81.16(17) .
C2 C1 Fe1 C3 37.61(16) .
C5 C1 Fe1 C7 160.38(15) .
C2 C1 Fe1 C7 -80.85(18) .
C5 C1 Fe1 C6 117.75(16) .
C2 C1 Fe1 C6 -123.48(15) .
C5 C1 Fe1 C10 74.10(18) .
C2 C1 Fe1 C10 -167.13(15) .
C5 C1 Fe1 C2 -118.8(2) .
C3 C2 Fe1 C9 -33.8(4) .
C1 C2 Fe1 C9 -153.0(3) .
C3 C2 Fe1 C4 37.29(18) .
C1 C2 Fe1 C4 -81.90(17) .
C3 C2 Fe1 C5 81.41(18) .
C1 C2 Fe1 C5 -37.78(16) .
C3 C2 Fe1 C8 -75.5(2) .
C1 C2 Fe1 C8 165.28(15) .
C1 C2 Fe1 C3 -119.2(2) .
C3 C2 Fe1 C7 -119.44(17) .
C1 C2 Fe1 C7 121.37(16) .
C3 C2 Fe1 C6 -163.23(16) .
C1 C2 Fe1 C6 77.57(19) .
C3 C2 Fe1 C10 153.6(3) .
C1 C2 Fe1 C10 34.4(4) .
C3 C2 Fe1 C1 119.2(2) .
C20 C19 Fe2 C15 72.80(18) .
C18 C19 Fe2 C15 -168.48(14) .
C20 C19 Fe2 C14 114.68(16) .
C18 C19 Fe2 C14 -126.60(15) .
C18 C19 Fe2 C20 118.7(2) .
C20 C19 Fe2 C17 -80.76(17) .
C18 C19 Fe2 C17 37.96(14) .
C20 C19 Fe2 C16 -37.24(15) .
C18 C19 Fe2 C16 81.48(16) .
C20 C19 Fe2 C13 156.74(15) .
C18 C19 Fe2 C13 -84.53(17) .
C20 C19 Fe2 C12 -170.5(2) .
C18 C19 Fe2 C12 -51.7(3) .
C20 C19 Fe2 C18 -118.7(2) .
C20 C19 Fe2 C11 39.7(4) .
C18 C19 Fe2 C11 158.4(3) .
C14 C15 Fe2 C19 77.29(17) .
C11 C15 Fe2 C19 -163.63(14) .
C11 C15 Fe2 C14 119.1(2) .
C14 C15 Fe2 C20 117.52(15) .
C11 C15 Fe2 C20 -123.40(15) .
C14 C15 Fe2 C17 -170.87(19) .
C11 C15 Fe2 C17 -51.8(3) .
C14 C15 Fe2 C16 159.39(14) .
C11 C15 Fe2 C16 -81.52(16) .
C14 C15 Fe2 C13 -37.41(14) .
C11 C15 Fe2 C13 81.67(15) .
C14 C15 Fe2 C12 -81.18(15) .
C11 C15 Fe2 C12 37.90(14) .
C14 C15 Fe2 C18 51.2(4) .
C11 C15 Fe2 C18 170.3(3) .
C14 C15 Fe2 C11 -119.1(2) .
C13 C14 Fe2 C19 118.75(14) .
C15 C14 Fe2 C19 -121.72(14) .
C13 C14 Fe2 C15 -119.53(19) .
C13 C14 Fe2 C20 161.58(13) .
C15 C14 Fe2 C20 -78.90(16) .
C13 C14 Fe2 C17 44.5(4) .
C15 C14 Fe2 C17 164.0(3) .
C13 C14 Fe2 C16 -163.41(19) .
C15 C14 Fe2 C16 -43.9(3) .
C15 C14 Fe2 C13 119.53(19) .
C13 C14 Fe2 C12 -37.85(14) .
C15 C14 Fe2 C12 81.68(14) .
C13 C14 Fe2 C18 77.43(16) .
C15 C14 Fe2 C18 -163.04(13) .
C13 C14 Fe2 C11 -81.71(14) .
C15 C14 Fe2 C11 37.82(14) .
C16 C20 Fe2 C19 -120.1(2) .
C19 C20 Fe2 C15 -124.66(15) .
C16 C20 Fe2 C15 115.20(14) .
C19 C20 Fe2 C14 -83.13(17) .
C16 C20 Fe2 C14 156.74(14) .
C19 C20 Fe2 C17 82.55(16) .
C16 C20 Fe2 C17 -37.58(14) .
C19 C20 Fe2 C16 120.1(2) .
C19 C20 Fe2 C13 -53.6(3) .
C16 C20 Fe2 C13 -173.8(2) .
C19 C20 Fe2 C12 168.8(3) .
C16 C20 Fe2 C12 48.6(4) .
C19 C20 Fe2 C18 38.24(15) .
C16 C20 Fe2 C18 -81.89(15) .
C19 C20 Fe2 C11 -165.17(15) .
C16 C20 Fe2 C11 74.70(17) .
C16 C17 Fe2 C19 81.72(15) .
C18 C17 Fe2 C19 -37.98(13) .
C16 C17 Fe2 C15 -42.5(3) .
C18 C17 Fe2 C15 -162.23(19) .
C16 C17 Fe2 C14 161.1(3) .
C18 C17 Fe2 C14 41.4(4) .
C16 C17 Fe2 C20 37.82(14) .
C18 C17 Fe2 C20 -81.87(14) .
C18 C17 Fe2 C16 -119.69(19) .
C16 C17 Fe2 C13 -163.64(14) .
C18 C17 Fe2 C13 76.66(16) .
C16 C17 Fe2 C12 -122.12(14) .
C18 C17 Fe2 C12 118.18(14) .
C16 C17 Fe2 C18 119.69(19) .
C16 C17 Fe2 C11 -78.75(16) .
C18 C17 Fe2 C11 161.56(13) .
C17 C16 Fe2 C19 -81.96(15) .
C20 C16 Fe2 C19 37.24(14) .
C17 C16 Fe2 C15 159.99(13) .
C20 C16 Fe2 C15 -80.81(16) .
C17 C16 Fe2 C14 -169.28(19) .
C20 C16 Fe2 C14 -50.1(3) .
C17 C16 Fe2 C20 -119.2(2) .
C20 C16 Fe2 C17 119.2(2) .
C17 C16 Fe2 C13 51.6(4) .
C20 C16 Fe2 C13 170.8(3) .
C17 C16 Fe2 C12 78.14(16) .
C20 C16 Fe2 C12 -162.66(14) .
C17 C16 Fe2 C18 -37.76(13) .
C20 C16 Fe2 C18 81.44(15) .
C17 C16 Fe2 C11 117.92(14) .
C20 C16 Fe2 C11 -122.88(14) .
C14 C13 Fe2 C19 -79.65(16) .
C12 C13 Fe2 C19 161.46(14) .
C14 C13 Fe2 C15 37.62(13) .
C12 C13 Fe2 C15 -81.28(15) .
C12 C13 Fe2 C14 -118.9(2) .
C14 C13 Fe2 C20 -41.4(3) .
C12 C13 Fe2 C20 -160.3(2) .
C14 C13 Fe2 C17 -166.74(13) .
C12 C13 Fe2 C17 74.37(17) .
C14 C13 Fe2 C16 153.1(3) .
C12 C13 Fe2 C16 34.2(4) .
C14 C13 Fe2 C12 118.9(2) .
C14 C13 Fe2 C18 -123.82(14) .
C12 C13 Fe2 C18 117.28(15) .
C14 C13 Fe2 C11 81.57(15) .
C12 C13 Fe2 C11 -37.33(14) .
C13 C12 Fe2 C19 -45.1(3) .
C11 C12 Fe2 C19 -165.0(2) .
C13 C12 Fe2 C15 81.84(16) .
C11 C12 Fe2 C15 -38.04(14) .
C13 C12 Fe2 C14 37.80(14) .
C11 C12 Fe2 C14 -82.08(15) .
C13 C12 Fe2 C20 154.4(3) .
C11 C12 Fe2 C20 34.5(4) .
C13 C12 Fe2 C17 -126.47(15) .
C11 C12 Fe2 C17 113.65(15) .
C13 C12 Fe2 C16 -168.77(14) .
C11 C12 Fe2 C16 71.35(18) .
C11 C12 Fe2 C13 -119.9(2) .
C13 C12 Fe2 C18 -82.94(17) .
C11 C12 Fe2 C18 157.18(14) .
C13 C12 Fe2 C11 119.9(2) .
C17 C18 Fe2 C19 119.1(2) .
P1 C18 Fe2 C19 -121.1(2) .
C19 C18 Fe2 C15 33.7(4) .
C17 C18 Fe2 C15 152.8(3) .
P1 C18 Fe2 C15 -87.3(3) .
C19 C18 Fe2 C14 73.27(17) .
C17 C18 Fe2 C14 -167.66(14) .
P1 C18 Fe2 C14 -47.8(2) .
C19 C18 Fe2 C20 -37.94(15) .
C17 C18 Fe2 C20 81.13(15) .
P1 C18 Fe2 C20 -159.01(19) .
C19 C18 Fe2 C17 -119.1(2) .
P1 C18 Fe2 C17 119.9(2) .
C19 C18 Fe2 C16 -81.83(16) .
C17 C18 Fe2 C16 37.23(14) .
P1 C18 Fe2 C16 157.10(19) .
C19 C18 Fe2 C13 115.73(15) .
C17 C18 Fe2 C13 -125.21(14) .
P1 C18 Fe2 C13 -5.34(19) .
C19 C18 Fe2 C12 159.12(14) .
C17 C18 Fe2 C12 -81.81(16) .
P1 C18 Fe2 C12 38.0(2) .
C19 C18 Fe2 C11 -162.1(2) .
C17 C18 Fe2 C11 -43.0(3) .
P1 C18 Fe2 C11 76.9(3) .
C12 C11 Fe2 C19 162.9(3) .
C15 C11 Fe2 C19 44.1(4) .
C10 C11 Fe2 C19 -78.9(4) .
C12 C11 Fe2 C15 118.8(2) .
C10 C11 Fe2 C15 -123.0(3) .
C12 C11 Fe2 C14 80.95(15) .
C15 C11 Fe2 C14 -37.81(14) .
C10 C11 Fe2 C14 -160.8(3) .
C12 C11 Fe2 C20 -167.34(15) .
C15 C11 Fe2 C20 73.90(17) .
C10 C11 Fe2 C20 -49.1(3) .
C12 C11 Fe2 C17 -85.16(16) .
C15 C11 Fe2 C17 156.08(14) .
C10 C11 Fe2 C17 33.1(3) .
C12 C11 Fe2 C16 -126.53(15) .
C15 C11 Fe2 C16 114.71(15) .
C10 C11 Fe2 C16 -8.3(2) .
C12 C11 Fe2 C13 37.27(15) .
C15 C11 Fe2 C13 -81.48(15) .
C10 C11 Fe2 C13 155.5(2) .
C15 C11 Fe2 C12 -118.8(2) .
C10 C11 Fe2 C12 118.2(3) .
C12 C11 Fe2 C18 -54.1(3) .
C15 C11 Fe2 C18 -172.8(2) .
C10 C11 Fe2 C18 64.2(3) .
C19 C18 P1 C21 -172.4(2) .
C17 C18 P1 C21 8.0(2) .
Fe2 C18 P1 C21 -81.97(17) .
C19 C18 P1 C27 79.7(2) .
C17 C18 P1 C27 -99.9(2) .
Fe2 C18 P1 C27 170.13(14) .
C19 C18 P1 Pd1 -43.3(2) .
C17 C18 P1 Pd1 137.19(18) .
Fe2 C18 P1 Pd1 47.20(17) .
C26 C21 P1 C18 -114.3(2) .
C22 C21 P1 C18 63.8(2) .
C26 C21 P1 C27 -3.6(2) .
C22 C21 P1 C27 174.43(19) .
C26 C21 P1 Pd1 117.6(2) .
C22 C21 P1 Pd1 -64.3(2) .
C28 C27 P1 C18 4.5(2) .
C32 C27 P1 C18 -177.69(19) .
C28 C27 P1 C21 -103.2(2) .
C32 C27 P1 C21 74.6(2) .
C28 C27 P1 Pd1 130.80(19) .
C32 C27 P1 Pd1 -51.4(2) .
Cl1 Pd1 P1 C18 -115.04(8) 2_776
Cl1 Pd1 P1 C18 64.96(8) .
P1 Pd1 P1 C18 91(100) 2_776
Cl1 Pd1 P1 C21 6.58(9) 2_776
Cl1 Pd1 P1 C21 -173.42(9) .
P1 Pd1 P1 C21 -147(100) 2_776
Cl1 Pd1 P1 C27 123.97(9) 2_776
Cl1 Pd1 P1 C27 -56.03(9) .
P1 Pd1 P1 C27 -30(100) 2_776
