#------------------------------------------------------------------------------
#$Date: 2016-03-21 10:35:27 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178658 $
#$URL: svn://www.crystallography.net/cod/cif/4/07/69/4076957.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4076957
loop_
_publ_author_name
'Rickard, Clifton E. F.'
'Roper, Warren R.'
'Williamson, Alex'
'Wright, L. James'
_publ_section_title
;
 Tethered Boryl and Base-Stabilized Borylene Osmium Complexes from the
 Reaction of Os(BCl2)Cl(CO)(PPh3)2with 2-Aminopyridine
;
_journal_issue                   22
_journal_name_full               Organometallics
_journal_page_first              4862
_journal_paper_doi               10.1021/om0203431
_journal_volume                  21
_journal_year                    2002
_chemical_formula_moiety         'C50 H51 B F6 N3 O4 Os P2, Sb F6, 2(C3 H6 O)'
_chemical_formula_sum            'C50 H51 B F6 N3 O4 Os P2 Sb'
_chemical_formula_weight         1256.64
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                80.7150(10)
_cell_angle_beta                 77.6790(10)
_cell_angle_gamma                80.4900(10)
_cell_formula_units_Z            2
_cell_length_a                   12.62920(10)
_cell_length_b                   13.77400(10)
_cell_length_c                   15.40200(10)
_cell_measurement_reflns_used    8192
_cell_measurement_temperature    203(2)
_cell_measurement_theta_max      26
_cell_measurement_theta_min      2
_cell_volume                     2559.37(3)
_computing_cell_refinement       'Siemens SMART'
_computing_data_collection       'Siemens SMART (Siemens, 1995)'
_computing_data_reduction        'Siemens SAINT  (Siemens, 1995)'
_computing_molecular_graphics    'Siemens SHELXTL (Siemens, 1994)'
_computing_publication_material  SHELXL-97
_computing_structure_refinement  'SHELXL-97 Sheldrick, (1997)'
_computing_structure_solution    'SHELXS Sheldrick, (1990)'
_diffrn_ambient_temperature      203(2)
_diffrn_measured_fraction_theta_full 0.941
_diffrn_measured_fraction_theta_max 0.941
_diffrn_measurement_device_type  'Siemens SMART'
_diffrn_measurement_method       'Area detector ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0300
_diffrn_reflns_av_sigmaI/netI    0.0387
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            24966
_diffrn_reflns_theta_full        27.40
_diffrn_reflns_theta_max         27.40
_diffrn_reflns_theta_min         1.36
_diffrn_standards_decay_%        '< 2'
_exptl_absorpt_coefficient_mu    3.138
_exptl_absorpt_correction_T_max  0.5726
_exptl_absorpt_correction_T_min  0.3390
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Blessing, 1995'
_exptl_crystal_colour            Colourless
_exptl_crystal_density_diffrn    1.631
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Prism
_exptl_crystal_F_000             1240
_exptl_crystal_size_max          0.44
_exptl_crystal_size_mid          0.26
_exptl_crystal_size_min          0.20
_refine_diff_density_max         1.690
_refine_diff_density_min         -2.044
_refine_diff_density_rms         0.120
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.914
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     620
_refine_ls_number_reflns         10944
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.914
_refine_ls_R_factor_all          0.0362
_refine_ls_R_factor_gt           0.0315
_refine_ls_shift/su_max          0.368
_refine_ls_shift/su_mean         0.003
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0568P)²+4.3167P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0819
_refine_ls_wR_factor_ref         0.0865
_reflns_number_gt                9993
_reflns_number_total             10944
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om0203431.cif
_cod_data_source_block           '[6]'
_cod_depositor_comments
;
The following automatic conversions were performed:
'_atom_site_symetry_multiplicity' tag replaced with
'_atom_site_symmetry_multiplicity'.

Automatic conversion script
Id: cif_correct_tags 1440 2010-10-19 06:21:57Z saulius 

The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'Multi-scan'
changed to 'multi-scan' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_cell_volume        2559.44(3)
_cod_database_code               4076957
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Os Os 0.509968(10) 0.899829(9) 0.744746(8) 0.02249(5) Uani 1 1 d .
P1 P 0.31746(7) 0.90042(7) 0.79911(6) 0.02628(18) Uani 1 1 d .
P2 P 0.70434(7) 0.89401(6) 0.70444(6) 0.02441(17) Uani 1 1 d .
B B 0.5129(3) 0.9694(3) 0.8561(3) 0.0277(8) Uani 1 1 d .
O1 O 0.4809(3) 1.0816(2) 0.6079(2) 0.0441(7) Uani 1 1 d .
O2 O 0.5002(3) 1.0642(2) 0.87755(19) 0.0353(6) Uani 1 1 d .
H2A H 0.495(4) 1.105(4) 0.840(4) 0.042 Uiso 1 1 d .
N1 N 0.5355(2) 0.7733(2) 0.84508(19) 0.0244(6) Uani 1 1 d .
N2 N 0.5309(3) 0.8947(2) 0.9326(2) 0.0297(6) Uani 1 1 d .
H2B H 0.528(4) 0.909(3) 0.983(3) 0.036 Uiso 1 1 d .
N3 N 0.5088(3) 0.7961(2) 0.6522(2) 0.0325(7) Uani 1 1 d .
C1 C 0.4904(3) 1.0141(3) 0.6616(2) 0.0277(7) Uani 1 1 d .
C2 C 0.5023(4) 0.7492(3) 0.5995(3) 0.0414(9) Uani 1 1 d .
C3 C 0.4920(6) 0.6911(4) 0.5310(4) 0.0680(16) Uani 1 1 d .
H3A H 0.4253 0.7171 0.5086 0.102 Uiso 1 1 calc R
H3B H 0.4894 0.6223 0.5568 0.102 Uiso 1 1 calc R
H3C H 0.5544 0.6953 0.4820 0.102 Uiso 1 1 calc R
C4 C 0.5428(3) 0.7957(3) 0.9258(2) 0.0279(7) Uani 1 1 d .
C5 C 0.5601(3) 0.7208(3) 0.9975(3) 0.0355(8) Uani 1 1 d .
H5A H 0.5637 0.7375 1.0535 0.043 Uiso 1 1 calc R
C6 C 0.5716(4) 0.6227(3) 0.9840(3) 0.0412(9) Uani 1 1 d .
H6A H 0.5841 0.5717 1.0306 0.049 Uiso 1 1 calc R
C7 C 0.5645(4) 0.5997(3) 0.9003(3) 0.0382(9) Uani 1 1 d .
H7A H 0.5723 0.5332 0.8901 0.046 Uiso 1 1 calc R
C8 C 0.5463(3) 0.6750(3) 0.8338(3) 0.0322(8) Uani 1 1 d .
H8A H 0.5408 0.6590 0.7780 0.039 Uiso 1 1 calc R
C11 C 0.2861(3) 0.8252(3) 0.9085(3) 0.0338(8) Uani 1 1 d .
C12 C 0.2737(4) 0.8707(4) 0.9862(3) 0.0479(10) Uani 1 1 d .
H12A H 0.2755 0.9394 0.9812 0.057 Uiso 1 1 calc R
C13 C 0.2587(4) 0.8142(5) 1.0704(3) 0.0619(15) Uani 1 1 d .
H13A H 0.2521 0.8447 1.1221 0.074 Uiso 1 1 calc R
C14 C 0.2536(5) 0.7142(5) 1.0783(4) 0.0686(17) Uani 1 1 d .
H14A H 0.2405 0.6771 1.1355 0.082 Uiso 1 1 calc R
C15 C 0.2677(5) 0.6679(5) 1.0026(4) 0.0663(16) Uani 1 1 d .
H15A H 0.2654 0.5992 1.0083 0.080 Uiso 1 1 calc R
C16 C 0.2852(4) 0.7231(4) 0.9174(3) 0.0475(10) Uani 1 1 d .
H16A H 0.2965 0.6912 0.8660 0.057 Uiso 1 1 calc R
C21 C 0.2454(3) 0.8554(3) 0.7245(3) 0.0326(8) Uani 1 1 d .
C22 C 0.2703(4) 0.8898(4) 0.6337(3) 0.0454(10) Uani 1 1 d .
H22A H 0.3264 0.9297 0.6120 0.055 Uiso 1 1 calc R
C23 C 0.2119(4) 0.8652(4) 0.5744(3) 0.0532(12) Uani 1 1 d .
H23A H 0.2284 0.8894 0.5131 0.064 Uiso 1 1 calc R
C24 C 0.1321(5) 0.8070(4) 0.6049(4) 0.0609(14) Uani 1 1 d .
H24A H 0.0972 0.7868 0.5640 0.073 Uiso 1 1 calc R
C25 C 0.1010(4) 0.7767(4) 0.6961(4) 0.0604(14) Uani 1 1 d .
H25A H 0.0421 0.7399 0.7173 0.072 Uiso 1 1 calc R
C26 C 0.1581(4) 0.8014(4) 0.7562(3) 0.0493(11) Uani 1 1 d .
H26A H 0.1373 0.7815 0.8181 0.059 Uiso 1 1 calc R
C31 C 0.2260(3) 1.0171(3) 0.8187(3) 0.0349(8) Uani 1 1 d .
C32 C 0.1161(4) 1.0109(4) 0.8557(4) 0.0533(12) Uani 1 1 d .
H32A H 0.0921 0.9483 0.8720 0.064 Uiso 1 1 calc R
C33 C 0.0414(4) 1.0963(4) 0.8689(4) 0.0618(14) Uani 1 1 d .
H33A H -0.0322 1.0910 0.8949 0.074 Uiso 1 1 calc R
C34 C 0.0759(4) 1.1894(4) 0.8436(4) 0.0547(12) Uani 1 1 d .
H34A H 0.0255 1.2473 0.8510 0.066 Uiso 1 1 calc R
C35 C 0.1846(4) 1.1959(3) 0.8078(3) 0.0492(11) Uani 1 1 d .
H35A H 0.2083 1.2587 0.7916 0.059 Uiso 1 1 calc R
C36 C 0.2603(3) 1.1106(3) 0.7950(3) 0.0379(9) Uani 1 1 d .
H36A H 0.3342 1.1164 0.7705 0.045 Uiso 1 1 calc R
C41 C 0.7761(3) 0.8304(3) 0.7940(2) 0.0302(7) Uani 1 1 d .
C42 C 0.7913(3) 0.7269(3) 0.8145(3) 0.0358(8) Uani 1 1 d .
H42A H 0.7690 0.6876 0.7789 0.043 Uiso 1 1 calc R
C43 C 0.8391(4) 0.6815(4) 0.8870(3) 0.0498(11) Uani 1 1 d .
H43A H 0.8496 0.6119 0.8995 0.060 Uiso 1 1 calc R
C44 C 0.8712(5) 0.7377(4) 0.9404(3) 0.0582(13) Uani 1 1 d .
H44A H 0.9041 0.7066 0.9889 0.070 Uiso 1 1 calc R
C45 C 0.8548(5) 0.8407(4) 0.9224(3) 0.0584(13) Uani 1 1 d .
H45A H 0.8755 0.8791 0.9596 0.070 Uiso 1 1 calc R
C46 C 0.8078(4) 0.8878(4) 0.8496(3) 0.0437(10) Uani 1 1 d .
H46A H 0.7974 0.9574 0.8378 0.052 Uiso 1 1 calc R
C51 C 0.7667(3) 0.8325(3) 0.6038(2) 0.0287(7) Uani 1 1 d .
C52 C 0.8574(3) 0.7585(3) 0.5984(3) 0.0371(8) Uani 1 1 d .
H52A H 0.8907 0.7367 0.6485 0.044 Uiso 1 1 calc R
C53 C 0.8986(3) 0.7169(3) 0.5191(3) 0.0431(10) Uani 1 1 d .
H53A H 0.9592 0.6669 0.5164 0.052 Uiso 1 1 calc R
C54 C 0.8514(4) 0.7484(4) 0.4448(3) 0.0448(10) Uani 1 1 d .
H54A H 0.8791 0.7197 0.3917 0.054 Uiso 1 1 calc R
C55 C 0.7631(4) 0.8223(4) 0.4490(3) 0.0463(10) Uani 1 1 d .
H55A H 0.7313 0.8447 0.3982 0.056 Uiso 1 1 calc R
C56 C 0.7204(3) 0.8642(3) 0.5281(3) 0.0386(9) Uani 1 1 d .
H56A H 0.6599 0.9143 0.5301 0.046 Uiso 1 1 calc R
C61 C 0.7647(3) 1.0105(3) 0.6755(2) 0.0291(7) Uani 1 1 d .
C62 C 0.8785(3) 1.0035(3) 0.6441(3) 0.0420(9) Uani 1 1 d .
H62A H 0.9197 0.9417 0.6337 0.050 Uiso 1 1 calc R
C63 C 0.9299(4) 1.0882(4) 0.6284(4) 0.0499(11) Uani 1 1 d .
H63A H 1.0058 1.0833 0.6070 0.060 Uiso 1 1 calc R
C64 C 0.8703(4) 1.1799(3) 0.6440(3) 0.0464(10) Uani 1 1 d .
H64A H 0.9058 1.2366 0.6344 0.056 Uiso 1 1 calc R
C65 C 0.7586(4) 1.1872(3) 0.6737(3) 0.0440(10) Uani 1 1 d .
H65A H 0.7179 1.2494 0.6833 0.053 Uiso 1 1 calc R
C66 C 0.7054(3) 1.1027(3) 0.6896(3) 0.0345(8) Uani 1 1 d .
H66A H 0.6292 1.1085 0.7100 0.041 Uiso 1 1 calc R
Sb Sb 0.44227(3) 0.38961(2) 0.728114(19) 0.04421(8) Uani 1 1 d .
F1 F 0.5454(3) 0.3986(3) 0.7967(2) 0.0787(11) Uani 1 1 d .
F2 F 0.3318(3) 0.3862(3) 0.8309(2) 0.0714(9) Uani 1 1 d .
F3 F 0.4717(3) 0.2503(2) 0.7508(3) 0.0743(10) Uani 1 1 d .
F4 F 0.4146(5) 0.5281(3) 0.7086(3) 0.1205(18) Uani 1 1 d .
F5 F 0.5529(3) 0.3898(3) 0.6261(2) 0.0782(11) Uani 1 1 d .
F6 F 0.3413(3) 0.3779(4) 0.6597(2) 0.0921(13) Uani 1 1 d .
O3 O -0.0141(5) 0.4285(4) 0.8871(4) 0.115(2) Uani 1 1 d .
C70 C 0.1130(6) 0.5356(5) 0.8818(5) 0.086(2) Uani 1 1 d .
H70A H 0.0918 0.5241 0.9465 0.129 Uiso 1 1 calc R
H70B H 0.0975 0.6059 0.8612 0.129 Uiso 1 1 calc R
H70C H 0.1906 0.5137 0.8643 0.129 Uiso 1 1 calc R
C71 C 0.0509(5) 0.4797(4) 0.8413(5) 0.0669(15) Uani 1 1 d .
C72 C 0.0705(7) 0.4872(6) 0.7421(5) 0.099(2) Uani 1 1 d .
H72A H 0.0237 0.4474 0.7248 0.149 Uiso 1 1 calc R
H72B H 0.1465 0.4631 0.7196 0.149 Uiso 1 1 calc R
H72C H 0.0540 0.5559 0.7170 0.149 Uiso 1 1 calc R
O4 O 0.9095(6) 0.4299(5) 0.6018(5) 0.126(2) Uani 1 1 d .
C80 C 0.7854(7) 0.4718(6) 0.5076(5) 0.097(2) Uani 1 1 d .
H80A H 0.8421 0.4345 0.4680 0.145 Uiso 1 1 calc R
H80B H 0.7719 0.5398 0.4794 0.145 Uiso 1 1 calc R
H80C H 0.7187 0.4417 0.5192 0.145 Uiso 1 1 calc R
C81 C 0.8207(5) 0.4710(4) 0.5920(5) 0.0692(16) Uani 1 1 d .
C82 C 0.7471(7) 0.5234(6) 0.6635(6) 0.119(4) Uani 1 1 d .
H82A H 0.7822 0.5164 0.7148 0.178 Uiso 1 1 calc R
H82B H 0.6792 0.4948 0.6814 0.178 Uiso 1 1 calc R
H82C H 0.7316 0.5932 0.6413 0.178 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Os Os -1.2165 7.6030 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
C1 Os B 98.57(16)
C1 Os N1 176.78(13)
B Os N1 78.37(14)
C1 Os N3 94.93(14)
B Os N3 166.45(15)
N1 Os N3 88.15(12)
C1 Os P2 90.96(11)
B Os P2 88.71(11)
N1 Os P2 87.98(7)
N3 Os P2 92.20(8)
C1 Os P1 93.31(11)
B Os P1 87.54(11)
N1 Os P1 87.58(7)
N3 Os P1 90.58(9)
P2 Os P1 174.69(3)
C11 P1 C21 106.24(18)
C11 P1 C31 101.27(19)
C21 P1 C31 98.81(18)
C11 P1 Os 112.75(12)
C21 P1 Os 114.65(13)
C31 P1 Os 121.07(13)
C41 P2 C61 100.95(17)
C41 P2 C51 106.41(17)
C61 P2 C51 100.74(16)
C41 P2 Os 113.40(12)
C61 P2 Os 119.57(12)
C51 P2 Os 113.97(11)
O2 B N2 111.7(3)
O2 B Os 138.1(3)
N2 B Os 110.2(2)
C4 N1 C8 118.3(3)
C4 N1 Os 115.2(2)
C8 N1 Os 126.5(2)
C4 N2 B 121.0(3)
C2 N3 Os 173.4(4)
O1 C1 Os 177.0(3)
N3 C2 C3 178.5(5)
N1 C4 N2 115.3(3)
N1 C4 C5 121.5(3)
N2 C4 C5 123.2(3)
C6 C5 C4 118.8(4)
C5 C6 C7 119.5(4)
C8 C7 C6 119.1(4)
C7 C8 N1 122.6(4)
C16 C11 C12 118.9(4)
C16 C11 P1 122.3(3)
C12 C11 P1 118.4(3)
C13 C12 C11 120.1(5)
C14 C13 C12 120.3(5)
C13 C14 C15 120.3(5)
C14 C15 C16 120.1(5)
C11 C16 C15 120.2(5)
C22 C21 C26 119.1(4)
C22 C21 P1 117.3(3)
C26 C21 P1 123.0(3)
C21 C22 C23 120.2(4)
C24 C23 C22 120.3(5)
C23 C24 C25 120.7(4)
C24 C25 C26 119.5(4)
C21 C26 C25 120.1(5)
C36 C31 C32 118.7(4)
C36 C31 P1 123.4(3)
C32 C31 P1 117.8(3)
C33 C32 C31 121.0(5)
C34 C33 C32 119.9(5)
C35 C34 C33 119.3(4)
C34 C35 C36 121.1(5)
C31 C36 C35 119.9(4)
C42 C41 C46 118.5(4)
C42 C41 P2 122.3(3)
C46 C41 P2 118.9(3)
C43 C42 C41 120.7(4)
C44 C43 C42 120.6(4)
C43 C44 C45 119.6(4)
C44 C45 C46 120.7(5)
C45 C46 C41 119.8(4)
C56 C51 C52 118.4(3)
C56 C51 P2 116.9(3)
C52 C51 P2 124.7(3)
C53 C52 C51 120.3(4)
C54 C53 C52 120.7(4)
C55 C54 C53 119.4(4)
C54 C55 C56 120.6(4)
C51 C56 C55 120.6(4)
C66 C61 C62 119.1(3)
C66 C61 P2 123.3(3)
C62 C61 P2 117.4(3)
C63 C62 C61 119.9(4)
C64 C63 C62 120.7(4)
C65 C64 C63 119.5(4)
C64 C65 C66 120.6(4)
C61 C66 C65 120.2(4)
F6 Sb F5 90.20(16)
F6 Sb F4 91.6(2)
F5 Sb F4 90.4(2)
F6 Sb F2 89.74(16)
F5 Sb F2 178.66(18)
F4 Sb F2 90.9(2)
F6 Sb F1 178.7(2)
F5 Sb F1 89.38(15)
F4 Sb F1 89.6(2)
F2 Sb F1 90.65(15)
F6 Sb F3 90.0(2)
F5 Sb F3 90.19(18)
F4 Sb F3 178.3(2)
F2 Sb F3 88.47(17)
F1 Sb F3 88.84(18)
O3 C71 C70 121.3(7)
O3 C71 C72 120.4(7)
C70 C71 C72 118.4(6)
O4 C81 C80 119.7(7)
O4 C81 C82 120.9(8)
C80 C81 C82 119.4(7)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
Os C1 1.880(4)
Os B 2.105(4)
Os N1 2.165(3)
Os N3 2.179(3)
Os P2 2.3913(9)
Os P1 2.3956(9)
P1 C11 1.833(4)
P1 C21 1.842(4)
P1 C31 1.844(4)
P2 C41 1.836(4)
P2 C61 1.840(4)
P2 C51 1.850(4)
B O2 1.374(5)
B N2 1.464(5)
O1 C1 1.149(5)
N1 C4 1.354(4)
N1 C8 1.373(5)
N2 C4 1.366(5)
N3 C2 1.139(5)
C2 C3 1.462(6)
C4 C5 1.411(5)
C5 C6 1.380(6)
C6 C7 1.401(6)
C7 C8 1.362(6)
C11 C16 1.392(6)
C11 C12 1.406(6)
C12 C13 1.394(7)
C13 C14 1.375(9)
C14 C15 1.384(9)
C15 C16 1.399(7)
C21 C22 1.388(6)
C21 C26 1.391(6)
C22 C23 1.401(6)
C23 C24 1.351(7)
C24 C25 1.390(8)
C25 C26 1.400(7)
C31 C36 1.395(6)
C31 C32 1.395(6)
C32 C33 1.394(7)
C33 C34 1.392(8)
C34 C35 1.378(7)
C35 C36 1.398(6)
C41 C42 1.400(5)
C41 C46 1.410(5)
C42 C43 1.393(6)
C43 C44 1.375(8)
C44 C45 1.392(8)
C45 C46 1.396(7)
C51 C56 1.392(6)
C51 C52 1.399(5)
C52 C53 1.395(6)
C53 C54 1.379(7)
C54 C55 1.378(7)
C55 C56 1.396(6)
C61 C66 1.388(5)
C61 C62 1.408(5)
C62 C63 1.390(6)
C63 C64 1.387(7)
C64 C65 1.379(6)
C65 C66 1.400(5)
Sb F6 1.859(3)
Sb F5 1.867(3)
Sb F4 1.868(4)
Sb F2 1.873(3)
Sb F1 1.874(3)
Sb F3 1.883(3)
O3 C71 1.205(8)
C70 C71 1.469(9)
C71 C72 1.485(10)
O4 C81 1.199(8)
C80 C81 1.460(10)
C81 C82 1.482(9)
