#------------------------------------------------------------------------------
#$Date: 2016-03-21 10:41:47 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178663 $
#$URL: svn://www.crystallography.net/cod/cif/4/07/74/4077460.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4077460
loop_
_publ_author_name
'Gröer, Thomas'
'Scheer, Manfred'
_publ_section_title
;
 Transition-Metal-Substituted Dichlorobismuthanes as Starting Materials
 for Novel Bismuth−Transition-Metal Clusters†
;
_journal_issue                   18
_journal_name_full               Organometallics
_journal_page_first              3683
_journal_paper_doi               10.1021/om000372g
_journal_volume                  19
_journal_year                    2000
_chemical_formula_sum            'C32 H50 Bi Cl7 Mo2 O3'
_chemical_formula_weight         1131.73
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL
_cell_angle_alpha                90.00
_cell_angle_beta                 112.88(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   17.835(3)
_cell_length_b                   13.276(2)
_cell_length_c                   18.353(4)
_cell_measurement_reflns_used    1103
_cell_measurement_temperature    200(1)
_cell_measurement_theta_max      26.62
_cell_measurement_theta_min      1.97
_cell_volume                     4003.7(15)
_computing_cell_refinement       'STOE IPDS software'
_computing_data_collection       'STOE IPDS software'
_computing_data_reduction        'STOE IPDS software'
_computing_molecular_graphics    'SIEMENS XP'
_computing_publication_material  SHELXL-93
_computing_structure_refinement  'SHELXL-93 (Sheldrick, 1993)'
_computing_structure_solution    'SHELXS-86 (Sheldrick, 1990)'
_diffrn_ambient_temperature      200(1)
_diffrn_measurement_device       'STOE IPDS'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0715
_diffrn_reflns_av_sigmaI/netI    0.0479
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            31289
_diffrn_reflns_theta_max         26.62
_diffrn_reflns_theta_min         1.97
_exptl_absorpt_coefficient_mu    5.499
_exptl_absorpt_correction_type   numerical
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    1.878
_exptl_crystal_description       route
_exptl_crystal_F_000             2208
_exptl_crystal_size_max          0.23
_exptl_crystal_size_mid          0.23
_exptl_crystal_size_min          0.04
_refine_diff_density_max         1.755
_refine_diff_density_min         -2.474
_refine_diff_density_rms         0.184
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_all   0.954
_refine_ls_goodness_of_fit_obs   1.021
_refine_ls_hydrogen_treatment    riding
_refine_ls_matrix_type           full
_refine_ls_number_parameters     418
_refine_ls_number_reflns         7928
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.954
_refine_ls_restrained_S_obs      1.021
_refine_ls_R_factor_all          0.0523
_refine_ls_R_factor_obs          0.0430
_refine_ls_shift/esd_max         -0.004
_refine_ls_shift/esd_mean        0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0771P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         0.1086
_refine_ls_wR_factor_obs         0.1047
_reflns_number_observed          6494
_reflns_number_total             7928
_reflns_observed_criterion       >2sigma(I)
_cod_data_source_file            8.cif
_cod_data_source_block           tbi5
_cod_depositor_comments
;
The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc
w=1/[\s^2^(Fo^2^)+(0.0771P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3' was
changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to
'w=1/[\s^2^(Fo^2^)+(0.0771P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_cell_volume        4003.6(14)
_cod_original_sg_symbol_H-M      P2(1)/n
_cod_database_code               4077460
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_thermal_displace_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
Bi Bi 0.130443(12) 0.01010(2) 0.024160(12) 0.03025(9) Uani 1 d .
Mo1 Mo 0.51444(3) -0.14883(4) 0.19114(2) 0.02349(12) Uani 1 d .
Mo2 Mo 0.64783(3) -0.16518(4) 0.14986(2) 0.02358(12) Uani 1 d .
Cl1 Cl 0.61649(8) -0.28677(11) 0.23393(8) 0.0324(3) Uani 1 d .
Cl2 Cl 0.50922(8) -0.22361(11) 0.07055(8) 0.0305(3) Uani 1 d .
Cl3 Cl 0.64767(8) -0.06173(12) 0.25859(8) 0.0323(3) Uani 1 d .
Cl4 Cl 0.01634(10) 0.07834(14) 0.08831(9) 0.0442(4) Uani 1 d .
Cl7 Cl 0.10211(10) 0.16117(14) -0.06259(11) 0.0484(4) Uani 1 d .
Cl6 Cl 0.21583(11) -0.08436(14) -0.03659(10) 0.0471(4) Uani 1 d .
Cl5 Cl 0.25794(10) 0.09945(15) 0.12227(11) 0.0511(4) Uani 1 d .
C1 C 0.4775(4) -0.0210(5) 0.1313(3) 0.0331(13) Uani 1 d .
O1 O 0.4546(3) 0.0518(4) 0.0972(3) 0.0486(12) Uani 1 d .
C2 C 0.6177(4) -0.0349(5) 0.0915(3) 0.0318(13) Uani 1 d .
O2 O 0.6022(3) 0.0399(4) 0.0594(3) 0.0484(12) Uani 1 d .
O3 O 0.1742(3) -0.1421(4) 0.1335(3) 0.0414(10) Uani 1 d .
C3 C 0.3803(3) -0.1420(5) 0.1663(4) 0.0302(12) Uani 1 d .
H3 H 0.3424(3) -0.1234(5) 0.1153(4) 0.036 Uiso 1 calc R
C4 C 0.4213(4) -0.0746(5) 0.2292(3) 0.0322(13) Uani 1 d .
H4 H 0.4157(4) -0.0034(5) 0.2277(3) 0.039 Uiso 1 calc R
C5 C 0.4718(4) -0.1323(5) 0.2944(3) 0.0294(12) Uani 1 d .
C6 C 0.4622(3) -0.2352(5) 0.2707(3) 0.0294(12) Uani 1 d .
H6 H 0.4900(3) -0.2904(5) 0.3028(3) 0.035 Uiso 1 calc R
C7 C 0.4053(3) -0.2422(4) 0.1921(3) 0.0278(11) Uani 1 d .
C8 C 0.5182(4) -0.0955(6) 0.3774(4) 0.041(2) Uani 1 d .
C9 C 0.4585(5) -0.1166(7) 0.4171(5) 0.061(2) Uani 1 d .
H9A H 0.4835(16) -0.0971(45) 0.4730(10) 0.091 Uiso 1 calc R
H9B H 0.4453(30) -0.1885(10) 0.4131(32) 0.091 Uiso 1 calc R
H9C H 0.4086(16) -0.0775(36) 0.3907(24) 0.091 Uiso 1 calc R
C10 C 0.5347(5) 0.0176(6) 0.3776(4) 0.049(2) Uani 1 d .
H10A H 0.5623(29) 0.0318(8) 0.3418(25) 0.073 Uiso 1 calc R
H10B H 0.5694(27) 0.0390(9) 0.4313(8) 0.073 Uiso 1 calc R
H10C H 0.4831(6) 0.0544(6) 0.3598(30) 0.073 Uiso 1 calc R
C11 C 0.5977(5) -0.1538(6) 0.4175(4) 0.051(2) Uani 1 d .
H11A H 0.6211(19) -0.1377(34) 0.4740(7) 0.076 Uiso 1 calc R
H11B H 0.6361(13) -0.1348(32) 0.3936(23) 0.076 Uiso 1 calc R
H11C H 0.5867(7) -0.2263(6) 0.4105(29) 0.076 Uiso 1 calc R
C12 C 0.3675(4) -0.3391(5) 0.1518(3) 0.0329(13) Uani 1 d .
C13 C 0.4310(4) -0.4230(5) 0.1649(4) 0.0387(14) Uani 1 d .
H13A H 0.4613(20) -0.4332(25) 0.2217(4) 0.058 Uiso 1 calc R
H13B H 0.4689(18) -0.4035(17) 0.1404(25) 0.058 Uiso 1 calc R
H13C H 0.4034(5) -0.4857(10) 0.1409(25) 0.058 Uiso 1 calc R
C14 C 0.3072(4) -0.3723(6) 0.1879(5) 0.047(2) Uani 1 d .
H14A H 0.3372(4) -0.3942(38) 0.2426(11) 0.071 Uiso 1 calc R
H14B H 0.2742(22) -0.4282(27) 0.1570(19) 0.071 Uiso 1 calc R
H14C H 0.2717(21) -0.3157(13) 0.1873(29) 0.071 Uiso 1 calc R
C15 C 0.3202(4) -0.3225(6) 0.0653(4) 0.042(2) Uani 1 d .
H15A H 0.2923(25) -0.3849(12) 0.0411(7) 0.063 Uiso 1 calc R
H15B H 0.3574(6) -0.3026(38) 0.0402(7) 0.063 Uiso 1 calc R
H15C H 0.2800(21) -0.2691(27) 0.0580(4) 0.063 Uiso 1 calc R
C16 C 0.7061(3) -0.2647(4) 0.0788(3) 0.0255(11) Uani 1 d .
C17 C 0.7479(3) -0.2843(5) 0.1584(3) 0.0276(12) Uani 1 d .
H17 H 0.7507(3) -0.3483(5) 0.1826(3) 0.033 Uiso 1 calc R
C18 C 0.7860(3) -0.1953(5) 0.1989(3) 0.0295(12) Uani 1 d .
C19 C 0.7650(3) -0.1170(5) 0.1424(3) 0.0300(12) Uani 1 d .
H19 H 0.7812(3) -0.0485(5) 0.1521(3) 0.036 Uiso 1 calc R
C20 C 0.7158(3) -0.1589(5) 0.0691(3) 0.0281(12) Uani 1 d .
H20 H 0.6926(3) -0.1230(5) 0.0207(3) 0.034 Uiso 1 calc R
C21 C 0.8534(4) -0.1935(5) 0.2796(3) 0.0377(14) Uani 1 d .
C22 C 0.8254(5) -0.2435(8) 0.3389(4) 0.066(3) Uani 1 d .
H22A H 0.7826(29) -0.2026(26) 0.3453(29) 0.099 Uiso 1 calc R
H22B H 0.8715(10) -0.2494(48) 0.3900(12) 0.099 Uiso 1 calc R
H22C H 0.8040(37) -0.3107(20) 0.3199(19) 0.099 Uiso 1 calc R
C23 C 0.9220(4) -0.2540(7) 0.2724(4) 0.057(2) Uani 1 d .
H23A H 0.9647(18) -0.2644(41) 0.3251(5) 0.086 Uiso 1 calc R
H23B H 0.9446(25) -0.2175(22) 0.2392(30) 0.086 Uiso 1 calc R
H23C H 0.9012(9) -0.3195(19) 0.2483(34) 0.086 Uiso 1 calc R
C24 C 0.8809(5) -0.0860(7) 0.3026(4) 0.058(2) Uani 1 d .
H24A H 0.9094(31) -0.0613(16) 0.2700(24) 0.087 Uiso 1 calc R
H24B H 0.9178(29) -0.0837(10) 0.3585(10) 0.087 Uiso 1 calc R
H24C H 0.8334(6) -0.0434(11) 0.2942(33) 0.087 Uiso 1 calc R
C25 C 0.6704(3) -0.3414(5) 0.0153(3) 0.0291(12) Uani 1 d .
C26 C 0.6336(4) -0.4316(5) 0.0424(4) 0.0402(15) Uani 1 d .
H26A H 0.6105(28) -0.4793(19) -0.0014(10) 0.060 Uiso 1 calc R
H26B H 0.5906(21) -0.4077(7) 0.0590(28) 0.060 Uiso 1 calc R
H26C H 0.6762(7) -0.4651(23) 0.0870(20) 0.060 Uiso 1 calc R
C27 C 0.7414(4) -0.3779(5) -0.0040(4) 0.0398(15) Uani 1 d .
H27A H 0.7210(5) -0.4208(30) -0.0512(18) 0.060 Uiso 1 calc R
H27B H 0.7791(16) -0.4166(31) 0.0407(12) 0.060 Uiso 1 calc R
H27C H 0.7699(18) -0.3198(6) -0.0140(28) 0.060 Uiso 1 calc R
C28 C 0.6053(4) -0.2949(5) -0.0573(3) 0.0354(14) Uani 1 d .
H28A H 0.5618(14) -0.2675(31) -0.0431(7) 0.053 Uiso 1 calc R
H28B H 0.5828(20) -0.3465(9) -0.0982(11) 0.053 Uiso 1 calc R
H28C H 0.6293(7) -0.2406(24) -0.0774(16) 0.053 Uiso 1 calc R
C29 C 0.1124(4) -0.2204(6) 0.1154(4) 0.050(2) Uani 1 d .
H29A H 0.1290(4) -0.2806(6) 0.0935(4) 0.060 Uiso 1 calc R
H29B H 0.0597(4) -0.1958(6) 0.0763(4) 0.060 Uiso 1 calc R
C30 C 0.1052(5) -0.2452(6) 0.1909(5) 0.053(2) Uani 1 d .
H30A H 0.1394(5) -0.3039(6) 0.2169(5) 0.063 Uiso 1 calc R
H30B H 0.0480(5) -0.2590(6) 0.1831(5) 0.063 Uiso 1 calc R
C31 C 0.1361(6) -0.1501(7) 0.2374(5) 0.068(2) Uani 1 d .
H31A H 0.0926(6) -0.0986(7) 0.2236(5) 0.081 Uiso 1 calc R
H31B H 0.1567(6) -0.1634(7) 0.2950(5) 0.081 Uiso 1 calc R
C32 C 0.2031(5) -0.1167(7) 0.2138(4) 0.053(2) Uani 1 d .
H32A H 0.2125(5) -0.0433(7) 0.2215(4) 0.064 Uiso 1 calc R
H32B H 0.2544(5) -0.1528(7) 0.2443(4) 0.064 Uiso 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mo Mo -1.6832 0.6857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Bi Bi -4.1077 10.2566 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_3
Cl7 Bi Cl6 97.14(6) .
Cl7 Bi Cl5 88.89(7) .
Cl6 Bi Cl5 90.98(7) .
Cl7 Bi O3 173.20(11) .
Cl6 Bi O3 84.78(11) .
Cl5 Bi O3 84.55(11) .
Cl7 Bi Cl4 90.46(6) .
Cl6 Bi Cl4 168.22(6) .
Cl5 Bi Cl4 98.17(6) .
O3 Bi Cl4 88.71(11) .
Cl7 Bi Cl4 88.17(6) 3
Cl6 Bi Cl4 90.98(6) 3
Cl5 Bi Cl4 176.65(6) 3
O3 Bi Cl4 98.34(11) 3
Cl4 Bi Cl4 80.24(5) 3
C1 Mo1 C3 75.9(2) .
C1 Mo1 C4 70.9(2) .
C3 Mo1 C4 36.6(2) .
C1 Mo1 C5 103.2(2) .
C3 Mo1 C5 60.0(2) .
C4 Mo1 C5 35.9(2) .
C1 Mo1 C7 111.2(2) .
C3 Mo1 C7 36.3(2) .
C4 Mo1 C7 60.6(2) .
C5 Mo1 C7 59.9(2) .
C1 Mo1 C6 129.9(2) .
C3 Mo1 C6 59.5(2) .
C4 Mo1 C6 59.9(2) .
C5 Mo1 C6 35.8(2) .
C7 Mo1 C6 35.4(2) .
C1 Mo1 Cl2 87.6(2) .
C3 Mo1 Cl2 99.9(2) .
C4 Mo1 Cl2 134.1(2) .
C5 Mo1 Cl2 152.9(2) .
C7 Mo1 Cl2 93.15(14) .
C6 Mo1 Cl2 119.8(2) .
C1 Mo1 Cl1 148.0(2) .
C3 Mo1 Cl1 133.0(2) .
C4 Mo1 Cl1 139.4(2) .
C5 Mo1 Cl1 104.2(2) .
C7 Mo1 Cl1 96.78(15) .
C6 Mo1 Cl1 82.0(2) .
Cl2 Mo1 Cl1 75.34(5) .
C1 Mo1 Cl3 85.7(2) .
C3 Mo1 Cl3 144.3(2) .
C4 Mo1 Cl3 108.5(2) .
C5 Mo1 Cl3 95.9(2) .
C7 Mo1 Cl3 152.37(14) .
C6 Mo1 Cl3 117.06(15) .
Cl2 Mo1 Cl3 109.75(5) .
Cl1 Mo1 Cl3 75.26(5) .
C1 Mo1 Mo2 92.9(2) .
C3 Mo1 Mo2 154.6(2) .
C4 Mo1 Mo2 158.4(2) .
C5 Mo1 Mo2 145.38(15) .
C7 Mo1 Mo2 140.76(14) .
C6 Mo1 Mo2 137.00(15) .
Cl2 Mo1 Mo2 56.21(4) .
Cl1 Mo1 Mo2 55.07(4) .
Cl3 Mo1 Mo2 54.48(4) .
C2 Mo2 C19 77.5(2) .
C2 Mo2 C20 73.6(2) .
C19 Mo2 C20 36.4(2) .
C2 Mo2 C18 112.6(2) .
C19 Mo2 C18 36.2(2) .
C20 Mo2 C18 59.7(2) .
C2 Mo2 C17 131.4(2) .
C19 Mo2 C17 59.5(2) .
C20 Mo2 C17 58.6(2) .
C18 Mo2 C17 35.6(2) .
C2 Mo2 C16 105.9(2) .
C19 Mo2 C16 60.3(2) .
C20 Mo2 C16 36.1(2) .
C18 Mo2 C16 59.1(2) .
C17 Mo2 C16 34.2(2) .
C2 Mo2 Cl3 82.2(2) .
C19 Mo2 Cl3 100.9(2) .
C20 Mo2 Cl3 134.0(2) .
C18 Mo2 Cl3 96.88(15) .
C17 Mo2 Cl3 124.88(14) .
C16 Mo2 Cl3 155.95(13) .
C2 Mo2 Cl1 146.3(2) .
C19 Mo2 Cl1 132.5(2) .
C20 Mo2 Cl1 138.9(2) .
C18 Mo2 Cl1 96.4(2) .
C17 Mo2 Cl1 82.34(15) .
C16 Mo2 Cl1 103.70(15) .
Cl3 Mo2 Cl1 77.33(5) .
C2 Mo2 Cl2 87.5(2) .
C19 Mo2 Cl2 143.29(15) .
C20 Mo2 Cl2 107.27(15) .
C18 Mo2 Cl2 148.6(2) .
C17 Mo2 Cl2 113.02(15) .
C16 Mo2 Cl2 93.07(14) .
Cl3 Mo2 Cl2 110.11(5) .
Cl1 Mo2 Cl2 74.98(5) .
C2 Mo2 Mo1 89.9(2) .
C19 Mo2 Mo1 156.2(2) .
C20 Mo2 Mo1 156.35(14) .
C18 Mo2 Mo1 143.84(13) .
C17 Mo2 Mo1 138.29(14) .
C16 Mo2 Mo1 143.45(14) .
Cl3 Mo2 Mo1 56.95(4) .
Cl1 Mo2 Mo1 56.47(4) .
Cl2 Mo2 Mo1 54.10(4) .
Mo2 Cl1 Mo1 68.45(4) .
Mo1 Cl2 Mo2 69.69(4) .
Mo2 Cl3 Mo1 68.57(4) .
Bi Cl4 Bi 99.76(5) 3
O1 C1 Mo1 178.4(6) .
O2 C2 Mo2 178.5(5) .
C32 O3 C29 110.4(5) .
C32 O3 Bi 118.5(4) .
C29 O3 Bi 112.6(4) .
C4 C3 C7 108.8(5) .
C4 C3 Mo1 72.0(3) .
C7 C3 Mo1 74.1(3) .
C5 C4 C3 107.7(5) .
C5 C4 Mo1 73.9(3) .
C3 C4 Mo1 71.4(3) .
C4 C5 C6 107.5(5) .
C4 C5 C8 126.9(6) .
C6 C5 C8 125.1(6) .
C4 C5 Mo1 70.2(3) .
C6 C5 Mo1 72.3(3) .
C8 C5 Mo1 129.3(4) .
C7 C6 C5 109.2(5) .
C7 C6 Mo1 72.2(3) .
C5 C6 Mo1 71.9(3) .
C6 C7 C3 106.7(5) .
C6 C7 C12 124.5(5) .
C3 C7 C12 127.7(5) .
C6 C7 Mo1 72.5(3) .
C3 C7 Mo1 69.7(3) .
C12 C7 Mo1 132.1(4) .
C5 C8 C10 110.6(6) .
C5 C8 C11 111.4(6) .
C10 C8 C11 110.7(6) .
C5 C8 C9 102.2(5) .
C10 C8 C9 110.3(6) .
C11 C8 C9 111.3(6) .
C15 C12 C7 110.8(5) .
C15 C12 C14 107.5(5) .
C7 C12 C14 106.7(5) .
C15 C12 C13 110.5(5) .
C7 C12 C13 112.3(5) .
C14 C12 C13 108.8(6) .
C17 C16 C20 106.0(5) .
C17 C16 C25 126.0(5) .
C20 C16 C25 127.3(5) .
C17 C16 Mo2 72.2(3) .
C20 C16 Mo2 67.8(3) .
C25 C16 Mo2 131.9(4) .
C16 C17 C18 110.3(5) .
C16 C17 Mo2 73.6(3) .
C18 C17 Mo2 70.8(3) .
C19 C18 C17 106.9(5) .
C19 C18 C21 126.6(6) .
C17 C18 C21 124.4(5) .
C19 C18 Mo2 69.4(3) .
C17 C18 Mo2 73.6(3) .
C21 C18 Mo2 135.0(4) .
C20 C19 C18 107.5(5) .
C20 C19 Mo2 72.3(3) .
C18 C19 Mo2 74.5(3) .
C19 C20 C16 109.2(5) .
C19 C20 Mo2 71.3(3) .
C16 C20 Mo2 76.1(3) .
C18 C21 C23 105.8(5) .
C18 C21 C24 109.7(6) .
C23 C21 C24 109.8(6) .
C18 C21 C22 109.9(5) .
C23 C21 C22 109.5(7) .
C24 C21 C22 111.9(7) .
C16 C25 C28 110.9(5) .
C16 C25 C27 105.0(5) .
C28 C25 C27 110.4(5) .
C16 C25 C26 112.6(5) .
C28 C25 C26 108.9(5) .
C27 C25 C26 109.1(5) .
O3 C29 C30 106.2(6) .
C29 C30 C31 101.4(6) .
C32 C31 C30 104.1(6) .
O3 C32 C31 103.0(6) .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Bi Cl7 2.487(2) .
Bi Cl6 2.541(2) .
Bi Cl5 2.576(2) .
Bi O3 2.739(5) .
Bi Cl4 2.866(2) .
Bi Cl4 2.879(2) 3
Mo1 C1 1.990(7) .
Mo1 C3 2.256(5) .
Mo1 C4 2.263(6) .
Mo1 C5 2.311(5) .
Mo1 C7 2.314(6) .
Mo1 C6 2.317(5) .
Mo1 Cl2 2.3942(14) .
Mo1 Cl1 2.484(2) .
Mo1 Cl3 2.496(2) .
Mo1 Mo2 2.7717(8) .
Mo2 C2 1.995(6) .
Mo2 C19 2.240(5) .
Mo2 C20 2.252(5) .
Mo2 C18 2.306(5) .
Mo2 C17 2.344(5) .
Mo2 C16 2.361(5) .
Mo2 Cl3 2.4234(14) .
Mo2 Cl1 2.443(2) .
Mo2 Cl2 2.456(2) .
Cl4 Bi 2.879(2) 3
C1 O1 1.138(8) .
C2 O2 1.132(8) .
O3 C32 1.399(8) .
O3 C29 1.456(9) .
C3 C4 1.418(9) .
C3 C7 1.423(8) .
C4 C5 1.412(8) .
C5 C6 1.423(9) .
C5 C8 1.504(8) .
C6 C7 1.407(8) .
C7 C12 1.507(8) .
C8 C10 1.530(10) .
C8 C11 1.529(10) .
C8 C9 1.532(9) .
C12 C15 1.496(8) .
C12 C14 1.532(9) .
C12 C13 1.539(9) .
C16 C17 1.382(7) .
C16 C20 1.434(8) .
C16 C25 1.492(8) .
C17 C18 1.421(8) .
C18 C19 1.412(9) .
C18 C21 1.501(7) .
C19 C20 1.403(8) .
C21 C23 1.511(10) .
C21 C24 1.515(11) .
C21 C22 1.516(10) .
C25 C28 1.516(8) .
C25 C27 1.521(8) .
C25 C26 1.539(9) .
C29 C30 1.478(10) .
C30 C31 1.504(12) .
C31 C32 1.489(11) .
