#------------------------------------------------------------------------------
#$Date: 2016-03-21 10:52:06 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178671 $
#$URL: svn://www.crystallography.net/cod/cif/4/07/82/4078223.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4078223
loop_
_publ_author_name
'Vaquero, Mónica'
'Vargas, Sergio'
'Suárez, Andrés'
'Garc\?ía-Garrido, Sergio E.'
'Álvarez, Eleuterio'
'Mancera, Manuel'
'Pizzano, Antonio'
_publ_section_title
;
 Synthesis, Characterization, and Reactivity of Ruthenium Bis-Allyl
 Complexes with Chiral Phosphine-Phosphite Ligands
;
_journal_issue                   9
_journal_name_full               Organometallics
_journal_page_first              3551
_journal_paper_doi               10.1021/om300018s
_journal_volume                  31
_journal_year                    2012
_chemical_absolute_configuration ad
_chemical_formula_moiety         'C50 H60 O3 P2 Ru, 0.5(C6 H14)'
_chemical_formula_sum            'C53 H67 O3 P2 Ru'
_chemical_formula_weight         915.08
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           4
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'P 2yb'
_symmetry_space_group_name_H-M   'P 1 21 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 115.76(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   15.042(3)
_cell_length_b                   10.687(2)
_cell_length_c                   16.519(3)
_cell_measurement_reflns_used    9929
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      29.75
_cell_measurement_theta_min      2.34
_cell_volume                     2391.6(10)
_computing_cell_refinement       'Bruker (2006). APEX 2. Version 2.1.'
_computing_data_collection       'Bruker (2006). APEX 2. Version 2.1.'
_computing_data_reduction        'Bruker (2006). APEX 2. Version 2.1.'
_computing_molecular_graphics    'XP, SHELXTL v. 6.14 (Bruker, 2003)'
_computing_publication_material  'XCIF, SHELXTL v. 6.14 (Bruker, 2003)'
_computing_structure_refinement  'XL, SHELXTL v. 6.14 (Bruker, 2003)'
_computing_structure_solution    'Bruker (2006). APEX 2. Version 2.1.'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 8.26
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type
;
 Bruker-Nonius X8kappa APEX II CCD area detector'
;
_diffrn_measurement_method       'phi and omega scans with narrow frames'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0352
_diffrn_reflns_av_sigmaI/netI    0.0371
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_number            46734
_diffrn_reflns_theta_full        30.60
_diffrn_reflns_theta_max         30.60
_diffrn_reflns_theta_min         1.37
_diffrn_standards_decay_%        0
_exptl_absorpt_coefficient_mu    0.436
_exptl_absorpt_correction_T_max  0.9640
_exptl_absorpt_correction_T_min  0.9375
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
 SADABS, Bruker (2006). APEX 2. Version 2.1. Bruker Analytical
 X-ray Solutions, Madison, Wisconsin, USA.
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.271
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             966
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.08
_refine_diff_density_max         1.811
_refine_diff_density_min         -0.958
_refine_diff_density_rms         0.086
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.01(2)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.038
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     584
_refine_ls_number_reflns         12661
_refine_ls_number_restraints     249
_refine_ls_restrained_S_all      1.035
_refine_ls_R_factor_all          0.0496
_refine_ls_R_factor_gt           0.0443
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0627P)²+2.1313P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1109
_refine_ls_wR_factor_ref         0.1151
_reflns_number_gt                11615
_reflns_number_total             12661
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om300018s_si_002.cif
_cod_data_source_block           1a
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_sg_symbol_H-M      P2(1)
_cod_database_code               4078223
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ru1 Ru 0.410841(15) 0.78129(2) 0.294685(14) 0.02173(6) Uani 1 1 d . A .
P1 P 0.29768(6) 0.87810(7) 0.17527(5) 0.02159(15) Uani 1 1 d . . .
P2 P 0.53313(6) 0.87690(9) 0.26783(6) 0.02696(17) Uani 1 1 d . . .
O1 O 0.21955(16) 0.9854(2) 0.17660(14) 0.0217(4) Uani 1 1 d . . .
O2 O 0.22857(14) 0.7892(3) 0.09305(13) 0.0267(4) Uani 1 1 d . . .
O3 O 0.34197(17) 0.9674(2) 0.12071(14) 0.0262(5) Uani 1 1 d . A .
C1 C 0.1280(2) 0.9564(3) 0.1733(2) 0.0225(6) Uani 1 1 d . . .
C2 C 0.0611(2) 0.8936(3) 0.0963(2) 0.0262(6) Uani 1 1 d . . .
C3 C 0.0762(2) 0.8966(3) 0.0130(2) 0.0272(7) Uani 1 1 d . . .
C4 C 0.1587(2) 0.8398(3) 0.0105(2) 0.0268(6) Uani 1 1 d . . .
C5 C 0.1707(3) 0.8261(3) -0.0678(2) 0.0296(7) Uani 1 1 d . . .
C6 C 0.1013(3) 0.8889(3) -0.1421(2) 0.0320(7) Uani 1 1 d . . .
H6 H 0.1086 0.8858 -0.1964 0.038 Uiso 1 1 calc R . .
C7 C 0.0224(3) 0.9556(3) -0.1424(2) 0.0339(8) Uani 1 1 d . . .
C8 C 0.0084(3) 0.9588(3) -0.0642(2) 0.0308(7) Uani 1 1 d . . .
C9 C -0.0241(2) 0.8393(3) 0.0964(3) 0.0332(8) Uani 1 1 d . . .
C10 C -0.0420(3) 0.8559(3) 0.1719(3) 0.0378(9) Uani 1 1 d . . .
C11 C 0.0181(3) 0.9369(3) 0.2386(3) 0.0336(8) Uani 1 1 d . . .
H11 H 0.0008 0.9540 0.2863 0.040 Uiso 1 1 calc R . .
C12 C 0.1022(2) 0.9953(3) 0.2411(2) 0.0268(6) Uani 1 1 d . . .
C13 C 0.2480(3) 0.7418(3) -0.0779(2) 0.0320(7) Uani 1 1 d . . .
C14 C 0.2255(5) 0.6091(5) -0.0555(5) 0.0665(15) Uani 1 1 d . . .
H14A H 0.2521 0.5479 -0.0833 0.100 Uiso 1 1 d R . .
H14B H 0.1542 0.5966 -0.0781 0.100 Uiso 1 1 d R . .
H14C H 0.2575 0.5982 0.0098 0.100 Uiso 1 1 d R . .
C15 C 0.3507(4) 0.7770(8) -0.0208(4) 0.0637(12) Uani 1 1 d . . .
H15A H 0.3524 0.8679 -0.0137 0.096 Uiso 1 1 d R . .
H15B H 0.3939 0.7526 -0.0484 0.096 Uiso 1 1 d R . .
H15C H 0.3735 0.7373 0.0382 0.096 Uiso 1 1 d R . .
C16 C 0.2277(6) 0.7160(12) -0.1717(5) 0.176(7) Uani 1 1 d . . .
H16A H 0.2170 0.7952 -0.2041 0.098 Uiso 1 1 d R . .
H16B H 0.1691 0.6632 -0.2008 0.098 Uiso 1 1 d R . .
H16C H 0.2850 0.6733 -0.1723 0.098 Uiso 1 1 d R . .
C17 C -0.0485(3) 1.0217(4) -0.2266(3) 0.0404(9) Uani 1 1 d . . .
H17A H -0.1138 0.9832 -0.2477 0.061 Uiso 1 1 d R . .
H17B H -0.0250 1.0134 -0.2730 0.061 Uiso 1 1 d R . .
H17C H -0.0529 1.1103 -0.2142 0.061 Uiso 1 1 d R . .
C18 C -0.0783(3) 1.0308(3) -0.0653(3) 0.0337(8) Uani 1 1 d . . .
H18A H -0.0736 1.0355 -0.0044 0.051 Uiso 1 1 d R . .
H18B H -0.1397 0.9885 -0.1048 0.051 Uiso 1 1 d R . .
H18C H -0.0779 1.1152 -0.0878 0.051 Uiso 1 1 d R . .
C19 C -0.0965(3) 0.7667(4) 0.0173(3) 0.0447(10) Uani 1 1 d . . .
H19A H -0.1045 0.6821 0.0355 0.067 Uiso 1 1 d R . .
H19B H -0.0712 0.7623 -0.0281 0.067 Uiso 1 1 d R . .
H19C H -0.1604 0.8095 -0.0080 0.067 Uiso 1 1 d R . .
C20 C -0.1288(3) 0.7986(4) 0.1784(4) 0.0555(13) Uani 1 1 d . . .
H20A H -0.1896 0.8335 0.1315 0.083 Uiso 1 1 d R . .
H20B H -0.1270 0.8142 0.2374 0.083 Uiso 1 1 d R . .
H20C H -0.1270 0.7084 0.1692 0.083 Uiso 1 1 d R . .
C21 C 0.1497(3) 1.1021(3) 0.3091(2) 0.0272(6) Uani 1 1 d . . .
C22 C 0.0645(3) 1.1867(4) 0.3049(3) 0.0358(8) Uani 1 1 d . . .
H22A H 0.0252 1.1427 0.3300 0.054 Uiso 1 1 d R . .
H22B H 0.0226 1.2075 0.2419 0.054 Uiso 1 1 d R . .
H22C H 0.0913 1.2635 0.3390 0.054 Uiso 1 1 d R . .
C23 C 0.2045(3) 1.0532(4) 0.4051(2) 0.0352(8) Uani 1 1 d . . .
H23A H 0.1622 0.9939 0.4171 0.053 Uiso 1 1 d R . .
H23B H 0.2202 1.1235 0.4470 0.053 Uiso 1 1 d R . .
H23C H 0.2656 1.0115 0.4131 0.053 Uiso 1 1 d R . .
C24 C 0.2171(3) 1.1865(3) 0.2847(2) 0.0310(7) Uani 1 1 d . . .
H24A H 0.2341 1.2610 0.3229 0.047 Uiso 1 1 d R . .
H24B H 0.1825 1.2115 0.2216 0.047 Uiso 1 1 d R . .
H24C H 0.2776 1.1415 0.2945 0.047 Uiso 1 1 d R . .
C25 C 0.4036(3) 1.0640(3) 0.1684(2) 0.0274(6) Uani 1 1 d . . .
C26 C 0.4984(3) 1.0395(4) 0.2343(2) 0.0323(7) Uani 1 1 d . A .
C27 C 0.5573(3) 1.1428(4) 0.2762(2) 0.0445(11) Uani 1 1 d . . .
H27 H 0.6227 1.1311 0.3215 0.053 Uiso 1 1 d R A .
C28 C 0.5228(4) 1.2629(4) 0.2526(3) 0.0550(14) Uani 1 1 d . A .
H28 H 0.5645 1.3309 0.2831 0.066 Uiso 1 1 d R . .
C29 C 0.4282(3) 1.2847(6) 0.1873(2) 0.0490(10) Uani 1 1 d . . .
H29 H 0.4056 1.3676 0.1697 0.059 Uiso 1 1 d R A .
C30 C 0.3668(3) 1.1848(4) 0.1462(2) 0.0368(8) Uani 1 1 d . A .
H30 H 0.3005 1.1983 0.1035 0.044 Uiso 1 1 d R . .
C31 C 0.5682(3) 0.8177(5) 0.1823(3) 0.0438(12) Uani 1 1 d . A .
C32 C 0.6086(3) 0.7002(6) 0.1932(3) 0.0523(12) Uani 1 1 d . . .
H32 H 0.6191 0.6564 0.2465 0.063 Uiso 1 1 d R A .
C33 C 0.6353(4) 0.6431(7) 0.1306(4) 0.0714(19) Uani 1 1 d . A .
H33 H 0.6596 0.5599 0.1398 0.086 Uiso 1 1 d R . .
C34 C 0.6208(4) 0.7102(10) 0.0555(4) 0.089(3) Uani 1 1 d . . .
H34 H 0.6391 0.6732 0.0128 0.107 Uiso 1 1 d R A .
C35 C 0.5820(4) 0.8251(9) 0.0425(3) 0.085(3) Uani 1 1 d . A .
H35 H 0.5757 0.8693 -0.0095 0.102 Uiso 1 1 d R . .
C36 C 0.5553(3) 0.8855(7) 0.1046(3) 0.0639(16) Uani 1 1 d . . .
H36 H 0.5293 0.9678 0.0942 0.077 Uiso 1 1 d R A .
C37A C 0.65639(18) 0.9073(6) 0.36197(16) 0.0233(11) Uani 0.654(15) 1 d PGU A 1
C38A C 0.67196(16) 0.9009(5) 0.45120(19) 0.0259(12) Uani 0.654(15) 1 d PGU A 1
H38A H 0.6205 0.8730 0.4656 0.031 Uiso 0.654(15) 1 calc PR A 1
C39A C 0.7628(2) 0.9352(6) 0.51941(15) 0.0348(14) Uani 0.654(15) 1 d PGU A 1
H39A H 0.7734 0.9308 0.5804 0.042 Uiso 0.654(15) 1 calc PR A 1
C40A C 0.8380(2) 0.9760(9) 0.49839(17) 0.050(2) Uani 0.654(15) 1 d PGU A 1
H40A H 0.9000 0.9994 0.5450 0.060 Uiso 0.654(15) 1 calc PR A 1
C41A C 0.8224(3) 0.9823(9) 0.40916(19) 0.053(2) Uani 0.654(15) 1 d PGU A 1
H41A H 0.8738 1.0102 0.3948 0.064 Uiso 0.654(15) 1 calc PR A 1
C42A C 0.7316(3) 0.9480(8) 0.34095(14) 0.0388(18) Uani 0.654(15) 1 d PGU A 1
H42A H 0.7210 0.9524 0.2800 0.047 Uiso 0.654(15) 1 calc PR A 1
C37B C 0.6618(2) 0.8756(6) 0.35662(17) 0.023(2) Uani 0.346(15) 1 d PGU A 2
C38B C 0.67220(17) 0.8772(5) 0.44429(19) 0.021(2) Uani 0.346(15) 1 d PGU A 2
H38B H 0.6162 0.8646 0.4558 0.025 Uiso 0.346(15) 1 calc PR A 2
C39B C 0.76442(19) 0.8974(6) 0.51530(14) 0.028(2) Uani 0.346(15) 1 d PGU A 2
H39B H 0.7714 0.8985 0.5753 0.033 Uiso 0.346(15) 1 calc PR A 2
C40B C 0.84628(15) 0.9158(9) 0.49863(17) 0.036(3) Uani 0.346(15) 1 d PGU A 2
H40B H 0.9093 0.9296 0.5472 0.043 Uiso 0.346(15) 1 calc PR A 2
C41B C 0.8359(2) 0.9142(10) 0.4110(2) 0.038(3) Uani 0.346(15) 1 d PGU A 2
H41B H 0.8919 0.9268 0.3995 0.046 Uiso 0.346(15) 1 calc PR A 2
C42B C 0.7437(3) 0.8940(9) 0.33995(17) 0.035(3) Uani 0.346(15) 1 d PGU A 2
H42B H 0.7367 0.8929 0.2800 0.042 Uiso 0.346(15) 1 calc PR A 2
C43 C 0.3853(3) 0.8240(3) 0.4119(2) 0.0279(6) Uani 1 1 d . . .
C44 C 0.2965(2) 0.7700(4) 0.3476(2) 0.0322(7) Uani 1 1 d . A .
H44A H 0.2388 0.8263 0.3197 0.039 Uiso 1 1 calc R . .
H44B H 0.2798 0.6854 0.3613 0.039 Uiso 1 1 calc R . .
C45 C 0.4191(3) 0.9354(3) 0.3880(2) 0.0259(6) Uani 1 1 d . A .
H45A H 0.4859 0.9645 0.4297 0.031 Uiso 1 1 calc R . .
H45B H 0.3704 1.0039 0.3628 0.031 Uiso 1 1 calc R . .
C46 C 0.4431(3) 0.7656(4) 0.5025(2) 0.0362(8) Uani 1 1 d . A .
H46A H 0.5104 0.7990 0.5302 0.054 Uiso 1 1 d R . .
H46B H 0.4454 0.6751 0.4956 0.054 Uiso 1 1 d R . .
H46C H 0.4103 0.7844 0.5408 0.054 Uiso 1 1 d R . .
C47 C 0.4315(3) 0.5791(3) 0.3044(3) 0.0323(8) Uani 1 1 d . . .
C48 C 0.5205(3) 0.6302(3) 0.3712(3) 0.0297(7) Uani 1 1 d . A .
H48A H 0.5801 0.6232 0.3605 0.036 Uiso 1 1 calc R . .
H48B H 0.5333 0.6172 0.4347 0.036 Uiso 1 1 calc R . .
C49 C 0.4010(3) 0.6136(3) 0.2126(3) 0.0346(8) Uani 1 1 d . A .
H49A H 0.3340 0.5872 0.1693 0.042 Uiso 1 1 calc R . .
H49B H 0.4511 0.6059 0.1889 0.042 Uiso 1 1 calc R . .
C50 C 0.3670(3) 0.4947(3) 0.3290(3) 0.0409(9) Uani 1 1 d . A .
H50A H 0.2971 0.5078 0.2887 0.061 Uiso 1 1 d R . .
H50B H 0.3787 0.5126 0.3910 0.061 Uiso 1 1 d R . .
H50C H 0.3849 0.4079 0.3247 0.061 Uiso 1 1 d R . .
C51 C 0.1475(19) -0.1297(18) 0.5848(11) 0.138(7) Uani 0.50 1 d PDU . .
H51A H 0.0848 -0.1058 0.5347 0.207 Uiso 0.50 1 d PR . .
H51B H 0.1345 -0.1817 0.6271 0.207 Uiso 0.50 1 d PR . .
H51C H 0.1874 -0.1769 0.5618 0.207 Uiso 0.50 1 d PR . .
C52 C 0.2051(11) -0.0232(14) 0.6322(8) 0.095(3) Uani 0.50 1 d PDU . .
H52A H 0.2473 0.0073 0.6043 0.114 Uiso 0.50 1 d PR . .
H52B H 0.2474 -0.0409 0.6964 0.114 Uiso 0.50 1 d PR . .
C53 C 0.1337(10) 0.0809(15) 0.6293(8) 0.098(4) Uani 0.50 1 d PDU . .
H53A H 0.0931 0.0402 0.6553 0.117 Uiso 0.50 1 d PR . .
H53B H 0.1705 0.1480 0.6720 0.117 Uiso 0.50 1 d PR . .
C54 C 0.0565(10) 0.1395(16) 0.5425(8) 0.098(4) Uani 0.50 1 d PDU . .
H54A H 0.0947 0.1958 0.5220 0.117 Uiso 0.50 1 d PR . .
H54B H 0.0253 0.0764 0.4946 0.117 Uiso 0.50 1 d PR . .
C55 C -0.0190(13) 0.2220(17) 0.5467(13) 0.124(5) Uani 0.50 1 d PDU . .
H55A H 0.0114 0.2883 0.5922 0.149 Uiso 0.50 1 d PR . .
H55B H -0.0568 0.1673 0.5687 0.149 Uiso 0.50 1 d PR . .
C56 C -0.0912(18) 0.290(3) 0.4663(14) 0.174(8) Uani 0.50 1 d PDU . .
H56A H -0.0577 0.3556 0.4489 0.261 Uiso 0.50 1 d PR . .
H56B H -0.1453 0.3262 0.4762 0.261 Uiso 0.50 1 d PR . .
H56C H -0.1177 0.2274 0.4182 0.261 Uiso 0.50 1 d PR . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
C47 Ru1 C43 102.52(14) .
C47 Ru1 C49 37.99(14) .
C43 Ru1 C49 136.34(14) .
C47 Ru1 C45 136.10(13) .
C43 Ru1 C45 37.51(13) .
C49 Ru1 C45 173.69(14) .
C47 Ru1 P1 123.84(10) .
C43 Ru1 P1 109.14(9) .
C49 Ru1 P1 90.67(10) .
C45 Ru1 P1 93.50(9) .
C47 Ru1 C44 91.54(16) .
C43 Ru1 C44 37.33(13) .
C49 Ru1 C44 109.69(16) .
C45 Ru1 C44 65.86(15) .
P1 Ru1 C44 87.13(10) .
C47 Ru1 C48 37.32(13) .
C43 Ru1 C48 91.17(14) .
C49 Ru1 C48 66.60(13) .
C45 Ru1 C48 109.51(13) .
P1 Ru1 C48 156.90(10) .
C44 Ru1 C48 103.88(15) .
C47 Ru1 P2 110.66(11) .
C43 Ru1 P2 122.72(10) .
C49 Ru1 P2 94.99(11) .
C45 Ru1 P2 89.79(10) .
P1 Ru1 P2 89.45(4) .
C44 Ru1 P2 155.11(12) .
C48 Ru1 P2 88.55(10) .
O2 P1 O3 98.46(13) .
O2 P1 O1 102.63(12) .
O3 P1 O1 93.71(12) .
O2 P1 Ru1 115.98(11) .
O3 P1 Ru1 114.91(9) .
O1 P1 Ru1 125.96(9) .
C31 P2 C26 103.6(2) .
C31 P2 C37B 93.2(2) .
C26 P2 C37B 108.0(2) .
C31 P2 C37A 100.9(2) .
C26 P2 C37A 97.9(2) .
C31 P2 Ru1 121.21(15) .
C26 P2 Ru1 109.39(13) .
C37B P2 Ru1 119.35(11) .
C37A P2 Ru1 120.31(9) .
C1 O1 P1 122.95(19) .
C4 O2 P1 121.5(2) .
C25 O3 P1 117.0(2) .
O1 C1 C12 121.1(3) .
O1 C1 C2 116.8(3) .
C12 C1 C2 121.9(3) .
C1 C2 C9 119.4(3) .
C1 C2 C3 119.3(3) .
C9 C2 C3 121.0(3) .
C4 C3 C8 118.8(3) .
C4 C3 C2 120.8(3) .
C8 C3 C2 120.4(3) .
C5 C4 C3 123.3(3) .
C5 C4 O2 120.9(3) .
C3 C4 O2 115.7(3) .
C4 C5 C6 114.8(3) .
C4 C5 C13 125.0(3) .
C6 C5 C13 120.1(3) .
C7 C6 C5 124.5(4) .
C7 C6 H6 117.7 .
C5 C6 H6 117.7 .
C6 C7 C8 118.9(3) .
C6 C7 C17 120.3(4) .
C8 C7 C17 120.8(3) .
C7 C8 C3 119.1(3) .
C7 C8 C18 118.5(3) .
C3 C8 C18 122.4(3) .
C10 C9 C2 118.6(3) .
C10 C9 C19 119.6(3) .
C2 C9 C19 121.8(4) .
C11 C10 C9 118.5(3) .
C11 C10 C20 119.4(4) .
C9 C10 C20 121.8(4) .
C10 C11 C12 125.0(4) .
C10 C11 H11 117.5 .
C12 C11 H11 117.5 .
C11 C12 C1 114.0(3) .
C11 C12 C21 118.7(3) .
C1 C12 C21 127.0(3) .
C15 C13 C16 113.8(5) .
C15 C13 C5 114.5(4) .
C16 C13 C5 113.8(4) .
C15 C13 C14 111.2(5) .
C16 C13 C14 96.5(6) .
C5 C13 C14 105.1(3) .
C13 C14 H14A 109.0 .
C13 C14 H14B 110.6 .
H14A C14 H14B 109.5 .
C13 C14 H14C 108.7 .
H14A C14 H14C 109.4 .
H14B C14 H14C 109.6 .
C13 C15 H15A 107.3 .
C13 C15 H15B 111.0 .
H15A C15 H15B 109.5 .
C13 C15 H15C 110.2 .
H15A C15 H15C 109.4 .
H15B C15 H15C 109.4 .
C13 C16 H16A 109.0 .
C13 C16 H16B 110.9 .
H16A C16 H16B 109.3 .
C13 C16 H16C 108.5 .
H16A C16 H16C 109.5 .
H16B C16 H16C 109.6 .
C7 C17 H17A 109.2 .
C7 C17 H17B 109.2 .
H17A C17 H17B 109.4 .
C7 C17 H17C 110.1 .
H17A C17 H17C 109.4 .
H17B C17 H17C 109.5 .
C8 C18 H18A 109.8 .
C8 C18 H18B 109.5 .
H18A C18 H18B 109.5 .
C8 C18 H18C 109.1 .
H18A C18 H18C 109.5 .
H18B C18 H18C 109.4 .
C9 C19 H19A 110.4 .
C9 C19 H19B 108.4 .
H19A C19 H19B 109.5 .
C9 C19 H19C 109.7 .
H19A C19 H19C 109.4 .
H19B C19 H19C 109.4 .
C10 C20 H20A 109.5 .
C10 C20 H20B 110.9 .
H20A C20 H20B 109.5 .
C10 C20 H20C 108.1 .
H20A C20 H20C 109.4 .
H20B C20 H20C 109.5 .
C23 C21 C24 110.7(3) .
C23 C21 C12 111.9(3) .
C24 C21 C12 113.2(3) .
C23 C21 C22 107.9(3) .
C24 C21 C22 105.9(3) .
C12 C21 C22 106.7(3) .
C21 C22 H22A 110.1 .
C21 C22 H22B 108.5 .
H22A C22 H22B 109.4 .
C21 C22 H22C 109.8 .
H22A C22 H22C 109.5 .
H22B C22 H22C 109.6 .
C21 C23 H23A 109.1 .
C21 C23 H23B 109.1 .
H23A C23 H23B 109.5 .
C21 C23 H23C 110.2 .
H23A C23 H23C 109.5 .
H23B C23 H23C 109.3 .
C21 C24 H24A 109.0 .
C21 C24 H24B 109.5 .
H24A C24 H24B 109.6 .
C21 C24 H24C 109.9 .
H24A C24 H24C 109.3 .
H24B C24 H24C 109.6 .
O3 C25 C30 116.9(3) .
O3 C25 C26 120.7(3) .
C30 C25 C26 122.4(3) .
C25 C26 C27 116.9(4) .
C25 C26 P2 118.4(3) .
C27 C26 P2 124.4(3) .
C28 C27 C26 121.2(4) .
C28 C27 H27 118.7 .
C26 C27 H27 120.1 .
C27 C28 C29 120.8(4) .
C27 C28 H28 119.0 .
C29 C28 H28 120.2 .
C30 C29 C28 119.7(5) .
C30 C29 H29 119.8 .
C28 C29 H29 120.5 .
C29 C30 C25 119.0(4) .
C29 C30 H30 120.7 .
C25 C30 H30 120.4 .
C32 C31 C36 117.8(5) .
C32 C31 P2 118.5(3) .
C36 C31 P2 123.7(4) .
C31 C32 C33 123.7(6) .
C31 C32 H32 117.4 .
C33 C32 H32 118.9 .
C34 C33 C32 117.2(7) .
C34 C33 H33 122.4 .
C32 C33 H33 120.3 .
C35 C34 C33 120.9(6) .
C35 C34 H34 120.8 .
C33 C34 H34 118.3 .
C34 C35 C36 123.1(6) .
C34 C35 H35 117.8 .
C36 C35 H35 118.9 .
C35 C36 C31 117.2(7) .
C35 C36 H36 121.2 .
C31 C36 H36 121.6 .
C38A C37A C42A 120.0 .
C38A C37A P2 121.71(16) .
C42A C37A P2 118.04(16) .
C39A C38A C37A 120.0 .
C39A C38A H38A 120.0 .
C37A C38A H38A 120.0 .
C40A C39A C38A 120.0 .
C40A C39A H39A 120.0 .
C38A C39A H39A 120.0 .
C39A C40A C41A 120.0 .
C39A C40A H40A 120.0 .
C41A C40A H40A 120.0 .
C42A C41A C40A 120.0 .
C42A C41A H41A 120.0 .
C40A C41A H41A 120.0 .
C41A C42A C37A 120.0 .
C41A C42A H42A 120.0 .
C37A C42A H42A 120.0 .
C42B C37B C38B 119.9 .
C42B C37B P2 123.64(16) .
C38B C37B P2 115.53(18) .
C37B C38B C39B 120.1 .
C37B C38B H38B 120.0 .
C39B C38B H38B 120.0 .
C40B C39B C38B 120.1 .
C40B C39B H39B 120.0 .
C38B C39B H39B 120.0 .
C39B C40B C41B 119.9 .
C39B C40B H40B 120.1 .
C41B C40B H40B 120.1 .
C40B C41B C42B 120.1 .
C40B C41B H41B 120.0 .
C42B C41B H41B 120.0 .
C37B C42B C41B 120.1 .
C37B C42B H42B 120.0 .
C41B C42B H42B 120.0 .
C45 C43 C44 118.0(3) .
C45 C43 C46 120.3(3) .
C44 C43 C46 121.7(3) .
C45 C43 Ru1 72.86(19) .
C44 C43 Ru1 73.9(2) .
C46 C43 Ru1 123.3(2) .
C43 C44 Ru1 68.77(19) .
C43 C44 H44A 116.8 .
Ru1 C44 H44A 116.8 .
C43 C44 H44B 116.8 .
Ru1 C44 H44B 116.8 .
H44A C44 H44B 113.8 .
C43 C45 Ru1 69.63(19) .
C43 C45 H45A 116.7 .
Ru1 C45 H45A 116.7 .
C43 C45 H45B 116.7 .
Ru1 C45 H45B 116.7 .
H45A C45 H45B 113.7 .
C43 C46 H46A 110.3 .
C43 C46 H46B 109.3 .
H46A C46 H46B 109.4 .
C43 C46 H46C 108.9 .
H46A C46 H46C 109.5 .
H46B C46 H46C 109.5 .
C48 C47 C49 118.9(3) .
C48 C47 C50 121.4(4) .
C49 C47 C50 119.6(3) .
C48 C47 Ru1 74.49(19) .
C49 C47 Ru1 72.3(2) .
C50 C47 Ru1 121.8(3) .
C47 C48 Ru1 68.19(19) .
C47 C48 H48A 116.9 .
Ru1 C48 H48A 116.9 .
C47 C48 H48B 116.9 .
Ru1 C48 H48B 116.9 .
H48A C48 H48B 113.9 .
C47 C49 Ru1 69.7(2) .
C47 C49 H49A 116.7 .
Ru1 C49 H49A 116.7 .
C47 C49 H49B 116.7 .
Ru1 C49 H49B 116.7 .
H49A C49 H49B 113.7 .
C47 C50 H50A 111.0 .
C47 C50 H50B 108.8 .
H50A C50 H50B 109.6 .
C47 C50 H50C 108.6 .
H50A C50 H50C 109.5 .
H50B C50 H50C 109.4 .
C56 C51 C52 171(2) 2_546
C56 C51 H51A 59.1 2_546
C52 C51 H51A 112.6 .
C56 C51 H51B 78.6 2_546
C52 C51 H51B 108.7 .
H51A C51 H51B 109.5 .
C56 C51 H51C 74.5 2_546
C52 C51 H51C 107.1 .
H51A C51 H51C 109.5 .
H51B C51 H51C 109.5 .
C51 C52 C53 108.0(16) .
C51 C52 H52A 111.4 .
C53 C52 H52A 109.2 .
C51 C52 H52B 112.8 .
C53 C52 H52B 106.7 .
H52A C52 H52B 108.6 .
C52 C53 C54 124.2(11) .
C52 C53 H53A 102.9 .
C54 C53 H53A 103.1 .
C52 C53 H53B 109.7 .
C54 C53 H53B 109.5 .
H53A C53 H53B 105.6 .
C55 C54 C53 119.3(12) .
C55 C54 H54A 103.2 .
C53 C54 H54A 104.5 .
C55 C54 H54B 109.9 .
C53 C54 H54B 111.9 .
H54A C54 H54B 106.7 .
C54 C55 C56 122.0(19) .
C54 C55 H55A 110.9 .
C56 C55 H55A 104.3 .
C54 C55 H55B 104.1 .
C56 C55 H55B 107.7 .
H55A C55 H55B 107.1 .
C51 C56 C55 164(2) 2_556
C51 C56 H56A 65.7 2_556
C55 C56 H56A 110.1 .
C51 C56 H56B 57.8 2_556
C55 C56 H56B 112.4 .
H56A C56 H56B 109.5 .
C51 C56 H56C 90.2 2_556
C55 C56 H56C 106.0 .
H56A C56 H56C 109.5 .
H56B C56 H56C 109.4 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ru1 C47 2.179(3) .
Ru1 C43 2.180(4) .
Ru1 C49 2.213(4) .
Ru1 C45 2.222(3) .
Ru1 P1 2.2227(11) .
Ru1 C44 2.247(3) .
Ru1 C48 2.261(3) .
Ru1 P2 2.3095(10) .
P1 O2 1.613(2) .
P1 O3 1.640(2) .
P1 O1 1.649(2) .
P2 C31 1.822(4) .
P2 C26 1.829(4) .
P2 C37B 1.852(3) .
P2 C37A 1.859(2) .
O1 C1 1.389(4) .
O2 C4 1.418(4) .
O3 C25 1.382(4) .
C1 C12 1.399(5) .
C1 C2 1.403(4) .
C2 C9 1.408(5) .
C2 C3 1.490(5) .
C3 C4 1.398(5) .
C3 C8 1.405(5) .
C4 C5 1.389(5) .
C5 C6 1.390(5) .
C5 C13 1.536(5) .
C6 C7 1.383(5) .
C6 H6 0.9500 .
C7 C8 1.396(6) .
C7 C17 1.511(5) .
C8 C18 1.508(5) .
C9 C10 1.397(6) .
C9 C19 1.503(5) .
C10 C11 1.383(6) .
C10 C20 1.488(5) .
C11 C12 1.396(5) .
C11 H11 0.9500 .
C12 C21 1.542(5) .
C13 C15 1.467(6) .
C13 C16 1.469(8) .
C13 C14 1.540(7) .
C14 H14A 0.9776 .
C14 H14B 0.9795 .
C14 H14C 0.9791 .
C15 H15A 0.9772 .
C15 H15B 0.9779 .
C15 H15C 0.9786 .
C16 H16A 0.9776 .
C16 H16B 0.9790 .
C16 H16C 0.9784 .
C17 H17A 0.9791 .
C17 H17B 0.9778 .
C17 H17C 0.9773 .
C18 H18A 0.9783 .
C18 H18B 0.9794 .
C18 H18C 0.9774 .
C19 H19A 0.9773 .
C19 H19B 0.9778 .
C19 H19C 0.9791 .
C20 H20A 0.9797 .
C20 H20B 0.9782 .
C20 H20C 0.9772 .
C21 C23 1.528(5) .
C21 C24 1.535(5) .
C21 C22 1.546(5) .
C22 H22A 0.9778 .
C22 H22B 0.9794 .
C22 H22C 0.9779 .
C23 H23A 0.9778 .
C23 H23B 0.9779 .
C23 H23C 0.9787 .
C24 H24A 0.9778 .
C24 H24B 0.9792 .
C24 H24C 0.9786 .
C25 C30 1.390(5) .
C25 C26 1.393(5) .
C26 C27 1.396(5) .
C27 C28 1.376(7) .
C27 H27 0.9500 .
C28 C29 1.382(7) .
C28 H28 0.9484 .
C29 C30 1.381(6) .
C29 H29 0.9476 .
C30 H30 0.9500 .
C31 C32 1.372(8) .
C31 C36 1.412(7) .
C32 C33 1.401(7) .
C32 H32 0.9483 .
C33 C34 1.368(10) .
C33 H33 0.9476 .
C34 C35 1.336(11) .
C34 H34 0.9478 .
C35 C36 1.410(9) .
C35 H35 0.9482 .
C36 H36 0.9476 .
C37A C38A 1.3900 .
C37A C42A 1.3900 .
C38A C39A 1.3900 .
C38A H38A 0.9500 .
C39A C40A 1.3900 .
C39A H39A 0.9500 .
C40A C41A 1.3900 .
C40A H40A 0.9500 .
C41A C42A 1.3900 .
C41A H41A 0.9500 .
C42A H42A 0.9500 .
C37B C42B 1.3877 .
C37B C38B 1.3877 .
C38B C39B 1.3900 .
C38B H38B 0.9500 .
C39B C40B 1.3877 .
C39B H39B 0.9500 .
C40B C41B 1.3877 .
C40B H40B 0.9500 .
C41B C42B 1.3900 .
C41B H41B 0.9500 .
C42B H42B 0.9500 .
C43 C45 1.416(5) .
C43 C44 1.418(5) .
C43 C46 1.502(5) .
C44 H44A 0.9900 .
C44 H44B 0.9900 .
C45 H45A 0.9900 .
C45 H45B 0.9900 .
C46 H46A 0.9794 .
C46 H46B 0.9772 .
C46 H46C 0.9778 .
C47 C48 1.423(5) .
C47 C49 1.430(5) .
C47 C50 1.504(5) .
C48 H48A 0.9900 .
C48 H48B 0.9900 .
C49 H49A 0.9900 .
C49 H49B 0.9900 .
C50 H50A 0.9799 .
C50 H50B 0.9785 .
C50 H50C 0.9773 .
C51 C56 1.24(3) 2_546
C51 C52 1.439(15) .
C51 H51A 0.9799 .
C51 H51B 0.9777 .
C51 H51C 0.9778 .
C52 C53 1.533(16) .
C52 H52A 0.9878 .
C52 H52B 0.9894 .
C53 C54 1.534(15) .
C53 H53A 0.9878 .
C53 H53B 0.9885 .
C54 C55 1.463(16) .
C54 H54A 0.9877 .
C54 H54B 0.9884 .
C55 C56 1.488(17) .
C55 H55A 0.9883 .
C55 H55B 0.9877 .
C56 C51 1.24(3) 2_556
C56 H56A 0.9776 .
C56 H56B 0.9782 .
C56 H56C 0.9783 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_4
C47 Ru1 P1 O2 0.19(16) .
C43 Ru1 P1 O2 -120.41(14) .
C49 Ru1 P1 O2 19.94(15) .
C45 Ru1 P1 O2 -155.32(13) .
C44 Ru1 P1 O2 -89.74(15) .
C48 Ru1 P1 O2 29.9(3) .
P2 Ru1 P1 O2 114.92(10) .
C47 Ru1 P1 O3 -113.80(16) .
C43 Ru1 P1 O3 125.60(14) .
C49 Ru1 P1 O3 -94.06(15) .
C45 Ru1 P1 O3 90.68(13) .
C44 Ru1 P1 O3 156.27(15) .
C48 Ru1 P1 O3 -84.1(3) .
P2 Ru1 P1 O3 0.93(10) .
C47 Ru1 P1 O1 131.03(16) .
C43 Ru1 P1 O1 10.43(15) .
C49 Ru1 P1 O1 150.78(15) .
C45 Ru1 P1 O1 -24.48(14) .
C44 Ru1 P1 O1 41.10(15) .
C48 Ru1 P1 O1 160.8(3) .
P2 Ru1 P1 O1 -114.24(11) .
C47 Ru1 P2 C31 46.6(2) .
C43 Ru1 P2 C31 167.8(2) .
C49 Ru1 P2 C31 11.0(2) .
C45 Ru1 P2 C31 -173.17(19) .
P1 Ru1 P2 C31 -79.67(17) .
C44 Ru1 P2 C31 -161.6(3) .
C48 Ru1 P2 C31 77.31(19) .
C47 Ru1 P2 C26 166.97(16) .
C43 Ru1 P2 C26 -71.85(16) .
C49 Ru1 P2 C26 131.32(15) .
C45 Ru1 P2 C26 -52.79(14) .
P1 Ru1 P2 C26 40.70(12) .
C44 Ru1 P2 C26 -41.3(3) .
C48 Ru1 P2 C26 -162.31(15) .
C47 Ru1 P2 C37B -68.0(3) .
C43 Ru1 P2 C37B 53.2(3) .
C49 Ru1 P2 C37B -103.6(3) .
C45 Ru1 P2 C37B 72.2(3) .
P1 Ru1 P2 C37B 165.7(2) .
C44 Ru1 P2 C37B 83.8(3) .
C48 Ru1 P2 C37B -37.3(3) .
C47 Ru1 P2 C37A -81.1(3) .
C43 Ru1 P2 C37A 40.1(3) .
C49 Ru1 P2 C37A -116.7(3) .
C45 Ru1 P2 C37A 59.2(3) .
P1 Ru1 P2 C37A 152.7(3) .
C44 Ru1 P2 C37A 70.7(3) .
C48 Ru1 P2 C37A -50.4(3) .
O2 P1 O1 C1 47.9(3) .
O3 P1 O1 C1 147.4(2) .
Ru1 P1 O1 C1 -87.9(2) .
O3 P1 O2 C4 -52.0(3) .
O1 P1 O2 C4 43.8(3) .
Ru1 P1 O2 C4 -175.1(2) .
O2 P1 O3 C25 177.0(2) .
O1 P1 O3 C25 73.6(2) .
Ru1 P1 O3 C25 -59.2(3) .
P1 O1 C1 C12 122.3(3) .
P1 O1 C1 C2 -61.7(3) .
O1 C1 C2 C9 167.1(3) .
C12 C1 C2 C9 -16.9(4) .
O1 C1 C2 C3 -19.0(4) .
C12 C1 C2 C3 157.0(3) .
C1 C2 C3 C4 65.3(4) .
C9 C2 C3 C4 -120.9(3) .
C1 C2 C3 C8 -113.5(3) .
C9 C2 C3 C8 60.3(4) .
C8 C3 C4 C5 -9.3(5) .
C2 C3 C4 C5 171.8(3) .
C8 C3 C4 O2 174.3(3) .
C2 C3 C4 O2 -4.6(4) .
P1 O2 C4 C5 112.6(3) .
P1 O2 C4 C3 -70.9(3) .
C3 C4 C5 C6 8.8(5) .
O2 C4 C5 C6 -175.0(3) .
C3 C4 C5 C13 -166.7(3) .
O2 C4 C5 C13 9.6(5) .
C4 C5 C6 C7 -3.2(5) .
C13 C5 C6 C7 172.5(3) .
C5 C6 C7 C8 -1.8(5) .
C5 C6 C7 C17 179.4(3) .
C6 C7 C8 C3 1.5(5) .
C17 C7 C8 C3 -179.7(3) .
C6 C7 C8 C18 -179.5(3) .
C17 C7 C8 C18 -0.7(5) .
C4 C3 C8 C7 3.7(5) .
C2 C3 C8 C7 -177.4(3) .
C4 C3 C8 C18 -175.3(3) .
C2 C3 C8 C18 3.6(5) .
C1 C2 C9 C10 3.6(5) .
C3 C2 C9 C10 -170.2(3) .
C1 C2 C9 C19 -177.7(3) .
C3 C2 C9 C19 8.6(5) .
C2 C9 C10 C11 7.5(5) .
C19 C9 C10 C11 -171.3(3) .
C2 C9 C10 C20 -178.2(3) .
C19 C9 C10 C20 3.0(5) .
C9 C10 C11 C12 -6.5(5) .
C20 C10 C11 C12 179.1(4) .
C10 C11 C12 C1 -5.8(5) .
C10 C11 C12 C21 168.2(3) .
O1 C1 C12 C11 -166.8(3) .
C2 C1 C12 C11 17.4(4) .
O1 C1 C12 C21 19.9(5) .
C2 C1 C12 C21 -155.9(3) .
C4 C5 C13 C15 -63.1(5) .
C6 C5 C13 C15 121.6(4) .
C4 C5 C13 C16 163.4(7) .
C6 C5 C13 C16 -11.8(8) .
C4 C5 C13 C14 59.1(5) .
C6 C5 C13 C14 -116.1(4) .
C11 C12 C21 C23 73.6(4) .
C1 C12 C21 C23 -113.3(4) .
C11 C12 C21 C24 -160.4(3) .
C1 C12 C21 C24 12.6(5) .
C11 C12 C21 C22 -44.3(4) .
C1 C12 C21 C22 128.8(3) .
P1 O3 C25 C30 -109.9(3) .
P1 O3 C25 C26 71.1(4) .
O3 C25 C26 C27 177.1(3) .
C30 C25 C26 C27 -1.9(6) .
O3 C25 C26 P2 -8.7(5) .
C30 C25 C26 P2 172.2(3) .
C31 P2 C26 C25 82.6(3) .
C37B P2 C26 C25 -179.4(3) .
C37A P2 C26 C25 -174.1(3) .
Ru1 P2 C26 C25 -48.0(3) .
C31 P2 C26 C27 -103.7(4) .
C37B P2 C26 C27 -5.7(4) .
C37A P2 C26 C27 -0.4(4) .
Ru1 P2 C26 C27 125.7(4) .
C25 C26 C27 C28 -0.3(6) .
P2 C26 C27 C28 -174.1(4) .
C26 C27 C28 C29 0.7(7) .
C27 C28 C29 C30 1.2(7) .
C28 C29 C30 C25 -3.3(6) .
O3 C25 C30 C29 -175.3(3) .
C26 C25 C30 C29 3.8(6) .
C26 P2 C31 C32 173.1(3) .
C37B P2 C31 C32 63.7(4) .
C37A P2 C31 C32 72.1(4) .
Ru1 P2 C31 C32 -63.8(4) .
C26 P2 C31 C36 -7.4(4) .
C37B P2 C31 C36 -116.9(4) .
C37A P2 C31 C36 -108.4(4) .
Ru1 P2 C31 C36 115.7(4) .
C36 C31 C32 C33 -1.8(7) .
P2 C31 C32 C33 177.7(4) .
C31 C32 C33 C34 0.9(8) .
C32 C33 C34 C35 -0.6(9) .
C33 C34 C35 C36 1.2(9) .
C34 C35 C36 C31 -2.1(8) .
C32 C31 C36 C35 2.2(7) .
P2 C31 C36 C35 -177.2(4) .
C31 P2 C37A C38A -151.4(3) .
C26 P2 C37A C38A 103.0(3) .
C37B P2 C37A C38A -103.36(19) .
Ru1 P2 C37A C38A -14.9(4) .
C31 P2 C37A C42A 34.4(3) .
C26 P2 C37A C42A -71.2(3) .
C37B P2 C37A C42A 82.37(18) .
Ru1 P2 C37A C42A 170.8(2) .
C42A C37A C38A C39A 0.0 .
P2 C37A C38A C39A -174.2(4) .
C37A C38A C39A C40A 0.0 .
C38A C39A C40A C41A 0.0 .
C39A C40A C41A C42A 0.0 .
C40A C41A C42A C37A 0.0 .
C38A C37A C42A C41A 0.0 .
P2 C37A C42A C41A 174.4(4) .
C31 P2 C37B C42B 30.5(3) .
C26 P2 C37B C42B -75.0(3) .
C37A P2 C37B C42B -102.5(2) .
Ru1 P2 C37B C42B 159.3(2) .
C31 P2 C37B C38B -160.6(3) .
C26 P2 C37B C38B 93.9(3) .
C37A P2 C37B C38B 66.30(15) .
Ru1 P2 C37B C38B -31.8(4) .
C42B C37B C38B C39B 0.0 .
P2 C37B C38B C39B -169.3(3) .
C37B C38B C39B C40B 0.0 .
C38B C39B C40B C41B 0.0 .
C39B C40B C41B C42B 0.0 .
C38B C37B C42B C41B 0.0 .
P2 C37B C42B C41B 168.4(4) .
C40B C41B C42B C37B 0.0 .
C47 Ru1 C43 C45 157.3(2) .
C49 Ru1 C43 C45 177.8(2) .
P1 Ru1 C43 C45 -69.7(2) .
C44 Ru1 C43 C45 -126.9(3) .
C48 Ru1 C43 C45 121.5(2) .
P2 Ru1 C43 C45 32.4(2) .
C47 Ru1 C43 C44 -75.8(2) .
C49 Ru1 C43 C44 -55.3(3) .
C45 Ru1 C43 C44 126.9(3) .
P1 Ru1 C43 C44 57.1(2) .
C48 Ru1 C43 C44 -111.7(2) .
P2 Ru1 C43 C44 159.3(2) .
C47 Ru1 C43 C46 41.9(3) .
C49 Ru1 C43 C46 62.4(4) .
C45 Ru1 C43 C46 -115.4(4) .
P1 Ru1 C43 C46 174.8(3) .
C44 Ru1 C43 C46 117.7(4) .
C48 Ru1 C43 C46 6.0(3) .
P2 Ru1 C43 C46 -83.0(3) .
C45 C43 C44 Ru1 59.9(3) .
C46 C43 C44 Ru1 -119.6(3) .
C47 Ru1 C44 C43 108.8(2) .
C49 Ru1 C44 C43 142.9(2) .
C45 Ru1 C44 C43 -32.3(2) .
P1 Ru1 C44 C43 -127.4(2) .
C48 Ru1 C44 C43 73.2(2) .
P2 Ru1 C44 C43 -44.9(4) .
C44 C43 C45 Ru1 -60.5(3) .
C46 C43 C45 Ru1 119.0(3) .
C47 Ru1 C45 C43 -32.9(3) .
P1 Ru1 C45 C43 117.38(18) .
C44 Ru1 C45 C43 32.1(2) .
C48 Ru1 C45 C43 -64.8(2) .
P2 Ru1 C45 C43 -153.18(19) .
C43 Ru1 C47 C48 -75.1(2) .
C49 Ru1 C47 C48 128.0(3) .
C45 Ru1 C47 C48 -55.3(3) .
P1 Ru1 C47 C48 161.28(19) .
C44 Ru1 C47 C48 -111.1(2) .
P2 Ru1 C47 C48 57.4(2) .
C43 Ru1 C47 C49 156.9(2) .
C45 Ru1 C47 C49 176.7(2) .
P1 Ru1 C47 C49 33.3(3) .
C44 Ru1 C47 C49 120.9(2) .
C48 Ru1 C47 C49 -128.0(3) .
P2 Ru1 C47 C49 -70.6(2) .
C43 Ru1 C47 C50 42.5(3) .
C49 Ru1 C47 C50 -114.4(4) .
C45 Ru1 C47 C50 62.3(4) .
P1 Ru1 C47 C50 -81.1(3) .
C44 Ru1 C47 C50 6.5(3) .
C48 Ru1 C47 C50 117.6(4) .
P2 Ru1 C47 C50 175.0(3) .
C49 C47 C48 Ru1 59.1(3) .
C50 C47 C48 Ru1 -118.1(3) .
C43 Ru1 C48 C47 109.3(2) .
C49 Ru1 C48 C47 -31.9(2) .
C45 Ru1 C48 C47 142.8(2) .
P1 Ru1 C48 C47 -42.8(4) .
C44 Ru1 C48 C47 73.8(3) .
P2 Ru1 C48 C47 -128.0(2) .
C48 C47 C49 Ru1 -60.2(3) .
C50 C47 C49 Ru1 117.0(3) .
C43 Ru1 C49 C47 -33.7(3) .
P1 Ru1 C49 C47 -152.9(2) .
C44 Ru1 C49 C47 -65.7(2) .
C48 Ru1 C49 C47 31.4(2) .
P2 Ru1 C49 C47 117.6(2) .
C51 C52 C53 C54 -60.1(18) .
C52 C53 C54 C55 169.3(14) .
C53 C54 C55 C56 175.1(18) .
C54 C55 C56 C51 -142(10) 2_556
