#------------------------------------------------------------------------------
#$Date: 2016-02-16 22:30:59 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176467 $
#$URL: svn://www.crystallography.net/cod/cif/4/07/82/4078227.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4078227
loop_
_publ_author_name
'Guo, Jia-Yi'
'Li, Yongxin'
'Ganguly, Rakesh'
'So, Cheuk-Wai'
_publ_section_title
;
 Reactivity of a Tin(II) (Iminophosphinoyl)(thiophosphinoyl)methanediide
 Complex toward Isocyanates and Rhodium(I) Chloride
;
_journal_issue                   10
_journal_name_full               Organometallics
_journal_page_first              3888
_journal_paper_doi               10.1021/om300062n
_journal_volume                  31
_journal_year                    2012
_chemical_formula_moiety         'C36 H44 Cl N P2 Rh S Si Sn, 1.5(C H2 Cl2)'
_chemical_formula_sum            'C37.5 H47 Cl4 N P2 Rh S Si Sn'
_chemical_formula_weight         997.25
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 97.5720(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   11.7899(2)
_cell_length_b                   16.7568(3)
_cell_length_c                   20.4015(3)
_cell_measurement_reflns_used    9783
_cell_measurement_temperature    103(2)
_cell_measurement_theta_max      34.94
_cell_measurement_theta_min      2.25
_cell_volume                     3995.39(12)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      103(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0393
_diffrn_reflns_av_sigmaI/netI    0.0379
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       27
_diffrn_reflns_limit_k_min       -27
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_limit_l_min       -32
_diffrn_reflns_number            74292
_diffrn_reflns_theta_full        35.11
_diffrn_reflns_theta_max         35.11
_diffrn_reflns_theta_min         1.58
_exptl_absorpt_coefficient_mu    1.497
_exptl_absorpt_correction_T_max  0.6622
_exptl_absorpt_correction_T_min  0.5858
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            brown
_exptl_crystal_density_diffrn    1.658
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2008
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.34
_exptl_crystal_size_min          0.30
_refine_diff_density_max         1.436
_refine_diff_density_min         -1.100
_refine_diff_density_rms         0.121
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.045
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     457
_refine_ls_number_reflns         17658
_refine_ls_number_restraints     3
_refine_ls_restrained_S_all      1.049
_refine_ls_R_factor_all          0.0412
_refine_ls_R_factor_gt           0.0290
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0270P)²+2.8452P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0657
_refine_ls_wR_factor_ref         0.0704
_reflns_number_gt                14406
_reflns_number_total             17658
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om300062n_si_001.cif
_cod_data_source_block           scw201s
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_cell_volume        3995.39(11)
_cod_original_sg_symbol_H-M      P2(1)/n
_cod_original_formula_sum        'C37.50 H47 Cl4 N P2 Rh S Si Sn'
_cod_database_code               4078227
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_group
Rh1 Rh 0.462734(10) 0.565116(7) 0.148613(6) 0.00897(3) Uani 1 1 d . .
Sn1 Sn 0.371963(9) 0.613446(6) 0.263212(5) 0.01005(3) Uani 1 1 d . .
C1 C 0.45166(12) 0.68756(9) 0.18204(7) 0.0094(2) Uani 1 1 d . .
C2 C 0.45250(13) 0.73974(10) 0.04204(8) 0.0116(3) Uani 1 1 d . .
C3 C 0.55438(14) 0.69886(11) 0.03663(8) 0.0141(3) Uani 1 1 d . .
H3 H 0.5817 0.6602 0.0690 0.017 Uiso 1 1 calc R .
C4 C 0.61578(15) 0.71423(11) -0.01546(9) 0.0173(3) Uani 1 1 d . .
H4 H 0.6857 0.6870 -0.0179 0.021 Uiso 1 1 calc R .
C5 C 0.57593(16) 0.76903(12) -0.06394(9) 0.0196(3) Uani 1 1 d . .
H5 H 0.6179 0.7792 -0.0997 0.024 Uiso 1 1 calc R .
C6 C 0.47385(16) 0.80900(12) -0.05961(9) 0.0190(3) Uani 1 1 d . .
H6 H 0.4457 0.8464 -0.0928 0.023 Uiso 1 1 calc R .
C7 C 0.41250(15) 0.79464(11) -0.00700(8) 0.0151(3) Uani 1 1 d . .
H7 H 0.3430 0.8224 -0.0045 0.018 Uiso 1 1 calc R .
C8 C 0.27321(13) 0.79820(10) 0.11055(8) 0.0110(3) Uani 1 1 d . .
C9 C 0.31539(14) 0.87602(10) 0.11711(8) 0.0140(3) Uani 1 1 d . .
H9 H 0.3952 0.8854 0.1188 0.017 Uiso 1 1 calc R .
C10 C 0.24140(15) 0.93972(11) 0.12123(9) 0.0171(3) Uani 1 1 d . .
H10 H 0.2705 0.9925 0.1264 0.020 Uiso 1 1 calc R .
C11 C 0.12454(16) 0.92579(12) 0.11771(9) 0.0193(3) Uani 1 1 d . .
H11 H 0.0735 0.9693 0.1200 0.023 Uiso 1 1 calc R .
C12 C 0.08238(15) 0.84894(12) 0.11087(9) 0.0186(3) Uani 1 1 d . .
H12 H 0.0024 0.8399 0.1083 0.022 Uiso 1 1 calc R .
C13 C 0.15603(14) 0.78492(11) 0.10767(9) 0.0154(3) Uani 1 1 d . .
H13 H 0.1266 0.7321 0.1035 0.018 Uiso 1 1 calc R .
C14 C 0.50906(13) 0.84462(9) 0.25035(8) 0.0107(3) Uani 1 1 d . .
C15 C 0.58944(14) 0.90391(10) 0.24249(9) 0.0148(3) Uani 1 1 d . .
H15 H 0.6609 0.8898 0.2290 0.018 Uiso 1 1 calc R .
C16 C 0.56549(15) 0.98342(11) 0.25428(10) 0.0196(3) Uani 1 1 d . .
H16 H 0.6206 1.0233 0.2488 0.023 Uiso 1 1 calc R .
C17 C 0.46160(16) 1.00487(11) 0.27408(10) 0.0196(3) Uani 1 1 d . .
H17 H 0.4453 1.0593 0.2820 0.024 Uiso 1 1 calc R .
C18 C 0.38161(16) 0.94603(11) 0.28229(10) 0.0183(3) Uani 1 1 d . .
H18 H 0.3105 0.9604 0.2961 0.022 Uiso 1 1 calc R .
C19 C 0.40463(14) 0.86644(10) 0.27056(9) 0.0146(3) Uani 1 1 d . .
H19 H 0.3493 0.8267 0.2763 0.018 Uiso 1 1 calc R .
C20 C 0.68711(13) 0.73472(9) 0.22895(8) 0.0105(3) Uani 1 1 d . .
C21 C 0.71424(13) 0.76023(10) 0.16758(8) 0.0128(3) Uani 1 1 d . .
H21 H 0.6571 0.7847 0.1369 0.015 Uiso 1 1 calc R .
C22 C 0.82362(14) 0.75014(11) 0.15113(9) 0.0162(3) Uani 1 1 d . .
H22 H 0.8405 0.7658 0.1087 0.019 Uiso 1 1 calc R .
C23 C 0.90881(14) 0.71696(11) 0.19679(9) 0.0166(3) Uani 1 1 d . .
H23 H 0.9840 0.7105 0.1857 0.020 Uiso 1 1 calc R .
C24 C 0.88371(13) 0.69343(11) 0.25835(9) 0.0148(3) Uani 1 1 d . .
H24 H 0.9423 0.6719 0.2898 0.018 Uiso 1 1 calc R .
C25 C 0.77296(13) 0.70121(10) 0.27437(8) 0.0125(3) Uani 1 1 d . .
H25 H 0.7558 0.6837 0.3162 0.015 Uiso 1 1 calc R .
C26 C 0.41307(17) 0.73610(16) 0.42741(10) 0.0284(5) Uani 1 1 d . .
H26A H 0.3801 0.7858 0.4080 0.043 Uiso 1 1 calc R .
H26B H 0.4299 0.7421 0.4755 0.043 Uiso 1 1 calc R .
H26C H 0.3584 0.6924 0.4171 0.043 Uiso 1 1 calc R .
C27 C 0.64672(16) 0.79945(11) 0.40884(9) 0.0197(3) Uani 1 1 d . .
H27A H 0.7166 0.7894 0.3889 0.030 Uiso 1 1 calc R .
H27B H 0.6663 0.8065 0.4567 0.030 Uiso 1 1 calc R .
H27C H 0.6094 0.8479 0.3896 0.030 Uiso 1 1 calc R .
C28 C 0.61410(18) 0.62070(12) 0.43140(9) 0.0223(4) Uani 1 1 d . .
H28A H 0.5611 0.5758 0.4220 0.033 Uiso 1 1 calc R .
H28B H 0.6306 0.6284 0.4793 0.033 Uiso 1 1 calc R .
H28C H 0.6854 0.6093 0.4133 0.033 Uiso 1 1 calc R .
C29 C 0.64417(13) 0.54413(10) 0.16612(8) 0.0129(3) Uani 1 1 d . .
H29 H 0.6908 0.5938 0.1750 0.015 Uiso 1 1 calc R .
C30 C 0.59615(13) 0.51602(10) 0.22116(8) 0.0133(3) Uani 1 1 d . .
H30 H 0.6144 0.5496 0.2617 0.016 Uiso 1 1 calc R .
C31 C 0.57542(15) 0.42846(11) 0.23527(9) 0.0165(3) Uani 1 1 d . .
H31A H 0.5837 0.4204 0.2837 0.020 Uiso 1 1 calc R .
H31B H 0.6347 0.3959 0.2177 0.020 Uiso 1 1 calc R .
C32 C 0.45628(15) 0.39864(11) 0.20470(9) 0.0172(3) Uani 1 1 d . .
H32A H 0.4611 0.3409 0.1952 0.021 Uiso 1 1 calc R .
H32B H 0.4021 0.4055 0.2374 0.021 Uiso 1 1 calc R .
C33 C 0.40976(14) 0.44162(10) 0.14179(9) 0.0140(3) Uani 1 1 d . .
H33 H 0.3258 0.4339 0.1282 0.017 Uiso 1 1 calc R .
C34 C 0.47115(14) 0.45739(10) 0.08953(9) 0.0146(3) Uani 1 1 d . .
H34 H 0.4231 0.4595 0.0454 0.018 Uiso 1 1 calc R .
C35 C 0.59249(15) 0.42816(11) 0.08722(9) 0.0169(3) Uani 1 1 d . .
H35A H 0.6017 0.4131 0.0413 0.020 Uiso 1 1 calc R .
H35B H 0.6068 0.3801 0.1154 0.020 Uiso 1 1 calc R .
C36 C 0.67997(14) 0.49311(11) 0.11151(9) 0.0158(3) Uani 1 1 d . .
H36A H 0.7540 0.4674 0.1275 0.019 Uiso 1 1 calc R .
H36B H 0.6918 0.5279 0.0738 0.019 Uiso 1 1 calc R .
C37 C 0.6681(2) 0.96737(14) 0.01506(11) 0.0304(5) Uani 1 1 d . .
H37A H 0.6129 0.9394 -0.0179 0.036 Uiso 1 1 calc R .
H37B H 0.6781 1.0222 -0.0012 0.036 Uiso 1 1 calc R .
C38 C 0.481(2) 1.0064(10) 0.5401(6) 0.059(4) Uani 0.27 1 d PD 1
Cl4 Cl 0.4251(3) 0.9272(2) 0.5034(3) 0.1310(17) Uani 0.54 1 d PD 1
C38A C 0.479(2) 1.0288(10) 0.5168(8) 0.059(4) Uani 0.23 1 d PD 2
Cl4A Cl 0.4412(4) 0.9404(4) 0.5368(2) 0.149(3) Uani 0.46 1 d PD 2
Cl1 Cl 0.20212(3) 0.70383(3) 0.27064(2) 0.01680(8) Uani 1 1 d . .
Cl2 Cl 0.79997(6) 0.91738(4) 0.02264(4) 0.04182(14) Uani 1 1 d . .
Cl3 Cl 0.61249(6) 0.97192(4) 0.09101(3) 0.04103(14) Uani 1 1 d . .
N1 N 0.51511(11) 0.69306(8) 0.30875(7) 0.0105(2) Uani 1 1 d . .
P1 P 0.37040(3) 0.71464(2) 0.10898(2) 0.00905(7) Uani 1 1 d . .
P2 P 0.53910(3) 0.73917(2) 0.24295(2) 0.00858(7) Uani 1 1 d . .
S1 S 0.28792(3) 0.61030(2) 0.08592(2) 0.01191(7) Uani 1 1 d . .
Si1 Si 0.54782(4) 0.71316(3) 0.39243(2) 0.01221(8) Uani 1 1 d . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn -0.6537 1.4246 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C29 Rh1 C33 97.29(6) . .
C29 Rh1 C1 101.65(6) . .
C33 Rh1 C1 153.67(6) . .
C29 Rh1 C30 37.87(6) . .
C33 Rh1 C30 81.87(6) . .
C1 Rh1 C30 102.22(6) . .
C29 Rh1 C34 80.78(6) . .
C33 Rh1 C34 37.37(7) . .
C1 Rh1 C34 164.80(6) . .
C30 Rh1 C34 88.94(6) . .
C29 Rh1 S1 154.88(5) . .
C33 Rh1 S1 92.70(4) . .
C1 Rh1 S1 77.67(4) . .
C30 Rh1 S1 167.24(5) . .
C34 Rh1 S1 93.73(5) . .
C29 Rh1 P1 122.21(5) . .
C33 Rh1 P1 137.58(4) . .
C1 Rh1 P1 37.84(4) . .
C30 Rh1 P1 138.75(5) . .
C34 Rh1 P1 128.59(5) . .
S1 Rh1 P1 44.931(13) . .
C29 Rh1 Sn1 112.81(5) . .
C33 Rh1 Sn1 100.99(5) . .
C1 Rh1 Sn1 54.71(4) . .
C30 Rh1 Sn1 82.16(5) . .
C34 Rh1 Sn1 138.36(5) . .
S1 Rh1 Sn1 87.598(11) . .
P1 Rh1 Sn1 78.879(9) . .
N1 Sn1 C1 68.42(5) . .
N1 Sn1 Cl1 100.17(4) . .
C1 Sn1 Cl1 96.79(4) . .
N1 Sn1 Rh1 99.59(4) . .
C1 Sn1 Rh1 48.63(4) . .
Cl1 Sn1 Rh1 127.741(11) . .
N1 Sn1 P2 32.58(4) . .
C1 Sn1 P2 36.06(4) . .
Cl1 Sn1 P2 97.433(13) . .
Rh1 Sn1 P2 75.824(9) . .
P1 C1 P2 134.23(10) . .
P1 C1 Rh1 91.53(7) . .
P2 C1 Rh1 129.83(8) . .
P1 C1 Sn1 121.19(7) . .
P2 C1 Sn1 90.79(6) . .
Rh1 C1 Sn1 76.66(5) . .
C7 C2 C3 118.61(15) . .
C7 C2 P1 121.77(13) . .
C3 C2 P1 119.46(12) . .
C4 C3 C2 120.64(16) . .
C4 C3 H3 119.7 . .
C2 C3 H3 119.7 . .
C5 C4 C3 120.53(17) . .
C5 C4 H4 119.7 . .
C3 C4 H4 119.7 . .
C4 C5 C6 119.26(17) . .
C4 C5 H5 120.4 . .
C6 C5 H5 120.4 . .
C5 C6 C7 120.53(17) . .
C5 C6 H6 119.7 . .
C7 C6 H6 119.7 . .
C6 C7 C2 120.41(16) . .
C6 C7 H7 119.8 . .
C2 C7 H7 119.8 . .
C13 C8 C9 119.48(15) . .
C13 C8 P1 120.12(13) . .
C9 C8 P1 120.36(12) . .
C10 C9 C8 120.36(16) . .
C10 C9 H9 119.8 . .
C8 C9 H9 119.8 . .
C9 C10 C11 119.63(17) . .
C9 C10 H10 120.2 . .
C11 C10 H10 120.2 . .
C12 C11 C10 120.20(16) . .
C12 C11 H11 119.9 . .
C10 C11 H11 119.9 . .
C11 C12 C13 120.45(16) . .
C11 C12 H12 119.8 . .
C13 C12 H12 119.8 . .
C12 C13 C8 119.87(17) . .
C12 C13 H13 120.1 . .
C8 C13 H13 120.1 . .
C15 C14 C19 119.03(15) . .
C15 C14 P2 122.75(12) . .
C19 C14 P2 117.97(12) . .
C16 C15 C14 120.38(16) . .
C16 C15 H15 119.8 . .
C14 C15 H15 119.8 . .
C17 C16 C15 120.42(17) . .
C17 C16 H16 119.8 . .
C15 C16 H16 119.8 . .
C16 C17 C18 119.39(17) . .
C16 C17 H17 120.3 . .
C18 C17 H17 120.3 . .
C19 C18 C17 120.64(17) . .
C19 C18 H18 119.7 . .
C17 C18 H18 119.7 . .
C18 C19 C14 120.14(16) . .
C18 C19 H19 119.9 . .
C14 C19 H19 119.9 . .
C25 C20 C21 119.03(14) . .
C25 C20 P2 122.84(12) . .
C21 C20 P2 117.92(11) . .
C22 C21 C20 120.62(15) . .
C22 C21 H21 119.7 . .
C20 C21 H21 119.7 . .
C21 C22 C23 119.96(16) . .
C21 C22 H22 120.0 . .
C23 C22 H22 120.0 . .
C24 C23 C22 119.92(15) . .
C24 C23 H23 120.0 . .
C22 C23 H23 120.0 . .
C23 C24 C25 120.32(15) . .
C23 C24 H24 119.8 . .
C25 C24 H24 119.8 . .
C24 C25 C20 120.10(15) . .
C24 C25 H25 119.9 . .
C20 C25 H25 119.9 . .
Si1 C26 H26A 109.5 . .
Si1 C26 H26B 109.5 . .
H26A C26 H26B 109.5 . .
Si1 C26 H26C 109.5 . .
H26A C26 H26C 109.5 . .
H26B C26 H26C 109.5 . .
Si1 C27 H27A 109.5 . .
Si1 C27 H27B 109.5 . .
H27A C27 H27B 109.5 . .
Si1 C27 H27C 109.5 . .
H27A C27 H27C 109.5 . .
H27B C27 H27C 109.5 . .
Si1 C28 H28A 109.5 . .
Si1 C28 H28B 109.5 . .
H28A C28 H28B 109.5 . .
Si1 C28 H28C 109.5 . .
H28A C28 H28C 109.5 . .
H28B C28 H28C 109.5 . .
C30 C29 C36 125.62(16) . .
C30 C29 Rh1 71.97(9) . .
C36 C29 Rh1 109.81(11) . .
C30 C29 H29 113.9 . .
C36 C29 H29 113.9 . .
Rh1 C29 H29 113.9 . .
C29 C30 C31 124.53(15) . .
C29 C30 Rh1 70.16(9) . .
C31 C30 Rh1 111.96(11) . .
C29 C30 H30 114.1 . .
C31 C30 H30 114.1 . .
Rh1 C30 H30 114.1 . .
C30 C31 C32 113.34(13) . .
C30 C31 H31A 108.9 . .
C32 C31 H31A 108.9 . .
C30 C31 H31B 108.9 . .
C32 C31 H31B 108.9 . .
H31A C31 H31B 107.7 . .
C33 C32 C31 113.48(14) . .
C33 C32 H32A 108.9 . .
C31 C32 H32A 108.9 . .
C33 C32 H32B 108.9 . .
C31 C32 H32B 108.9 . .
H32A C32 H32B 107.7 . .
C34 C33 C32 125.07(15) . .
C34 C33 Rh1 72.07(10) . .
C32 C33 Rh1 109.42(11) . .
C34 C33 H33 114.1 . .
C32 C33 H33 114.1 . .
Rh1 C33 H33 114.1 . .
C33 C34 C35 123.37(16) . .
C33 C34 Rh1 70.57(10) . .
C35 C34 Rh1 113.32(11) . .
C33 C34 H34 114.0 . .
C35 C34 H34 114.0 . .
Rh1 C34 H34 114.0 . .
C34 C35 C36 110.89(14) . .
C34 C35 H35A 109.5 . .
C36 C35 H35A 109.5 . .
C34 C35 H35B 109.5 . .
C36 C35 H35B 109.5 . .
H35A C35 H35B 108.0 . .
C29 C36 C35 113.50(14) . .
C29 C36 H36A 108.9 . .
C35 C36 H36A 108.9 . .
C29 C36 H36B 108.9 . .
C35 C36 H36B 108.9 . .
H36A C36 H36B 107.7 . .
Cl2 C37 Cl3 111.80(12) . .
Cl2 C37 H37A 109.3 . .
Cl3 C37 H37A 109.3 . .
Cl2 C37 H37B 109.3 . .
Cl3 C37 H37B 109.3 . .
H37A C37 H37B 107.9 . .
Cl4 C38 C38 67.0(8) . 3_676
Cl4 C38 Cl4 119.8(7) . 3_676
C38 C38 Cl4 52.8(8) 3_676 3_676
C38 Cl4 C38 60.2(7) . 3_676
C38A C38A Cl4A 66.0(10) 3_676 3_676
C38A C38A Cl4A 66.0(9) 3_676 .
Cl4A C38A Cl4A 132.0(14) 3_676 .
C38A Cl4A C38A 48.0(14) 3_676 .
P2 N1 Si1 133.57(9) . .
P2 N1 Sn1 98.34(6) . .
Si1 N1 Sn1 125.35(7) . .
C1 P1 C8 117.96(7) . .
C1 P1 C2 114.77(7) . .
C8 P1 C2 103.55(8) . .
C1 P1 S1 99.71(6) . .
C8 P1 S1 112.68(5) . .
C2 P1 S1 108.12(6) . .
C1 P1 Rh1 50.63(5) . .
C8 P1 Rh1 155.01(5) . .
C2 P1 Rh1 101.39(5) . .
S1 P1 Rh1 56.821(15) . .
N1 P2 C1 101.84(7) . .
N1 P2 C20 113.11(7) . .
C1 P2 C20 111.16(7) . .
N1 P2 C14 109.97(7) . .
C1 P2 C14 116.17(7) . .
C20 P2 C14 104.88(7) . .
N1 P2 Sn1 49.08(5) . .
C1 P2 Sn1 53.16(5) . .
C20 P2 Sn1 132.03(5) . .
C14 P2 Sn1 122.89(5) . .
P1 S1 Rh1 78.247(17) . .
N1 Si1 C27 112.41(8) . .
N1 Si1 C28 106.55(8) . .
C27 Si1 C28 110.58(9) . .
N1 Si1 C26 109.07(8) . .
C27 Si1 C26 108.43(10) . .
C28 Si1 C26 109.77(11) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Rh1 C29 2.1508(15) .
Rh1 C33 2.1608(17) .
Rh1 C1 2.1715(16) .
Rh1 C30 2.1743(15) .
Rh1 C34 2.1800(17) .
Rh1 S1 2.4005(4) .
Rh1 P1 2.8080(4) .
Rh1 Sn1 2.81545(17) .
Sn1 N1 2.2535(13) .
Sn1 C1 2.3617(16) .
Sn1 Cl1 2.5311(4) .
Sn1 P2 2.9508(4) .
C1 P1 1.7233(15) .
C1 P2 1.7370(15) .
C2 C7 1.395(2) .
C2 C3 1.400(2) .
C2 P1 1.8241(17) .
C3 C4 1.386(2) .
C3 H3 0.9500 .
C4 C5 1.386(3) .
C4 H4 0.9500 .
C5 C6 1.390(3) .
C5 H5 0.9500 .
C6 C7 1.392(2) .
C6 H6 0.9500 .
C7 H7 0.9500 .
C8 C13 1.393(2) .
C8 C9 1.396(2) .
C8 P1 1.8122(16) .
C9 C10 1.388(2) .
C9 H9 0.9500 .
C10 C11 1.390(3) .
C10 H10 0.9500 .
C11 C12 1.381(3) .
C11 H11 0.9500 .
C12 C13 1.387(2) .
C12 H12 0.9500 .
C13 H13 0.9500 .
C14 C15 1.397(2) .
C14 C19 1.398(2) .
C14 P2 1.8124(16) .
C15 C16 1.390(2) .
C15 H15 0.9500 .
C16 C17 1.387(3) .
C16 H16 0.9500 .
C17 C18 1.390(3) .
C17 H17 0.9500 .
C18 C19 1.388(2) .
C18 H18 0.9500 .
C19 H19 0.9500 .
C20 C25 1.397(2) .
C20 C21 1.399(2) .
C20 P2 1.8065(16) .
C21 C22 1.385(2) .
C21 H21 0.9500 .
C22 C23 1.392(2) .
C22 H22 0.9500 .
C23 C24 1.385(3) .
C23 H23 0.9500 .
C24 C25 1.393(2) .
C24 H24 0.9500 .
C25 H25 0.9500 .
C26 Si1 1.865(2) .
C26 H26A 0.9800 .
C26 H26B 0.9800 .
C26 H26C 0.9800 .
C27 Si1 1.8600(18) .
C27 H27A 0.9800 .
C27 H27B 0.9800 .
C27 H27C 0.9800 .
C28 Si1 1.865(2) .
C28 H28A 0.9800 .
C28 H28B 0.9800 .
C28 H28C 0.9800 .
C29 C30 1.404(2) .
C29 C36 1.508(2) .
C29 H29 1.0000 .
C30 C31 1.521(2) .
C30 H30 1.0000 .
C31 C32 1.543(2) .
C31 H31A 0.9900 .
C31 H31B 0.9900 .
C32 C33 1.510(2) .
C32 H32A 0.9900 .
C32 H32B 0.9900 .
C33 C34 1.391(2) .
C33 H33 1.0000 .
C34 C35 1.519(2) .
C34 H34 1.0000 .
C35 C36 1.536(2) .
C35 H35A 0.9900 .
C35 H35B 0.9900 .
C36 H36A 0.9900 .
C36 H36B 0.9900 .
C37 Cl2 1.754(2) .
C37 Cl3 1.762(2) .
C37 H37A 0.9900 .
C37 H37B 0.9900 .
C38 Cl4 1.622(13) .
C38 C38 1.76(2) 3_676
C38 Cl4 1.873(16) 3_676
Cl4 C38 1.873(16) 3_676
C38A C38A 1.32(4) 3_676
C38A Cl4A 1.615(14) 3_676
C38A Cl4A 1.616(12) .
Cl4A C38A 1.615(14) 3_676
N1 P2 1.6060(14) .
N1 Si1 1.7330(14) .
P1 S1 2.0256(6) .
